Title: Synthesis and crystal structure of one Schiff base complex [Cd(H_2SalN)_2(OAc)_2(H_2O)]·3(H_2O)
Abstract: One Schiff base complex,[Cd(H2SalN)2(OAc)2(H2O)]·3(H2O)(H2SalN = salicylaldehyde isonicotinoylhydrazone),was obtained by one-pot reaction,and structurally characterized by IR and single-crystal X-ray diffraction method.The complex crystallizes in triclinic system,space group P-1 with a =1.554 4(3) nm,b = 1.556 9(3) nm,c = 1.716 3(3) nm,α = 66.972(3)°,β = 64.634(3)°,γ = 81.289(3)°,Z = 4,Dc = 1.545 g/cm3,μ = 0.705 mm-1,F(000) = 1 648,R1 = 0.075 2,wR2 = 0.191 4.In the complex,the metal center ion CdⅡ is seven coordinated by five oxygen atoms from two carboxyl groups and one water molecules,and two nitrogen atoms from two ligands H2SalN.With intramolecular and intermolecular hydrogen bonds,the 3D extended network is built up.
Publication Year: 2011
Publication Date: 2011-01-01
Language: en
Type: article
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