Title: Synthesis and Crystal Structure of Nickel Complex with Singal Schiff Base of 1,2-Diaminopropane
Abstract: The title complex Ni(HCSP)2·H2O [H2CSP=N-3-carboxylsalicylidene-1,2-diaminopropane] was synthesized in methanol at room temperture.The structure was characterized by IR and single crystal X-ray diffraction.It crystallizes in monoclinic system,space group P2(1)/c,with a = 0.975 6(2) nm,b = 1.423 6(3) nm,c = 1.740 3(4) nm,α= 90°,β = 98.951(3)°,γ = 90°,Molecular formula is C22H28NiN4O7,Mr=519.19,V =2.3878(8)nm3,Z =4,Dc = 1.430 Mg/m3,F(000) = 1 068,R1 = 0.071 9,wR2 = 0.184 4,S =0.962.The crystal is constructed with mononuclear units,in which the nickel atoms are coordinated by two phenolic oxygen atoms and four imine nitrogen atoms.
Publication Year: 2008
Publication Date: 2008-01-01
Language: en
Type: article
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