Title: Synthesis,Character and Crystal Structure of Bis(N-picolinylidene N′-salicyloylhydrazinato) nickel(II)
Abstract: The synthesis,spectral and X-ray crystal structure of the title complex are described.The crystal crystallize in monoclinic system,space group P2(1)/n with C_(26)H_(20)NiN_6O_4,cell parameters:a=1.254 9(3) nm,b=1.778 8(5) nm,c=1.329 2(4) nm;β=115.310(5)°,M_r=539.18,in the complex,the nickel(Ⅱ) ion is six coordinated by two ligand anions forming a distorted octahedron geometry,and the dimer is formed by intermolecule hydrogen bond.
Publication Year: 2006
Publication Date: 2006-01-01
Language: en
Type: article
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