Title: Indium Metal and Its Halides in Organic Synthesis
Abstract: European Journal of Organic ChemistryVolume 2000, Issue 13 p. 2347-2356 Microreview Indium Metal and Its Halides in Organic Synthesis Brindaban C. Ranu, Brindaban C. Ranu [email protected] Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta 700032, India, Fax: (internat.) + 91-33/473-2805Search for more papers by this author Brindaban C. Ranu, Brindaban C. Ranu [email protected] Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta 700032, India, Fax: (internat.) + 91-33/473-2805Search for more papers by this author First published: July 2000 https://doi.org/10.1002/1099-0690(200007)2000:13<2347::AID-EJOC2347>3.0.CO;2-XCitations: 216AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract This review highlights the applications of indium metal and indium(III) halides in organic synthesis with particular reference to regio-, stereo-, and chemoselectivity. Indium-mediated reactions include the regioselective allylation of alkynes, the stereoselective debromination of vic-aryl-substituted dibromides, the homocoupling of alkyl/aryl halides, and the reduction of α-halocarbonyl compounds. Indium trichloride has been used as a Lewis acid catalyst in epoxide rearrangements, in the synthesis of α-amino phosphonates, and in the construction of the quinoline system. Indium triiodide has proven to be a very efficient catalyst for transesterification processes. References [1]H. Gilman, R. G. Jones, J. Am. Chem. Soc. 1940, 62, 2353−2357. Google Scholar [2]Reviews: Google Scholar [2a]P. Cintas, Synlett 1995, 1087−1096. − Google Scholar [2b]C.-J. Li, T.-H. Chan, Tetrahedron 1999, 55, 11149−11176. 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Publication Year: 2000
Publication Date: 2000-07-01
Language: en
Type: article
Indexed In: ['crossref']
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