Title: Remote substituent effects on regioselectivity in the Pauson–Khand reaction of 2-substituted norbornenes
Abstract: The effect of a remote substituent on the regioselectivity in the Pauson–Khand reaction of 2-substituted norbornenes has been investigated. Moderate level of regioselectivity was observed and the regioselectivity increases as the electron-withdrawing power of the remote substituent increases. exo Substituents at C-2 of norbornenes generally gave a higher regioselectivity than the endo substituents.
Publication Year: 2001
Publication Date: 2001-07-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 19
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