Chelation-Assisted Reactions of Phosphine- and Olefin-Tethered Imidazolium Derivatives and Their Affiliated N-Heterocyclic Carbenes with Roper’s Complex Ru(CO)2(PPh3)3

Name: Work Video:
Duration: 3 min 30 s
Laure Benhamou; J. G. Wolf; Vincent César; Agnès Labande; Rinaldo Poli; Noël Lugan; Guy Lavigne
{'id': 'https://openalex.org/W1986765652', 'doi': 'https://doi.org/10.1021/om900813p', 'title': 'Chelation-Assisted Reactions of Phosphine- and Olefin-Tethered Imidazolium Derivatives and Their Affiliated N-Heterocyclic Carbenes with Roper’s Complex Ru(CO)<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>', 'display_name': 'Chelation-Assisted Reactions of Phosphine- and Olefin-Tethered Imidazolium Derivatives and Their Affiliated N-Heterocyclic Carbenes with Roper’s Complex Ru(CO)<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>', 'publication_year': 2009, 'publication_date': '2009-11-06', 'ids': {'openalex': 'https://openalex.org/W1986765652', 'doi': 'https://doi.org/10.1021/om900813p', 'mag': '1986765652'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om900813p', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': True, 'oa_status': 'green', 'oa_url': 'https://hal.science/hal-03178363/document', 'any_repository_has_fulltext': True}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5061374437', 'display_name': 'Laure Benhamou', 'orcid': 'https://orcid.org/0000-0003-0419-7739'}, 'institutions': [{'id': 'https://openalex.org/I17866349', 'display_name': 'Université de Toulouse', 'ror': 'https://ror.org/004raaa70', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I17866349']}, {'id': 'https://openalex.org/I205747304', 'display_name': 'Institut National Polytechnique de Toulouse', 'ror': 'https://ror.org/033p9g875', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I205747304']}, {'id': 'https://openalex.org/I134560555', 'display_name': 'Université Toulouse III - Paul Sabatier', 'ror': 'https://ror.org/02v6kpv12', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I134560555']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}, {'id': 'https://openalex.org/I4210119060', 'display_name': 'Laboratoire de Chimie de Coordination', 'ror': 'https://ror.org/01rtzw447', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I4210119060', 'https://openalex.org/I4210128300']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Laure Benhamou', 'raw_affiliation_strings': ['LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France'], 'affiliations': [{'raw_affiliation_string': 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France', 'institution_ids': ['https://openalex.org/I17866349', 'https://openalex.org/I205747304', 'https://openalex.org/I134560555', 'https://openalex.org/I1294671590', 'https://openalex.org/I4210119060']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5112169263', 'display_name': 'J. G. Wolf', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210119060', 'display_name': 'Laboratoire de Chimie de Coordination', 'ror': 'https://ror.org/01rtzw447', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I4210119060', 'https://openalex.org/I4210128300']}, {'id': 'https://openalex.org/I17866349', 'display_name': 'Université de Toulouse', 'ror': 'https://ror.org/004raaa70', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I17866349']}, {'id': 'https://openalex.org/I205747304', 'display_name': 'Institut National Polytechnique de Toulouse', 'ror': 'https://ror.org/033p9g875', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I205747304']}, {'id': 'https://openalex.org/I134560555', 'display_name': 'Université Toulouse III - Paul Sabatier', 'ror': 'https://ror.org/02v6kpv12', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I134560555']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Joffrey Wolf', 'raw_affiliation_strings': ['LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France'], 'affiliations': [{'raw_affiliation_string': 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France', 'institution_ids': ['https://openalex.org/I4210119060', 'https://openalex.org/I17866349', 'https://openalex.org/I205747304', 'https://openalex.org/I134560555', 'https://openalex.org/I1294671590']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5071786606', 'display_name': 'Vincent César', 'orcid': 'https://orcid.org/0000-0002-6203-6434'}, 'institutions': [{'id': 'https://openalex.org/I4210119060', 'display_name': 'Laboratoire de Chimie de Coordination', 'ror': 'https://ror.org/01rtzw447', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I4210119060', 'https://openalex.org/I4210128300']}, {'id': 'https://openalex.org/I17866349', 'display_name': 'Université de Toulouse', 'ror': 'https://ror.org/004raaa70', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I17866349']}, {'id': 'https://openalex.org/I205747304', 'display_name': 'Institut National Polytechnique de Toulouse', 'ror': 'https://ror.org/033p9g875', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I205747304']}, {'id': 'https://openalex.org/I134560555', 'display_name': 'Université Toulouse III - Paul Sabatier', 'ror': 'https://ror.org/02v6kpv12', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I134560555']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Vincent César', 'raw_affiliation_strings': ['LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France'], 'affiliations': [{'raw_affiliation_string': 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France', 'institution_ids': ['https://openalex.org/I4210119060', 'https://openalex.org/I17866349', 'https://openalex.org/I205747304', 'https://openalex.org/I134560555', 'https://openalex.org/I1294671590']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5003429896', 'display_name': 'Agnès Labande', 'orcid': 'https://orcid.org/0000-0003-0192-2499'}, 'institutions': [{'id': 'https://openalex.org/I4210119060', 'display_name': 'Laboratoire de Chimie de Coordination', 'ror': 'https://ror.org/01rtzw447', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I4210119060', 'https://openalex.org/I4210128300']}, {'id': 'https://openalex.org/I17866349', 'display_name': 'Université de Toulouse', 'ror': 'https://ror.org/004raaa70', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I17866349']}, {'id': 'https://openalex.org/I205747304', 'display_name': 'Institut National Polytechnique de Toulouse', 'ror': 'https://ror.org/033p9g875', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I205747304']}, {'id': 'https://openalex.org/I134560555', 'display_name': 'Université Toulouse III - Paul Sabatier', 'ror': 'https://ror.org/02v6kpv12', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I134560555']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Agnès Labande', 'raw_affiliation_strings': ['LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France'], 'affiliations': [{'raw_affiliation_string': 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France', 'institution_ids': ['https://openalex.org/I4210119060', 'https://openalex.org/I17866349', 'https://openalex.org/I205747304', 'https://openalex.org/I134560555', 'https://openalex.org/I1294671590']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5073644685', 'display_name': 'Rinaldo Poli', 'orcid': 'https://orcid.org/0000-0002-5220-2515'}, 'institutions': [{'id': 'https://openalex.org/I4210119060', 'display_name': 'Laboratoire de Chimie de Coordination', 'ror': 'https://ror.org/01rtzw447', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I4210119060', 'https://openalex.org/I4210128300']}, {'id': 'https://openalex.org/I17866349', 'display_name': 'Université de Toulouse', 'ror': 'https://ror.org/004raaa70', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I17866349']}, {'id': 'https://openalex.org/I205747304', 'display_name': 'Institut National Polytechnique de Toulouse', 'ror': 'https://ror.org/033p9g875', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I205747304']}, {'id': 'https://openalex.org/I134560555', 'display_name': 'Université Toulouse III - Paul Sabatier', 'ror': 'https://ror.org/02v6kpv12', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I134560555']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}, {'id': 'https://openalex.org/I185839726', 'display_name': 'Institut Universitaire de France', 'ror': 'https://ror.org/055khg266', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I185839726']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Rinaldo Poli', 'raw_affiliation_strings': ['Institut Universitaire de France, 103 Boulevard Saint-Michel, 75005 Paris, France', 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France'], 'affiliations': [{'raw_affiliation_string': 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France', 'institution_ids': ['https://openalex.org/I4210119060', 'https://openalex.org/I17866349', 'https://openalex.org/I205747304', 'https://openalex.org/I134560555', 'https://openalex.org/I1294671590']}, {'raw_affiliation_string': 'Institut Universitaire de France, 103 Boulevard Saint-Michel, 75005 Paris, France', 'institution_ids': ['https://openalex.org/I185839726']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5022953044', 'display_name': 'Noël Lugan', 'orcid': 'https://orcid.org/0000-0002-3744-5252'}, 'institutions': [{'id': 'https://openalex.org/I4210119060', 'display_name': 'Laboratoire de Chimie de Coordination', 'ror': 'https://ror.org/01rtzw447', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I4210119060', 'https://openalex.org/I4210128300']}, {'id': 'https://openalex.org/I17866349', 'display_name': 'Université de Toulouse', 'ror': 'https://ror.org/004raaa70', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I17866349']}, {'id': 'https://openalex.org/I205747304', 'display_name': 'Institut National Polytechnique de Toulouse', 'ror': 'https://ror.org/033p9g875', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I205747304']}, {'id': 'https://openalex.org/I134560555', 'display_name': 'Université Toulouse III - Paul Sabatier', 'ror': 'https://ror.org/02v6kpv12', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I134560555']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Noël Lugan', 'raw_affiliation_strings': ['LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France'], 'affiliations': [{'raw_affiliation_string': 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France', 'institution_ids': ['https://openalex.org/I4210119060', 'https://openalex.org/I17866349', 'https://openalex.org/I205747304', 'https://openalex.org/I134560555', 'https://openalex.org/I1294671590']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5113624297', 'display_name': 'Guy Lavigne', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210119060', 'display_name': 'Laboratoire de Chimie de Coordination', 'ror': 'https://ror.org/01rtzw447', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I4210119060', 'https://openalex.org/I4210128300']}, {'id': 'https://openalex.org/I17866349', 'display_name': 'Université de Toulouse', 'ror': 'https://ror.org/004raaa70', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I17866349']}, {'id': 'https://openalex.org/I205747304', 'display_name': 'Institut National Polytechnique de Toulouse', 'ror': 'https://ror.org/033p9g875', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I205747304']}, {'id': 'https://openalex.org/I134560555', 'display_name': 'Université Toulouse III - Paul Sabatier', 'ror': 'https://ror.org/02v6kpv12', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I134560555']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Guy Lavigne', 'raw_affiliation_strings': ['LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France'], 'affiliations': [{'raw_affiliation_string': 'LCC (Laboratoire de Chimie de Coordination), CNRS, 205 Route de Narbonne, F-31077 Toulouse, France, and UPS, INPT, LCC, Université de Toulouse, F-31077 Toulouse, France', 'institution_ids': ['https://openalex.org/I4210119060', 'https://openalex.org/I17866349', 'https://openalex.org/I205747304', 'https://openalex.org/I134560555', 'https://openalex.org/I1294671590']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 6, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 2.472, 'has_fulltext': True, 'fulltext_origin': 'pdf', 'cited_by_count': 51, 'citation_normalized_percentile': {'value': 0.857915, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 94, 'max': 95}, 'biblio': {'volume': '28', 'issue': '24', 'first_page': '6981', 'last_page': '6993'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11790', 'display_name': 'N-Heterocyclic Carbenes in Organic and Inorganic Chemistry', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11790', 'display_name': 'N-Heterocyclic Carbenes in Organic and Inorganic Chemistry', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10548', 'display_name': 'Catalytic Cross-Coupling Reactions', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11549', 'display_name': 'Synthetic Organic Chemistry Methods', 'score': 0.9993, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/protonolysis', 'display_name': 'Protonolysis', 'score': 0.48642993}, {'id': 'https://openalex.org/keywords/tetrafluoroborate', 'display_name': 'Tetrafluoroborate', 'score': 0.4827413}, {'id': 'https://openalex.org/keywords/moiety', 'display_name': 'Moiety', 'score': 0.44819888}], 'concepts': [{'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.9258534}, {'id': 'https://openalex.org/C2777716191', 'wikidata': 'https://www.wikidata.org/wiki/Q207877', 'display_name': 'Phosphine', 'level': 3, 'score': 0.84891033}, {'id': 'https://openalex.org/C178516000', 'wikidata': 'https://www.wikidata.org/wiki/Q3023362', 'display_name': 'Denticity', 'level': 3, 'score': 0.80785394}, {'id': 'https://openalex.org/C118629725', 'wikidata': 'https://www.wikidata.org/wiki/Q2686738', 'display_name': 'Deprotonation', 'level': 3, 'score': 0.73940754}, {'id': 'https://openalex.org/C155647269', 'wikidata': 'https://www.wikidata.org/wiki/Q243455', 'display_name': 'Medicinal chemistry', 'level': 1, 'score': 0.7296733}, {'id': 'https://openalex.org/C2777164566', 'wikidata': 'https://www.wikidata.org/wiki/Q419257', 'display_name': 'Carbene', 'level': 3, 'score': 0.7031439}, {'id': 'https://openalex.org/C2776300020', 'wikidata': 'https://www.wikidata.org/wiki/Q422423', 'display_name': 'Bromide', 'level': 2, 'score': 0.6727568}, {'id': 'https://openalex.org/C116569031', 'wikidata': 'https://www.wikidata.org/wiki/Q899107', 'display_name': 'Ligand (biochemistry)', 'level': 3, 'score': 0.64543754}, {'id': 'https://openalex.org/C197404232', 'wikidata': 'https://www.wikidata.org/wiki/Q319827', 'display_name': 'Chelation', 'level': 2, 'score': 0.59765697}, {'id': 'https://openalex.org/C51886252', 'wikidata': 'https://www.wikidata.org/wiki/Q4118667', 'display_name': 'Olefin fiber', 'level': 3, 'score': 0.5366494}, {'id': 'https://openalex.org/C30095370', 'wikidata': 'https://www.wikidata.org/wiki/Q899488', 'display_name': 'Protonation', 'level': 3, 'score': 0.51876616}, {'id': 'https://openalex.org/C2779588249', 'wikidata': 'https://www.wikidata.org/wiki/Q25326845', 'display_name': 'Protonolysis', 'level': 3, 'score': 0.48642993}, {'id': 'https://openalex.org/C2780872544', 'wikidata': 'https://www.wikidata.org/wiki/Q7706343', 'display_name': 'Tetrafluoroborate', 'level': 4, 'score': 0.4827413}, {'id': 'https://openalex.org/C2776568683', 'wikidata': 'https://www.wikidata.org/wiki/Q23005640', 'display_name': 'Moiety', 'level': 2, 'score': 0.44819888}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.37766194}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.20906743}, {'id': 'https://openalex.org/C154881586', 'wikidata': 'https://www.wikidata.org/wiki/Q898579', 'display_name': 'Ionic liquid', 'level': 3, 'score': 0.19036543}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.18111777}, {'id': 'https://openalex.org/C115624301', 'wikidata': 'https://www.wikidata.org/wiki/Q895901', 'display_name': 'Crystal structure', 'level': 2, 'score': 0.12634674}, {'id': 'https://openalex.org/C145148216', 'wikidata': 'https://www.wikidata.org/wiki/Q36496', 'display_name': 'Ion', 'level': 2, 'score': 0.060566157}, {'id': 'https://openalex.org/C55493867', 'wikidata': 'https://www.wikidata.org/wiki/Q7094', 'display_name': 'Biochemistry', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C170493617', 'wikidata': 'https://www.wikidata.org/wiki/Q208467', 'display_name': 'Receptor', 'level': 2, 'score': 0.0}], 'mesh': [], 'locations_count': 5, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om900813p', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': True, 'landing_page_url': 'https://hal.science/hal-03178363', 'pdf_url': 'https://hal.science/hal-03178363/document', 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'submittedVersion', 'is_accepted': False, 'is_published': False}, {'is_oa': True, 'landing_page_url': 'https://hal.science/hal-03178363/file/268-10.1021-om900813p-Accepted.pdf', 'pdf_url': 'https://hal.science/hal-03178363/file/268-10.1021-om900813p-Accepted.pdf', 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': 'submittedVersion', 'is_accepted': False, 'is_published': False}, {'is_oa': True, 'landing_page_url': 'https://hal.archives-ouvertes.fr/hal-03178363/document', 'pdf_url': 'https://hal.archives-ouvertes.fr/hal-03178363/document', 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': 'submittedVersion', 'is_accepted': False, 'is_published': False}, {'is_oa': True, 'landing_page_url': 'https://hal.archives-ouvertes.fr/hal-03178363/file/268-10.1021-om900813p-Accepted.pdf', 'pdf_url': 'https://hal.archives-ouvertes.fr/hal-03178363/file/268-10.1021-om900813p-Accepted.pdf', 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': 'submittedVersion', 'is_accepted': False, 'is_published': False}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://hal.science/hal-03178363', 'pdf_url': 'https://hal.science/hal-03178363/document', 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'submittedVersion', 'is_accepted': False, 'is_published': False}, 'sustainable_development_goals': [], 'grants': [], 'datasets': ['https://openalex.org/W4398098331', 'https://openalex.org/W4398073314'], 'versions': [], 'referenced_works_count': 118, 'referenced_works': ['https://openalex.org/W1492433109', 'https://openalex.org/W1498073544', 'https://openalex.org/W1922163249', 'https://openalex.org/W1964564850', 'https://openalex.org/W1966219336', 'https://openalex.org/W1966444728', 'https://openalex.org/W1966473578', 'https://openalex.org/W1967253297', 'https://openalex.org/W1969188989', 'https://openalex.org/W1969936644', 'https://openalex.org/W1973051984', 'https://openalex.org/W1976894600', 'https://openalex.org/W1979795446', 'https://openalex.org/W1981568462', 'https://openalex.org/W1982643872', 'https://openalex.org/W1984315233', 'https://openalex.org/W1984879171', 'https://openalex.org/W1986022560', 'https://openalex.org/W1990614364', 'https://openalex.org/W1991312972', 'https://openalex.org/W1993082419', 'https://openalex.org/W1997440217', 'https://openalex.org/W2000543888', 'https://openalex.org/W2000737132', 'https://openalex.org/W2002142325', 'https://openalex.org/W2002374188', 'https://openalex.org/W2002503083', 'https://openalex.org/W2002750389', 'https://openalex.org/W2003876494', 'https://openalex.org/W2005227604', 'https://openalex.org/W2005264507', 'https://openalex.org/W2006854140', 'https://openalex.org/W2006883955', 'https://openalex.org/W2011414215', 'https://openalex.org/W2011851250', 'https://openalex.org/W2012853998', 'https://openalex.org/W2015377195', 'https://openalex.org/W2015998822', 'https://openalex.org/W2019586630', 'https://openalex.org/W2020176820', 'https://openalex.org/W2022195431', 'https://openalex.org/W2030436151', 'https://openalex.org/W2033292408', 'https://openalex.org/W2034248489', 'https://openalex.org/W2035536419', 'https://openalex.org/W2038359552', 'https://openalex.org/W2042263114', 'https://openalex.org/W2044400951', 'https://openalex.org/W2046209801', 'https://openalex.org/W2047352071', 'https://openalex.org/W2049450984', 'https://openalex.org/W2050791488', 'https://openalex.org/W2051325415', 'https://openalex.org/W2051745373', 'https://openalex.org/W2052631542', 'https://openalex.org/W2056090152', 'https://openalex.org/W2056650687', 'https://openalex.org/W2057585656', 'https://openalex.org/W2063334178', 'https://openalex.org/W2064307411', 'https://openalex.org/W2064501275', 'https://openalex.org/W2065839792', 'https://openalex.org/W2067226609', 'https://openalex.org/W2067543006', 'https://openalex.org/W2068371599', 'https://openalex.org/W2068580249', 'https://openalex.org/W2068667356', 'https://openalex.org/W2069966030', 'https://openalex.org/W2072243238', 'https://openalex.org/W2073823010', 'https://openalex.org/W2077940867', 'https://openalex.org/W2080142944', 'https://openalex.org/W2080182825', 'https://openalex.org/W2083176586', 'https://openalex.org/W2084264699', 'https://openalex.org/W2086365824', 'https://openalex.org/W2089906374', 'https://openalex.org/W2090070778', 'https://openalex.org/W2092442366', 'https://openalex.org/W2093125996', 'https://openalex.org/W2093172824', 'https://openalex.org/W2094533942', 'https://openalex.org/W2098166392', 'https://openalex.org/W2104057453', 'https://openalex.org/W2110019490', 'https://openalex.org/W2113789305', 'https://openalex.org/W2116741024', 'https://openalex.org/W2117536005', 'https://openalex.org/W2119423701', 'https://openalex.org/W2120152336', 'https://openalex.org/W2120355202', 'https://openalex.org/W2131880545', 'https://openalex.org/W2133502386', 'https://openalex.org/W2134268644', 'https://openalex.org/W2139509084', 'https://openalex.org/W2139749423', 'https://openalex.org/W2139891148', 'https://openalex.org/W2144439207', 'https://openalex.org/W2145269241', 'https://openalex.org/W2150192126', 'https://openalex.org/W2150484258', 'https://openalex.org/W2150761023', 'https://openalex.org/W2161501839', 'https://openalex.org/W2164631251', 'https://openalex.org/W2172875269', 'https://openalex.org/W2177093154', 'https://openalex.org/W2330776018', 'https://openalex.org/W2333643197', 'https://openalex.org/W2492185691', 'https://openalex.org/W2949350526', 'https://openalex.org/W2950568692', 'https://openalex.org/W2951346745', 'https://openalex.org/W2952433704', 'https://openalex.org/W2952618229', 'https://openalex.org/W2952848839', 'https://openalex.org/W3024521450', 'https://openalex.org/W4211172071', 'https://openalex.org/W628009773'], 'related_works': ['https://openalex.org/W4236553230', 'https://openalex.org/W2968211161', 'https://openalex.org/W2953123463', 'https://openalex.org/W2912130535', 'https://openalex.org/W2132994740', 'https://openalex.org/W2118126257', 'https://openalex.org/W2068569406', 'https://openalex.org/W2065425435', 'https://openalex.org/W2037644505', 'https://openalex.org/W2034735037'], 'abstract_inverted_index': {'Complex': [0], 'Ru(CO)2(PPh3)3,': [1], '1,': [2, 24], 'is': [3, 48, 243], 'a': [4, 51, 186, 198, 202, 258, 358], 'suitable': [5], 'starting': [6], 'compound': [7], 'for': [8, 372], 'the': [9, 43, 46, 91, 94, 98, 105, 115, 126, 132, 160, 195, 206, 209, 215, 225, 247, 265, 268, 273, 278, 281, 291, 311, 316, 326, 329, 343, 349, 353, 363], 'generation': [10, 227], 'of': [11, 15, 55, 97, 110, 135, 166, 197, 214, 224, 228, 272, 280, 290, 313, 328, 332, 338, 342], 'N-heterocyclic': [12, 28], 'carbene': [13], 'complexes': [14], 'Ru(0).': [16], 'Although': [17, 288], 'monodentate': [18], 'NHCs': [19], 'are': [20, 376], 'totally': [21], 'unreactive': [22], 'toward': [23], 'phosphine-': [25], 'or': [26, 45, 298], 'olefin-functionalized': [27, 143], 'carbenes,': [29], 'as': [30, 32, 50, 73], 'well': [31], 'their': [33, 302], 'imidazolium': [34, 144], 'precursors,': [35], 'react': [36], 'with': [37, 66, 112, 122, 150, 172, 180, 335], '1': [38, 67, 123, 151, 173], 'under': [39], 'chelation': [40], 'assistance': [41], 'where': [42], 'phosphine': [44], 'olefin': [47], 'acting': [49], 'directing': [52], 'group.': [53], 'Reactions': [54], '1-mesityl-3-(2-diphenylphosphinoeth-1-yl)imidazolium': [56, 59], 'bromide,': [57, 64, 147], '[HL1a]+Br−,': [58], 'tetrafluoroborate,': [60], '[HL1a]+BF4−,': [61], 'and': [62, 156, 208, 267, 356, 374], '1-(2,6-diisopropylphenyl)-3-(2-diphenylphosphinoeth-1-yl)imidazolium': [63], '[HL1b]+Br−,': [65], 'give': [68, 125, 175], 'cationic': [69, 187, 283, 294], 'hydrido': [70], 'species': [71, 285], 'formulated': [72], '[RuH{L*1a,b}(CO)2(PPh3)]+X−,': [74], '[2a,b]+X−': [75], '(a,': [76], 'Ar': [77, 81], '=': [78, 82], 'mesityl;': [79], 'b,': [80], '2,6': [83], 'diisopropylphenyl),': [84], 'in': [85, 222], 'which': [86, 120, 170, 218, 351], 'abnormal': [87], 'activation': [88, 155], '(symbolized': [89], 'by': [90, 348], 'asterisk)': [92], 'at': [93, 182, 321], 'C(4)': [95], 'position': [96], 'heterocycle': [99], 'has': [100], 'taken': [101], 'place': [102], 'to': [103, 124, 159, 174, 315, 325], 'yield': [104], 'bidentate': [106, 118], 'ligands': [107], 'L*1a,b.': [108], 'Deprotonation': [109, 165], '[HL1b]+': [111], 'KOtBu': [113], 'gives': [114, 168, 185], 'corresponding': [116], 'NHC/phosphine': [117, 128], 'ligand,': [119], 'reacts': [121, 149, 171], 'chelated': [127], 'complex': [129, 137, 250], 'Ru{L1b}(CO)2(PPh3)': [130], '(3b),': [131], 'first': [133, 344], 'analogue': [134, 331], "Roper's": [136], 'incorporating': [138], 'an': [139, 229], 'NHC': [140], 'moiety.': [141], 'The': [142, 368], 'ligand': [145], '3-(but-3-enyl)-1-mesitylimidazolium': [146], '[HL2a]+Br−,': [148], 'via': [152], 'chelation-assisted': [153], 'C−H': [154], 'H': [157], 'transfer': [158], 'olefin,': [161, 217, 275], 'giving': [162], 'Ru{Ar(N2C3H2)CH2C(H)(CH2CH3)}(CO)2(PPh3)Br': [163], '(4a).': [164], '[HL2a]+Br−': [167], 'L2a,': [169], 'Ru{L2a}(CO)2(PPh3)': [176], '(5a).': [177], 'Its': [178], 'protonation': [179], 'HBF4': [181, 339], '−80': [183], '°C': [184, 323], 'NHC/olefin-hydrido': [188, 249], 'complex,': [189], '[RuH{L2a}(CO)2(PPh3)]+BF4−,': [190], '[6a]+BF4−.': [191], 'NMR': [192, 255], 'data': [193, 256], 'indicate': [194], 'occurrence': [196, 303], 'dynamic': [199, 259], 'process': [200, 260, 355], 'involving': [201, 261], 'fast': [203, 262], 'exchange': [204, 263], 'between': [205, 264], 'hydride': [207, 266], 'two': [210], 'terminal': [211, 269], 'hydrogen': [212, 270], 'atoms': [213], 'coordinated': [216, 274], 'can': [219], 'be': [220, 305], 'rationalized': [221], 'terms': [223], 'transient': [226], 'elusive': [230, 282, 345], 'higher': [231], 'energy': [232], 'NHC/alkyl': [233, 284, 364], 'intermediate,': [234], '[Ru{Ar(N2C3H2)CH2CH2C(H)CH3)}(CO)2(PPh3)]+BF4−,': [235], '[7a]+BF4−.': [236], 'At': [237], 'temperatures': [238], 'above': [239, 292, 317], '−20': [240], '°C,': [241], '[6a]+BF4−': [242], 'irreversibly': [244], 'converted': [245], 'into': [246], 'isomerized': [248], '[RuH{Ar(N2C3H2)CH2CH═C(H)CH3}(CO)2(PPh3)]+BF4−,': [251], '[8a]+BF4−.': [252], 'Here': [253], 'again,': [254], 'reveal': [257], 'atom': [271], 'now': [276], 'through': [277], 'intermediacy': [279], '[Ru{Ar(N2C3H2)CH2C(H)CH2CH3}(CO)2(PPh3)]+BF4−,': [286], '[9a]+BF4−.': [287], 'neither': [289], 'unsaturated': [293], 'alkyl': [295], 'intermediates': [296], '[7a]+': [297, 347], '[9a]+': [299], 'was': [300], 'observed,': [301], 'could': [304], 'inferred': [306], 'from': [307], 'trapping': [308], 'experiments.': [309], 'Indeed,': [310], 'addition': [312], '[PPN]Cl': [314], 'mixture': [318], 'after': [319], 'equilibration': [320], '25': [322], 'leads': [324], 'formation': [327], 'chloride': [330], '4a.': [333], 'Protonation': [334], 'HCl': [336], 'instead': [337], 'allows': [340], 'capture': [341], 'intermediate': [346], 'halide,': [350], 'quenches': [352], 'isomerization': [354], 'promotes': [357], 'migratory': [359], 'CO': [360], 'insertion': [361], 'yielding': [362], 'derivative': [365], 'Ru{Ar(N2C3H2)CH2CH2C(H)(CH3)C═O}(CO)(PPh3),': [366], '10a.': [367], 'X-ray': [369], 'structure': [370], 'analyses': [371], '4': [373], '5': [375], 'included.': [377]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1986765652', 'counts_by_year': [{'year': 2024, 'cited_by_count': 2}, {'year': 2022, 'cited_by_count': 2}, {'year': 2020, 'cited_by_count': 3}, {'year': 2019, 'cited_by_count': 2}, {'year': 2018, 'cited_by_count': 3}, {'year': 2017, 'cited_by_count': 2}, {'year': 2016, 'cited_by_count': 2}, {'year': 2015, 'cited_by_count': 8}, {'year': 2014, 'cited_by_count': 6}, {'year': 2013, 'cited_by_count': 5}, {'year': 2012, 'cited_by_count': 8}], 'updated_date': '2025-01-11T05:01:34.206990', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
