Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex

Name: Work Video:
Duration: 3 min 30 s
Erli Lu; Oliver J. Cooper; Jonathan McMaster; Floriana Tuna; Eric J. L. McInnes; William Lewis; Alexander J. Blake; Stephen T. Liddle
{'id': 'https://openalex.org/W2132994740', 'doi': 'https://doi.org/10.1002/anie.201403892', 'title': 'Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex', 'display_name': 'Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex', 'publication_year': 2014, 'publication_date': '2014-05-19', 'ids': {'openalex': 'https://openalex.org/W2132994740', 'doi': 'https://doi.org/10.1002/anie.201403892', 'mag': '2132994740', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/24842784', 'pmcid': 'https://www.ncbi.nlm.nih.gov/pmc/articles/4464547'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1002/anie.201403892', 'pdf_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201403892', 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': True, 'oa_status': 'hybrid', 'oa_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201403892', 'any_repository_has_fulltext': True}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5082680062', 'display_name': 'Erli Lu', 'orcid': 'https://orcid.org/0000-0002-0619-5967'}, 'institutions': [{'id': 'https://openalex.org/I142263535', 'display_name': 'University of Nottingham', 'ror': 'https://ror.org/01ee9ar58', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I142263535']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'Erli Lu', 'raw_affiliation_strings': ['School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)', 'institution_ids': ['https://openalex.org/I142263535']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5033955654', 'display_name': 'Oliver J. Cooper', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I142263535', 'display_name': 'University of Nottingham', 'ror': 'https://ror.org/01ee9ar58', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I142263535']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'Oliver J. Cooper', 'raw_affiliation_strings': ['School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)', 'institution_ids': ['https://openalex.org/I142263535']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5091424152', 'display_name': 'Jonathan McMaster', 'orcid': 'https://orcid.org/0000-0003-0917-7454'}, 'institutions': [{'id': 'https://openalex.org/I142263535', 'display_name': 'University of Nottingham', 'ror': 'https://ror.org/01ee9ar58', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I142263535']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'Jonathan McMaster', 'raw_affiliation_strings': ['School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)', 'institution_ids': ['https://openalex.org/I142263535']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5050699980', 'display_name': 'Floriana Tuna', 'orcid': 'https://orcid.org/0000-0002-5541-1750'}, 'institutions': [{'id': 'https://openalex.org/I28407311', 'display_name': 'University of Manchester', 'ror': 'https://ror.org/027m9bs27', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I28407311']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'Floriana Tuna', 'raw_affiliation_strings': ['School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL, UK'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL, UK', 'institution_ids': ['https://openalex.org/I28407311']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5056494829', 'display_name': 'Eric J. L. McInnes', 'orcid': 'https://orcid.org/0000-0002-4090-7040'}, 'institutions': [{'id': 'https://openalex.org/I28407311', 'display_name': 'University of Manchester', 'ror': 'https://ror.org/027m9bs27', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I28407311']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'Eric J. L. McInnes', 'raw_affiliation_strings': ['School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL, UK'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry and Photon Science Institute, University of Manchester, Oxford Road, Manchester, M13 9PL, UK', 'institution_ids': ['https://openalex.org/I28407311']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5015509328', 'display_name': 'William Lewis', 'orcid': 'https://orcid.org/0000-0001-7103-6981'}, 'institutions': [{'id': 'https://openalex.org/I142263535', 'display_name': 'University of Nottingham', 'ror': 'https://ror.org/01ee9ar58', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I142263535']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'William Lewis', 'raw_affiliation_strings': ['School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)', 'institution_ids': ['https://openalex.org/I142263535']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5084750854', 'display_name': 'Alexander J. Blake', 'orcid': 'https://orcid.org/0000-0003-2257-8332'}, 'institutions': [{'id': 'https://openalex.org/I142263535', 'display_name': 'University of Nottingham', 'ror': 'https://ror.org/01ee9ar58', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I142263535']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'Alexander J. Blake', 'raw_affiliation_strings': ['School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)', 'institution_ids': ['https://openalex.org/I142263535']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5086963679', 'display_name': 'Stephen T. Liddle', 'orcid': 'https://orcid.org/0000-0001-9911-8778'}, 'institutions': [{'id': 'https://openalex.org/I142263535', 'display_name': 'University of Nottingham', 'ror': 'https://ror.org/01ee9ar58', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I142263535']}], 'countries': ['GB'], 'is_corresponding': False, 'raw_author_name': 'Stephen T. Liddle', 'raw_affiliation_strings': ['School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)'], 'affiliations': [{'raw_affiliation_string': 'School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK)', 'institution_ids': ['https://openalex.org/I142263535']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 5250, 'currency': 'USD', 'value_usd': 5250, 'provenance': 'doaj'}, 'apc_paid': {'value': 5250, 'currency': 'USD', 'value_usd': 5250, 'provenance': 'doaj'}, 'fwci': 6.676, 'has_fulltext': True, 'fulltext_origin': 'pdf', 'cited_by_count': 109, 'citation_normalized_percentile': {'value': 0.999959, 'is_in_top_1_percent': True, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 98, 'max': 99}, 'biblio': {'volume': '53', 'issue': '26', 'first_page': '6696', 'last_page': '6700'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9996, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9996, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11790', 'display_name': 'N-Heterocyclic Carbenes in Organic and Inorganic Chemistry', 'score': 0.9978, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11279', 'display_name': 'Lanthanide and Transition Metal Complexes', 'score': 0.9971, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/protonolysis', 'display_name': 'Protonolysis', 'score': 0.76376104}, {'id': 'https://openalex.org/keywords/heteroatom', 'display_name': 'Heteroatom', 'score': 0.65868896}, {'id': 'https://openalex.org/keywords/uranyl', 'display_name': 'Uranyl', 'score': 0.5363983}, {'id': 'https://openalex.org/keywords/reactivity', 'display_name': 'Reactivity', 'score': 0.43671447}], 'concepts': [{'id': 'https://openalex.org/C2777164566', 'wikidata': 'https://www.wikidata.org/wiki/Q419257', 'display_name': 'Carbene', 'level': 3, 'score': 0.97338235}, {'id': 'https://openalex.org/C2779588249', 'wikidata': 'https://www.wikidata.org/wiki/Q25326845', 'display_name': 'Protonolysis', 'level': 3, 'score': 0.76376104}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.699675}, {'id': 'https://openalex.org/C555451288', 'wikidata': 'https://www.wikidata.org/wiki/Q1098', 'display_name': 'Uranium', 'level': 2, 'score': 0.6615965}, {'id': 'https://openalex.org/C20950531', 'wikidata': 'https://www.wikidata.org/wiki/Q161940', 'display_name': 'Heteroatom', 'level': 3, 'score': 0.65868896}, {'id': 'https://openalex.org/C2779485729', 'wikidata': 'https://www.wikidata.org/wiki/Q210385', 'display_name': 'Pyridine', 'level': 2, 'score': 0.5884617}, {'id': 'https://openalex.org/C2778468930', 'wikidata': 'https://www.wikidata.org/wiki/Q421141', 'display_name': 'Uranyl', 'level': 3, 'score': 0.5363983}, {'id': 'https://openalex.org/C155647269', 'wikidata': 'https://www.wikidata.org/wiki/Q243455', 'display_name': 'Medicinal chemistry', 'level': 1, 'score': 0.52286553}, {'id': 'https://openalex.org/C2776910235', 'wikidata': 'https://www.wikidata.org/wiki/Q18574', 'display_name': 'Reactivity (psychology)', 'level': 3, 'score': 0.43671447}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.32571346}, {'id': 'https://openalex.org/C2780378348', 'wikidata': 'https://www.wikidata.org/wiki/Q25351438', 'display_name': 'Ring (chemistry)', 'level': 2, 'score': 0.20620134}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.204979}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.11752638}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.093842894}, {'id': 'https://openalex.org/C145148216', 'wikidata': 'https://www.wikidata.org/wiki/Q36496', 'display_name': 'Ion', 'level': 2, 'score': 0.0}, {'id': 'https://openalex.org/C185544564', 'wikidata': 'https://www.wikidata.org/wiki/Q81197', 'display_name': 'Nuclear physics', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C71924100', 'wikidata': 'https://www.wikidata.org/wiki/Q11190', 'display_name': 'Medicine', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C204787440', 'wikidata': 'https://www.wikidata.org/wiki/Q188504', 'display_name': 'Alternative medicine', 'level': 2, 'score': 0.0}, {'id': 'https://openalex.org/C142724271', 'wikidata': 'https://www.wikidata.org/wiki/Q7208', 'display_name': 'Pathology', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 6, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.1002/anie.201403892', 'pdf_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201403892', 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://europepmc.org/articles/pmc4464547', 'pdf_url': 'https://europepmc.org/articles/pmc4464547?pdf=render', 'source': {'id': 'https://openalex.org/S4306400806', 'display_name': 'Europe PMC (PubMed Central)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1303153112', 'host_organization_name': 'European Bioinformatics Institute', 'host_organization_lineage': ['https://openalex.org/I1303153112'], 'host_organization_lineage_names': ['European Bioinformatics Institute'], 'type': 'repository'}, 'license': 'cc-by', 'license_id': 'https://openalex.org/licenses/cc-by', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://nottingham-repository.worktribe.com/file/730199/1/Lu_et_al-2014-Angewandte_Chemie_International_Edition.pdf', 'pdf_url': 'https://nottingham-repository.worktribe.com/file/730199/1/Lu_et_al-2014-Angewandte_Chemie_International_Edition.pdf', 'source': {'id': 'https://openalex.org/S4306402482', 'display_name': 'Repository@Nottingham (University of Nottingham)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I142263535', 'host_organization_name': 'University of Nottingham', 'host_organization_lineage': ['https://openalex.org/I142263535'], 'host_organization_lineage_names': ['University of Nottingham'], 'type': 'repository'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://nottingham-repository.worktribe.com/output/730199', 'pdf_url': 'https://nottingham-repository.worktribe.com/preview/730227/Lu_et_al-2014-Angewandte_Chemie_International_Edition.pdf', 'source': {'id': 'https://openalex.org/S4306402482', 'display_name': 'Repository@Nottingham (University of Nottingham)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I142263535', 'host_organization_name': 'University of Nottingham', 'host_organization_lineage': ['https://openalex.org/I142263535'], 'host_organization_lineage_names': ['University of Nottingham'], 'type': 'repository'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464547', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S2764455111', 'display_name': 'PubMed Central', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/24842784', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1002/anie.201403892', 'pdf_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201403892', 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [{'id': 'https://metadata.un.org/sdg/6', 'display_name': 'Clean water and sanitation', 'score': 0.55}], 'grants': [], 'datasets': ['https://openalex.org/W4397486680', 'https://openalex.org/W4397093901', 'https://openalex.org/W4397141045', 'https://openalex.org/W4397190030', 'https://openalex.org/W4397243756'], 'versions': [], 'referenced_works_count': 80, 'referenced_works': ['https://openalex.org/W1943686379', 'https://openalex.org/W1964172910', 'https://openalex.org/W1964640330', 'https://openalex.org/W1966193095', 'https://openalex.org/W1966909878', 'https://openalex.org/W1967842385', 'https://openalex.org/W1971038878', 'https://openalex.org/W1971451395', 'https://openalex.org/W1972377671', 'https://openalex.org/W1975835184', 'https://openalex.org/W1978188241', 'https://openalex.org/W1980605271', 'https://openalex.org/W1980606694', 'https://openalex.org/W1985578003', 'https://openalex.org/W1989852103', 'https://openalex.org/W1993273070', 'https://openalex.org/W1994135413', 'https://openalex.org/W1998937082', 'https://openalex.org/W1999670950', 'https://openalex.org/W2004354800', 'https://openalex.org/W2004689978', 'https://openalex.org/W2005252890', 'https://openalex.org/W2005785841', 'https://openalex.org/W2007302041', 'https://openalex.org/W2015443506', 'https://openalex.org/W2019176142', 'https://openalex.org/W2020007000', 'https://openalex.org/W2021657198', 'https://openalex.org/W2023045222', 'https://openalex.org/W2024863575', 'https://openalex.org/W2025377780', 'https://openalex.org/W2029777690', 'https://openalex.org/W2032581014', 'https://openalex.org/W2035259526', 'https://openalex.org/W2038633742', 'https://openalex.org/W2039902128', 'https://openalex.org/W2042483575', 'https://openalex.org/W2043800343', 'https://openalex.org/W2044956834', 'https://openalex.org/W2045865533', 'https://openalex.org/W2050247157', 'https://openalex.org/W2051058309', 'https://openalex.org/W2052530292', 'https://openalex.org/W2057535075', 'https://openalex.org/W2063673531', 'https://openalex.org/W2083518550', 'https://openalex.org/W2085615658', 'https://openalex.org/W2086191107', 'https://openalex.org/W2093478557', 'https://openalex.org/W2094045270', 'https://openalex.org/W2097720788', 'https://openalex.org/W2101899438', 'https://openalex.org/W2107473053', 'https://openalex.org/W2114737710', 'https://openalex.org/W2118126257', 'https://openalex.org/W2123715208', 'https://openalex.org/W2158621087', 'https://openalex.org/W2159098862', 'https://openalex.org/W2182738981', 'https://openalex.org/W2218495967', 'https://openalex.org/W2314129795', 'https://openalex.org/W2314821784', 'https://openalex.org/W2315962296', 'https://openalex.org/W2319818810', 'https://openalex.org/W2319945980', 'https://openalex.org/W2320715933', 'https://openalex.org/W2322313666', 'https://openalex.org/W2323470254', 'https://openalex.org/W2325027728', 'https://openalex.org/W2328072234', 'https://openalex.org/W2329439329', 'https://openalex.org/W2334842634', 'https://openalex.org/W2335553647', 'https://openalex.org/W2944912331', 'https://openalex.org/W2951244216', 'https://openalex.org/W4233302586', 'https://openalex.org/W4235535421', 'https://openalex.org/W4236349187', 'https://openalex.org/W4247984921', 'https://openalex.org/W4253984266'], 'related_works': ['https://openalex.org/W4236553230', 'https://openalex.org/W3121883004', 'https://openalex.org/W2141207036', 'https://openalex.org/W2132994740', 'https://openalex.org/W2118126257', 'https://openalex.org/W2083575295', 'https://openalex.org/W2037644505', 'https://openalex.org/W2034735037', 'https://openalex.org/W1990749895', 'https://openalex.org/W1575852573'], 'abstract_inverted_index': {'We': [0], 'report': [1], 'the': [2, 22, 36, 58, 84, 99, 107], 'uranium(VI)': [3], 'carbene': [4, 103, 109], 'imido': [5, 72, 100], 'oxo': [6, 55, 70], 'complex': [7, 45, 110], '[U(BIPM(TMS))(NMes)(O)(DMAP)2]': [8], '(5,': [9], 'BIPM(TMS)': [10], '=': [11, 15, 18], 'C(PPh2': [12], 'NSiMe3)2;': [13], 'Mes': [14], '2,4,6-Me3C6H2;': [16], 'DMAP': [17], '4-(dimethylamino)pyridine)': [19], 'which': [20, 86], 'exhibits': [21], 'unprecedented': [23], 'arrangement': [24], 'of': [25, 50], 'three': [26], 'formal': [27], 'multiply': [28], 'bonded': [29], 'ligands': [30], 'to': [31, 83, 105], 'one': [32], 'metal': [33], 'center': [34, 60], 'where': [35], 'coordinated': [37], 'heteroatoms': [38], 'derive': [39], 'from': [40], 'different': [41], 'element': [42], 'groups.': [43], 'This': [44], 'was': [46], 'prepared': [47], 'by': [48, 61], 'incorporation': [49], 'carbene,': [51, 85], 'imido,': [52], 'and': [53, 65, 71], 'then': [54], 'groups': [56, 73], 'at': [57, 98], 'uranium': [59], 'salt': [62], 'elimination,': [63], 'protonolysis,': [64], 'two-electron': [66], 'oxidation,': [67], 'respectively.': [68], 'The': [69], 'adopt': [74], 'axial': [75], 'positions': [76], 'in': [77], 'a': [78], 'T-shaped': [79], 'motif': [80], 'with': [81, 89, 96], 'respect': [82], 'is': [87], 'consistent': [88], 'an': [90], 'inverse': [91], 'trans-influence.': [92], 'Complex': [93], '5': [94], 'reacts': [95], 'tert-butylisocyanate': [97], 'rather': [101], 'than': [102], 'group': [104], 'afford': [106], 'uranyl(VI)': [108], '[U(BIPM(TMS))(O)2(DMAP)2]': [111], '(6).': [112]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2132994740', 'counts_by_year': [{'year': 2024, 'cited_by_count': 6}, {'year': 2023, 'cited_by_count': 10}, {'year': 2022, 'cited_by_count': 6}, {'year': 2021, 'cited_by_count': 8}, {'year': 2020, 'cited_by_count': 9}, {'year': 2019, 'cited_by_count': 9}, {'year': 2018, 'cited_by_count': 14}, {'year': 2017, 'cited_by_count': 17}, {'year': 2016, 'cited_by_count': 8}, {'year': 2015, 'cited_by_count': 16}, {'year': 2014, 'cited_by_count': 6}], 'updated_date': '2025-01-06T19:16:11.896757', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
