Publication Information

{'id': 'https://openalex.org/W2037644505', 'doi': 'https://doi.org/10.1021/om990743x', 'title': 'Metal−Alkyl Bond Protonolysis Studies of (dfepe)Pt(Me)X Complexes in Acidic Media', 'display_name': 'Metal−Alkyl Bond Protonolysis Studies of (dfepe)Pt(Me)X Complexes in Acidic Media', 'publication_year': 2000, 'publication_date': '2000-01-20', 'ids': {'openalex': 'https://openalex.org/W2037644505', 'doi': 'https://doi.org/10.1021/om990743x', 'mag': '2037644505'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om990743x', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5103474148', 'display_name': 'Byron L. Bennett', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I12834331', 'display_name': 'University of Wyoming', 'ror': 'https://ror.org/01485tq96', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I12834331']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Byron L. Bennett', 'raw_affiliation_strings': ['Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071', 'institution_ids': ['https://openalex.org/I12834331']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5061396745', 'display_name': 'Justin M. Hoerter', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I12834331', 'display_name': 'University of Wyoming', 'ror': 'https://ror.org/01485tq96', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I12834331']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Justin M. Hoerter', 'raw_affiliation_strings': ['Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071', 'institution_ids': ['https://openalex.org/I12834331']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5051287420', 'display_name': 'James F. Houlis', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I12834331', 'display_name': 'University of Wyoming', 'ror': 'https://ror.org/01485tq96', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I12834331']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'James F. Houlis', 'raw_affiliation_strings': ['Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071', 'institution_ids': ['https://openalex.org/I12834331']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5040522842', 'display_name': 'Dean M. Roddick', 'orcid': 'https://orcid.org/0000-0002-5981-4178'}, 'institutions': [{'id': 'https://openalex.org/I12834331', 'display_name': 'University of Wyoming', 'ror': 'https://ror.org/01485tq96', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I12834331']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Dean M. Roddick', 'raw_affiliation_strings': ['Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Box 3838, University of Wyoming, Laramie, Wyoming 82071', 'institution_ids': ['https://openalex.org/I12834331']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 2.358, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 37, 'citation_normalized_percentile': {'value': 0.855353, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 89, 'max': 90}, 'biblio': {'volume': '19', 'issue': '4', 'first_page': '615', 'last_page': '621'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9946, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9946, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10947', 'display_name': 'Fluorine in Organic Chemistry', 'score': 0.9893, 'subfield': {'id': 'https://openalex.org/subfields/3003', 'display_name': 'Pharmaceutical Science'}, 'field': {'id': 'https://openalex.org/fields/30', 'display_name': 'Pharmacology, Toxicology and Pharmaceutics'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, {'id': 'https://openalex.org/T10002', 'display_name': 'Advanced Chemical Physics Studies', 'score': 0.9884, 'subfield': {'id': 'https://openalex.org/subfields/3107', 'display_name': 'Atomic and Molecular Physics, and Optics'}, 'field': {'id': 'https://openalex.org/fields/31', 'display_name': 'Physics and Astronomy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/protonolysis', 'display_name': 'Protonolysis', 'score': 0.9978324}, {'id': 'https://openalex.org/keywords/trifluoroacetic-acid', 'display_name': 'Trifluoroacetic acid', 'score': 0.7528122}, {'id': 'https://openalex.org/keywords/oxidative-addition', 'display_name': 'Oxidative addition', 'score': 0.50947195}], 'concepts': [{'id': 'https://openalex.org/C2779588249', 'wikidata': 'https://www.wikidata.org/wiki/Q25326845', 'display_name': 'Protonolysis', 'level': 3, 'score': 0.9978324}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.8631441}, {'id': 'https://openalex.org/C2780112151', 'wikidata': 'https://www.wikidata.org/wiki/Q412033', 'display_name': 'Trifluoroacetic acid', 'level': 2, 'score': 0.7528122}, {'id': 'https://openalex.org/C155647269', 'wikidata': 'https://www.wikidata.org/wiki/Q243455', 'display_name': 'Medicinal chemistry', 'level': 1, 'score': 0.6558095}, {'id': 'https://openalex.org/C2777716191', 'wikidata': 'https://www.wikidata.org/wiki/Q207877', 'display_name': 'Phosphine', 'level': 3, 'score': 0.52693284}, {'id': 'https://openalex.org/C94882840', 'wikidata': 'https://www.wikidata.org/wiki/Q2123471', 'display_name': 'Oxidative addition', 'level': 3, 'score': 0.50947195}, {'id': 'https://openalex.org/C2780263894', 'wikidata': 'https://www.wikidata.org/wiki/Q335268', 'display_name': 'Alkyl', 'level': 2, 'score': 0.43995225}, {'id': 'https://openalex.org/C134121241', 'wikidata': 'https://www.wikidata.org/wiki/Q899301', 'display_name': 'Yield (engineering)', 'level': 2, 'score': 0.4210803}, {'id': 'https://openalex.org/C201194858', 'wikidata': 'https://www.wikidata.org/wiki/Q898238', 'display_name': 'Steric effects', 'level': 2, 'score': 0.41902074}, {'id': 'https://openalex.org/C544153396', 'wikidata': 'https://www.wikidata.org/wiki/Q11426', 'display_name': 'Metal', 'level': 2, 'score': 0.41350675}, {'id': 'https://openalex.org/C179104552', 'wikidata': 'https://www.wikidata.org/wiki/Q11165', 'display_name': 'Inorganic chemistry', 'level': 1, 'score': 0.3485657}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.28060287}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.24962547}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.17355564}, {'id': 'https://openalex.org/C192562407', 'wikidata': 'https://www.wikidata.org/wiki/Q228736', 'display_name': 'Materials science', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C191897082', 'wikidata': 'https://www.wikidata.org/wiki/Q11467', 'display_name': 'Metallurgy', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om990743x', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 41, 'referenced_works': ['https://openalex.org/W1576751465', 'https://openalex.org/W1969880338', 'https://openalex.org/W1969980436', 'https://openalex.org/W1974146756', 'https://openalex.org/W1981726635', 'https://openalex.org/W1982369756', 'https://openalex.org/W1997552419', 'https://openalex.org/W1998868134', 'https://openalex.org/W2005148229', 'https://openalex.org/W2007970047', 'https://openalex.org/W2012285948', 'https://openalex.org/W2021153367', 'https://openalex.org/W2025323770', 'https://openalex.org/W2026269878', 'https://openalex.org/W2029405156', 'https://openalex.org/W2030465511', 'https://openalex.org/W2035772214', 'https://openalex.org/W2047262311', 'https://openalex.org/W2051785075', 'https://openalex.org/W2053613161', 'https://openalex.org/W2066671943', 'https://openalex.org/W2066781626', 'https://openalex.org/W2067542903', 'https://openalex.org/W2080358453', 'https://openalex.org/W2081551027', 'https://openalex.org/W2085580730', 'https://openalex.org/W2088085604', 'https://openalex.org/W2092199401', 'https://openalex.org/W2094157319', 'https://openalex.org/W2097145740', 'https://openalex.org/W2221437205', 'https://openalex.org/W2321289962', 'https://openalex.org/W2322534800', 'https://openalex.org/W236624720', 'https://openalex.org/W2949309223', 'https://openalex.org/W2951807536', 'https://openalex.org/W3137706210', 'https://openalex.org/W3139044887', 'https://openalex.org/W351104759', 'https://openalex.org/W388365042', 'https://openalex.org/W4240339722'], 'related_works': ['https://openalex.org/W3097187068', 'https://openalex.org/W2264803669', 'https://openalex.org/W2141207036', 'https://openalex.org/W2139540260', 'https://openalex.org/W2058078781', 'https://openalex.org/W2037644505', 'https://openalex.org/W2034735037', 'https://openalex.org/W2026631209', 'https://openalex.org/W1972673117', 'https://openalex.org/W1963826760'], 'abstract_inverted_index': {'Protonolyses': [0], 'of': [1, 76, 90, 128, 143], '(dfepe)Pt(Me)X': [2, 93], '(dfepe': [3], '=': [4, 7, 45], '(C2F5)2PCH2CH2P(C2F5)2;': [5], 'X': [6], 'O2CCF3,': [8], 'OSO2H,': [9], 'OSO2CF3,': [10], 'OSO2F)': [11], 'complexes': [12], 'in': [13, 38, 58, 67, 83, 133, 148], 'their': [14], 'respective': [15], 'neat': [16], 'acid': [17, 28, 85], 'solutions': [18], 'cleanly': [19], 'yield': [20], '(dfepe)Pt(X)2': [21], 'products': [22], 'with': [23], 'rates': [24], 'dependent': [25], 'on': [26], 'relative': [27], 'strengths.': [29], 'No': [30], '(dfepe)Pt(Me)(X)2(H)+': [31], 'intermediates': [32], 'were': [33, 72, 101], 'observed': [34], 'by': [35], 'variable-temperature': [36], 'NMR': [37], 'dichloromethane.': [39], 'The': [40, 145], '(perfluoroaryl)phosphine': [41], 'analogue': [42], '(dfppe)Pt(Me)2': [43], '(dfppe': [44], '(C6F5)2PCH2CH2P(C6F5)2)': [46], 'is': [47, 95], 'much': [48], 'less': [49], 'resistant': [50], 'to': [51, 56, 92], 'protonolysis': [52, 66, 105, 159], 'and': [53, 69, 79, 135, 157], 'rapidly': [54], 'converts': [55], '(dfppe)Pt(OTf)2': [57], 'HOTf': [59], 'at': [60], '20': [61], '°C.': [62], 'Kinetic': [63], 'studies': [64, 106, 150], 'for': [65], 'CF3CO2H(D)': [68], 'CF3SO3H(D)': [70], 'solvents': [71], 'carried': [73], 'out.': [74], 'Examination': [75], 'ionic': [77], 'strength': [78], 'chloride': [80], 'anion': [81, 91], 'effects': [82], 'trifluoroacetic': [84], 'indicate': [86], 'that': [87], 'prior': [88], 'association': [89], 'systems': [94], 'not': [96, 152], 'kinetically': [97], 'important.': [98], 'kH/kD': [99, 141], 'values': [100], 'obtained': [102, 147], 'from': [103], 'competitive': [104], '(CF3CO2H,': [107], '9': [108], '±': [109, 115, 121], '2': [110, 116], '(20': [111], '°C);': [112, 118], 'H2SO4,': [113], '7': [114], '(100': [117, 123], 'CF3SO3H,': [119], '2.7': [120], '0.7': [122], '°C)).': [124], 'In': [125], 'the': [126], 'case': [127], 'CF3CO2H,': [129], 'separate': [130], 'kinetic': [131], 'runs': [132], 'protio': [134], 'deuterio': [136], 'acids': [137], 'gave': [138], 'a': [139], 'lower': [140], 'value': [142], '3.6(4).': [144], 'data': [146], 'these': [149], 'do': [151], 'differentiate': [153], 'between': [154], 'limiting': [155], 'SE2': [156], 'SE(oxidative)': [158], 'mechanisms.': [160]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2037644505', 'counts_by_year': [{'year': 2022, 'cited_by_count': 3}, {'year': 2021, 'cited_by_count': 1}, {'year': 2016, 'cited_by_count': 1}, {'year': 2014, 'cited_by_count': 3}, {'year': 2013, 'cited_by_count': 3}, {'year': 2012, 'cited_by_count': 1}], 'updated_date': '2025-01-07T04:39:17.428959', 'created_date': '2016-06-24'}