Publication Information

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'https://openalex.org/W2318353229', 'https://openalex.org/W2103646416', 'https://openalex.org/W2103622752', 'https://openalex.org/W2088242308', 'https://openalex.org/W2087983713', 'https://openalex.org/W2071325709', 'https://openalex.org/W2065561546', 'https://openalex.org/W2054955153', 'https://openalex.org/W2054260995', 'https://openalex.org/W2018784157', 'https://openalex.org/W2012815807', 'https://openalex.org/W2012689599', 'https://openalex.org/W2006652057', 'https://openalex.org/W1963615477', 'https://openalex.org/W1617280153', 'https://openalex.org/W1473652842', 'https://openalex.org/W1253687791', 'https://openalex.org/W1021185609'], 'abstract_inverted_index': {'This': [0, 38], 'thesis': [1], 'describes': [2], 'the': [3, 20, 43, 115, 125, 211, 215, 265, 272, 292], 'synthesis': [4, 116, 225], 'of': [5, 14, 22, 45, 68, 88, 117, 124, 196, 214, 226, 239, 296], 'low': [6], 'valent': [7], '\\(N\\)-heterocyclic': [8, 26], 'carbene': [9, 27], 'palladium': [10, 28, 94, 288, 297], 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[67], 'bulky': [69, 231], 'chelating': [70], 'ligands': [71], 'is': [72, 291], 'an': [73], 'important': [74], 'factor': [75], 'catalytic': [77], 'performance': [78, 269], 'in': [79, 140, 179, 250], 'these': [80, 240], 'reactions.': [81], 'Consequently,': [82], 'we': [83], 'focussed': [84], 'on': [85], 'a': [86, 287], 'variety': [87], 'arylsubstituted': [89], 'methylene': [90], 'bridged': [91], 'bis(N-heterocyclic': [92], 'carbene)': [93], 'In': [96], 'order': [97], 'achieve': [99], 'our': [100], 'aims,': [101], 'attempts': [103], 'synthesise': [105], 'reductive/basic': [108], 'were': [110, 167, 236, 248, 276], 'undertaken,': [111], 'which': [112, 283], 'led': [113, 150], 'several': [118], 'known': [119], 'precursors': [120], 'novel': [122, 143], 'complexes.\r\nReaction': [123], 'dicationic': [126], 'Pd(II)': [127], "[{1,1'-di(aryl)-3,3'-methylenediimidazolin-2,2'-diylidene}": [129], 'palladium(II)bis(acetonitrile)]': [130], '[PF\\(_6\\)]\\(_2\\)': [131], '(aryl': [132], '=': [133], '2,4,6-mesityl': [134], '2,6-diisopropylphenyl)': [136], 'with': [137, 229], 'sodium': [138], 'carbonate': [139], 'methanol': [141], 'afforded': [142], 'dipalladium(I)': [144], 'hydride': [145, 199, 244, 274, 298], '[{bis(μ-carbene)}\\(_2\\)Pd\\(_2\\)H][PF\\(_6\\)].': [147], 'Steric': [148], 'influences': [149], 'major': [152], 'structural': [153], 'differences;': [154], 'Pd-Pd-H': [155, 216], 'core': [156, 162], '(for': [157, 163], '2,4,6-mesityl)': [158], 'linear': [160], 'Pd-H-Pd': [161, 218], '2,6-diisopropylphenyl).': [164], 'characterised': [168], '\\(^1\\)H,': [170], '\\(^{13}\\)C,': [171], '2D': [172], 'VT': [174], 'NMR': [175], 'spectroscopy': [176], '(revealing': [177], 'differences': [178], 'fluxional': [180], 'behaviour),': [181], 'mass': [182], 'spectroscopy,': [183], 'microanalysis': [184], 'X-ray': [186], 'neutron': [188], '(2,4,6-mesityl': [189, 261], 'only)': [190], 'crystallography.': [191], 'metal': [193], 'oxidation': [194], 'states': [195], 'both': [197], 'dipalladium': [198], 'have': [201], 'been': [202], 'shown': [203], 'be': [205, 222], 'Pd(I)': [206, 243], 'DFT': [208], 'calculations,': [209], 'but': [210], 'precise': [212], 'nature': [213], 'interactions': [219], 'remains': [220], 'confirmed.': [223], 'analogous': [227], 'less': [230], 'phenyl': [232], '\\(tert\\)-butyl': [234], 'substituents': [235], 'unsuccessful.\r\nThe': [237], 'reactivity': [238], 'dinuclear': [242], 'catalysts': [247, 278], 'examined': [249], 'reactions': [260], 'substituent': [262], 'only': [263], 'latter).': [266], 'Their': [267], 'poor': [268], 'indicated': [270], 'that': [271, 286], 'dipalladium(D': [273], 'inefficient': [277], 'monoxide/ethep.e': [281], 'copolymerisation,': [282], 'may': [284], 'suggest': [285], 'methoxide': [289], 'actual': [293], 'catalyst': [294], 'instead': [295]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W196250718', 'counts_by_year': [], 'updated_date': '2024-12-12T05:25:33.426291', 'created_date': 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