Title: Heteroleptic Tetravalent 𝛽-Diketonate Molybdenum Complexes as Highly Active Catalysts for Allylic Substitution Reactions
Abstract:The synthesis and characterization of a series of Mo(IV) bis-𝛽-diketonate (^(R)diket, R = Me, tBu, Ph) dichloride (RMo^(IV)Cl_2) and bistriflate (^(R)Mo^(IV)(OTf)_2) complexes are reported. All comple...The synthesis and characterization of a series of Mo(IV) bis-𝛽-diketonate (^(R)diket, R = Me, tBu, Ph) dichloride (RMo^(IV)Cl_2) and bistriflate (^(R)Mo^(IV)(OTf)_2) complexes are reported. All complexes are characterized in solid and solution state by XRD and 1H NMR spectroscopy. We demonstrate that the bistriflate complexes constitute highly active catalysts for allylic substitution reactions.Read More
Publication Year: 2023
Publication Date: 2023-02-27
Language: en
Type: preprint
Indexed In: ['crossref']
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