Title: Remarkable Ligand Effects in Regioselective Palladium-Catalysed Allylic Substitution Reactions
Abstract: Advanced Synthesis & CatalysisVolume 343, Issue 1 p. 75-77 Update Remarkable Ligand Effects in Regioselective Palladium-Catalysed Allylic Substitution Reactions Lara Acemoglu, Lara Acemoglu Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, United Kingdom, Fax: +44 (0)1225–826–231Search for more papers by this authorJonathan M. J. Williams, Jonathan M. J. Williams [email protected] Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, United Kingdom, Fax: +44 (0)1225–826–231Search for more papers by this author Lara Acemoglu, Lara Acemoglu Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, United Kingdom, Fax: +44 (0)1225–826–231Search for more papers by this authorJonathan M. J. Williams, Jonathan M. J. Williams [email protected] Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, United Kingdom, Fax: +44 (0)1225–826–231Search for more papers by this author First published: 06 February 2001 https://doi.org/10.1002/1615-4169(20010129)343:1<75::AID-ADSC75>3.0.CO;2-WCitations: 17AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract The use of tricyclohexylphosphine (and related phosphines) in palladium-catalysed allylic substitution reactions enables the selective conversion of branched allylic acetates into the branched substitution products (up to 120:1 regioselectivity). Linear allylic acetates do not show the same selectivity for the branched substitution products, thereby demonstrating a memory effect. Citing Literature Volume343, Issue129 January 2001Pages 75-77 RelatedInformation
Publication Year: 2001
Publication Date: 2001-01-29
Language: en
Type: article
Indexed In: ['crossref']
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