Abstract: We study a family of posets and the associated chain and order polytopes. We identify the order polytope as a maximal Kogan face in a Gelfand-Tsetlin polytope of a multiple of a fundamental weight. We show that the character of such a Kogan face equals to the character of a Demazure module which occurs in the irreducible representation of $\mathfrak{sl}_n$ having highest weight multiple of fundamental weight and for any such Demazure module there exists a corresponding poset and associated maximal Kogan face. We prove that the chain polytope parametrizes a monomial basis of the associated PBW-graded Demazure module and further, that the Demazure module is a favourable module, e.g. interesting geometric properties are governed by combinatorics of convex polytopes. Thus, we obtain for any minuscule Schubert variety a flat degeneration into a toric projective variety which is projectively normal and arithmetically Cohen-Macaulay. We provide a necessary and sufficient condition on the Weyl group element such that the toric variety associated to the chain polytope and the toric variety associated to the order polytope are isomorphic.