Title: Synthesis and Structure of Coordination Polymer {[Nd_2(C_2O_4)_3(H_2O)_6]·3CH_3OH}_n
Abstract: A Nd(Ⅲ) coordination polymer {[Nd2(C2O4)3(H2O)6]·3CH3OH}n(1) was synthesized with pyrazinetetracarboxylic acid by hydrothermal method.The pink block crystals were obtained and elemental analysis was tested.It crystallized in monoclinic crystal system and P21/c space group and the crystallographic data for complex 1 is:a= 1.1200(2) nm,b = 0.96325(17) nm,c = 1.02580(18) nm,α = 90°,β = 114.278(3)°,γ = 90°,Z = 4,V = 1.0088(3) nm3.In the complex,Nd(III) ion is nine-coordinated by oxygen atoms.The oxalate anions and Nd3+ form two-dimensional alveolate structure and the 2D layers were connected by hydrogen bonds to construct a three-dimensional supramolecular complex.
Publication Year: 2010
Publication Date: 2010-01-01
Language: en
Type: article
Access and Citation
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot