Title: Hydrothermal synthesis,crystal structure and vibrational spectroscopy of [Zn(C_4H_(13)N_3)_2][B_5O_6(OH)_4]_2
Abstract: A crystal of the [Zn(C_4H_(13)N_3)_2][B_5O_6(OH)_4]_2 has been synthesized by hydrothermal reaction,and characterized by FT-IR spectroscopy,Raman spectroscopy,and elemental analyses.Its crystal structure is determined from single crystal X-ray diffraction data.It belongs to the P2(1)/c monoclinic space group,with the following cell parameters: a=0.856 96(14) nm,b=1.178 07(19) nm,c=1.454 2(2)nm,α=90°,β=91.260(2)°,γ=90°,Z=2,V=1.467 7(4) nm~3,Dc=1.602 g/cm~3.The [B_5O_6(OH)_4]~-units are connected to one another through hydrogen bonds,forming a three-dimensional framework with large channel along the a and c axes,in which the templating [Zn(C_4H_(13)N_3)_2]~(2+) cations are located.
Publication Year: 2005
Publication Date: 2005-01-01
Language: en
Type: article
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