Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W2322069559', 'doi': 'https://doi.org/10.1021/jo402650a', 'title': 'Computational Replication of the Abnormal Secondary Kinetic Isotope Effects in a Hydride Transfer Reaction in Solution with a Motion Assisted H-Tunneling Model', 'display_name': 'Computational Replication of the Abnormal Secondary Kinetic Isotope Effects in a Hydride Transfer Reaction in Solution with a Motion Assisted H-Tunneling Model', 'publication_year': 2014, 'publication_date': '2014-02-05', 'ids': {'openalex': 'https://openalex.org/W2322069559', 'doi': 'https://doi.org/10.1021/jo402650a', 'mag': '2322069559', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/24498946', 'pmcid': 'https://www.ncbi.nlm.nih.gov/pmc/articles/3985929'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1021/jo402650a', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S205050996', 'display_name': 'The Journal of Organic Chemistry', 'issn_l': '0022-3263', 'issn': ['0022-3263', '1520-6904'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': 'publisher-specific-oa', 'license_id': 'https://openalex.org/licenses/publisher-specific-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': True, 'oa_status': 'hybrid', 'oa_url': 'https://doi.org/10.1021/jo402650a', 'any_repository_has_fulltext': True}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5083998771', 'display_name': 'Sadra Kashefolgheta', 'orcid': 'https://orcid.org/0000-0002-6772-0999'}, 'institutions': [{'id': 'https://openalex.org/I87547150', 'display_name': 'Southern Illinois University Edwardsville', 'ror': 'https://ror.org/04cqs5j56', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I2801502357', 'https://openalex.org/I87547150']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Sadra Kashefolgheta', 'raw_affiliation_strings': ['Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States', 'institution_ids': ['https://openalex.org/I87547150']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5060309642', 'display_name': 'Mortezaali Razzaghi', 'orcid': 'https://orcid.org/0000-0002-5048-3624'}, 'institutions': [{'id': 'https://openalex.org/I87547150', 'display_name': 'Southern Illinois University Edwardsville', 'ror': 'https://ror.org/04cqs5j56', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I2801502357', 'https://openalex.org/I87547150']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Mortezaali Razzaghi', 'raw_affiliation_strings': ['Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States', 'institution_ids': ['https://openalex.org/I87547150']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5072827131', 'display_name': 'Blake A. Hammann', 'orcid': 'https://orcid.org/0000-0003-2972-091X'}, 'institutions': [{'id': 'https://openalex.org/I87547150', 'display_name': 'Southern Illinois University Edwardsville', 'ror': 'https://ror.org/04cqs5j56', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I2801502357', 'https://openalex.org/I87547150']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Blake Hammann', 'raw_affiliation_strings': ['Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States', 'institution_ids': ['https://openalex.org/I87547150']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5045219360', 'display_name': 'James E. Eilers', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I87547150', 'display_name': 'Southern Illinois University Edwardsville', 'ror': 'https://ror.org/04cqs5j56', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I2801502357', 'https://openalex.org/I87547150']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'James Eilers', 'raw_affiliation_strings': ['Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States', 'institution_ids': ['https://openalex.org/I87547150']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5077227533', 'display_name': 'Daniel Roston', 'orcid': 'https://orcid.org/0000-0002-0617-0516'}, 'institutions': [{'id': 'https://openalex.org/I126307644', 'display_name': 'University of Iowa', 'ror': 'https://ror.org/036jqmy94', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I126307644']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Daniel Roston', 'raw_affiliation_strings': ['Department of Chemistry, The University of Iowa, Iowa City, Iowa 52242, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, The University of Iowa, Iowa City, Iowa 52242, United States', 'institution_ids': ['https://openalex.org/I126307644']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5046657694', 'display_name': 'Yun Lü', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I87547150', 'display_name': 'Southern Illinois University Edwardsville', 'ror': 'https://ror.org/04cqs5j56', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I2801502357', 'https://openalex.org/I87547150']}], 'countries': ['US'], 'is_corresponding': True, 'raw_author_name': 'Yun Lu', 'raw_affiliation_strings': ['Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, Illinois 62026, United States', 'institution_ids': ['https://openalex.org/I87547150']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 2, 'corresponding_author_ids': ['https://openalex.org/A5046657694'], 'corresponding_institution_ids': ['https://openalex.org/I87547150'], 'apc_list': None, 'apc_paid': None, 'fwci': 0.458, 'has_fulltext': True, 'fulltext_origin': 'pdf', 'cited_by_count': 10, 'citation_normalized_percentile': {'value': 0.733865, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 86, 'max': 87}, 'biblio': {'volume': '79', 'issue': '5', 'first_page': '1989', 'last_page': '1994'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T13561', 'display_name': 'Chemical Reactions and Isotopes', 'score': 0.9996, 'subfield': {'id': 'https://openalex.org/subfields/3003', 'display_name': 'Pharmaceutical Science'}, 'field': {'id': 'https://openalex.org/fields/30', 'display_name': 'Pharmacology, Toxicology and Pharmaceutics'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, 'topics': [{'id': 'https://openalex.org/T13561', 'display_name': 'Chemical Reactions and Isotopes', 'score': 0.9996, 'subfield': {'id': 'https://openalex.org/subfields/3003', 'display_name': 'Pharmaceutical Science'}, 'field': {'id': 'https://openalex.org/fields/30', 'display_name': 'Pharmacology, Toxicology and Pharmaceutics'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, {'id': 'https://openalex.org/T13253', 'display_name': 'Chemical Reactions and Mechanisms', 'score': 0.997, 'subfield': {'id': 'https://openalex.org/subfields/1606', 'display_name': 'Physical and Theoretical Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10002', 'display_name': 'Advanced Chemical Physics Studies', 'score': 0.9947, 'subfield': {'id': 'https://openalex.org/subfields/3107', 'display_name': 'Atomic and Molecular Physics, and Optics'}, 'field': {'id': 'https://openalex.org/fields/31', 'display_name': 'Physics and Astronomy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/kinetic-isotope-effect', 'display_name': 'Kinetic isotope effect', 'score': 0.9694488}, {'id': 'https://openalex.org/keywords/carbocation', 'display_name': 'Carbocation', 'score': 0.5569053}, {'id': 'https://openalex.org/keywords/transition-state', 'display_name': 'Transition state', 'score': 0.44604152}], 'concepts': [{'id': 'https://openalex.org/C69928629', 'wikidata': 'https://www.wikidata.org/wiki/Q1386472', 'display_name': 'Kinetic isotope effect', 'level': 3, 'score': 0.9694488}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.86880815}, {'id': 'https://openalex.org/C58364064', 'wikidata': 'https://www.wikidata.org/wiki/Q102296', 'display_name': 'Deuterium', 'level': 2, 'score': 0.68248427}, {'id': 'https://openalex.org/C2777961443', 'wikidata': 'https://www.wikidata.org/wiki/Q106520', 'display_name': 'Hydride', 'level': 3, 'score': 0.6775344}, {'id': 'https://openalex.org/C109057382', 'wikidata': 'https://www.wikidata.org/wiki/Q212270', 'display_name': 'Carbocation', 'level': 2, 'score': 0.5569053}, {'id': 'https://openalex.org/C147597530', 'wikidata': 'https://www.wikidata.org/wiki/Q369472', 'display_name': 'Computational chemistry', 'level': 1, 'score': 0.49903965}, {'id': 'https://openalex.org/C164304813', 'wikidata': 'https://www.wikidata.org/wiki/Q25276', 'display_name': 'Isotope', 'level': 2, 'score': 0.4800871}, {'id': 'https://openalex.org/C201194858', 'wikidata': 'https://www.wikidata.org/wiki/Q898238', 'display_name': 'Steric effects', 'level': 2, 'score': 0.47996664}, {'id': 'https://openalex.org/C135889238', 'wikidata': 'https://www.wikidata.org/wiki/Q46276', 'display_name': 'Kinetic energy', 'level': 2, 'score': 0.44695246}, {'id': 'https://openalex.org/C89031862', 'wikidata': 'https://www.wikidata.org/wiki/Q906964', 'display_name': 'Transition state', 'level': 3, 'score': 0.44604152}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.35654426}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.33576763}, {'id': 'https://openalex.org/C159467904', 'wikidata': 'https://www.wikidata.org/wiki/Q2001702', 'display_name': 'Chemical physics', 'level': 1, 'score': 0.32491744}, {'id': 'https://openalex.org/C512968161', 'wikidata': 'https://www.wikidata.org/wiki/Q556', 'display_name': 'Hydrogen', 'level': 2, 'score': 0.27991268}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.2212756}, {'id': 'https://openalex.org/C184779094', 'wikidata': 'https://www.wikidata.org/wiki/Q26383', 'display_name': 'Atomic physics', 'level': 1, 'score': 0.12877744}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.110412866}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.08986178}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.07397434}, {'id': 'https://openalex.org/C185544564', 'wikidata': 'https://www.wikidata.org/wiki/Q81197', 'display_name': 'Nuclear physics', 'level': 1, 'score': 0.06267539}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}], 'mesh': [{'descriptor_ui': 'D000438', 'descriptor_name': 'Alcohols', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': True}, {'descriptor_ui': 'D003903', 'descriptor_name': 'Deuterium', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': True}, {'descriptor_ui': 'D007554', 'descriptor_name': 'Isotopes', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': True}, {'descriptor_ui': 'D000097', 'descriptor_name': 'Acetonitriles', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': False}, {'descriptor_ui': 'D000097', 'descriptor_name': 'Acetonitriles', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D000438', 'descriptor_name': 'Alcohols', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D020134', 'descriptor_name': 'Catalytic Domain', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D039301', 'descriptor_name': 'Computers, Molecular', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D003903', 'descriptor_name': 'Deuterium', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D007554', 'descriptor_name': 'Isotopes', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D007700', 'descriptor_name': 'Kinetics', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D008956', 'descriptor_name': 'Models, Chemical', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D012996', 'descriptor_name': 'Solutions', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}], 'locations_count': 4, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.1021/jo402650a', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S205050996', 'display_name': 'The Journal of Organic Chemistry', 'issn_l': '0022-3263', 'issn': ['0022-3263', '1520-6904'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': 'publisher-specific-oa', 'license_id': 'https://openalex.org/licenses/publisher-specific-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://europepmc.org/articles/pmc3985929', 'pdf_url': 'https://europepmc.org/articles/pmc3985929?pdf=render', 'source': {'id': 'https://openalex.org/S4306400806', 'display_name': 'Europe PMC (PubMed Central)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1303153112', 'host_organization_name': 'European Bioinformatics Institute', 'host_organization_lineage': ['https://openalex.org/I1303153112'], 'host_organization_lineage_names': ['European Bioinformatics Institute'], 'type': 'repository'}, 'license': 'other-oa', 'license_id': 'https://openalex.org/licenses/other-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985929', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S2764455111', 'display_name': 'PubMed Central', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/24498946', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1021/jo402650a', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S205050996', 'display_name': 'The Journal of Organic Chemistry', 'issn_l': '0022-3263', 'issn': ['0022-3263', '1520-6904'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': 'publisher-specific-oa', 'license_id': 'https://openalex.org/licenses/publisher-specific-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [{'display_name': 'Clean water and sanitation', 'id': 'https://metadata.un.org/sdg/6', 'score': 0.58}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 47, 'referenced_works': ['https://openalex.org/W1681177208', 'https://openalex.org/W1966444654', 'https://openalex.org/W1966686825', 'https://openalex.org/W1971832507', 'https://openalex.org/W1972978945', 'https://openalex.org/W1974328999', 'https://openalex.org/W1976001978', 'https://openalex.org/W1980031829', 'https://openalex.org/W1983205652', 'https://openalex.org/W1986499322', 'https://openalex.org/W1986869433', 'https://openalex.org/W1988373345', 'https://openalex.org/W1988449405', 'https://openalex.org/W2004981069', 'https://openalex.org/W2013032090', 'https://openalex.org/W2020041009', 'https://openalex.org/W2021824819', 'https://openalex.org/W2025495414', 'https://openalex.org/W2027666203', 'https://openalex.org/W2034282744', 'https://openalex.org/W2037353343', 'https://openalex.org/W2043838469', 'https://openalex.org/W2044014214', 'https://openalex.org/W2046562899', 'https://openalex.org/W2048801950', 'https://openalex.org/W2050056843', 'https://openalex.org/W2055268267', 'https://openalex.org/W2061271735', 'https://openalex.org/W2061611283', 'https://openalex.org/W2063104454', 'https://openalex.org/W2064187591', 'https://openalex.org/W2065526049', 'https://openalex.org/W2076065258', 'https://openalex.org/W2076299995', 'https://openalex.org/W2080658778', 'https://openalex.org/W2085090540', 'https://openalex.org/W2087123471', 'https://openalex.org/W2091021757', 'https://openalex.org/W2116385702', 'https://openalex.org/W2121890116', 'https://openalex.org/W2130477943', 'https://openalex.org/W2154547861', 'https://openalex.org/W2163920704', 'https://openalex.org/W2320310083', 'https://openalex.org/W4206557276', 'https://openalex.org/W62248180', 'https://openalex.org/W951465247'], 'related_works': ['https://openalex.org/W4386022506', 'https://openalex.org/W4309953213', 'https://openalex.org/W2124869374', 'https://openalex.org/W2088834747', 'https://openalex.org/W2081392774', 'https://openalex.org/W2061113752', 'https://openalex.org/W2059598980', 'https://openalex.org/W2058423644', 'https://openalex.org/W2053059272', 'https://openalex.org/W1973503745'], 'abstract_inverted_index': {'We': [0], 'recently': [1], 'reported': [2], 'abnormal': [3], 'secondary': [4], 'deuterium': [5], 'kinetic': [6], 'isotope': [7, 65, 92, 126, 153, 163, 173], 'effects': [8], '(2°': [9], 'KIEs)': [10], 'for': [11, 98], 'hydride': [12], 'transfer': [13, 93], 'reactions': [14, 188], 'from': [15], 'alcohols': [16], 'to': [17, 32, 53, 112, 115, 148, 180], 'carbocations': [18], 'in': [19, 39, 49, 89, 132, 145, 151, 187, 190], 'acetonitrile': [20], '(Chem.': [21], 'Comm.': [22], '2012,': [23], '48,': [24], '11337).': [25], 'Experimental': [26], '2°': [27, 68, 96, 128, 162, 167, 175], 'KIE': [28], 'values': [29, 55], 'were': [30, 75, 108], 'found': [31], 'be': [33, 178, 181], 'inflated': [34], 'on': [35, 45, 67, 127, 174], 'the': [36, 40, 46, 54, 58, 73, 78, 113, 117, 135, 143, 149, 158, 161, 166, 195], '9-C': [37], 'position': [38, 48], 'xanthylium': [41], 'cation': [42], 'but': [43], 'deflated': [44], 'β-C': [47], '2-propanol': [50], 'with': [51], 'respect': [52], 'predicted': [56], 'by': [57, 77], 'semi-classical': [59], 'transition-state': [60], 'theory.': [61], 'No': [62], 'primary': [63], '(1°)': [64], 'effect': [66, 123, 170], 'KIEs': [69, 74, 97, 129, 176], 'was': [70], 'observed.': [71], 'Herein,': [72], 'replicated': [76], 'Marcus-like': [79], 'H-tunneling': [80], 'model': [81], 'that': [82, 142], 'requires': [83], 'a': [84, 90, 99], 'longer': [85], 'donor-acceptor': [86], 'distance': [87], '(DAD)': [88], 'lighter': [91], 'process.': [94], 'The': [95, 120, 169], 'range': [100], 'of': [101, 105, 124, 134, 160, 171, 202], 'potential': [102], 'tunneling-ready-states': [103], '(TRSs)': [104], 'different': [106], 'DADs': [107], 'calculated': [109], 'and': [110, 164, 184, 197], 'fitted': [111], 'experiments': [114], 'find': [116], 'TRS': [118, 139], 'structure.': [119], 'observed': [121], 'no': [122], '1°': [125, 152, 172], 'is': [130], 'explained': [131], 'terms': [133], 'less': [136], 'sterically': [137], 'hindered': [138], 'structure': [140], 'so': [141], 'change': [144, 150], 'DAD': [146], 'due': [147], 'does': [154], 'not': [155], 'significantly': [156], 'affect': [157], 'reorganization': [159], 'hence': [165], 'KIE.': [168], 'may': [177], 'expected': [179], 'more': [182], 'pronounced': [183], 'thus': [185], 'observable': [186], 'occurring': [189], 'restrictive': [191], 'environments': [192], 'such': [193], 'as': [194], 'crowded': [196], 'relatively': [198], 'rigid': [199], 'active': [200], 'site': [201], 'enzymes.': [203]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2322069559', 'counts_by_year': [{'year': 2024, 'cited_by_count': 2}, {'year': 2023, 'cited_by_count': 1}, {'year': 2021, 'cited_by_count': 1}, {'year': 2020, 'cited_by_count': 1}, {'year': 2019, 'cited_by_count': 2}, {'year': 2017, 'cited_by_count': 1}, {'year': 2016, 'cited_by_count': 1}, {'year': 2015, 'cited_by_count': 1}], 'updated_date': '2025-01-12T18:18:48.347200', 'created_date': '2016-06-24'}