Publication Information

{'id': 'https://openalex.org/W2081392774', 'doi': 'https://doi.org/10.1039/p29810000684', 'title': 'Kinetic hydrogen isotope effects in intermolecular hydride transfer from arylalkanes to 9-arylfluoren-9-yl cations', 'display_name': 'Kinetic hydrogen isotope effects in intermolecular hydride transfer from arylalkanes to 9-arylfluoren-9-yl cations', 'publication_year': 1981, 'publication_date': '1981-01-01', 'ids': {'openalex': 'https://openalex.org/W2081392774', 'doi': 'https://doi.org/10.1039/p29810000684', 'mag': '2081392774'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1039/p29810000684', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210179874', 'display_name': 'Journal of the Chemical Society. Perkin transactions II', 'issn_l': '0300-9580', 'issn': ['0300-9580', '2050-8239'], 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5059215516', 'display_name': 'Donald Bethell', 'orcid': 'https://orcid.org/0000-0002-7320-7585'}, 'institutions': [], 'countries': [], 'is_corresponding': False, 'raw_author_name': 'Donald Bethell', 'raw_affiliation_strings': [], 'affiliations': []}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5081275096', 'display_name': 'Gerard J. Hare', 'orcid': None}, 'institutions': [], 'countries': [], 'is_corresponding': False, 'raw_author_name': 'Gerard J. Hare', 'raw_affiliation_strings': [], 'affiliations': []}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5085244523', 'display_name': 'Paul A. Kearney', 'orcid': None}, 'institutions': [], 'countries': [], 'is_corresponding': False, 'raw_author_name': 'Paul A. Kearney', 'raw_affiliation_strings': [], 'affiliations': []}], 'institution_assertions': [], 'countries_distinct_count': 0, 'institutions_distinct_count': 0, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 0.711, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 7, 'citation_normalized_percentile': {'value': 0.758289, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 76, 'max': 77}, 'biblio': {'volume': None, 'issue': '4', 'first_page': '684', 'last_page': '684'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T13561', 'display_name': 'Chemical Reactions and Isotopes', 'score': 0.9996, 'subfield': {'id': 'https://openalex.org/subfields/3003', 'display_name': 'Pharmaceutical Science'}, 'field': {'id': 'https://openalex.org/fields/30', 'display_name': 'Pharmacology, Toxicology and Pharmaceutics'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, 'topics': [{'id': 'https://openalex.org/T13561', 'display_name': 'Chemical Reactions and Isotopes', 'score': 0.9996, 'subfield': {'id': 'https://openalex.org/subfields/3003', 'display_name': 'Pharmaceutical Science'}, 'field': {'id': 'https://openalex.org/fields/30', 'display_name': 'Pharmacology, Toxicology and Pharmaceutics'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, {'id': 'https://openalex.org/T12191', 'display_name': 'Chemical Reaction Mechanisms', 'score': 0.9928, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10947', 'display_name': 'Fluorine in Organic Chemistry', 'score': 0.9928, 'subfield': {'id': 'https://openalex.org/subfields/3003', 'display_name': 'Pharmaceutical Science'}, 'field': {'id': 'https://openalex.org/fields/30', 'display_name': 'Pharmacology, Toxicology and Pharmaceutics'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/kinetic-isotope-effect', 'display_name': 'Kinetic isotope effect', 'score': 0.9054123}, {'id': 'https://openalex.org/keywords/trifluoroacetic-acid', 'display_name': 'Trifluoroacetic acid', 'score': 0.55129915}], 'concepts': [{'id': 'https://openalex.org/C69928629', 'wikidata': 'https://www.wikidata.org/wiki/Q1386472', 'display_name': 'Kinetic isotope effect', 'level': 3, 'score': 0.9054123}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.8848144}, {'id': 'https://openalex.org/C2777961443', 'wikidata': 'https://www.wikidata.org/wiki/Q106520', 'display_name': 'Hydride', 'level': 3, 'score': 0.88400674}, {'id': 'https://openalex.org/C58364064', 'wikidata': 'https://www.wikidata.org/wiki/Q102296', 'display_name': 'Deuterium', 'level': 2, 'score': 0.73135173}, {'id': 'https://openalex.org/C2780112151', 'wikidata': 'https://www.wikidata.org/wiki/Q412033', 'display_name': 'Trifluoroacetic acid', 'level': 2, 'score': 0.55129915}, {'id': 'https://openalex.org/C179104552', 'wikidata': 'https://www.wikidata.org/wiki/Q11165', 'display_name': 'Inorganic chemistry', 'level': 1, 'score': 0.49277118}, {'id': 'https://openalex.org/C145148216', 'wikidata': 'https://www.wikidata.org/wiki/Q36496', 'display_name': 'Ion', 'level': 2, 'score': 0.47156593}, {'id': 'https://openalex.org/C2780178953', 'wikidata': 'https://www.wikidata.org/wiki/Q2001841', 'display_name': 'Formate', 'level': 3, 'score': 0.4698887}, {'id': 'https://openalex.org/C512968161', 'wikidata': 'https://www.wikidata.org/wiki/Q556', 'display_name': 'Hydrogen', 'level': 2, 'score': 0.45340317}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.35554412}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.34330517}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.18160981}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.087352216}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1039/p29810000684', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210179874', 'display_name': 'Journal of the Chemical Society. Perkin transactions II', 'issn_l': '0300-9580', 'issn': ['0300-9580', '2050-8239'], 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'display_name': 'Clean water and sanitation', 'score': 0.74, 'id': 'https://metadata.un.org/sdg/6'}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 0, 'referenced_works': [], 'related_works': ['https://openalex.org/W4253065726', 'https://openalex.org/W2096555896', 'https://openalex.org/W2071483687', 'https://openalex.org/W2012838653', 'https://openalex.org/W2012647383', 'https://openalex.org/W2009539630', 'https://openalex.org/W1999436281', 'https://openalex.org/W1848696798', 'https://openalex.org/W1518029896', 'https://openalex.org/W1504075764'], 'abstract_inverted_index': {'Rates': [0], 'of': [1, 7, 44, 69, 96, 102, 108, 133, 139, 142], 'hydride-ion': [2], 'transfer': [3, 79, 89, 115], 'to': [4, 77, 93, 118, 126, 136], 'a': [5, 45, 94], 'series': [6, 95, 101], '9-phenylfluoren-9-yl': [8], 'cations,': [9], 'substituted': [10], 'in': [11, 24, 55, 80], 'the': [12, 48, 53, 59, 74, 134, 137, 140], 'phenyl': [13], 'group,': [14], 'from': [15, 90, 116], 'triphenylmethane': [16], 'and': [17, 41, 61, 121], '4,4′-dimethoxydiphenylmethane': [18, 117], 'have': [19, 37, 123], 'been': [20, 38, 106, 124], 'measured': [21, 39], 'at': [22], '30°C': [23], 'trifluoroacetic': [25], 'acid': [26], 'solution': [27], 'containing': [28], '6%': [29], 'v/v': [30], 'acetic': [31], 'acid.': [32], 'Deuterium': [33], 'kinetic': [34, 110], 'isotope': [35, 111, 129], 'effects': [36, 112], 'directly': [40], 'show': [42], 'evidence': [43], 'broad': [46], 'maximum,': [47], 'peak': [49], 'value': [50], 'occurring': [51], 'when': [52], 'difference': [54], 'pKR+': [56], 'values': [57], 'between': [58], 'product': [60], 'reactant': [62], 'carbenium': [63], 'ions': [64], 'is': [65, 83, 145], 'around': [66], 'zero.': [67], 'Application': [68], 'Marcus': [70], 'theory': [71], 'suggests': [72], 'that': [73], 'intrinsic': [75], 'barrier': [76], 'hydride': [78, 88, 114], 'these': [81, 122], 'systems': [82], 'substantially': [84], 'larger': [85], 'than': [86], 'for': [87], 'formate': [91], 'ion': [92], 'triphenylmethyl': [97], 'cations.': [98], 'A': [99], 'limited': [100], 'measurements': [103], 'has': [104], 'also': [105], 'made': [107], 'tritium': [109], 'on': [113], '9-arylfluoren-9-yl': [119], 'cations': [120], 'used': [125], 'derive': [127], 'deuterium–tritium': [128], 'effects.': [130], 'The': [131], 'relevance': [132], 'results': [135], 'question': [138], 'origin': [141], 'isotope-effect': [143], 'maxima': [144], 'briefly': [146], 'discussed.': [147]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2081392774', 'counts_by_year': [{'year': 2016, 'cited_by_count': 1}], 'updated_date': '2024-12-29T19:41:04.079039', 'created_date': '2016-06-24'}