Publication Information

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282, 328, 333, 414, 421, 452, 466, 481, 521, 530, 554, 561], 'its': [7, 408, 453, 517, 544], 'metal-free': [8, 143], 'base': [9, 100, 512, 566], 'yielded': [10], 'sta\xad': [11], 'ble': [12], 'cation': [13, 59, 109], 'radicals.': [14], 'Electron': [15], 'spin': [16, 40, 74, 129, 211, 318, 358], 'resonance': [17, 75, 130, 212, 273], 'hyperfine': [18, 375, 384, 448], 'splittings': [19], 'were': [20], 'assigned': [21], 'by': [22, 391, 488], 'selective': [23, 392], 'deuterations.': [24], 'These': [25], 'results': [26, 286], 'indicate': [27], 'that': [28, 71, 142, 296, 386, 432, 462], 'the': [29, 32, 36, 52, 72, 78, 86, 96, 107, 196, 202, 206, 220, 248, 252, 261, 265, 269, 290, 297, 315, 323, 398, 442, 473, 489, 510, 527, 534, 541], 'protons': [30], 'saturated': [33], 'rings': [34], 'bacteriochlorins': [37, 56, 103], 'carry': [38], 'large': [39], 'densities,': [41], 'in': [42, 49, 93, 106, 146, 170, 179, 280, 283, 397, 498, 526, 570], 'accord': [43], 'with': [44, 61, 233, 417], 'molecular': [45], 'orbital': [46], 'calculations.': [47], 'Comparison': [48], 'vitro': [50, 281], 'optical': [53, 475, 499, 553], 'spectra': [54], 'their': [58, 137, 436], 'radicals': [60, 97, 110, 192, 222], 'those': [62, 135, 418, 547], 'bacteriochlorophyll': [64, 121, 177], 'show': [65], 'close': [66], 'cor\xad': [67], 'respondence': [68], 'suggest': [70, 431], 'electron': [73, 128, 164, 198, 210, 357, 443], 'data': [76, 556], 'from': [77, 166, 176, 326, 331, 446], 'former': [79], 'may': [80], 'also': [81, 457], 'prove': [82], 'a': [83, 168, 301, 402, 459], 'guide': [84], 'to': [85, 134, 278, 322, 363, 394, 430, 546, 573], 'bio\xad': [87], 'logical': [88], 'molecule.': [89, 208], 'The': [90, 140, 150, 183, 226, 285], 'surprising': [91], 'similarity': [92, 542], 'properties': [94, 131, 188, 438, 545], 'between': [95, 435, 478], 'free': [99, 118, 490, 511, 565], 'is': [104, 148, 199, 300, 401, 439, 516], 'maintained': [105], 'chlorophylls:': [108], 'bac\xad': [112, 559], 'teriopheophytin': [113], 'methyl': [115, 123, 346, 562, 568], 'pheophorbide': [116, 563], '(the': [117, 564], 'bases': [119, 491], 'chlorophyllide,': [124], 're\xad': [125], 'spectively)': [126], 'exhibit': [127, 187, 468], 'simi\xad': [132], 'lar': [133], 'magnesium-containing': [138], 'derivatives.': [139], 'possibility': [141], 'chlorophylls': [144, 162, 186], 'participate': [145], 'photosynthesis': [147], 'discussed.': [149], 'primary': [151, 535], 'photochemical': [152], 'step': [153, 537], 'intact': [155], 'photosynthesizing': [156], 'systems,': [157], 'extracted': [158], 'reaction': [159, 293], 'centers,': [160], 'involves': [163], 'ejection': [165], 'chlorophyll': [167, 221], '(ChI)': [169], 'green': [171], 'plants': [172], 'algae': [174], '(BChl)': [178], 'purple': [180], 'bacteria': [181], '(1-9).': [182], 'resultant': [184], 'oxidized': [185, 253, 335], 'characteristic': [189], 'r-cation': [191], '(7,': [193], '8),': [194], 'i.e.,': [195], 'unpaired': [197], 'delocalized': [200], 'over': [201], 'r': [203], 'system': [204], 'aromatic': [207], 'No': [209], '(ESR)': [213], 'hyperfinestructure': [214], 'has': [215, 275, 522], 'ever': [216], 'been': [217, 276, 524], 'resolved': [218], 'for': [219, 461], '(2,': [223, 235], '7,': [224], '10--13).': [225], 'singlet': [227, 368], 'ESR': [228, 324, 369, 447, 531, 555], 'signals': [229], 'observed': [230, 477], 'narrow': [231], 'significantly': [232], 'deuterochlorophyll': [234], '7,12)': [236], 'broaden': [238], 'upon': [239], '13C': [240], 'sub\xad': [241], 'stitution': [242], '(11,': [243], '12),': [244], 'which,': [245], 'while': [246], 'confirming': [247], 'r-radical': [249], 'nature': [250], 'molecules,': [254], 'yields': [255, 383], 'little': [256, 496], 'additional': [257], 'in\xad': [258], 'formation': [259], 'about': [260], 'spin-density': [262], 'distribution': [263], 'or': [264, 345, 372, 486], 'reactive': [266], 'sites': [267, 316], 'chlorophylls.': [270], 'Electron-nuclear': [271], 'double': [272], '(14)': [274], 'applied': [277], 'bacteriochlorophylls': [279], 'vivo.': [284], '(15,': [287], '16)': [288], 'support': [289], 'hypothesis': [291], 'regarding': [292], 'centers': [294, 502], '(7),': [295], 'photoactivated': [298], 'BChl': [299, 400, 413, 415, 465], 'bridged': [302], 'dimeric': [303], 'cation,': [304], '(BChlh': [305], "+',": [306, 416], 'but': [307], 'they': [308], 'do': [309], 'not': [310], 'yield': [311], 'sufficient': [312, 425], 'information': [313], 'to.specify': [314], 'delocalization.': [319], 'In': [320], 'contrast': [321], 'singlets': [325], "Chl+'": [327], "BChl+'": [329], '(or': [330], "Chb+'": [332], "BChb+'),": [334], 'tetraphenyl-': [337], 'Abbreviations:': [338], 'Chl,': [339], 'chlorophyll;': [340], 'BChl,': [341], 'bacteriochlorophyll;': [342], 'Ph,': [343], 'pheophytin': [344], 'pheophorbide;': [347], 'BPh,': [348], 'bacteriopheophy\xad': [349], 'tin;': [350], 'TPBC,': [351], 'tetraphenylbacteriochlorin;': [352], 'TPP,': [353], 'tetraphenylpor\xad': [354], 'phyrin;': [355], 'ESR,': [356], 'resonance;': [359], 'll.H,': [360], 'linewidth,': [361], 'peak': [362], 'peak,': [364], 'first': [366], 'derivative': [367], 'signal;': [370], 'an.': [371], 'An.,': [373], 'proton': [374], 'splitting': [376], 'constant': [377], 'at': [378], 'position-X.': [379], '994': [380], 'bacteriochlorin': [381, 404, 467], "(ZnTPBC+')": [382], 'structure': [385, 449], 'can': [387], 'be': [388], 'readily': [389], 'assigned,': [390], 'deuterations,': [393], 'specific': [395], 'positions': [396], 'radical.': [399], 'modified': [403], '(tetrahydroporphyrin);': [405], 'comparison': [406], 'electronic': [409, 437], 'spectra,': [410], 'both': [411], 'as': [412], 'ZnTPBC': [420], 'Zn\xad': [422], "TPBC+'": [423], 'shows': [424], 'correspondence': [426], 'spectral': [428], 'features': [429], 'an': [433, 469, 571], 'analogy': [434], 'valid.': [440], 'Hence,': [441], 'delocalization': [444], 'determined': [445], "ZnTPBC+'": [451], 'deuterated': [454], 'derivatives': [455], 'should': [456], 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