Title: Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene
Abstract:The intermolecular-intramolecular rate constants derived from the thermolysis and photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gave an excellent Arrhenius plot; an activation energy...The intermolecular-intramolecular rate constants derived from the thermolysis and photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gave an excellent Arrhenius plot; an activation energy of 6.4 kcal mol–1(26.8 kJ mol–1) was obtained for the 1,2-H migration in benzylchlorocarbene.Read More
Publication Year: 1985
Publication Date: 1985-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 21
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