Title: Adaptable Hetero Diels-Alder Networks for Fast Self-Healing under Mild Conditions
Abstract: Advanced MaterialsVolume 26, Issue 21 p. 3561-3566 Communication Adaptable Hetero Diels–Alder Networks for Fast Self-Healing under Mild Conditions Kim K. Oehlenschlaeger, Kim K. Oehlenschlaeger Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany, und Institut für Biologische Grenzflächen, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanySearch for more papers by this authorJan O. Mueller, Jan O. Mueller Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany, und Institut für Biologische Grenzflächen, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanySearch for more papers by this authorJosef Brandt, Josef Brandt Leibniz-Institut für Polymerforschung Dresden, Hohe Strasse 6, 01069 Dresden, Germany, Universität Dresden, 01062 Dresden, GermanySearch for more papers by this authorStefan Hilf, Stefan Hilf Evonik Industries AG, Rodenbacher Chaussee 4, 63457 Hanau-Wolfgang, GermanySearch for more papers by this authorAlbena Lederer, Albena Lederer Leibniz-Institut für Polymerforschung Dresden, Hohe Strasse 6, 01069 Dresden, Germany, Universität Dresden, 01062 Dresden, GermanySearch for more papers by this authorManfred Wilhelm, Manfred Wilhelm Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, GermanySearch for more papers by this authorRobert Graf, Robert Graf Max-Planck Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, GermanySearch for more papers by this authorMichelle L. Coote, Michelle L. Coote ARC Centre of Excellence for Free-Radical, Chemistry and Biotechnology, Research School of Chemistry, Australian National University, Canberra, ACT 0200 AustraliaSearch for more papers by this authorFriedrich G. Schmidt, Friedrich G. Schmidt Evonik Industries AG Paul-Baumann-Strasse 1, 45764 Marl, GermanySearch for more papers by this authorChristopher Barner-Kowollik, Corresponding Author Christopher Barner-Kowollik Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany, und Institut für Biologische Grenzflächen, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyE-Mail: [email protected]Search for more papers by this author Kim K. Oehlenschlaeger, Kim K. Oehlenschlaeger Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany, und Institut für Biologische Grenzflächen, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanySearch for more papers by this authorJan O. Mueller, Jan O. Mueller Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany, und Institut für Biologische Grenzflächen, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanySearch for more papers by this authorJosef Brandt, Josef Brandt Leibniz-Institut für Polymerforschung Dresden, Hohe Strasse 6, 01069 Dresden, Germany, Universität Dresden, 01062 Dresden, GermanySearch for more papers by this authorStefan Hilf, Stefan Hilf Evonik Industries AG, Rodenbacher Chaussee 4, 63457 Hanau-Wolfgang, GermanySearch for more papers by this authorAlbena Lederer, Albena Lederer Leibniz-Institut für Polymerforschung Dresden, Hohe Strasse 6, 01069 Dresden, Germany, Universität Dresden, 01062 Dresden, GermanySearch for more papers by this authorManfred Wilhelm, Manfred Wilhelm Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, GermanySearch for more papers by this authorRobert Graf, Robert Graf Max-Planck Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, GermanySearch for more papers by this authorMichelle L. Coote, Michelle L. Coote ARC Centre of Excellence for Free-Radical, Chemistry and Biotechnology, Research School of Chemistry, Australian National University, Canberra, ACT 0200 AustraliaSearch for more papers by this authorFriedrich G. Schmidt, Friedrich G. Schmidt Evonik Industries AG Paul-Baumann-Strasse 1, 45764 Marl, GermanySearch for more papers by this authorChristopher Barner-Kowollik, Corresponding Author Christopher Barner-Kowollik Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany, und Institut für Biologische Grenzflächen, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyE-Mail: [email protected]Search for more papers by this author First published: 21 March 2014 https://doi.org/10.1002/adma.201306258Citations: 224Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract A novel adaptable network based on the reversible hetero Diels–Alder reaction of a cyanodithioester and cyclopentadiene is presented. Reversible between 50–120 °C, the adjustable and self-healing features of the network are evidenced via temperature dependent rheology experiments and repetitive tensile tests whereas the network's chemical structure is explored by temperature dependent 1H MAS-NMR spectroscopy. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. 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Instrum. 1965, 36, 1230. Citing Literature Volume26, Issue21June 4, 2014Pages 3561-3566 ReferencesRelatedInformation
Publication Year: 2014
Publication Date: 2014-03-21
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 259
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