Publication Information

{'id': 'https://openalex.org/W1975751386', 'doi': 'https://doi.org/10.1063/1.1672879', 'title': 'Oxidation of 4a,4<i>b</i>-Dihydrophenanthrene. IV. Kinetic Isotope Effect of Deuterium in the Propagation and the Initiation Steps', 'display_name': 'Oxidation of 4a,4<i>b</i>-Dihydrophenanthrene. IV. Kinetic Isotope Effect of Deuterium in the Propagation and the Initiation Steps', 'publication_year': 1970, 'publication_date': '1970-06-01', 'ids': {'openalex': 'https://openalex.org/W1975751386', 'doi': 'https://doi.org/10.1063/1.1672879', 'mag': '1975751386'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1063/1.1672879', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S77047749', 'display_name': 'The Journal of Chemical Physics', 'issn_l': '0021-9606', 'issn': ['0021-9606', '1089-7690', '1520-9032'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320257', 'host_organization_name': 'American Institute of Physics', 'host_organization_lineage': ['https://openalex.org/P4310320257'], 'host_organization_lineage_names': ['American Institute of Physics'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5002465977', 'display_name': 'A. Bromberg', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I53964585', 'display_name': 'Weizmann Institute of Science', 'ror': 'https://ror.org/0316ej306', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I53964585']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'A. Bromberg', 'raw_affiliation_strings': ['Department of Chemistry and Department of Chemical Physics, The Weizmann Institute of Science, Rehovot, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Department of Chemical Physics, The Weizmann Institute of Science, Rehovot, Israel', 'institution_ids': ['https://openalex.org/I53964585']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5008758542', 'display_name': 'K. A. Muszkat', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I53964585', 'display_name': 'Weizmann Institute of Science', 'ror': 'https://ror.org/0316ej306', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I53964585']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'K. A. Muszkat', 'raw_affiliation_strings': ['Department of Chemistry and Department of Chemical Physics, The Weizmann Institute of Science, Rehovot, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Department of Chemical Physics, The Weizmann Institute of Science, Rehovot, Israel', 'institution_ids': ['https://openalex.org/I53964585']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5088665303', 'display_name': 'Arieh Warshel', 'orcid': 'https://orcid.org/0000-0001-7971-5401'}, 'institutions': [{'id': 'https://openalex.org/I53964585', 'display_name': 'Weizmann Institute of Science', 'ror': 'https://ror.org/0316ej306', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I53964585']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'A. Warshel', 'raw_affiliation_strings': ['Department of Chemistry and Department of Chemical Physics, The Weizmann Institute of Science, Rehovot, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Department of Chemical Physics, The Weizmann Institute of Science, Rehovot, Israel', 'institution_ids': ['https://openalex.org/I53964585']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 3500, 'currency': 'USD', 'value_usd': 3500, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 0.686, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 11, 'citation_normalized_percentile': {'value': 0.678499, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 85, 'max': 86}, 'biblio': {'volume': '52', 'issue': '11', 'first_page': '5952', 'last_page': '5959'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T12967', 'display_name': 'Molecular Spectroscopy and Structure', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1607', 'display_name': 'Spectroscopy'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T12967', 'display_name': 'Molecular Spectroscopy and Structure', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1607', 'display_name': 'Spectroscopy'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10002', 'display_name': 'Advanced Chemical Physics Studies', 'score': 0.9994, 'subfield': {'id': 'https://openalex.org/subfields/3107', 'display_name': 'Atomic and Molecular Physics, and Optics'}, 'field': {'id': 'https://openalex.org/fields/31', 'display_name': 'Physics and Astronomy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T14068', 'display_name': 'Organic and Inorganic Chemical Reactions', 'score': 0.9979, 'subfield': {'id': 'https://openalex.org/subfields/1607', 'display_name': 'Spectroscopy'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/kinetic-isotope-effect', 'display_name': 'Kinetic isotope effect', 'score': 0.97162795}, {'id': 'https://openalex.org/keywords/two-step', 'display_name': 'Two step', 'score': 0.51433957}], 'concepts': [{'id': 'https://openalex.org/C69928629', 'wikidata': 'https://www.wikidata.org/wiki/Q1386472', 'display_name': 'Kinetic isotope effect', 'level': 3, 'score': 0.97162795}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.74999654}, {'id': 'https://openalex.org/C135889238', 'wikidata': 'https://www.wikidata.org/wiki/Q46276', 'display_name': 'Kinetic energy', 'level': 2, 'score': 0.7427914}, {'id': 'https://openalex.org/C58364064', 'wikidata': 'https://www.wikidata.org/wiki/Q102296', 'display_name': 'Deuterium', 'level': 2, 'score': 0.7384319}, {'id': 'https://openalex.org/C164304813', 'wikidata': 'https://www.wikidata.org/wiki/Q25276', 'display_name': 'Isotope', 'level': 2, 'score': 0.6279777}, {'id': 'https://openalex.org/C120398109', 'wikidata': 'https://www.wikidata.org/wiki/Q175751', 'display_name': 'Quantum tunnelling', 'level': 2, 'score': 0.5882852}, {'id': 'https://openalex.org/C3019136120', 'wikidata': 'https://www.wikidata.org/wiki/Q2462428', 'display_name': 'Two step', 'level': 2, 'score': 0.51433957}, {'id': 'https://openalex.org/C147597530', 'wikidata': 'https://www.wikidata.org/wiki/Q369472', 'display_name': 'Computational chemistry', 'level': 1, 'score': 0.44648388}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.34342647}, {'id': 'https://openalex.org/C184779094', 'wikidata': 'https://www.wikidata.org/wiki/Q26383', 'display_name': 'Atomic physics', 'level': 1, 'score': 0.14784259}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.10194859}, {'id': 'https://openalex.org/C185544564', 'wikidata': 'https://www.wikidata.org/wiki/Q81197', 'display_name': 'Nuclear physics', 'level': 1, 'score': 0.10089895}, {'id': 'https://openalex.org/C21951064', 'wikidata': 'https://www.wikidata.org/wiki/Q899212', 'display_name': 'Combinatorial chemistry', 'level': 1, 'score': 0.06677315}, {'id': 'https://openalex.org/C26873012', 'wikidata': 'https://www.wikidata.org/wiki/Q214781', 'display_name': 'Condensed matter physics', 'level': 1, 'score': 0.061756253}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0588558}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1063/1.1672879', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S77047749', 'display_name': 'The Journal of Chemical Physics', 'issn_l': '0021-9606', 'issn': ['0021-9606', '1089-7690', '1520-9032'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320257', 'host_organization_name': 'American Institute of Physics', 'host_organization_lineage': ['https://openalex.org/P4310320257'], 'host_organization_lineage_names': ['American Institute of Physics'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'display_name': 'Clean water and sanitation', 'score': 0.75, 'id': 'https://metadata.un.org/sdg/6'}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 23, 'referenced_works': ['https://openalex.org/W1964431505', 'https://openalex.org/W1982560722', 'https://openalex.org/W1984722979', 'https://openalex.org/W2001441871', 'https://openalex.org/W2005842837', 'https://openalex.org/W2013409872', 'https://openalex.org/W2022514168', 'https://openalex.org/W2024717662', 'https://openalex.org/W2025466482', 'https://openalex.org/W2035196826', 'https://openalex.org/W2045292764', 'https://openalex.org/W2047269263', 'https://openalex.org/W2051438753', 'https://openalex.org/W2053259695', 'https://openalex.org/W2055811531', 'https://openalex.org/W2063887965', 'https://openalex.org/W2066677535', 'https://openalex.org/W2067031587', 'https://openalex.org/W2095032213', 'https://openalex.org/W2317677004', 'https://openalex.org/W2328586413', 'https://openalex.org/W4251299242', 'https://openalex.org/W4362197236'], 'related_works': ['https://openalex.org/W4253065726', 'https://openalex.org/W2096555896', 'https://openalex.org/W2071483687', 'https://openalex.org/W2012838653', 'https://openalex.org/W2012647383', 'https://openalex.org/W2009539630', 'https://openalex.org/W1999436281', 'https://openalex.org/W1848696798', 'https://openalex.org/W1518029896', 'https://openalex.org/W1504075764'], 'abstract_inverted_index': {'A': [0], 'kinetic': [1, 25, 116, 132], 'isotope': [2, 26, 51, 88, 117, 133], 'effect': [3, 27, 52, 89, 118, 134, 197], 'was': [4], 'found': [5], 'in': [6, 102, 111, 126, 141, 151, 177, 191], 'one': [7], 'of': [8, 12, 15, 53, 59, 71, 77, 86, 100, 158], 'the': [9, 13, 24, 42, 54, 60, 69, 84, 87, 93, 97, 103, 112, 115, 127, 131, 142, 148, 152, 156, 159, 178, 181, 198], 'propagation': [10, 113], 'steps': [11], 'reaction': [14], 'perdeutero-4a,4b-dihydrophenanthrene': [16], '(PH2)': [17], 'with': [18, 193], 'O2.': [19], 'In': [20], 'this': [21, 48], 'step,': [22, 114], 'PH2+HO2·→PH·+H2O2,': [23], 'is': [28, 79, 108, 119, 135, 164, 172, 183, 188], '7.2': [29], 'at': [30, 35], '−': [31, 36], '10°C': [32], 'and': [33, 91, 161], '9.9': [34], '31°C.': [37], 'The': [38, 57, 145], 'theoretical': [39, 66], 'calculation': [40], 'by': [41], 'previously': [43], 'described': [44], 'method': [45], 'predicts': [46], 'for': [47, 68, 155, 168], 'step': [49, 154, 180], 'an': [50], 'correct': [55], 'magnitude.': [56], 'success': [58], 'same': [61], 'method,': [62], 'using': [63], 'a': [64, 80, 194], 'similar': [65], 'model,': [67], 'treatment': [70], 'reactions': [72, 169, 192], 'involving': [73, 170], 'widely': [74], 'different': [75], 'extents': [76], 'tunneling': [78, 101, 107, 171, 196], 'good': [81], 'indication': [82], 'to': [83, 123, 139, 185], 'validity': [85], 'calculations': [90], 'supports': [92], 'previous': [94], 'conclusions': [95], 'about': [96], 'exceptional': [98], 'importance': [99], 'initiation': [104, 128, 143, 153, 179], 'step.': [105, 129, 144], 'As': [106], 'relatively': [109], 'unimportant': [110], 'markedly': [120], 'reduced': [121, 137], 'compared': [122, 138], 'its': [124], 'value': [125], 'Hence,': [130], 'significantly': [136], 'that': [140, 190], 'ratio': [146, 182, 199], 'between': [147], 'pre-exponential': [149], 'factors': [150], 'oxidation': [157], 'perhydro': [160], 'perdeutero': [162], 'compounds': [163], 'discussed.': [165], "Bell's": [166], 'criterion': [167], 'AD': [173, 200], '/': [174, 201], 'AH≫1,': [175], 'while': [176], 'close': [184], 'unity.': [186, 215], 'It': [187], 'concluded': [189], 'significant': [195], 'AH': [202], 'may': [203], 'vary': [204], 'within': [205], 'limits,': [206], 'being': [207], 'less': [208], 'than,': [209], 'equal': [210], 'to,': [211], 'or': [212], 'greater': [213], 'than': [214]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1975751386', 'counts_by_year': [{'year': 2018, 'cited_by_count': 1}], 'updated_date': '2024-12-12T16:21:19.079200', 'created_date': '2016-06-24'}