Title: Nucleophilic Addition of Samarium Enolates to Imines
Abstract:This paper reports an addition of samarium enolates derived from esters and amides to imines as an alternative to conventional metal enolate addition. The corresponding β-amino esters and amides were ...This paper reports an addition of samarium enolates derived from esters and amides to imines as an alternative to conventional metal enolate addition. The corresponding β-amino esters and amides were obtained in good to high yields. Furthermore, an enantiopure 3,4-diamino ester could be obtained from the addition of samarium enolate to enantiopure imine 1 with very high diastereoselectivity.Read More
Publication Year: 2009
Publication Date: 2009-08-21
Language: en
Type: article
Indexed In: ['crossref']
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