Synthesis of an enantiopure scorpionate ligand by a nucleophilic addition to a ketenimine and a zinc initiator for the isoselective ROP of <i>rac</i>-lactide

Name: Work Video:
Duration: 3 min 30 s
Description: The first example of nucleophilic addition of an organolithium to a ketenimine to prepare an enantiopure NNN-heteroscorpionate ligand is reported. Its utility to induce chirality is verified <italic>via</italic> preparation of two new zinc complexes, producing highly isotactic poly(lactide)s.
Manuel Honrado; Sonia Sobrino; Juan Fernández‐Baeza; Luis F. Sánchez‐Barba; Andrés Garcés; Agustı́n Lara-Sánchez; Ana M. Rodrı́guez
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