Title: Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Metal-organic Coordination Polymer with Supramolecular Structure: [Cd_2(dpphen)_2(BDC)_(0.5)Cl_3]_n
Abstract: A novel metal-organic coordination polymer [Cd2(dpphen)2(BDC)0.5Cl3]n (dpphen = 4,7-diphenyl-1,10-phenanthroline, BDC = terephthalate) 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The complex crystallizes in triclinic, space group P1 with a = 9.981(5), b = 10.436(5), c = 21.104(10) , α = 94.640(7), β = 103.160(7), γ = 92.958(8)o, V = 2127.8(17) 3, C52H34Cd2Cl3N4O2, Mr = 1077.98, Dc = 1.682 g/cm3, μ(MoKα) = 1.237 mm-1, F(000) = 1074, Z = 2, the final R = 0.0314 and wR = 0.0757 for 7358 observed reflections (I 2σ(I)). Furthermore, compound 1 shows blue photoluminescent property at room temperature.
Publication Year: 2007
Publication Date: 2007-01-01
Language: en
Type: article
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