α-Diazo-λ<sup>3</sup>-iodanes and α-diazo sulfonium salts: the umpolung of diazo compounds

Name: Work Video:
Duration: 3 min 30 s
Description: This article reviews the strategies available to achieve the umpolung of diazocompounds and the synthetic applications of such compounds.
Sven Timmann; Manuel Alcarazo
{'id': 'https://openalex.org/W4379508247', 'doi': 'https://doi.org/10.1039/d3cc01620j', 'title': 'α-Diazo-λ<sup>3</sup>-iodanes and α-diazo sulfonium salts: the umpolung of diazo compounds', 'display_name': 'α-Diazo-λ<sup>3</sup>-iodanes and α-diazo sulfonium salts: the umpolung of diazo compounds', 'publication_year': 2023, 'publication_date': '2023-01-01', 'ids': {'openalex': 'https://openalex.org/W4379508247', 'doi': 'https://doi.org/10.1039/d3cc01620j', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/37278355'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1039/d3cc01620j', 'pdf_url': 'https://pubs.rsc.org/en/content/articlepdf/2023/cc/d3cc01620j', 'source': {'id': 'https://openalex.org/S152760256', 'display_name': 'Chemical Communications', 'issn_l': '1359-7345', 'issn': ['1359-7345', '1364-548X'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': 'cc-by-nc', 'license_id': 'https://openalex.org/licenses/cc-by-nc', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'review', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': True, 'oa_status': 'hybrid', 'oa_url': 'https://pubs.rsc.org/en/content/articlepdf/2023/cc/d3cc01620j', 'any_repository_has_fulltext': True}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5092095974', 'display_name': 'Sven Timmann', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I74656192', 'display_name': 'University of Göttingen', 'ror': 'https://ror.org/01y9bpm73', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I74656192']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Sven Timmann', 'raw_affiliation_strings': ['Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen Tammannstr. 2, 37077 Göttingen, Germany'], 'affiliations': [{'raw_affiliation_string': 'Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen Tammannstr. 2, 37077 Göttingen, Germany', 'institution_ids': ['https://openalex.org/I74656192']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5058517447', 'display_name': 'Manuel Alcarazo', 'orcid': 'https://orcid.org/0000-0002-5491-5682'}, 'institutions': [{'id': 'https://openalex.org/I74656192', 'display_name': 'University of Göttingen', 'ror': 'https://ror.org/01y9bpm73', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I74656192']}], 'countries': ['DE'], 'is_corresponding': True, 'raw_author_name': 'Manuel Alcarazo', 'raw_affiliation_strings': ['Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen Tammannstr. 2, 37077 Göttingen, Germany'], 'affiliations': [{'raw_affiliation_string': 'Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen Tammannstr. 2, 37077 Göttingen, Germany', 'institution_ids': ['https://openalex.org/I74656192']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': ['https://openalex.org/A5058517447'], 'corresponding_institution_ids': ['https://openalex.org/I74656192'], 'apc_list': None, 'apc_paid': None, 'fwci': 1.002, 'has_fulltext': True, 'fulltext_origin': 'pdf', 'cited_by_count': 12, 'citation_normalized_percentile': {'value': 0.997114, 'is_in_top_1_percent': True, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 96, 'max': 97}, 'biblio': {'volume': '59', 'issue': '52', 'first_page': '8032', 'last_page': '8042'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11611', 'display_name': 'Cyclopropane Reaction Mechanisms', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11611', 'display_name': 'Cyclopropane Reaction Mechanisms', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10354', 'display_name': 'Catalytic C–H Functionalization Methods', 'score': 0.9954, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T12251', 'display_name': 'Synthesis and Catalytic Reactions', 'score': 0.9947, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/umpolung', 'display_name': 'Umpolung', 'score': 0.9664016}, {'id': 'https://openalex.org/keywords/sulfonium', 'display_name': 'Sulfonium', 'score': 0.9403527}], 'concepts': [{'id': 'https://openalex.org/C2776904781', 'wikidata': 'https://www.wikidata.org/wiki/Q424424', 'display_name': 'Diazo', 'level': 2, 'score': 0.9859376}, {'id': 'https://openalex.org/C76164948', 'wikidata': 'https://www.wikidata.org/wiki/Q904718', 'display_name': 'Umpolung', 'level': 4, 'score': 0.9664016}, {'id': 'https://openalex.org/C2777040163', 'wikidata': 'https://www.wikidata.org/wiki/Q423240', 'display_name': 'Sulfonium', 'level': 3, 'score': 0.9403527}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.5048007}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.41629508}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.043987274}, {'id': 'https://openalex.org/C2776371256', 'wikidata': 'https://www.wikidata.org/wiki/Q12370', 'display_name': 'Salt (chemistry)', 'level': 2, 'score': 0.0}, {'id': 'https://openalex.org/C178907741', 'wikidata': 'https://www.wikidata.org/wiki/Q745930', 'display_name': 'Nucleophile', 'level': 3, 'score': 0.0}], 'mesh': [], 'locations_count': 4, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.1039/d3cc01620j', 'pdf_url': 'https://pubs.rsc.org/en/content/articlepdf/2023/cc/d3cc01620j', 'source': {'id': 'https://openalex.org/S152760256', 'display_name': 'Chemical Communications', 'issn_l': '1359-7345', 'issn': ['1359-7345', '1364-548X'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': 'cc-by-nc', 'license_id': 'https://openalex.org/licenses/cc-by-nc', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://resolver.sub.uni-goettingen.de/purl?gro-2/129126', 'pdf_url': 'https://publications.goettingen-research-online.de/bitstream/2/129126/1/document.pdf', 'source': {'id': 'https://openalex.org/S4306401634', 'display_name': 'GoeScholar  The Publication Server of the Georg-August-Universität Göttingen (Georg-August-Universität Göttingen)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I4210122495', 'host_organization_name': 'Asklepios Klinik St. Georg', 'host_organization_lineage': ['https://openalex.org/I4210122495'], 'host_organization_lineage_names': ['Asklepios Klinik St. Georg'], 'type': 'repository'}, 'license': 'cc-by-nc', 'license_id': 'https://openalex.org/licenses/cc-by-nc', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10297868', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S2764455111', 'display_name': 'PubMed Central', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/37278355', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1039/d3cc01620j', 'pdf_url': 'https://pubs.rsc.org/en/content/articlepdf/2023/cc/d3cc01620j', 'source': {'id': 'https://openalex.org/S152760256', 'display_name': 'Chemical Communications', 'issn_l': '1359-7345', 'issn': ['1359-7345', '1364-548X'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': 'cc-by-nc', 'license_id': 'https://openalex.org/licenses/cc-by-nc', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [], 'grants': [{'funder': 'https://openalex.org/F4320321870', 'funder_display_name': 'Georg-August-Universität Göttingen', 'award_id': None}, {'funder': 'https://openalex.org/F4320338335', 'funder_display_name': 'H2020 European Research Council', 'award_id': 'ERC CoG 771295'}], 'datasets': [], 'versions': [], 'referenced_works_count': 73, 'referenced_works': ['https://openalex.org/W1148208603', 'https://openalex.org/W1964284609', 'https://openalex.org/W1969802834', 'https://openalex.org/W1976507668', 'https://openalex.org/W1976801308', 'https://openalex.org/W1981024714', 'https://openalex.org/W1984232099', 'https://openalex.org/W1988091937', 'https://openalex.org/W1992480888', 'https://openalex.org/W1995926560', 'https://openalex.org/W1996162362', 'https://openalex.org/W2008637485', 'https://openalex.org/W2013081608', 'https://openalex.org/W2016808634', 'https://openalex.org/W2025097578', 'https://openalex.org/W2029617469', 'https://openalex.org/W2032527209', 'https://openalex.org/W2051778076', 'https://openalex.org/W2055427088', 'https://openalex.org/W2074856009', 'https://openalex.org/W2075029904', 'https://openalex.org/W2080234953', 'https://openalex.org/W2119547517', 'https://openalex.org/W2137041649', 'https://openalex.org/W2143981217', 'https://openalex.org/W2152029656', 'https://openalex.org/W2322231982', 'https://openalex.org/W2327703479', 'https://openalex.org/W2334919103', 'https://openalex.org/W2465690517', 'https://openalex.org/W2593772636', 'https://openalex.org/W2785508050', 'https://openalex.org/W2883327144', 'https://openalex.org/W2886724778', 'https://openalex.org/W2891403265', 'https://openalex.org/W2896521341', 'https://openalex.org/W2939595671', 'https://openalex.org/W2946331747', 'https://openalex.org/W2949713047', 'https://openalex.org/W2950190566', 'https://openalex.org/W2951346394', 'https://openalex.org/W2952752375', 'https://openalex.org/W2956147480', 'https://openalex.org/W2972373562', 'https://openalex.org/W2985378770', 'https://openalex.org/W2987917511', 'https://openalex.org/W2991636900', 'https://openalex.org/W2995044761', 'https://openalex.org/W3009259094', 'https://openalex.org/W3017332432', 'https://openalex.org/W3020906212', 'https://openalex.org/W3106972623', 'https://openalex.org/W3110512703', 'https://openalex.org/W3114241796', 'https://openalex.org/W3129550611', 'https://openalex.org/W3135712912', 'https://openalex.org/W3156054564', 'https://openalex.org/W3159998786', 'https://openalex.org/W3217520505', 'https://openalex.org/W4214917715', 'https://openalex.org/W4220805830', 'https://openalex.org/W4220853291', 'https://openalex.org/W4223503437', 'https://openalex.org/W4226389596', 'https://openalex.org/W4230558246', 'https://openalex.org/W4230847303', 'https://openalex.org/W4249117536', 'https://openalex.org/W4282924538', 'https://openalex.org/W4289782538', 'https://openalex.org/W4294992517', 'https://openalex.org/W4317436354', 'https://openalex.org/W4321502069', 'https://openalex.org/W4360810379'], 'related_works': ['https://openalex.org/W4391375266', 'https://openalex.org/W4387497383', 'https://openalex.org/W4386448162', 'https://openalex.org/W4379508247', 'https://openalex.org/W2948807893', 'https://openalex.org/W2899084033', 'https://openalex.org/W2778153218', 'https://openalex.org/W2748952813', 'https://openalex.org/W1533384178', 'https://openalex.org/W1531601525'], 'abstract_inverted_index': {'This': [0], 'article': [1], 'reviews': [2], 'the': [3, 8, 13], 'strategies': [4], 'available': [5], 'to': [6], 'achieve': [7], 'umpolung': [9], 'of': [10, 16], 'diazocompounds': [11], 'and': [12], 'synthetic': [14], 'applications': [15], 'such': [17], 'compounds.': [18]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W4379508247', 'counts_by_year': [{'year': 2024, 'cited_by_count': 11}, {'year': 2023, 'cited_by_count': 1}], 'updated_date': '2024-12-08T13:54:39.879741', 'created_date': '2023-06-07'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
