Click-Type Synthesis of Homoconjugated Push–Pull Chromophores: Computational Investigation of Optical and Nonlinear Optical (NLO) Properties

Name: Work Video:
Duration: 3 min 30 s
Description: Abstract Homoconjugated push–pull chromophores were obtained by an efficient, click-type formal [2+2] cycloaddition. With these short synthetic transformations, complex chromophore structures were achieved in a single step without any by-product formation. Significant second-order optical nonlinearities have been calculated for the synthesized compounds.
Cagatay Dengiz; Fevzi Can Inyurt; Flora Mammadova
{'id': 'https://openalex.org/W4313332762', 'doi': 'https://doi.org/10.1055/a-2004-6344', 'title': 'Click-Type Synthesis of Homoconjugated Push–Pull Chromophores: Computational Investigation of Optical and Nonlinear Optical (NLO) Properties', 'display_name': 'Click-Type Synthesis of Homoconjugated Push–Pull Chromophores: Computational Investigation of Optical and Nonlinear Optical (NLO) Properties', 'publication_year': 2022, 'publication_date': '2022-12-29', 'ids': {'openalex': 'https://openalex.org/W4313332762', 'doi': 'https://doi.org/10.1055/a-2004-6344'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1055/a-2004-6344', 'pdf_url': 'http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-2004-6344.pdf', 'source': {'id': 'https://openalex.org/S4210211857', 'display_name': 'SynOpen', 'issn_l': '2509-9396', 'issn': ['2509-9396'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310321135', 'host_organization_name': 'Georg Thieme Verlag', 'host_organization_lineage': ['https://openalex.org/P4310321135', 'https://openalex.org/P4310320000'], 'host_organization_lineage_names': ['Georg Thieme Verlag', 'Thieme Medical Publishers (Germany)'], 'type': 'journal'}, 'license': 'cc-by', 'license_id': 'https://openalex.org/licenses/cc-by', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': True, 'oa_status': 'gold', 'oa_url': 'http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-2004-6344.pdf', 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5043797732', 'display_name': 'Cagatay Dengiz', 'orcid': 'https://orcid.org/0000-0002-8238-6941'}, 'institutions': [{'id': 'https://openalex.org/I201799495', 'display_name': 'Middle East Technical University', 'ror': 'https://ror.org/014weej12', 'country_code': 'TR', 'type': 'education', 'lineage': ['https://openalex.org/I201799495']}], 'countries': ['TR'], 'is_corresponding': False, 'raw_author_name': 'Cagatay Dengiz', 'raw_affiliation_strings': [' Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey'], 'affiliations': [{'raw_affiliation_string': ' Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'institution_ids': ['https://openalex.org/I201799495']}, {'raw_affiliation_string': 'Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'institution_ids': ['https://openalex.org/I201799495']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5060307263', 'display_name': 'Fevzi Can Inyurt', 'orcid': 'https://orcid.org/0000-0002-7192-6690'}, 'institutions': [{'id': 'https://openalex.org/I201799495', 'display_name': 'Middle East Technical University', 'ror': 'https://ror.org/014weej12', 'country_code': 'TR', 'type': 'education', 'lineage': ['https://openalex.org/I201799495']}], 'countries': ['TR'], 'is_corresponding': False, 'raw_author_name': 'Fevzi Can Inyurt', 'raw_affiliation_strings': [' Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'institution_ids': ['https://openalex.org/I201799495']}, {'raw_affiliation_string': ' Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'institution_ids': ['https://openalex.org/I201799495']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5010314495', 'display_name': 'Flora Mammadova', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I201799495', 'display_name': 'Middle East Technical University', 'ror': 'https://ror.org/014weej12', 'country_code': 'TR', 'type': 'education', 'lineage': ['https://openalex.org/I201799495']}], 'countries': ['TR'], 'is_corresponding': False, 'raw_author_name': 'Flora Mammadova', 'raw_affiliation_strings': [' Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey'], 'affiliations': [{'raw_affiliation_string': ' Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'institution_ids': ['https://openalex.org/I201799495']}, {'raw_affiliation_string': 'Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey', 'institution_ids': ['https://openalex.org/I201799495']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 300, 'currency': 'EUR', 'value_usd': 340, 'provenance': 'doaj'}, 'apc_paid': {'value': 300, 'currency': 'EUR', 'value_usd': 340, 'provenance': 'doaj'}, 'fwci': 0.0, 'has_fulltext': True, 'fulltext_origin': 'pdf', 'cited_by_count': 0, 'citation_normalized_percentile': {'value': 0.0, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 0, 'max': 60}, 'biblio': {'volume': '07', 'issue': '01', 'first_page': '1', 'last_page': '7'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11025', 'display_name': 'Nonlinear Optical Materials Research', 'score': 0.9987, 'subfield': {'id': 'https://openalex.org/subfields/2504', 'display_name': 'Electronic, Optical and Magnetic Materials'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11025', 'display_name': 'Nonlinear Optical Materials Research', 'score': 0.9987, 'subfield': {'id': 'https://openalex.org/subfields/2504', 'display_name': 'Electronic, Optical and Magnetic Materials'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11708', 'display_name': 'Photochromic and Fluorescence Chemistry', 'score': 0.998, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10903', 'display_name': 'Porphyrin and Phthalocyanine Chemistry', 'score': 0.9963, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/chromophore', 'display_name': 'Chromophore', 'score': 0.9788382}], 'concepts': [{'id': 'https://openalex.org/C192468462', 'wikidata': 'https://www.wikidata.org/wiki/Q533543', 'display_name': 'Chromophore', 'level': 2, 'score': 0.9788382}, {'id': 'https://openalex.org/C2991936344', 'wikidata': 'https://www.wikidata.org/wiki/Q756033', 'display_name': 'Nonlinear optical', 'level': 3, 'score': 0.7399476}, {'id': 'https://openalex.org/C2779664164', 'wikidata': 'https://www.wikidata.org/wiki/Q898648', 'display_name': 'Cycloaddition', 'level': 3, 'score': 0.620121}, {'id': 'https://openalex.org/C158622935', 'wikidata': 'https://www.wikidata.org/wiki/Q660848', 'display_name': 'Nonlinear system', 'level': 2, 'score': 0.51386}, {'id': 'https://openalex.org/C192562407', 'wikidata': 'https://www.wikidata.org/wiki/Q228736', 'display_name': 'Materials science', 'level': 0, 'score': 0.41618013}, {'id': 'https://openalex.org/C78854221', 'wikidata': 'https://www.wikidata.org/wiki/Q756033', 'display_name': 'Nonlinear optics', 'level': 3, 'score': 0.4151878}, {'id': 'https://openalex.org/C21951064', 'wikidata': 'https://www.wikidata.org/wiki/Q899212', 'display_name': 'Combinatorial chemistry', 'level': 1, 'score': 0.37452167}, {'id': 'https://openalex.org/C49040817', 'wikidata': 'https://www.wikidata.org/wiki/Q193091', 'display_name': 'Optoelectronics', 'level': 1, 'score': 0.34511542}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.33058918}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.31506634}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.15475509}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.08868468}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.08031988}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.1055/a-2004-6344', 'pdf_url': 'http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-2004-6344.pdf', 'source': {'id': 'https://openalex.org/S4210211857', 'display_name': 'SynOpen', 'issn_l': '2509-9396', 'issn': ['2509-9396'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310321135', 'host_organization_name': 'Georg Thieme Verlag', 'host_organization_lineage': ['https://openalex.org/P4310321135', 'https://openalex.org/P4310320000'], 'host_organization_lineage_names': ['Georg Thieme Verlag', 'Thieme Medical Publishers (Germany)'], 'type': 'journal'}, 'license': 'cc-by', 'license_id': 'https://openalex.org/licenses/cc-by', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1055/a-2004-6344', 'pdf_url': 'http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-2004-6344.pdf', 'source': {'id': 'https://openalex.org/S4210211857', 'display_name': 'SynOpen', 'issn_l': '2509-9396', 'issn': ['2509-9396'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310321135', 'host_organization_name': 'Georg Thieme Verlag', 'host_organization_lineage': ['https://openalex.org/P4310321135', 'https://openalex.org/P4310320000'], 'host_organization_lineage_names': ['Georg Thieme Verlag', 'Thieme Medical Publishers (Germany)'], 'type': 'journal'}, 'license': 'cc-by', 'license_id': 'https://openalex.org/licenses/cc-by', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [], 'grants': [{'funder': 'https://openalex.org/F4320322628', 'funder_display_name': 'Türkiye Bilimler Akademisi', 'award_id': 'GEBIP Award'}], 'datasets': [], 'versions': [], 'referenced_works_count': 31, 'referenced_works': ['https://openalex.org/W1246536934', 'https://openalex.org/W1968652549', 'https://openalex.org/W1982052532', 'https://openalex.org/W1986312165', 'https://openalex.org/W1990774515', 'https://openalex.org/W1993557294', 'https://openalex.org/W2015983831', 'https://openalex.org/W2023271753', 'https://openalex.org/W2039559098', 'https://openalex.org/W2047307858', 'https://openalex.org/W2058398316', 'https://openalex.org/W2079226464', 'https://openalex.org/W2082649227', 'https://openalex.org/W2145662716', 'https://openalex.org/W2147037359', 'https://openalex.org/W2320823423', 'https://openalex.org/W2334127072', 'https://openalex.org/W2343448508', 'https://openalex.org/W2473910758', 'https://openalex.org/W2791007737', 'https://openalex.org/W2791994949', 'https://openalex.org/W2919424914', 'https://openalex.org/W2955410799', 'https://openalex.org/W2972859277', 'https://openalex.org/W3043747096', 'https://openalex.org/W3080850181', 'https://openalex.org/W3129857606', 'https://openalex.org/W3209141787', 'https://openalex.org/W4214870720', 'https://openalex.org/W4256503849', 'https://openalex.org/W4308072133'], 'related_works': ['https://openalex.org/W67749286', 'https://openalex.org/W4321272456', 'https://openalex.org/W2121467256', 'https://openalex.org/W2076645717', 'https://openalex.org/W2038479127', 'https://openalex.org/W1981231625', 'https://openalex.org/W1974818623', 'https://openalex.org/W1599687761', 'https://openalex.org/W1526161830', 'https://openalex.org/W1506762016'], 'abstract_inverted_index': {'Abstract': [0], 'Homoconjugated': [1], 'push–pull': [2], 'chromophores': [3], 'were': [4, 21], 'obtained': [5], 'by': [6], 'an': [7], 'efficient,': [8], 'click-type': [9], 'formal': [10], '[2+2]': [11], 'cycloaddition.': [12], 'With': [13], 'these': [14], 'short': [15], 'synthetic': [16], 'transformations,': [17], 'complex': [18], 'chromophore': [19], 'structures': [20], 'achieved': [22], 'in': [23], 'a': [24], 'single': [25], 'step': [26], 'without': [27], 'any': [28], 'by-product': [29], 'formation.': [30], 'Significant': [31], 'second-order': [32], 'optical': [33], 'nonlinearities': [34], 'have': [35], 'been': [36], 'calculated': [37], 'for': [38], 'the': [39], 'synthesized': [40], 'compounds.': [41]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W4313332762', 'counts_by_year': [], 'updated_date': '2024-12-09T21:49:10.517308', 'created_date': '2023-01-06'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
