Publication Information

{'id': 'https://openalex.org/W4304943980', 'doi': 'https://doi.org/10.31635/ccschem.022.202202296', 'title': 'Boosting Plasmonic Hot Electron Utilization for Visible-Light Photocatalysis Using Polarized Ag-TiO <sub>2</sub> Nanoparticles', 'display_name': 'Boosting Plasmonic Hot Electron Utilization for Visible-Light Photocatalysis Using Polarized Ag-TiO <sub>2</sub> Nanoparticles', 'publication_year': 2022, 'publication_date': '2022-10-13', 'ids': {'openalex': 'https://openalex.org/W4304943980', 'doi': 'https://doi.org/10.31635/ccschem.022.202202296'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.31635/ccschem.022.202202296', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210239486', 'display_name': 'CCS Chemistry', 'issn_l': '2096-5745', 'issn': ['2096-5745'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310311897', 'host_organization_name': 'Chinese Chemical Society', 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5218, 5240, 5288], 'Advanced': [37, 77, 117, 157, 197, 237, 283], 'Energy': [38, 59, 78, 99, 118, 139, 158, 179, 198, 219, 238, 259, 284, 305, 3722, 4660, 4833], 'Materials': [39, 79, 119, 159, 199, 239, 285], 'Chemistry': [40, 80, 120, 160, 200, 240, 286], '(Ministry': [41, 81, 121, 161, 201, 241, 287], 'Education),': [43, 83, 123, 163, 203, 243, 289], 'Tianjin': [44, 69, 84, 109, 124, 149, 164, 189, 204, 229, 244, 269, 290, 315, 3588], 'Biosensing': [48, 88, 128, 168, 208, 248, 294], 'Molecular': [50, 90, 130, 170, 210, 250, 296, 4063, 4147], 'Recognition,': [51, 91, 131, 171, 211, 251, 297], 'Haihe': [52, 92, 132, 172, 212, 252, 298, 3602], 'Sustainable': [55, 95, 135, 175, 215, 255, 301, 3605], 'Chemical': [56, 96, 136, 176, 216, 256, 302, 3606, 3651, 4067, 4090, 4285, 4483, 5347], 'Transformations,': [57, 97, 137, 177, 217, 257, 303], 'Renewable': [58, 98, 138, 178, 218, 258, 304], 'Conversion': [60, 100, 140, 180, 220, 260, 306], 'Storage': [62, 102, 142, 182, 222, 262, 308], 'Center,': [63, 103, 143, 183, 223, 263, 309], 'College': [64, 104, 144, 184, 224, 264, 310], 'Chemistry,': [66, 106, 146, 186, 226, 266, 312], 'Nankai': [67, 107, 147, 187, 227, 267, 313], 'University,': [68, 108, 148, 188, 228, 268, 314], '300071': [70, 110, 150, 190, 230, 270, 316], ',': [71, 111, 151, 191, 231], 'Yu†': [73], 'Zhang': [153, 3699, 3766, 3787, 3823, 3874, 3909, 3975, 4161, 4165, 4168, 4359, 4395, 4573, 4798, 4820, 4873, 4884, 4985, 5026, 5062, 5199], 'Gao': [193, 3667, 3862, 4749, 4787], '*Corresponding': [274], 'author:': [275], 'E-mail': [276], 'Address:': [277], '[email': [278, 4953], 'protected]': [279], 'https://doi.org/10.31635/ccschem.022.202202296': [317], 'SectionsSupplemental': [318], 'MaterialAboutAbstractPDF': [319], 'ToolsAdd': [320], 'to': [321, 372, 399, 460, 479, 577, 704, 717, 753, 767, 810, 825, 896, 1003, 1064, 1076, 1131, 1193, 1308, 1350, 1407, 1426, 1459, 1517, 1738, 1953, 1960, 2113, 2120, 2165, 2211, 2319, 2475, 2598, 2605, 2652, 2677, 2702, 2719, 2744, 2761, 2830, 2967, 2991, 3018, 3031, 3152, 3171, 3195, 3231, 3257, 3264, 3411, 3553, 4065, 4480, 4658, 4665, 4928], 'favoritesDownload': [322], 'CitationsTrack': [323], 'Citations': [324], 'ShareFacebookTwitterLinked': [325], 'InEmail': [326], 'hot': [328, 368, 630, 748, 806, 906, 1958, 2610, 2798, 2942, 2983, 3032, 3074, 3110, 3173, 3406, 3492], 'electrons': [329, 369, 514, 749, 807, 907, 1959, 2943, 2984, 3033, 3075, 3111, 3174, 3407, 3493], 'have': [330, 383, 700, 763, 3471], 'long': [331], 'been': [332, 702, 3472], 'regarded': [333], 'as': [334, 448, 1174, 1561, 1851, 1933, 1976, 2107, 2135, 2518, 3149, 3247, 3338, 4336, 4518], 'a': [335, 384, 432, 440, 457, 476, 529, 569, 609, 764, 864, 929, 954, 1008, 1019, 1053, 1154, 1224, 1237, 1246, 1321, 1351, 1372, 1475, 1480, 1486, 1513, 1587, 1670, 1680, 1692, 1747, 1780, 1880, 1948, 1971, 1977, 2060, 2074, 2108, 2144, 2253, 2268, 2398, 2693, 2730, 2737, 2756, 3221, 3454, 4519, 5245], 'promising': [336, 477], 'energy': [337, 482], 'source': [338, 1564], 'inducing': [340], 'chemical': [341, 401, 579, 784, 2161], 'transformations.': [342], 'However,': [343, 756, 3050], 'because': [344, 627], 'the': [346, 349, 356, 363, 378, 388, 394, 404, 411, 523, 549, 589, 596, 605, 628, 636, 652, 656, 674, 736, 758, 770, 796, 813, 826, 829, 873, 898, 904, 909, 915, 922, 936, 1065, 1100, 1105, 1124, 1132, 1139, 1186, 1199, 1203, 1214, 1260, 1267, 1277, 1387, 1432, 1451, 1527, 1533, 1537, 1543, 1562, 1566, 1593, 1638, 1660, 1712, 1719, 1751, 1786, 1835, 1849, 1852, 1886, 1917, 1931, 1955, 1964, 1983, 2041, 2053, 2058, 2080, 2092, 2102, 2114, 2121, 2138, 2160, 2169, 2175, 2201, 2212, 2220, 2224, 2272, 2283, 2321, 2338, 2344, 2350, 2369, 2391, 2406, 2421, 2443, 2455, 2467, 2477, 2481, 2495, 2519, 2562, 2574, 2584, 2599, 2607, 2622, 2629, 2635, 2640, 2646, 2679, 2703, 2709, 2714, 2726, 2745, 2751, 2763, 2776, 2785, 2797, 2808, 2813, 2819, 2823, 2831, 2875, 2915, 2922, 2927, 2930, 2939, 2945, 2959, 2964, 2975, 2982, 2986, 2992, 2999, 3005, 3043, 3066, 3072, 3086, 3095, 3100, 3108, 3132, 3141, 3176, 3232, 3258, 3291, 3311, 3325, 3339, 3353, 3398, 3417, 3425, 3433, 3438, 3446, 3461, 3476, 3499, 3559, 3563, 3573, 3583, 3594, 3601, 4209, 4258, 4439, 4472, 4477, 4490, 4511, 4545, 4548, 4768, 5322], 'mismatch': [347, 827], 'between': [348, 551, 691, 828, 876, 2609], 'electron': [350, 830, 2005, 2015, 3020, 3097, 3439], 'cloud': [351, 831, 3440], 'reactant': [353, 379, 759, 792, 833, 3419], 'molecules': [354, 380, 422, 637, 692, 760, 834, 2957, 3156], 'hot-electron': [357, 836, 2217], 'gas': [358, 837, 1041, 1235, 1739], 'metal': [360, 389, 524, 531, 606, 644, 839, 1331, 1409, 2047, 2049, 2116, 3207], 'nanoparticles': [361, 485], '(NPs),': [362], 'highly': [364], 'localized': [365, 494, 509], 'short-lived': [367, 629, 805], 'are': [370, 499, 518, 602, 673, 733, 808, 1867, 2030, 2209, 2385, 2485, 2800, 2989, 3028, 3317, 3413], 'difficult': [371, 809], 'utilize': [373], 'in': [374, 423, 465, 593, 599, 682, 812, 821, 853, 869, 921, 928, 950, 1052, 1442, 1474, 1498, 1532, 1542, 1565, 1990, 2137, 2174, 2179, 2187, 2387, 2405, 2420, 2454, 2487, 2573, 2583, 2645, 2673, 2775, 2782, 2858, 2874, 2893, 2926, 2944, 2974, 3059, 3080, 3089, 3099, 3114, 3160, 3183, 3285, 3303, 3343, 3397, 3494, 3630, 3683, 3936, 4121, 4411, 4444, 4773, 4948, 5214, 5325], 'bulk': [375, 424, 640, 822, 951, 2339, 2422, 2809, 3399], 'synthesis': [376, 1570, 1763, 1857, 3126, 3400], 'when': [377, 726, 757, 857], 'do': [381, 761], 'not': [382, 430, 701, 762, 848, 2149, 3077], 'strong': [385, 488, 865, 2623], 'affinity': [386, 2625], 'surface.': [390, 2618, 2753, 2846], 'Here,': [391], 'we': [392, 794, 887, 2291, 2633], 'propose': [393, 795], 'concept': [395, 797, 3484], 'polarized': [397, 800, 973, 992, 1942, 2170, 2240, 2255, 2288, 2548, 2946, 3133, 3292, 3477, 3486], 'nanocatalysts': [398, 3507], 'mimic': [400], 'polarity': [402, 785], 'at': [403, 655, 1380, 1391, 1705, 2381, 2427, 2578, 3035, 3803, 5321], 'nanometer': [405], 'scale.': [406], 'Under': [407, 901, 2689, 2979, 4627, 5070], 'plasmonic': [408, 530, 582, 623, 670, 697, 723, 743, 771, 801, 899, 905, 974, 1943, 2241, 2289, 2616, 2793, 2844, 2976, 3014, 3073, 3162, 3391, 3405, 3491], 'photorecycling': [409, 978, 3142, 3177], 'conditions,': [410], 'rationally': [412], 'designed': [413, 888, 2202, 2307], 'asymmetric': [414, 892, 1951], 'hybrid': [416, 662, 698, 894, 982, 2948, 3506], 'NPs': [417, 725, 994, 1015, 1137, 2000, 2045, 2072, 2182, 2644, 2672, 2857], 'enable': [418, 461], 'six-electron': [419, 714, 774, 948, 977, 2139], 'reduction': [420, 541, 720, 775, 949, 1144, 2140, 2340, 2379, 2401, 2424, 2545, 2554, 2568], 'solution.': [425, 2070, 2877], 'This': [426, 455, 2513, 2811, 3483], 'hot-electron-driven': [427, 540, 675, 957, 2514], 'reaction': [428, 1141, 1204, 1262, 1268, 1278, 1649, 1687, 1714, 1720, 2190, 2213, 2341, 2351, 2458, 2474, 2515, 2569, 3202], 'does': [429, 847, 2148], 'require': [431, 2150], 'conventional': [433, 2151, 3210], 'hydrogen': [434, 2152, 2520, 2529], 'or': [435, 611, 688, 731, 1336, 1759, 2048, 2153, 2530, 3212, 3250, 3382], 'hydride': [436, 2154, 2531], 'reducing': [437, 2155, 2532], 'agent.': [438, 2533], 'As': [439, 953, 2780], 'proof-of-concept,': [441, 955], 'one-pot': [442, 956], 'photocatalytic': [443, 667, 2189, 2553, 2567, 2977, 3163], 'syntheses': [444, 958], 'amides,': [446], 'such': [447, 3246], 'paracetamol,': [449], 'using': [450, 939, 962, 1236, 1519, 1974, 2528, 3131, 3205, 3269, 3324, 3508], 'nitro': [451, 963, 1575, 1594, 1768, 1788, 3128, 3237], 'reactants': [452, 820, 964], 'were': [453, 562, 912, 965, 1016, 1115, 1348, 1418, 1447, 1471, 1496, 1635, 1832, 1848, 1914, 1930, 2088, 2133, 2172, 3076, 3112, 3138, 3168, 3282], 'performed.': [454, 966], 'provides': [456, 475], 'new': [458], 'opportunity': [459], 'challenging': [462, 626], 'multielectron': [463], 'transformations': [464], 'organic': [466, 683, 3150], 'chemistry.': [467], 'Download': [468, 470, 984, 986, 2275, 2277, 2591, 2593, 2950, 2952, 3385, 3387], 'figure': [469, 985, 2276, 2592, 2951, 3386], 'PowerPoint': [471, 987, 2278, 2594, 2953, 3388], 'Introduction': [472], 'Heterogeneous': [473], 'photocatalysis': [474], 'pathway': [478], 'drive': [480], 'solar-to-chemical': [481], 'conversion.1': [483], 'Metal': [484, 3718, 3955, 4153, 4409, 5120, 5241], '(NPs)': [486], 'having': [487], 'interactions': [489], 'with': [490, 573, 850, 1035, 1081, 1117, 1123, 1153, 1159, 1190, 1233, 1239, 1245, 1284, 1292, 1302, 1355, 1366, 1399, 1479, 1512, 1586, 1592, 1643, 1679, 1683, 1731, 1779, 1785, 1840, 1879, 1885, 1922, 2046, 2073, 2432, 2450, 2503, 2559, 2770, 3121, 3157, 3333, 3806, 3842, 3892, 4891, 5178], 'visible': [491, 1369, 2911], 'light': [492, 1370, 1563, 2664, 2912, 3481], 'through': [493], 'surface': [495, 519, 575, 607, 911, 938, 1456, 1967, 2222, 2457, 2624, 2641, 2962, 2988, 3429], 'plasmon': [496], 'resonances': [497], '(LSPR)': [498], 'emerging': [500], 'heterogeneous': [501], 'photocatalysts.2–11': [502], 'The': [503, 1095, 1219, 1241, 1401, 1414, 1554, 1648, 1665, 1686, 1845, 1864, 1927, 1993, 2130, 2196, 2347, 2492, 3372, 3404, 3448], 'nonradiative': [504], 'decay': [505], 'plasmons': [507], 'generates': [508], 'energetic': [510], 'charge': [511, 653, 866], 'carriers': [512, 631], '(hot': [513, 3430], 'holes),': [516], 'which': [517, 846, 2147, 2215, 2447, 2522, 2740, 3003, 3027, 3436], 'redox': [520, 536], 'centers': [521], 'on': [522, 581, 604, 622, 722, 745, 769, 908, 980, 1450, 1998, 2033, 2079, 2126, 2219, 2299, 2555, 2570, 2615, 2639, 2686, 2708, 2750, 2767, 2788, 2818, 2843, 2883, 2958, 2985, 3013, 3239, 3658, 3686, 3953, 4092, 4151, 4214, 4377, 4487, 4556, 4894, 4952, 5118], 'NP': [525, 532, 2035, 2128, 2889], 'surface.12,13': [526], 'Upon': [527], 'photoexcitation,': [528], 'accomplishes': [533], 'two': [534], 'aligned': [535], 'transformations,': [537], 'that': [538, 713, 786, 2206, 2796, 3071, 3107], 'is,': [539], 'hot-hole-driven': [543], 'oxidation.14,15': [544], 'A': [545, 976, 995, 1147, 1324, 1580, 1773, 1873, 3307, 4414], 'prominent': [546], 'example': [547], 'is': [548, 843, 860, 2001, 2205, 2267, 2359, 2363, 2403, 2448, 2500, 2603, 2735, 2759, 3294, 3393, 3451, 3517, 3548], 'plasmonicconversions': [550], '4-nitrothiophenol': [552], '(4-NTP),': [553], '4-aminothiophenol': [554], '(4-ATP)': [555], '4,4′-dimercaptoazobenzene': [557], '(4,4′-DMAB).16': [558], 'These': [559], 'model': [560, 2456], 'reactions': [561, 601, 706, 3137], 'studied': [563, 2459], 'by': [564, 635, 783, 862, 1018, 1223, 1298, 1320, 1364, 1669, 1691, 1727, 1981, 2003, 2168, 2343, 2460, 2547, 2802, 2920, 3378, 3416, 3453, 3475, 4095, 4190, 4256, 4292, 4345, 4383, 4559, 4698, 5181, 5244], 'surface-enhanced': [565], 'Raman': [566, 3798, 4097, 4143, 4191, 4436], 'spectroscopy': [567, 2019], '(SERS),': [568], 'chosen': [570], 'analytical': [571], 'tool': [572], 'high': [574, 666, 2009, 2418, 2478], 'sensitivity': [576], 'detect': [578], 'species': [580], 'metals,': [583], 'enabling': [584], 'deep': [585], 'mechanistic': [586], 'understanding': [587], 'hot-carrier-driven': [590, 600], 'reactions.17–27': [591], 'Nevertheless,': [592], 'most': [594, 2197], 'cases': [595], 'chemicals': [597], 'involved': [598], 'anchored': [603], 'via': [608, 651, 2223, 2295, 3140, 3432], 'thiol': [610], 'other': [612, 3275], 'surface-seeking': [613, 620, 765, 2145], 'group.': [614], 'Synthetic': [615], 'chemistry': [616, 3496], 'involving': [617, 686], 'substances': [618], 'without': [619, 2066, 2561], 'groups': [621, 681, 3159, 3238], 'catalysts': [624, 1216, 1417, 1662, 3479], 'remains': [625], 'cannot': [632, 776], 'be': [633, 751, 1961, 2742, 3063, 3181, 3228, 3254, 3330, 4481], 'utilized': [634, 2039, 2760, 3182], 'diffusing': [638], 'from': [639, 998, 1371, 1573, 1766, 1862, 1869, 2807, 2929, 3054, 3127, 3175, 3409, 3562, 4476, 4562, 5154], 'solution.28': [641], 'Heterojunctions': [642], 'semiconductor': [646, 1316, 1329, 3511], 'can': [647, 750, 787, 2335, 2741, 3062, 3180, 3227], 'enhance': [648], 'hot-electron-hole': [649], 'separation': [650, 867], 'transfer': [654, 690, 3098], 'Schottky': [657, 916], 'barrier': [658, 917], 'interfaces.28–35': [659], 'Therefore,': [660], 'metal–semiconductor': [661, 1172, 2970], 'nanomaterials': [663, 699], 'usually': [664], 'exhibit': [665], 'activity': [668, 2186, 2419, 2452], 'under': [669, 778, 1138, 1360, 1420, 1464, 1708, 2910, 2933, 3065, 3200, 3480], 'excitation.36–41': [671], 'Examples': [672], 'reductions': [676], 'C–X': [678], 'C=O': [680], 'synthesis,': [684, 1010, 2059, 2104, 3522], 'typically': [685], 'one-': [687], 'two-electron': [689], 'catalysts.32,41': [694], 'So': [695], 'far,': [696], 'able': [703], 'catalyze': [705], 'beyond': [707], 'four-electron': [708], 'transfer.': [709], 'We': [710, 1946, 1969, 2306, 2954, 3557], 'previously': [711], 'reported': [712, 1020], '4-NTP': [715, 2882, 2956], '(–NO2)': [716], '4-ATP': [718], '(–NH2)': [719], 'occurs': [721], 'Ag': [724, 910, 937, 1014, 1071, 1530, 1999, 2081, 2115, 2127, 2207, 2221, 2298, 2367, 2617, 2631, 2643, 2669, 2710, 2771, 2820, 2845, 2854, 2869, 2888, 2961, 2987, 3410, 3428, 4488], 'halide': [727, 940, 1178, 2588, 2613, 2637, 2684, 3304, 3422], 'anions': [728, 941, 3423], '(Cl−,': [729], 'Br−,': [730], 'I−)': [732], 'present.42,43': [734], 'Because': [735], 'formation': [737, 1133, 2225, 2704, 3006, 3044], 'photodissociation': [739, 2715], 'AgX': [741, 2842], 'consume': [742], 'holes': [744, 2611, 2799], 'Ag,': [746, 2325], 'more': [747, 1048, 3466], 'transferred': [752, 913, 2990, 3109, 3408], 'adjacent': [754, 3418], 'molecules.': [755], 'group': [766], 'anchor': [768], 'metal,': [772], 'this': [773, 885, 2188, 3161], 'occur': [777], 'otherwise': [779], 'identical': [780, 3067], 'conditions.': [781, 1142], 'Inspired': [782], 'help': [788], 'attract': [789], 'align': [791], 'molecules,': [793, 3420], 'designing': [799], 'catalysts.': [802], 'Localized': [803], 'inject': [811], 'lowest': [814], 'unoccupied': [815], 'molecular': [816, 844, 3527], 'orbitals': [817], '(LUMOs)': [818], 'solution': [823, 1029, 1066, 1073, 1106, 1122, 1180, 1187, 1546, 1688, 2409, 2676, 2861, 2896], 'due': [824, 2701, 2829], 'NPs.': [840], 'An': [841], 'analogy': [842], 'hydrogen,': [845], 'react': [849], 'hydroxide': [851], 'anion': [852], 'aqueous': [854, 1167, 1177, 2069, 2674, 2860, 2895], 'alkaline': [855], 'solution:': [856], 'one': [858], 'H': [859], 'replaced': [861], 'F,': [863], 'forms': [868], 'H(δ+)···F(δ−),': [870], 'thus': [872], 'electron-cloud': [874], 'overlap': [875], 'HF': [877], 'OH−': [879], 'becomes': [880], 'easy': [881], '(Figure': [882, 2022, 2095, 2313, 2357, 2410, 2436, 2658, 3009, 3025, 3103, 3144, 3315], '1).': [883], 'In': [884, 1007, 2101, 2412, 2754, 3219], 'work,': [886], 'synthesized': [890, 1017, 3199, 3331, 3474], 'an': [891, 1264, 1465, 1644, 1716, 1841, 1923, 2416, 2720, 2768, 2859, 2894, 3296], 'nanoparticle': [895], 'polarize': [897], 'catalyst.': [900], 'visible-light': [902, 3068], 'irradiation,': [903], 'across': [914], '(φSB)': [918], 'accumulated': [920], 'conduction': [923, 2993], 'band': [924, 2850, 2994], 'TiO2,': [926], 'resulting': [927], 'nanoscale-polarized': [930], 'hot-carrier': [931], 'dipole:': [932], 'Ag(δ+)···TiO2(δ−).': [933], 'Photorecycling': [934, 5119], 'further': [942], 'inhibited': [943], 'charge-carrier': [944], 'recombination': [945], 'enabled': [947], 'synthesis.': [952, 3164], 'amide': [960, 3125, 3135, 3234, 3265, 3301, 3313, 3402, 3469], 'compounds': [961, 1576, 1595, 1769, 1789, 1888, 3129, 3225, 3470], 'Figure': [967, 1991, 2086, 2099, 2194, 2234, 2304, 2376, 2388, 2464, 2490, 2511, 2534, 2660, 2783, 2835, 3092, 3119, 3188, 3362], '1': [968, 1082, 1288, 1293], '|': [969, 2236, 2536, 2837, 3364], 'Conceptual': [970], 'design': [971, 3503], 'photocatalyst.': [975, 2346, 2482, 3447], 'process': [979, 2682, 3143, 3178], 'nanostructure.': [983], 'Experimental': [988], 'Methods': [989], 'Synthesis': [990, 1940, 2238], 'modified': [996, 1868], 'method': [997, 1973, 2507, 2758, 3459, 3463], 'Ref.': [999], '44': [1000], 'was': [1001, 1033, 1042, 1062, 1074, 1097, 1157, 1188, 1206, 1217, 1221, 1243, 1272, 1282, 1318, 1389, 1403, 1437, 1540, 1559, 1590, 1641, 1651, 1663, 1667, 1689, 1724, 1754, 1783, 1838, 1883, 1920, 2064, 2699, 2918, 3147, 3198, 3376], 'used': [1002, 1970, 2134, 2364, 2516, 3148, 3396], 'synthesize': [1004], 'heterostructures.': [1006], 'typical': [1009, 1853, 1870, 1934, 2663, 3360], '∼90': [1011], 'nm': [1012, 2698, 2723], 'quasi-spherical': [1013], 'method.43': [1021], 'To': [1022, 1430, 1521, 2051, 2281], 'prepare': [1023, 1431], 'heterostructures,': [1025], '0.15': [1026], 'mL': [1027, 1037, 1055, 1070, 1078, 1083, 1149, 1294, 1338, 1353, 1357, 1500, 1582, 1775, 1875], 'HCl': [1028], '15%': [1031], 'TiCl3': [1032, 1986], 'diluted': [1034, 1169, 1189, 1291], '4': [1036, 1194, 2836], 'N2-saturated': [1038, 1084], 'H2O': [1039, 1085], '(nitrogen': [1040], 'introduced': [1043], 'into': [1044, 1099, 1963, 3845], 'deionized': [1045, 1191, 1295, 1358], 'water': [1046, 1129, 1192, 1359, 2517], 'than': [1049, 3467], '20': [1050, 1054, 1148, 1581, 1774, 1874], 'min)': [1051], 'glass': [1056], 'vial.': [1057], 'NaHCO3': [1058], '(0.6': [1059], 'mL,': [1060], '1M)': [1061], 'added': [1063, 1098, 1349, 1636, 1755, 1833, 1915], 'dropwise.': [1067], 'Afterwards,': [1068], '10': [1069, 1163, 1395], 'core': [1072, 2082], 'concentrated': [1075], '0.5': [1077, 1502, 1627, 1824, 2898], 'mixed': [1080, 1283], '400': [1087], 'μL': [1088, 1161, 1286], '0.2': [1090], 'M': [1091, 1289, 1489, 1503, 2899], 'cetyltrimethylammonium': [1092], 'bromide': [1093], '(CTAB).': [1094], 'mixture': [1096, 1205, 1220, 1242, 1269, 1279, 1545, 1650, 1666, 1721], 'above': [1101, 1544], 'solution,': [1102, 1168, 2214], 'then': [1104, 1185, 1231, 1440, 1448, 1654, 1677, 1736, 2713, 3262], 'became': [1107], 'blue': [1108], 'grey.': [1109], 'After': [1110, 1259, 1711, 2157], '60': [1111], 'min,': [1112], 'heterostructures': [1114, 2094, 2132, 2204, 3102], 'washed': [1116, 1398], 'ethanol': [1118], 'twice.': [1119], 'Replacing': [1120], 'CTAB': [1121, 1607, 1810, 1900, 1975, 2029, 2056, 2068, 2105], 'same': [1125, 1140, 1850, 1932, 2392], 'volume': [1126], 'degassed': [1128, 1222, 1668], 'led': [1130, 2718], 'core-shell': [1136], 'Photocatalytic': [1143, 1569, 1762, 1856, 2279, 3124, 3631, 3656, 4212, 4731, 4993, 5040], '4-nitrophenol': [1146, 1165, 2142], 'quartz': [1150, 1583, 1639, 1776, 1836, 1876, 1918], 'tube': [1151, 1584, 1640, 1777, 1837, 1877, 1919], 'equipped': [1152, 1585, 1642, 1678, 1778, 1839, 1878, 1921], 'stir': [1155, 1588, 1781, 1881], 'bar': [1156, 1589, 1782, 1882], 'charged': [1158, 1591, 1784, 1884, 3427], '150': [1160], 'mM': [1164, 1341], '(4-NP)': [1166], 'sulfuric': [1170], 'acid,': [1171], 'nanocomposites': [1173, 2294, 2472, 2572], 'catalysts,': [1175, 3327], 'ions': [1179, 2334, 2589, 2614, 2638, 2685], 'certain': [1182, 1748], 'concentration,': [1183], 'mL.': [1195], 'Supporting': [1196, 2084, 2097, 2192, 2302, 2315, 2374, 2438, 2462, 2488, 2509, 3090, 3117, 3186, 3346, 3513, 3515], 'Information': [1197, 2085, 2098, 2193, 2303, 2316, 2375, 2439, 2463, 2489, 2510, 3091, 3118, 3187, 3347, 3514, 3516, 3556, 5341], 'shows': [1198, 2415, 2466, 2662], 'experimental': [1200, 1865, 2444], 'details.': [1201], 'Subsequently,': [1202, 1610, 1813, 1903], 'stirred': [1207, 1652], 'sonicated': [1209, 1655], 'until': [1210, 1549, 1656], 'fine': [1211, 1657], 'dispersion': [1212, 1658], 'solid': [1215, 1416, 1661], 'obtained.': [1218], 'vacuum': [1225, 1671], 'pump': [1226, 1672], '3–5': [1228], 'min': [1229, 1396, 1463, 1675], 'filled': [1232, 1682], 'N2': [1234, 1684], 'balloon': [1238, 1681], 'needle.': [1240], 'irradiated': [1244, 1690], 'white': [1247], 'light-emitting': [1248], 'diode': [1249], '(powder': [1250, 1695], 'intensity': [1251, 1696], '∼165': [1252], 'mW/cm2,': [1253, 1699], 'wavelength': [1254, 1700], 'region': [1255, 1701, 2649], '400–700': [1257], 'nm).': [1258], 'respective': [1261, 1713], 'time,': [1263, 1715], 'aliquot': [1265, 1717], '(∼600': [1270], 'μL)': [1271, 1281, 1723], 'centrifuged.': [1273], 'For': [1274, 1744, 2729, 3288], 'UV–vis': [1275, 1309, 2176], 'analysis,': [1276, 1746], '(150': [1280], '450': [1285], 'NaOH': [1290], 'water,': [1296], 'filtered': [1297, 1726], 'nylon': [1299, 1728], 'syringe': [1300, 1729], 'filter': [1301, 1730], '2.2': [1303, 1732], 'μm': [1304, 1733], 'aperture,': [1305], 'subjected': [1307, 1737], 'analysis.': [1310, 1743], 'Preparation': [1311], 'Ag/Au-TiO2': [1313], 'photocatalysts': [1314, 1945, 2136, 2171], 'Metal-loaded': [1315], '(TiO2)': [1317], 'prepared': [1319, 1947, 2292, 3284], 'photodeposition': [1322, 2296], 'method.45': [1323], '2': [1325, 2235], 'g': [1326, 1393, 3039], 'amount': [1327, 1749], 'powder,': [1330], 'precursor': [1332, 1410], '(130': [1333], 'mg': [1334, 1345], 'AgNO3': [1335], '24': [1337], '25': [1340, 2722], 'HAuCl4),': [1342], '65': [1344], 'sodium': [1346, 1412], 'citrate': [1347], '250': [1352, 2653], 'beaker': [1354], '50': [1356, 1499], 'vigorous': [1361], 'stirring,': [1362], 'followed': [1363], 'irradiation': [1365], 'UV': [1367], 'mercury': [1373], 'vapor': [1374], 'lamp': [1375, 1423, 1558, 1694], '(power': [1376], 'density': [1377], '200': [1378], 'mW/cm2)': [1379], 'room': [1381, 1706], 'temperature': [1382, 1707], '120': [1384, 1506, 2651, 2863], 'min.': [1385], 'Then,': [1386], 'suspension': [1388, 1436], 'centrifuged': [1390, 1438], '6577': [1392], 'water.': [1400], 'procedure': [1402, 1578, 1771, 1854, 1871, 1935], 'repeated': [1404], 'five': [1405], 'times': [1406, 5356], 'remove': [1408], 'citrate.': [1413], 'metal-loaded': [1415], 'dried': [1419], 'infrared': [1421, 1466], 'heat': [1422, 1467], 'ground': [1425], 'powder.': [1427], 'Electrochemical': [1428, 1469], 'measurements': [1429, 1470], 'electrodes,': [1433], 'Au/Ag': [1434], 'colloid': [1435, 1445], 'resuspended': [1441], 'ethanol.': [1443], 'suspensions': [1446], 'dip-coated': [1449], 'pretreated': [1452], 'indium': [1453], 'tin': [1454], 'oxide': [1455], 'allowed': [1458], 'dry': [1460], '30': [1462], 'lamp.': [1468], 'carried': [1472, 2501, 3169], 'out': [1473, 2502, 3170], 'three-electrode': [1476], 'electrochemical': [1477, 1494, 3214], 'cell': [1478], 'Pt': [1481], 'wire': [1482], 'counter': [1483], 'electrode': [1484, 1531, 1539, 2769, 2790], 'Hg/Hg2Cl2': [1487], '(3.5': [1488], 'KCl)': [1490], 'reference': [1491], 'electrode.46': [1492], 'All': [1493], 'experiments': [1495, 2312, 2542, 3167], 'conducted': [1497], 'NaClO4': [1504], 'μM': [1507, 2864], 'potassium': [1508], 'iodide': [1509], '(KI)': [1510], 'solutions': [1511], 'pH': [1514], 'value': [1515], 'tuned': [1516], '3.0': [1518], 'H2SO4.': [1520, 2900], 'measure': [1522], 'open-circuit': [1523], 'potential': [1524, 1552, 3215], '(OCP)': [1525], 'Au': [1528, 2362, 2671, 2732, 2752, 2773, 2789, 2856, 2871, 4557], 'presence': [1534, 2563, 2575, 2585, 2777], 'iodide,': [1536], 'working': [1538], 'immersed': [1541], 'containing': [1547, 2408, 3310], 'KI': [1548, 2675, 2876], 'its': [1550], 'rest': [1551], 'stabilized.': [1553], '300': [1555], 'W': [1556], 'xenon': [1557, 1693], 'employed': [1560], 'OCP': [1567, 2765, 2787, 2815, 2867], 'measurements.': [1568, 1761], 'amides': [1572, 1765, 3278, 3375], 'aromatic': [1574, 3240, 3368], '(typical': [1577, 1770], 'A)': [1579], '(0.05': [1596, 1889], 'mmol,': [1597, 1614, 1791, 1817, 1890, 1907], '1.0': [1598, 1891], 'equiv),': [1599, 1892], '(50': [1601, 1804], 'mg,': [1602, 1805, 1895], '∼0.14': [1603, 1806, 1896], 'wt': [1604, 1807, 1897], '%),': [1605, 1808, 1898], '(5': [1608, 1811], 'mg).': [1609, 1812, 1902], 'acid': [1611, 1814], 'anhydride': [1612, 1815, 1822, 1905, 3271, 3337], '(0.1–0.5': [1613], '2.0–10.0': [1615], 'equiv,': [1616], 'i.e.,': [1617, 1792, 1818], '0.1': [1618, 1798], 'mmol': [1619, 1623, 1628, 1794, 1799, 1820, 1825], 'benzoic': [1620, 1821, 3270, 3336], 'anhydride,': [1621, 1625, 3274], '0.25': [1622, 1819], 'succinic': [1624, 3273], 'acetic': [1629, 1826, 1904], 'anhydride)': [1630, 1827], 'isopropanol': [1632, 1829, 1911, 3184], '(6': [1633], 'mL)': [1634, 1831, 1913], 'air': [1645, 1842, 1924], 'vent': [1646, 1843, 1925], 'valve.': [1647, 1844, 1926], 'achieved.': [1664], '3': [1674, 2535], 'gas.': [1685], '∼150': [1698], '320–800': [1703], 'nm)': [1704], 'rapid': [1709], 'stirring.': [1710], '(∼650': [1722], 'centrifuged,': [1725], 'aperture': [1734], 'chromatography–mass': [1740], 'spectrometry': [1741], '(GC-MS)': [1742], 'quantitative': [1745], 'internal': [1752], 'standard': [1753, 2506], '1H': [1757, 3354, 3379, 3539], 'NMR': [1758, 3355, 3380, 3540], 'GC': [1760, 3357, 3383], 'alkyl': [1767, 1787, 3289, 3370], 'B)': [1772], '(0.05–0.1': [1790], '0.05': [1793], 'nitrocyclohexane': [1795, 3334], '(nitromethyl)benzene,': [1797], 'nitromethane': [1800], '1-nitropropane),': [1802], '(0.25–0.5': [1816], '(8': [1830, 1912], 'following': [1846, 1928], 'steps': [1847, 1929], 'A.': [1855, 1872, 1936, 4305, 4871, 5086, 5197], '4-acetamido': [1859], 'phenol': [1860], '(paracetamol)': [1861], '4-NP': [1863, 1887, 2164, 2378, 2400, 2499, 2544, 2552, 2566], 'methods': [1866], '(80': [1894], '(20': [1901], '(0.5': [1906], '10.0': [1908], 'equiv)': [1909], 'Results': [1937], 'Discussion': [1939], 'specific': [1949], 'nanostructure': [1952, 3443], 'prolong': [1954], 'lifetime': [1956], 'injected': [1962], 'LUMOs': [1965, 3000], 'adsorbates.': [1968], 'wet-chemistry': [1972, 2103], 'soft': [1978], 'template': [1979], 'controlling': [1982], 'degree': [1984], 'hydrolysis': [1987], '(as': [1988], 'shown': [1989, 2002, 2386, 2486, 2781], '2a).44': [1992], 'anisotropic': [1994, 2042, 2122], 'overgrowth': [1995, 2043, 2123], 'TiO2': [1997, 2075, 2125, 2300, 2326, 2907, 2996, 3061, 3115, 3412, 5146], 'transmission': [2004, 2014], 'microscopy': [2006], '(TEM)': [2007], 'angle': [2010], 'annular': [2011], 'dark': [2012, 2928], 'field-scanning': [2013], 'microscopy-energy': [2016], 'dispersive': [2017], 'X-ray': [2018, 3533, 3535], '(HAADF-STEM-EDX)': [2020], 'analyses': [2021], '2b,c).': [2023], 'Bilayers': [2024], 'surface-capping': [2026], 'agents': [2027], 'like': [2028], 'densely': [2031], 'packed': [2032], 'metallic': [2034, 2324, 2687, 2960], 'surfaces': [2036, 2117, 2208, 2892], 'frequently': [2038], 'CTAB-capped': [2044], 'oxide.44,47,48': [2050], 'understand': [2052, 2606], 'role': [2054, 2322], 'during': [2057], 'negative': [2061], 'control': [2062, 2311, 2541, 3166], 'experiment': [2063], 'performed': [2065, 3139], 'adding': [2067, 2354], 'Agcore-TiO2shell': [2071], 'shell': [2076], 'fully': [2077], 'covered': [2078], '(': [2083, 2191, 2301, 2508, 3116], 'S1)': [2087], 'obtained': [2089, 2919, 3342], 'instead': [2090, 2365, 2997], '2d,': [2096], 'S2).': [2100], 'acts': [2106], 'protective': [2109], 'agent': [2110], 'selectively': [2111, 3255], 'adsorbed': [2112, 2636, 2826], 'leads': [2119, 3017], 'surfaces.44': [2129], '(without': [2143, 3204], 'group),': [2146], 'agents.': [2156], 'several': [2158], 'hours,': [2159], 'transformation': [2162, 2681], '4-aminophenol': [2166], 'catalyzed': [2167, 2342, 2546], 'observed': [2173, 2700, 2817], 'absorption': [2177], 'spectra;': [2178], 'contrast,': [2180], 'Agcore–TiO2shell': [2181], 'show': [2183, 2282, 3352], 'very': [2184, 3318], 'low': [2185, 2647], 'S3).': [2195], 'exciting': [2198], 'feature': [2199], 'exposed': [2210], 'enables': [2216, 3488], 'recycling': [2218], 'subsequent': [2227], 'optical': [2228], 'field-accelerated': [2229], 'dissociation': [2230], 'silver': [2232], 'halide.': [2233], '(a)': [2237, 2537, 2838], 'photocatalysts.': [2243, 2264, 2550], 'Elemental': [2244], 'map': [2245], '(b)': [2246, 2551, 2847], 'corresponding': [2248, 2370, 3233, 3259], 'elemental': [2249], 'profiles': [2250], '(c)': [2251, 2581, 2866], 'single': [2254, 2668, 2731, 2853, 3455], 'nanoparticle.': [2257], '(d)': [2258, 2878], 'SEM': [2259], 'image': [2260], 'many': [2262], '(The': [2265], 'inset': [2266], 'TEM': [2269], 'picture': [2270], 'photocatalysts).': [2274], 'performance': [2280], 'general': [2284], 'applicability': [2285], 'utilizing': [2287, 3490], 'photocatalysts,': [2290, 3134], 'S4).': [2305], '36': [2308], 'sets': [2309, 2539], '3a,': [2314], 'Tables': [2317], 'S1–S6),': [2318], 'uncover': [2320], 'semiconductor,': [2327], 'halogen': [2328, 2333, 2355], 'ion,': [2329], 'illumination.': [2331, 2913, 3482], 'Remarkably,': [2332], 'significantly': [2336], 'accelerate': [2337], 'promotion': [2348], 'rate': [2352, 2380, 2402], 'after': [2353, 2473], 'ion': [2356], '3b)': [2358], 'negligible': [2360], 'if': [2361], '(for': [2368], 'characterization': [2371, 2468, 2596, 3528], 'data': [2372], 'see': [2373], 'S5).': [2377], 'different': [2382, 2579, 2587, 2680, 3158], 'Br−': [2383, 2395, 2407, 2433, 2577], 'concentrations': [2384, 2430, 2580], '3c.': [2389], 'With': [2390], 'concentration': [2393, 2497, 2824], 'Cl−,': [2397], 'higher': [2399], 'achieved': [2404], '3d).': [2411], 'particular,': [2413], 'I−': [2414, 2806, 2827], 'extremely': [2417], 'phase': [2423], 'reaction,': [2425], 'even': [2426], 'much': [2428], 'lower': [2429], 'compared': [2431], 'Cl−': [2435], '3d,': [2437], 'Table': [2440], 'S2': [2441], 'gives': [2442], 'operating': [2445], 'details),': [2446], 'consistent': [2449], 'their': [2451], 'trend': [2453], 'SERS.42,43': [2461], 'S6': [2465], 'results': [2469, 2484, 3084, 3358, 3531], 'illustrate': [2476], 'stability': [2479], 'Wavelength-dependence': [2483], 'S7.': [2491], 'determination': [2493], 'conversion': [2496], 'UV-vis': [2504], 'external': [2505], 'S8).': [2512], 'source,': [2521], 'offers': [2523], 'advantages': [2524], 'over': [2525, 3890, 4735], 'current': [2526], 'technologies': [2527], 'Thirty-six': [2538], 'demonstrating': [2543], 'Au-TiO2,': [2558], 'Br−.': [2565], '(d).': [2590], 'Mechanism': [2595], 'According': [2597], 'proposed': [2600, 3394, 3449], 'mechanism,': [2601], 'it': [2602], 'crucial': [2604], 'interaction': [2608], 'Taking': [2619], 'advantage': [2620], 'X−': [2627], 'plasmon-generated': [2630], 'holes,': [2632], 'detected': [2634, 3064], 'wavenumber': [2648], '(from': [2650], 'cm−1)': [2654], 'SERS': [2656, 2839, 2879, 4491], 'spectra': [2657, 2666, 2840, 2880, 2905], '4a).49': [2659], '4b': [2661], 'scattering': [2665, 2849, 3457], 'compare': [2678], 'holes.': [2688], 'continuous': [2690], 'laser': [2691, 2980], 'illumination,': [2692, 2981, 3069], 'redshift': [2694], 'about': [2696], '35': [2697], 'photosensitive': [2706], 'AgI': [2707, 2717, 2833], 'surface,': [2711], 'approximate': [2721], 'blueshift': [2724], 'LSPR': [2727], 'peak.': [2728], 'nanoparticle,': [2733], 'there': [2734], 'only': [2736], 'slight': [2738], 'redshift,': [2739], 'attributed': [2743, 3029], 'physical': [2746], 'adsorption': [2747], 'iodides': [2749], 'addition,': [2755, 3220], 'photoelectrochemical': [2757, 3462], 'study': [2762], 'anodic': [2764, 2786], 'shift': [2766, 2816, 2851], 'nanostructures': [2774], 'iodides.46': [2779], '4c,': [2784], 'decreases': [2791], 'upon': [2792], 'excitation,': [2794], 'indicating': [2795, 3070], 'trapped': [2801, 3034, 3113], 'anions,': [2803], 'mainly': [2804], 'including': [2805], 'electrolyte.': [2810], 'contrasts': [2812], 'cathodic': [2814], 'electrode,': [2821], 'where': [2822], 'deceases': [2828], 'plasmon-promoted': [2832], 'dissociation.': [2834], 'Light': [2848, 3011], 'KI.': [2865], 'nanocrystal-modified': [2872], 'electrodes': [2873], '(blue': [2885], 'curve)': [2886, 2891], '(yellow': [2890], '(e)': [2901], 'EPR': [2902, 2923, 2931, 3057], 'light-minus-dark': [2903], 'difference': [2904, 2916], 'Note:': [2914], 'spectrum': [2917, 2924, 2932], 'subtracting': [2921], 'measured': [2925], 'light.': [2934], '(f)': [2935], 'Schematic': [2936], 'illustration': [2937], 'excitation': [2940], 'catalyst–molecule': [2947], 'system.': [2949, 2978], 'immobilized': [2955], 'nanocomposites,': [2966], 'construct': [2968], 'both': [2969], 'metal–molecule': [2972], 'interfaces': [2973], '4-NTP,': [3002], 'prevents': [3004], '4,4′-DMAB': [3008], '4d).': [3010], 'illumination': [3012], 'also': [3016, 3179, 3283, 3295], 'distinct': [3019], 'paramagnetic': [3021], 'resonance': [3022], '(EPR)': [3023], 'bands': [3024], '4e),': [3026], 'respectively': [3030], 'oxygen': [3036], 'vacancies': [3037], '(VO,': [3038], '=': [3040, 3048], '2.006)': [3041], 'Ti3+': [3046, 3056], '(g': [3047], '1.966).35': [3049], 'no': [3051, 3549], 'discernible': [3052], 'contributions': [3053], 'light-induced': [3055], 'signal': [3058], 'pure': [3060], 'directly': [3078], 'generated': [3079], 'TiO2.35': [3081], 'Collectively,': [3082], 'these': [3083], '(including': [3085], 'photocurrent': [3087], 'responses': [3088], 'S9)': [3093], 'validate': [3094], 'plasmon-mediated': [3096], '4f)': [3104], 'confirm': [3106], 'S10)': [3120], 'prolonged': [3122], 'lifetime.': [3123], 'By': [3130, 3268, 3323], 'bond-formation': [3136], '5).': [3145], 'Isopropanol': [3146], 'solvent': [3151], 'dissolve': [3153], 'various': [3154], 'substrate': [3155], 'Additionally,': [3165], 'demonstrate': [3172], '(see': [3185], 'S11).': [3189], 'Paracetamol,': [3190], 'suitable': [3191], 'relieving': [3193], 'mild': [3194, 3201], 'moderate': [3196, 3344], 'pain,': [3197], 'conditions': [3203], 'noble': [3206], 'catalyst': [3208], 'reductant': [3211], 'applying': [3213], 'elevated': [3217], 'temperature).': [3218], 'series': [3222], 'nitroaromatic': [3224], '(1–5)': [3226], 'smoothly': [3229], 'converted': [3230], 'products.': [3235, 3361], 'Significantly,': [3236], 'rings': [3241], 'carrying': [3242], 'another': [3243], 'unsaturated': [3244], 'unit,': [3245], 'ester,': [3248], 'cyano,': [3249], 'alkynyl': [3251], 'group,': [3252], 'could': [3253, 3329], 'reduced': [3256], 'anilines': [3260], 'functionalized': [3263], 'products': [3266, 3302], '(6–8).': [3267], 'kinds': [3276], '(9': [3279], '10)': [3281], 'our': [3286], 'experiments.': [3287], 'nitro-reactants,': [3290], 'efficient': [3297], 'photocatalyst': [3298, 3392, 3487, 3521], 'synthesizing': [3300], 'media.': [3305], 'Compound': [3306], 'B': [3309], 'N-cyclohexyl': [3312], 'moiety': [3314], '5)': [3316], 'important': [3319], 'biologically': [3320], 'active': [3321], 'compounds.': [3322, 3403], 'n-cyclohexylbenzamide': [3328], 'photocatalytically': [3332], 'substrates': [3340], 'yields.': [3345], 'Figures': [3348], 'S12': [3349], 'S13': [3351], '5': [3363], 'Substrate': [3365], 'scope': [3366], 'nitro-compounds.': [3371], 'yield': [3373], 'determined': [3377], 'analysisa': [3381], 'analysisb.': [3384], 'Conclusion': [3389], 'eventually': [3414], 'captured': [3415], 'compensate': [3424], 'positively': [3426], 'holes)': [3431], 'oxidation': [3434], 'counter-half-reaction,': [3435], 'rebalances': [3437], 'reactivates': [3445], 'mechanism': [3450], 'supported': [3452], 'particle': [3456], 'spectral': [3458], '(OCP).': [3464], 'Finally,': [3465], 'ten': [3468], 'successfully': [3473], 'efficiently': [3489], 'synthetic': [3495], 'paves': [3498], 'way': [3500], 'rational': [3502], 'high-performance': [3505], 'metals': [3509], 'materials.': [3512], 'available': [3518], 'includes': [3520], 'characterization,': [3523], 'spectroscopic/electrochemical': [3524], 'measurement,': [3525], 'additional': [3530], 'diffraction,': [3534], 'photoelectron': [3536], 'spectroscopy,': [3537, 3541], 'TEM,': [3538], 'GC-MS.': [3543], 'Conflict': [3544], 'Interest': [3546], 'There': [3547], 'conflict': [3550], 'interest': [3552], 'report.': [3554], 'Funding': [3555], 'acknowledge': [3558], 'financial': [3560], 'support': [3561], 'National': [3564, 3574], 'R&D': [3566], 'Program': [3567], 'China': [3569, 3579], '(grant': [3570, 3580, 3589, 3597], 'no.': [3571, 3581, 3598], '2021YFB4000600),': [3572], 'Natural': [3575, 3584], 'Science': [3576, 3585], 'Foundation': [3577, 3586], '22022406),': [3582], 'nos.': [3590], '20JCJQJC00110': [3591], '20JCYBJC00590),': [3593], '111': [3595], 'project': [3596], 'B12015),': [3599], 'Transformations.': [3607], 'References': [3608], '1.': [3609], 'Bai': [3610], 'S.;': [3611, 3676, 3879, 3945, 4024, 4029, 4107, 4281, 4310, 4319, 4405, 4577, 4721, 4753, 4841, 4975, 5020, 5087, 5093, 5135, 5166, 5232, 5307], 'Qiu': [3612], 'H.;': [3613, 3704, 3788, 3790, 3819, 3855, 3912, 4022, 4162, 4203, 4228, 4234, 4272, 4278, 4330, 4646, 4684, 4713, 4726, 4800, 4874, 4877, 4969, 4986, 5008, 5027, 5130, 5235, 5283], 'Song': [3614], 'M.;': [3615, 3765, 3824, 3977, 4027, 4173, 4307, 4360, 4366, 4805, 4978, 5014, 5023, 5140, 5311], 'He': [3616, 4020, 4200, 4576, 4840, 4965, 5266], 'G.;': [3617, 3768, 4110, 4167, 4275, 4313, 4638, 4762, 4942], 'F.;': [3619, 3678, 3762, 3780, 3876, 3908, 3979, 4016, 4055, 4083, 4178, 4358, 4457, 4615, 4649, 4681, 4724, 4756, 4883, 5061, 5230], 'Liu': [3620, 3963, 4202, 4461, 4639, 4754, 4790, 4806, 5131, 5310], 'Y.;': [3621, 3668, 3698, 3710, 3858, 3864, 3988, 4058, 4086, 4176, 4369, 4397, 4466, 4582, 4748, 4751, 4789, 4794, 4803, 5052, 5133, 5200, 5202], 'Guo': [3622, 4578, 4714, 4727, 5194], 'L.Porous': [3623], 'Fixed-Bed': [3624], 'Photoreactor': [3625], 'Boosting': [3627], 'C–C': [3628], 'Coupling': [3629], 'CO2': [3632], 'Reduction.eScience2022,': [3633], '2,': [3634, 4071], '428–437.': [3635], 'Google': [3636, 3664, 3694, 3728, 3749, 3815, 3851, 3900, 3941, 3960, 4003, 4043, 4073, 4103, 4136, 4158, 4195, 4220, 4264, 4300, 4353, 4392, 4423, 4452, 4498, 4532, 4570, 4598, 4633, 4673, 4708, 4743, 4781, 4837, 4864, 4906, 4934, 4959, 5004, 5047, 5076, 5106, 5125, 5162, 5191, 5226, 5254, 5301, 5331], 'Scholar': [3637, 3665, 3695, 3729, 3750, 3816, 3852, 3901, 3942, 3961, 4004, 4044, 4074, 4104, 4137, 4159, 4196, 4221, 4265, 4301, 4354, 4393, 4424, 4453, 4499, 4533, 4571, 4599, 4634, 4674, 4709, 4744, 4782, 4838, 4865, 4907, 4935, 4960, 5005, 5048, 5077, 5107, 5126, 5163, 5192, 5227, 5255, 5302, 5332], '2.': [3638], 'Christopher': [3639, 3828, 3921], 'P.;': [3640, 3829, 3834, 3922, 3927, 4238, 4243, 4460, 4612, 4811, 5091, 5271], 'Xin': [3641], 'H.': [3642, 3756, 3872, 3914, 3987, 4240, 4268, 4277, 4333, 4459, 4509, 4543, 4785, 4810, 4868, 4971, 5016, 5276, 5279, 5285], 'L.;': [3643, 3712, 3754, 3775, 3822, 3870, 3917, 3920, 4431, 4503, 4537, 4677, 4689, 4847, 4869, 4916, 4964, 4967, 4972, 4984, 5011, 5017, 5025, 5055, 5058, 5063, 5309], 'Marimuthu': [3644], 'A.;': [3645, 3737, 3832, 3925, 4322, 4401, 4506, 4540, 4849, 4910, 5172, 5305], 'Linic': [3646, 3944], 'S.Singular': [3647], 'Characteristics': [3648], 'Unique': [3650], 'Bond': [3652, 3840, 4126], 'Activation': [3653, 3841], 'Mechanisms': [3654], 'Reactions': [3657, 4091, 4213, 4626], 'Nanostructures.Nat.': [3660], 'Mater.2012,': [3661], '11,': [3662, 4041, 4262, 4957, 5002], '1044–1050.': [3663], '3.': [3666], 'Nie': [3669], 'W.;': [3670, 3702, 3777, 4019, 4140, 4201, 4585, 4797, 4844, 5082, 5110, 5195, 5268, 5274], 'Zhu': [3671, 3758, 3986, 4014, 4458, 5308], 'Q.;': [3672, 3793, 3915, 4013, 4181, 4641, 4652, 4939, 4989, 5032], 'X.;': [3674, 3770, 3964, 4010, 4580, 4603, 4610, 4644, 4814, 4872, 5280], 'Fan': [3677, 3781, 3880, 4763, 4815, 5275], 'Li': [3679, 3794, 3854, 3883, 4017, 4053, 4182, 4242, 4249, 4601, 4760, 4766, 4792, 4818, 4940, 4979, 4990, 5033, 5264], 'C.The': [3680], 'Polarization': [3681], 'Effect': [3682], 'Surface-Plasmon-Induced': [3684], 'Au/TiO2': [3687, 3891], 'Nanoparticles.Angew.': [3688], 'Chem.': [3689, 3810, 3895, 3998, 4099, 4131, 4296, 4348, 4387, 4448, 4494, 4565, 4739, 4777, 4859, 4902, 5158, 5187, 5222, 5249, 5296], 'Int.': [3690, 3811, 3896, 3999, 4132, 4349, 4388, 4566, 4860, 5250, 5297], 'Ed.2020,': [3691, 5298], '59,': [3692, 5299], '18218–18223.': [3693], '4.': [3696], 'J.;': [3700, 3757, 3967, 4050, 4052, 4080, 4164, 4170, 4199, 4236, 4248, 4327, 4687, 4791, 4808, 5029, 5084, 5168, 5204, 5259, 5261, 5277], 'Liang': [3701], 'Yang': [3703, 3752, 3763, 3773, 4244, 4685, 4725, 4875, 4962, 4976, 4982, 5009, 5012], 'Guan': [3705, 3771], 'T.;': [3706, 3861, 3882, 3972, 4605, 4607, 4719, 4765, 4817, 4912, 5138, 5263], 'Zhao': [3707, 3868, 3913, 4011, 4232, 4361, 4650, 5064], 'B.;': [3708, 3867, 3873, 4225, 4246, 4363, 4371, 4468, 4880, 5066], 'Sun': [3709, 5024], 'Chi': [3711, 3871], 'Jiang': [3713, 4878], 'L.Rational': [3714], 'Design': [3715], 'Nanostructures': [3719, 4093, 4622, 5291], 'Solar': [3721], 'Conversion.CCS': [3723], 'Chem.2022,': [3724, 3746], '4,': [3725, 4530], '1153–1168.': [3726], 'Abstract,': [3727], '5.': [3730], 'Cortés': [3731, 5079, 5315], 'E.;': [3732, 3974, 3985, 4944, 5080, 5316], 'Grzeschik': [3733], 'R.;': [3734, 3783, 3982, 4325, 4588, 5089], 'Maier': [3735, 5094], 'S.': [3736, 3857, 3869, 3984, 4007, 4643, 4747, 5095], 'Schlücker': [3738, 4141, 5092, 5111], 'S.Experimental': [3739], 'Characterization': [3740], 'Techniques': [3741], 'Plasmon-Assisted': [3743], 'Chemistry.Nat.': [3744, 5102], 'Rev.': [3745, 4069], '6,': [3747, 4193, 5123], '259–274.': [3748], '6.': [3751], 'J.': [3753, 3785, 3795, 3821, 3866, 3878, 4015, 4054, 4112, 4183, 4230, 4365, 4502, 4536, 4584, 4587, 4609, 4614, 4617, 4654, 4683, 4807, 4821, 4843, 4846, 4876, 4882, 4963, 4974, 4991, 5010, 5019, 5034, 5237, 5270], 'Z.;': [3759, 3772, 4786], 'Yue': [3760], 'M.': [3761, 3860, 4026, 4796, 4980], 'W.': [3764, 4227, 4271, 4403, 4579, 4590, 4813, 4851, 4977, 5013, 5206, 5258], 'X.': [3767, 3976, 4049, 4079, 4166, 4637, 4715, 4728, 4793, 4802, 4938], 'Ruan': [3769], 'Z.': [3774, 3792, 4060, 4088, 4180, 4283, 4373, 4396, 4470, 4723, 4983, 4988, 5031, 5234], 'Cai': [3776], 'Wu': [3778, 4056, 4084, 4174, 4367, 4464, 5128], 'Y.': [3779, 3863, 3966, 3969, 4021, 4082, 4169, 4250, 4357, 4456, 4574, 4718, 4750, 4788, 4966, 5051, 5054, 5273, 5282], 'F.': [3782, 3881, 4324, 4764, 4816], 'Dong': [3784, 3918, 5050], 'C.;': [3786, 3910, 3949, 3970, 4008, 4047, 4077, 4428, 4575, 4759, 4819, 5198, 5265, 5314], 'Xu': [3789, 3978, 4645, 4804, 5028, 5257, 5278], 'Tian': [3791, 4059, 4087, 4179, 4372, 4469, 4987, 5030], 'F.In': [3796], 'Situ': [3797], 'Probing': [3799, 4437], 'Hot-Electron': [3801, 4186], 'Transfer': [3802, 4187, 4561], 'Gold–Graphene': [3804], 'Interfaces': [3805], 'Atomic': [3807], 'Layer': [3808], 'Accuracy.Angew.': [3809], 'Ed.2022,': [3812, 3897, 4000], '61,': [3813, 3898, 4001], 'e202112749.': [3814], '7.': [3817], 'Robatjazi': [3818, 3911], 'Bao': [3820, 5233], 'Zhou': [3825, 3903, 4198, 4223, 4688], 'L.': [3826, 3904, 3919, 4245, 4329, 4362, 4640, 4758, 4921, 5057], 'N.;': [3827, 3905, 4716], 'Carter': [3830, 3923], 'E.': [3831, 3924, 3981, 4404, 4430, 4799], 'Nordlander': [3833, 3926], 'Halas': [3835, 3928], 'N.': [3836, 3929, 4427, 4651], 'J.Plasmon-Driven': [3837], 'Carbon–Fluorine': [3838], '(C(sp3)–F)': [3839], 'Mechanistic': [3843], 'Insights': [3844], 'Hot-Carrier-Mediated': [3846], 'Pathways.Nat.': [3847], 'Catal.2020,': [3848], '3,': [3849, 5045], '564–573.': [3850], '8.': [3853], 'Tang': [3865], 'P.': [3875, 4172, 4332, 4508, 4542, 5022], 'Qu': [3877], 'C.Enhancement': [3884], 'Plasmon-Induced': [3886, 4700], 'Photoelectrocatalytic': [3887], 'Water': [3888, 4769, 5041, 5155], 'Oxidation': [3889, 4553, 4770], 'Lithium': [3893], 'Intercalation.Angew.': [3894], 'e202204272.': [3899], '9.': [3902], 'Swearer': [3906], 'D.': [3907, 4057, 4085, 4175, 4368, 4465, 4648, 4686, 5065, 5132], 'Henderson': [3916], 'J.Quantifying': [3930], 'Carrier': [3932], 'Thermal': [3934], 'Contributions': [3935], 'Photocatalysis.Science2018,': [3938], '362,': [3939], '69–72.': [3940], '10.': [3943], 'Aslam': [3946], 'U.;': [3947], 'Boerigter': [3948], 'Morabito': [3950], 'M.Photochemical': [3951], 'Transformations': [3952], 'Nanoparticles.Nat.': [3956], 'Mater.2015,': [3957], '14,': [3958], '567–576.': [3959], '11.': [3962], 'Shi': [3965], 'Jin': [3968, 4911], 'Tana': [3971], 'Peiris': [3973], 'Waclawik': [3980], 'Bottle': [3983], 'Sarina': [3989], 'S.Surface-Plasmon-Enhanced': [3990], 'Transmetalation': [3991], 'Between': [3992], 'Copper': [3993], 'Palladium': [3995], 'Nanoparticle': [3996], 'Catalyst.Angew.': [3997], 'e202203158.': [4002], '12.': [4005], 'Huang': [4006, 4081, 4204, 4356, 4455, 4583, 4842, 5203], 'Q.': [4012, 4691], 'C.': [4018, 4205, 4233, 4274, 4618, 4712, 4885], 'Hu': [4023, 4581, 5201], 'Sartin': [4025], 'Yan': [4028], 'Ren': [4030, 4370, 4467, 4968, 5007], 'B.Probing': [4031], 'Nanoscale': [4032], 'Spatial': [4033], 'Distribution': [4034], 'Plasmonically': [4036], 'Excited': [4037], 'Carriers.Nat.': [4039], 'Commun.2020,': [4040], '4211.': [4042], '13.': [4045], 'Zhan': [4046, 4076], 'Chen': [4048, 4078, 4678, 4720, 4812, 5284], 'Yi': [4051], 'Q.From': [4061], 'Plasmon-Enhanced': [4062, 4624, 4926, 5151], 'Spectroscopy': [4064], 'Plasmon-Mediated': [4066, 4512, 4666], 'Reactions.Nat.': [4068], 'Chem.2018,': [4070], '216–230.': [4072], '14.': [4075], 'Q.Plasmon-Mediated': [4089], 'Unveiled': [4094], 'Surface-Enhanced': [4096, 4435], 'Spectroscopy.Acc.': [4098], 'Res.2019,': [4100], '52,': [4101, 5252], '2784–2792.': [4102], '15.': [4105], 'Swaminathan': [4106], 'Rao': [4108], 'V.': [4109, 4312], 'Bera': [4111], 'K.;': [4113, 4269, 4463, 4679, 5170], 'Chandra': [4114], 'M.The': [4115], 'Pivotal': [4116], 'Role': [4117, 4440], 'Carriers': [4120, 4947], 'Catalysis': [4123], 'C–N': [4125], 'Forming': [4127], 'Reaction': [4128, 4286, 4771, 4996], 'Amines.Angew.': [4130], 'Ed.2021,': [4133], '60,': [4134], '12532–12538.': [4135], '16.': [4138], 'S.Surface-Enhanced': [4142], 'Spectroscopic': [4144], 'Detection': [4145], 'Chemo-': [4148], 'Plasmo-Catalysis': [4150], 'Noble': [4152], 'Nanoparticles.Chem.': [4154], 'Commun.2018,': [4155], '54,': [4156, 4568], '2326–2336.': [4157], '17.': [4160], 'Radjenovica': [4171], 'Pan': [4177, 4717], 'F.Plasmon-Induced': [4184], 'Interfacial': [4185], 'Directly': [4188, 4290], 'Probed': [4189, 4291], 'Spectroscopy.Chem2020,': [4192], '689–702.': [4194], '18.': [4197], 'Z.Energy': [4206], 'Flow': [4207], 'During': [4208, 4489], 'Plasmon': [4210, 4341, 4385, 4550], 'Resonance-Driven': [4211], 'Single': [4215, 4288], 'Nanoparticles.ACS': [4216], 'Catal.2022,': [4217], '12,': [4218], '847–853.': [4219], '19.': [4222], 'B.': [4224, 4602, 5129, 5267], 'Ou': [4226], 'Shen': [4229], 'D.;': [4231, 4241, 4919, 4981], 'Zhong': [4235, 4970, 5015], 'Du': [4237, 4870, 5056], 'Bian': [4239], 'Lu': [4247], 'Y.Controlling': [4251], 'Plasmon-Aided': [4252], 'Reduction': [4253, 5114], 'p-Nitrothiophenol': [4255], 'Tuning': [4257, 5287], 'Illumination': [4259], 'Wavelength.ACS': [4260], 'Catal.2021,': [4261, 5001], '14898–14905.': [4263], '20.': [4266], 'Choi': [4267], 'Park': [4270, 4273, 5165], 'Shin': [4276], 'Lee': [4279, 5306], 'K.': [4280], 'Kim': [4282], 'H.Metal-Catalyzed': [4284], 'Molecules': [4289, 5117], 'Vibrational': [4293], 'Spectroscopy.J.': [4294], 'Am.': [4295, 4493, 4738, 4776, 4901, 5157, 5186, 5221], 'Soc.2016,': [4297, 4740, 5159], '138,': [4298, 4741, 5160], '4673–4684.': [4299], '21.': [4302], 'da': [4303], 'Silva': [4304], 'G.': [4306, 4462, 4918, 4941, 5142], 'Rodrigues': [4308], 'T.': [4309, 4315, 4755, 5137], 'Correia': [4311], 'Alves': [4314, 4317], 'V.;': [4316, 4399, 4922], 'R.': [4318, 4321, 4433, 4505, 4539, 4761, 4879, 5060, 5313], 'Ando': [4320, 4504, 4538], 'Ornellas': [4323], 'Andrade': [4328], 'Camargo': [4331, 4507, 4541], 'C.Plasmonic': [4334], 'Nanorattles': [4335], 'Next-Generation': [4337], 'Catalysts': [4338], 'Surface': [4340, 4384, 4549, 5212], 'Resonance-Mediated': [4342], 'Oxidations': [4343], 'Promoted': [4344], 'Activated': [4346], 'Oxygen.Angew.': [4347], 'Ed.2016,': [4350], '55,': [4351], '7111–7115.': [4352], '22.': [4355], 'Feng': [4364, 5281], 'Q.Activation': [4374], 'Oxygen': [4376, 4892], 'Gold': [4378, 4895, 5148, 5219], 'Silver': [4380], 'Assisted': [4382], 'Resonances.Angew.': [4386], 'Ed.2014,': [4389], '53,': [4390], '2353–2357.': [4391], '23.': [4394], 'Merk': [4398], 'Hermanns': [4400], 'Unger': [4402], 'Kneipp': [4406], 'J.Role': [4407], 'Cations': [4410], 'Plasmon-Catalyzed': [4412], 'Oxidation:': [4413], 'Case': [4415], 'Study': [4416], 'p-Aminothiophenol': [4418, 4555], 'Dimerization.ACS': [4419], 'Catal.2017,': [4420], '7,': [4421, 4450], '7803–7809.': [4422], '24.': [4425], 'Brandt': [4426], 'Keller': [4429], 'Frontiera': [4432], 'R.Ultrafast': [4434], 'Electrons': [4443], 'Plasmon-Driven': [4445, 5215], 'Chemistry.J.': [4446], 'Phys.': [4447], 'Lett.2016,': [4449], '3179–3285.': [4451], '25.': [4454], 'Q.When': [4471], 'Signal': [4473], 'Is': [4474], 'Not': [4475], 'Original': [4478], 'Molecule': [4479], 'Detected:': [4482], 'Transformation': [4484], 'Para-Aminothiophenol': [4486], 'Measurement.J.': [4492], 'Soc.2010,': [4495], '132,': [4496], '9244–9246.': [4497], '26.': [4500], 'C.Investigating': [4510], 'Catalytic': [4513, 4625], 'Activity': [4514], 'AgAu': [4516], 'Function': [4520], 'Composition:': [4522], 'Are': [4523], 'Two': [4524], 'Metals': [4525], 'Better': 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[4839], 'Goodsell': [4845], 'Angerhofer': [4848], 'D.Plasmonic': [4852], 'Nickel–TiO2': [4853], 'Heterostructures': [4854, 5242], 'Visible-Light-Driven': [4856], 'Photochemical': [4857], 'Reactions.Angew.': [4858], 'Ed.2019,': [4861], '58,': [4862], '6038–6041.': [4863], '36.': [4866], 'Jia': [4867, 5260], 'Y.Site-Selective': [4886], 'Growth': [4887, 5144, 5217], 'Crystalline': [4889], 'Ceria': [4890], 'Vacancies': [4893], 'Nanocrystals': [4896], 'Near-Infrared': [4898], 'Nitrogen': [4899], 'Photofixation.J.': [4900], 'Soc.2019,': [4903], '141,': [4904], '5083–5086.': [4905], '37.': [4908], 'Gellé': [4909], 'de': [4913], 'la': [4914], 'Garza': [4915], 'Price': [4917], 'Besteiro': [4920], 'Moores': [4923], 'A.Applications': [4924], 'Nanocatalysis': [4927], 'Organic': [4929], 'Transformations.Chem.': [4930], 'Rev.2020,': [4931], '120,': [4932], '986–1041.': [4933], '38.': [4936], 'Fu': [4937], 'Villarreal': [4943], 'H.Hot': [4946], 'Action:': [4949], 'Multimodal': [4950], 'protected]2': 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