Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W4288036009', 'doi': 'https://doi.org/10.1073/pnas.2122677119', 'title': 'A complete biomimetic iron-sulfur cubane redox series', 'display_name': 'A complete biomimetic iron-sulfur cubane redox series', 'publication_year': 2022, 'publication_date': '2022-07-26', 'ids': {'openalex': 'https://openalex.org/W4288036009', 'doi': 'https://doi.org/10.1073/pnas.2122677119', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/35881795'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1073/pnas.2122677119', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S125754415', 'display_name': 'Proceedings of the National Academy of Sciences', 'issn_l': '0027-8424', 'issn': ['0027-8424', '1091-6490'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320052', 'host_organization_name': 'National Academy of Sciences', 'host_organization_lineage': ['https://openalex.org/P4310320052'], 'host_organization_lineage_names': ['National Academy of Sciences'], 'type': 'journal'}, 'license': 'cc-by-nc-nd', 'license_id': 'https://openalex.org/licenses/cc-by-nc-nd', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': True, 'oa_status': 'hybrid', 'oa_url': 'https://doi.org/10.1073/pnas.2122677119', 'any_repository_has_fulltext': True}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5012579270', 'display_name': 'Liam Grunwald', 'orcid': 'https://orcid.org/0000-0001-7710-1326'}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'Liam Grunwald', 'raw_affiliation_strings': ['Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5037633972', 'display_name': 'Martin Clémancey', 'orcid': 'https://orcid.org/0000-0001-6088-3026'}, 'institutions': [{'id': 'https://openalex.org/I3020098449', 'display_name': 'CEA Grenoble', 'ror': 'https://ror.org/02mg6n827', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131', 'https://openalex.org/I3020098449']}, {'id': 'https://openalex.org/I899635006', 'display_name': 'Université Grenoble Alpes', 'ror': 'https://ror.org/02rx3b187', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I899635006']}, {'id': 'https://openalex.org/I2738703131', 'display_name': "Commissariat à l'Énergie Atomique et aux Énergies Alternatives", 'ror': 'https://ror.org/00jjx8s55', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}, {'id': 'https://openalex.org/I4210127966', 'display_name': 'Laboratoire de Chimie et Biologie des Métaux', 'ror': 'https://ror.org/02dd25k08', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I2738703131', 'https://openalex.org/I4210091409', 'https://openalex.org/I4210127966', 'https://openalex.org/I4210128300', 'https://openalex.org/I899635006']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Martin Clémancey', 'raw_affiliation_strings': ["University of Grenoble Alpes, CNRS, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Laboratoire de Chimie et Biologie des Métaux, Physicochimie des Métaux en Biologie (PMB), CEA Grenoble, Grenoble Cedex, F-38054 France"], 'affiliations': [{'raw_affiliation_string': "University of Grenoble Alpes, CNRS, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Laboratoire de Chimie et Biologie des Métaux, Physicochimie des Métaux en Biologie (PMB), CEA Grenoble, Grenoble Cedex, F-38054 France", 'institution_ids': ['https://openalex.org/I3020098449', 'https://openalex.org/I899635006', 'https://openalex.org/I2738703131', 'https://openalex.org/I1294671590', 'https://openalex.org/I4210127966']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5045814455', 'display_name': 'Daniel Klose', 'orcid': 'https://orcid.org/0000-0002-3597-0889'}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'Daniel Klose', 'raw_affiliation_strings': ['Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5042137930', 'display_name': 'Lionel Dubois', 'orcid': 'https://orcid.org/0000-0003-3336-4938'}, 'institutions': [{'id': 'https://openalex.org/I899635006', 'display_name': 'Université Grenoble Alpes', 'ror': 'https://ror.org/02rx3b187', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I899635006']}, {'id': 'https://openalex.org/I2738703131', 'display_name': "Commissariat à l'Énergie Atomique et aux Énergies Alternatives", 'ror': 'https://ror.org/00jjx8s55', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}, {'id': 'https://openalex.org/I4400600907', 'display_name': "Systèmes Moléculaires et nanoMatériaux pour l'Énergie et la Santé", 'ror': 'https://ror.org/0535cbn94', 'country_code': None, 'type': 'education', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I2738703131', 'https://openalex.org/I4210091409', 'https://openalex.org/I4400600907', 'https://openalex.org/I899635006']}, {'id': 'https://openalex.org/I3020098449', 'display_name': 'CEA Grenoble', 'ror': 'https://ror.org/02mg6n827', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131', 'https://openalex.org/I3020098449']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Lionel Dubois', 'raw_affiliation_strings': ["University of Grenoble Alpes, CNRS, CEA, IRIG, Systèmes Moléculaires et nanoMatériaux pour l'Énergie et la Santé (SyMMES), CEA Grenoble, Grenoble Cedex, F-38054 France"], 'affiliations': [{'raw_affiliation_string': "University of Grenoble Alpes, CNRS, CEA, IRIG, Systèmes Moléculaires et nanoMatériaux pour l'Énergie et la Santé (SyMMES), CEA Grenoble, Grenoble Cedex, F-38054 France", 'institution_ids': ['https://openalex.org/I899635006', 'https://openalex.org/I2738703131', 'https://openalex.org/I1294671590', 'https://openalex.org/I4400600907', 'https://openalex.org/I3020098449']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5103491703', 'display_name': 'Serge Gambarelli', 'orcid': 'https://orcid.org/0000-0002-7204-7022'}, 'institutions': [{'id': 'https://openalex.org/I3020098449', 'display_name': 'CEA Grenoble', 'ror': 'https://ror.org/02mg6n827', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131', 'https://openalex.org/I3020098449']}, {'id': 'https://openalex.org/I899635006', 'display_name': 'Université Grenoble Alpes', 'ror': 'https://ror.org/02rx3b187', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I899635006']}, {'id': 'https://openalex.org/I2738703131', 'display_name': "Commissariat à l'Énergie Atomique et aux Énergies Alternatives", 'ror': 'https://ror.org/00jjx8s55', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}, {'id': 'https://openalex.org/I4400600907', 'display_name': "Systèmes Moléculaires et nanoMatériaux pour l'Énergie et la Santé", 'ror': 'https://ror.org/0535cbn94', 'country_code': None, 'type': 'education', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I2738703131', 'https://openalex.org/I4210091409', 'https://openalex.org/I4400600907', 'https://openalex.org/I899635006']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Serge Gambarelli', 'raw_affiliation_strings': ["University of Grenoble Alpes, CNRS, CEA, IRIG, Systèmes Moléculaires et nanoMatériaux pour l'Énergie et la Santé (SyMMES), CEA Grenoble, Grenoble Cedex, F-38054 France"], 'affiliations': [{'raw_affiliation_string': "University of Grenoble Alpes, CNRS, CEA, IRIG, Systèmes Moléculaires et nanoMatériaux pour l'Énergie et la Santé (SyMMES), CEA Grenoble, Grenoble Cedex, F-38054 France", 'institution_ids': ['https://openalex.org/I3020098449', 'https://openalex.org/I899635006', 'https://openalex.org/I2738703131', 'https://openalex.org/I1294671590', 'https://openalex.org/I4400600907']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5013565453', 'display_name': 'Gunnar Jeschke', 'orcid': 'https://orcid.org/0000-0001-6853-8585'}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'Gunnar Jeschke', 'raw_affiliation_strings': ['Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5048941488', 'display_name': 'Michael Wörle', 'orcid': 'https://orcid.org/0000-0001-8087-5779'}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'Michael Wörle', 'raw_affiliation_strings': ['Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5035631163', 'display_name': 'Geneviève Blondin', 'orcid': 'https://orcid.org/0000-0002-8045-6328'}, 'institutions': [{'id': 'https://openalex.org/I4210127966', 'display_name': 'Laboratoire de Chimie et Biologie des Métaux', 'ror': 'https://ror.org/02dd25k08', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I2738703131', 'https://openalex.org/I4210091409', 'https://openalex.org/I4210127966', 'https://openalex.org/I4210128300', 'https://openalex.org/I899635006']}, {'id': 'https://openalex.org/I3020098449', 'display_name': 'CEA Grenoble', 'ror': 'https://ror.org/02mg6n827', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131', 'https://openalex.org/I3020098449']}, {'id': 'https://openalex.org/I899635006', 'display_name': 'Université Grenoble Alpes', 'ror': 'https://ror.org/02rx3b187', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I899635006']}, {'id': 'https://openalex.org/I2738703131', 'display_name': "Commissariat à l'Énergie Atomique et aux Énergies Alternatives", 'ror': 'https://ror.org/00jjx8s55', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I2738703131']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Geneviève Blondin', 'raw_affiliation_strings': ["University of Grenoble Alpes, CNRS, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Laboratoire de Chimie et Biologie des Métaux, Physicochimie des Métaux en Biologie (PMB), CEA Grenoble, Grenoble Cedex, F-38054 France"], 'affiliations': [{'raw_affiliation_string': "University of Grenoble Alpes, CNRS, Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Laboratoire de Chimie et Biologie des Métaux, Physicochimie des Métaux en Biologie (PMB), CEA Grenoble, Grenoble Cedex, F-38054 France", 'institution_ids': ['https://openalex.org/I4210127966', 'https://openalex.org/I3020098449', 'https://openalex.org/I899635006', 'https://openalex.org/I2738703131', 'https://openalex.org/I1294671590']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5017673806', 'display_name': 'Victor Mougel', 'orcid': 'https://orcid.org/0000-0003-4136-7442'}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'Victor Mougel', 'raw_affiliation_strings': ['Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry and Applied Biosciences (D-CHAB), ETH Zürich, CH-8093 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}], 'institution_assertions': [], 'countries_distinct_count': 2, 'institutions_distinct_count': 7, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 0.481, 'has_fulltext': True, 'fulltext_origin': 'pdf', 'cited_by_count': 7, 'citation_normalized_percentile': {'value': 0.496704, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 87, 'max': 88}, 'biblio': {'volume': '119', 'issue': '31', 'first_page': None, 'last_page': None}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11626', 'display_name': 'Metalloenzymes and iron-sulfur proteins', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2105', 'display_name': 'Renewable Energy, Sustainability and the Environment'}, 'field': {'id': 'https://openalex.org/fields/21', 'display_name': 'Energy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11626', 'display_name': 'Metalloenzymes and iron-sulfur proteins', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2105', 'display_name': 'Renewable Energy, Sustainability and the Environment'}, 'field': {'id': 'https://openalex.org/fields/21', 'display_name': 'Energy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11747', 'display_name': 'Metal-Catalyzed Oxygenation Mechanisms', 'score': 0.9989, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10163', 'display_name': 'Metal complexes synthesis and properties', 'score': 0.9982, 'subfield': {'id': 'https://openalex.org/subfields/2730', 'display_name': 'Oncology'}, 'field': {'id': 'https://openalex.org/fields/27', 'display_name': 'Medicine'}, 'domain': {'id': 'https://openalex.org/domains/4', 'display_name': 'Health Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/cubane', 'display_name': 'Cubane', 'score': 0.9032753}, {'id': 'https://openalex.org/keywords/oxidation-state', 'display_name': 'Oxidation state', 'score': 0.58713883}, {'id': 'https://openalex.org/keywords/x-ray-absorption-spectroscopy', 'display_name': 'X-ray absorption spectroscopy', 'score': 0.41508383}], 'concepts': [{'id': 'https://openalex.org/C2780750454', 'wikidata': 'https://www.wikidata.org/wiki/Q413624', 'display_name': 'Cubane', 'level': 3, 'score': 0.9032753}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.76997346}, {'id': 'https://openalex.org/C55904794', 'wikidata': 'https://www.wikidata.org/wiki/Q82682', 'display_name': 'Redox', 'level': 2, 'score': 0.74964726}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.6593535}, {'id': 'https://openalex.org/C187961010', 'wikidata': 'https://www.wikidata.org/wiki/Q260463', 'display_name': 'Electron paramagnetic resonance', 'level': 2, 'score': 0.59187114}, {'id': 'https://openalex.org/C2778591166', 'wikidata': 'https://www.wikidata.org/wiki/Q484152', 'display_name': 'Oxidation state', 'level': 3, 'score': 0.58713883}, {'id': 'https://openalex.org/C70854507', 'wikidata': 'https://www.wikidata.org/wiki/Q899927', 'display_name': 'Mössbauer spectroscopy', 'level': 2, 'score': 0.5699384}, {'id': 'https://openalex.org/C52859227', 'wikidata': 'https://www.wikidata.org/wiki/Q7877', 'display_name': 'Electrochemistry', 'level': 3, 'score': 0.5045346}, {'id': 'https://openalex.org/C116569031', 'wikidata': 'https://www.wikidata.org/wiki/Q899107', 'display_name': 'Ligand (biochemistry)', 'level': 3, 'score': 0.44834113}, {'id': 'https://openalex.org/C2777869211', 'wikidata': 'https://www.wikidata.org/wiki/Q1147647', 'display_name': 'Cyclic voltammetry', 'level': 4, 'score': 0.44346792}, {'id': 'https://openalex.org/C544153396', 'wikidata': 'https://www.wikidata.org/wiki/Q11426', 'display_name': 'Metal', 'level': 2, 'score': 0.43627793}, {'id': 'https://openalex.org/C62284982', 'wikidata': 'https://www.wikidata.org/wiki/Q903103', 'display_name': 'X-ray absorption spectroscopy', 'level': 3, 'score': 0.41508383}, {'id': 'https://openalex.org/C518881349', 'wikidata': 'https://www.wikidata.org/wiki/Q682', 'display_name': 'Sulfur', 'level': 2, 'score': 0.4115725}, {'id': 'https://openalex.org/C179104552', 'wikidata': 'https://www.wikidata.org/wiki/Q11165', 'display_name': 'Inorganic chemistry', 'level': 1, 'score': 0.3758396}, {'id': 'https://openalex.org/C119824511', 'wikidata': 'https://www.wikidata.org/wiki/Q13553575', 'display_name': 'Absorption spectroscopy', 'level': 2, 'score': 0.36600953}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.16359362}, {'id': 'https://openalex.org/C115624301', 'wikidata': 'https://www.wikidata.org/wiki/Q895901', 'display_name': 'Crystal structure', 'level': 2, 'score': 0.13074681}, {'id': 'https://openalex.org/C46141821', 'wikidata': 'https://www.wikidata.org/wiki/Q209402', 'display_name': 'Nuclear magnetic resonance', 'level': 1, 'score': 0.10225585}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.08729929}, {'id': 'https://openalex.org/C17525397', 'wikidata': 'https://www.wikidata.org/wiki/Q176140', 'display_name': 'Electrode', 'level': 2, 'score': 0.083435774}, {'id': 'https://openalex.org/C55493867', 'wikidata': 'https://www.wikidata.org/wiki/Q7094', 'display_name': 'Biochemistry', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C170493617', 'wikidata': 'https://www.wikidata.org/wiki/Q208467', 'display_name': 'Receptor', 'level': 2, 'score': 0.0}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}], 'mesh': [{'descriptor_ui': 'D040761', 'descriptor_name': 'Biomimetic Materials', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': True}, {'descriptor_ui': 'D003067', 'descriptor_name': 'Coenzymes', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': True}, {'descriptor_ui': 'D006838', 'descriptor_name': 'Hydrocarbons', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': True}, {'descriptor_ui': 'D007501', 'descriptor_name': 'Iron', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': True}, {'descriptor_ui': 'D009591', 'descriptor_name': 'Nitrogenase', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': True}, {'descriptor_ui': 'D013455', 'descriptor_name': 'Sulfur', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': True}, {'descriptor_ui': 'D040761', 'descriptor_name': 'Biomimetic Materials', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': False}, {'descriptor_ui': 'D040761', 'descriptor_name': 'Biomimetic Materials', 'qualifier_ui': 'Q000138', 'qualifier_name': 'chemical synthesis', 'is_major_topic': False}, {'descriptor_ui': 'D003067', 'descriptor_name': 'Coenzymes', 'qualifier_ui': 'Q000138', 'qualifier_name': 'chemical synthesis', 'is_major_topic': False}, {'descriptor_ui': 'D003067', 'descriptor_name': 'Coenzymes', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': False}, {'descriptor_ui': 'D006838', 'descriptor_name': 'Hydrocarbons', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': False}, {'descriptor_ui': 'D006838', 'descriptor_name': 'Hydrocarbons', 'qualifier_ui': 'Q000138', 'qualifier_name': 'chemical synthesis', 'is_major_topic': False}, {'descriptor_ui': 'D007501', 'descriptor_name': 'Iron', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': False}, {'descriptor_ui': 'D009591', 'descriptor_name': 'Nitrogenase', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': False}, {'descriptor_ui': 'D010084', 'descriptor_name': 'Oxidation-Reduction', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D013455', 'descriptor_name': 'Sulfur', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': False}], 'locations_count': 6, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.1073/pnas.2122677119', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S125754415', 'display_name': 'Proceedings of the National Academy of Sciences', 'issn_l': '0027-8424', 'issn': ['0027-8424', '1091-6490'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320052', 'host_organization_name': 'National Academy of Sciences', 'host_organization_lineage': ['https://openalex.org/P4310320052'], 'host_organization_lineage_names': ['National Academy of Sciences'], 'type': 'journal'}, 'license': 'cc-by-nc-nd', 'license_id': 'https://openalex.org/licenses/cc-by-nc-nd', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://hal.science/hal-04032654', 'pdf_url': 'https://hal.science/hal-04032654/document', 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': 'cc-by-nc-nd', 'license_id': 'https://openalex.org/licenses/cc-by-nc-nd', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9351461', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S2764455111', 'display_name': 'PubMed Central', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': True, 'landing_page_url': 'https://doi.org/10.26434/chemrxiv-2021-4qzlh', 'pdf_url': 'https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/61b06f72476fcd5ab80b2a86/original/a-complete-biomimetic-iron-sulfur-cubane-redox-series.pdf', 'source': None, 'license': 'cc-by-nc-nd', 'license_id': 'https://openalex.org/licenses/cc-by-nc-nd', 'version': 'submittedVersion', 'is_accepted': False, 'is_published': False}, {'is_oa': True, 'landing_page_url': 'https://doi.org/10.26434/chemrxiv-2021-4qzlh-v2', 'pdf_url': 'https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/61b1da29535d63178d954226/original/a-complete-biomimetic-iron-sulfur-cubane-redox-series.pdf', 'source': None, 'license': 'cc-by-nc-nd', 'license_id': 'https://openalex.org/licenses/cc-by-nc-nd', 'version': 'submittedVersion', 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/35881795', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1073/pnas.2122677119', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S125754415', 'display_name': 'Proceedings of the National Academy of Sciences', 'issn_l': '0027-8424', 'issn': ['0027-8424', '1091-6490'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320052', 'host_organization_name': 'National Academy of Sciences', 'host_organization_lineage': ['https://openalex.org/P4310320052'], 'host_organization_lineage_names': ['National Academy of Sciences'], 'type': 'journal'}, 'license': 'cc-by-nc-nd', 'license_id': 'https://openalex.org/licenses/cc-by-nc-nd', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [{'display_name': 'Clean water and sanitation', 'id': 'https://metadata.un.org/sdg/6', 'score': 0.73}], 'grants': [{'funder': 'https://openalex.org/F4320320883', 'funder_display_name': 'Agence Nationale de la Recherche', 'award_id': 'ANR-17-EURE-0003'}, {'funder': 'https://openalex.org/F4320322364', 'funder_display_name': 'Labex', 'award_id': 'Arcane'}, {'funder': 'https://openalex.org/F4320334678', 'funder_display_name': 'European Research Council', 'award_id': '853064'}], 'datasets': ['https://openalex.org/W4397836508', 'https://openalex.org/W4397863700', 'https://openalex.org/W4397924070', 'https://openalex.org/W4397915478', 'https://openalex.org/W4397953021', 'https://openalex.org/W4397986759', 'https://openalex.org/W4398022416'], 'versions': [], 'referenced_works_count': 53, 'referenced_works': ['https://openalex.org/W1515548591', 'https://openalex.org/W1627176155', 'https://openalex.org/W1964804396', 'https://openalex.org/W1966282709', 'https://openalex.org/W1976347486', 'https://openalex.org/W1979945414', 'https://openalex.org/W1982175028', 'https://openalex.org/W1985339035', 'https://openalex.org/W1994565127', 'https://openalex.org/W2003456382', 'https://openalex.org/W2005341395', 'https://openalex.org/W2006702354', 'https://openalex.org/W2007174379', 'https://openalex.org/W2030043066', 'https://openalex.org/W2036290658', 'https://openalex.org/W2036809711', 'https://openalex.org/W2040412213', 'https://openalex.org/W2051509289', 'https://openalex.org/W2051784835', 'https://openalex.org/W2056268013', 'https://openalex.org/W2057687774', 'https://openalex.org/W2058053026', 'https://openalex.org/W2060986410', 'https://openalex.org/W2061407935', 'https://openalex.org/W2064224876', 'https://openalex.org/W2075421001', 'https://openalex.org/W2079584731', 'https://openalex.org/W2081109344', 'https://openalex.org/W2083116340', 'https://openalex.org/W2083569181', 'https://openalex.org/W2083701649', 'https://openalex.org/W2088435565', 'https://openalex.org/W2118760448', 'https://openalex.org/W2120233976', 'https://openalex.org/W2163349415', 'https://openalex.org/W2165886769', 'https://openalex.org/W2313290078', 'https://openalex.org/W2321750096', 'https://openalex.org/W2326318157', 'https://openalex.org/W2410025082', 'https://openalex.org/W2591304766', 'https://openalex.org/W2605185437', 'https://openalex.org/W2805003544', 'https://openalex.org/W2911364839', 'https://openalex.org/W2951842384', 'https://openalex.org/W3000680601', 'https://openalex.org/W3002794944', 'https://openalex.org/W3003831101', 'https://openalex.org/W3005439858', 'https://openalex.org/W3114391595', 'https://openalex.org/W3164001450', 'https://openalex.org/W3217267830', 'https://openalex.org/W433983911'], 'related_works': ['https://openalex.org/W4386671743', 'https://openalex.org/W4312312159', 'https://openalex.org/W4296181560', 'https://openalex.org/W4214722386', 'https://openalex.org/W4205421858', 'https://openalex.org/W2970359518', 'https://openalex.org/W2952543679', 'https://openalex.org/W238070727', 'https://openalex.org/W1984176813', 'https://openalex.org/W1972944739'], 'abstract_inverted_index': {'Synthetic': [0], 'iron-sulfur': [1], 'cubanes': [2], 'are': [3, 9], 'models': [4], 'for': [5, 113, 126], 'biological': [6], 'cofactors,': [7], 'which': [8, 131], 'essential': [10], 'to': [11], 'delineate': [12], 'oxidation': [13, 136], 'states': [14, 36], 'in': [15, 80], 'the': [16, 42, 55, 67, 75, 81, 84, 87, 114, 117, 127, 141, 149, 154, 175, 190], 'more': [17], 'complex': [18], 'enzymatic': [19], 'systems.': [20], 'However,': [21], 'a': [22, 70, 91, 187], 'complete': [23], 'series': [24], 'of': [25, 41, 58, 69, 77, 83, 89, 116, 148, 153, 189], '[Fe': [26, 156, 176], '4': [27, 29, 119, 121, 144, 157, 159, 177, 179], 'S': [28, 120, 142, 158, 178], ']': [30, 160, 180], 'n': [31, 47], 'complexes': [32], 'spanning': [33], 'all': [34], 'redox': [35], 'accessible': [37, 170], 'by': [38, 94], '1-electron': [39], 'transformations': [40], 'individual': [43], 'iron': [44, 192], 'atoms': [45], '(': [46], '=': [48, 143], '0–4+)': [49], 'has': [50], 'never': [51], 'been': [52], 'prepared,': [53], 'deterring': [54], 'methodical': [56], 'comparison': [57], 'structure': [59], 'and': [60, 107, 163], 'spectroscopic': [61], 'signature.': [62], 'Here,': [63], 'we': [64, 139], 'demonstrate': [65], 'that': [66, 167], 'use': [68], 'bulky': [71], 'arylthiolate': [72], 'ligand': [73], 'promoting': [74], 'encapsulation': [76], 'alkali-metal': [78], 'cations': [79], 'vicinity': [82], 'cubane': [85], 'enables': [86], 'synthesis': [88], 'such': [90], 'series.': [92], 'Characterization': [93], 'EPR,': [95], '57': [96], 'Fe': [97, 118], 'Mössbauer': [98, 128], 'spectroscopy,': [99], 'UV-visible': [100], 'electronic': [101, 145], 'absorption,': [102], 'variable-temperature': [103], 'X-ray': [104], 'diffraction': [105], 'analysis,': [106], 'cyclic': [108], 'voltammetry': [109], 'reveals': [110], 'key': [111], 'trends': [112], 'geometry': [115], 'core': [122], 'as': [123, 125, 186], 'well': [124], 'isomer': [129], 'shift,': [130], 'both': [132], 'correlate': [133], 'systematically': [134], 'with': [135], 'state.': [137], 'Furthermore,': [138], 'confirm': [140], 'ground': [146], 'state': [147], 'most': [150], 'reduced': [151], 'member': [152], 'series,': [155], '0': [161], ',': [162], 'provide': [164], 'electrochemical': [165], 'evidence': [166], 'it': [168], 'is': [169], 'within': [171], '0.82': [172], 'V': [173], 'from': [174], '2+': [181], 'state,': [182], 'highlighting': [183], 'its': [184], 'relevance': [185], 'mimic': [188], 'nitrogenase': [191], 'protein': [193], 'cluster.': [194]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W4288036009', 'counts_by_year': [{'year': 2024, 'cited_by_count': 4}, {'year': 2023, 'cited_by_count': 3}], 'updated_date': '2025-01-12T22:27:54.421857', 'created_date': '2022-07-27'}