Publication Information

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'wok.Google': [79, 114], 'Scholar': [80, 115, 141, 167, 193, 219, 241, 263, 289, 325, 361, 3408, 3425, 3462, 3488, 3507, 3551, 3590, 3618, 3663, 3692, 3721, 3776, 3817, 3847, 3894, 3928, 3952, 3970, 4011, 4044, 4092, 4123, 4166, 4200], 'More': [81, 116, 142, 168, 194, 220, 242, 264, 290, 326, 362, 1868], 'articles': [82, 117, 143, 169, 195, 221, 243, 265, 291, 327, 363], 'by': [83, 118, 144, 170, 196, 222, 244, 266, 292, 328, 364, 853, 878, 888, 1321, 1382, 1521, 1643, 1657, 1695, 2207, 2368, 2419, 2566, 2745, 2771, 2775, 2855, 2887, 2900, 2926, 3052, 3351, 3449, 4185], 'author': [85, 120, 146, 172, 198, 224, 246, 268, 294, 330, 366], ',': [86, 121, 147, 173, 199, 225, 247, 269, 295], 'Wu†': [88], 'Mei': [123], 'Google': [140, 166, 192, 218, 240, 262, 288, 324, 360, 3407, 3424, 3461, 3487, 3506, 3550, 3589, 3617, 3662, 3691, 3720, 3775, 3816, 3846, 3893, 3927, 3951, 3969, 4010, 4043, 4091, 4122, 4165, 4199], 'Zeng': [149], 'Huang': [175, 3723], 'Yu': [201, 3596], 'Nie': [227], 'Gibson': [250], 'Sciences': [252], 'Division,': [253], 'Lawrence': [254], 'Berkeley': [255], 'National': [256, 3316, 3333], '(LBNL),': [258], 'Berkeley,': [259], 'California': [260], '94720': [261], 'Chai': [271, 4074, 4144], '*Corresponding': [298, 334], 'authors:': [299, 335], 'E-mail': [300, 304, 336, 340], 'Address:': [301, 305, 337, 341], '[email': [302, 306, 338, 342], 'protected]': [303, 307, 339, 343], 'https://doi.org/10.31635/ccschem.022.202202054': [367], 'SectionsSupplemental': [368], 'MaterialAboutAbstractPDF': [369], 'ToolsAdd': [370], 'favoritesDownload': [372], 'CitationsTrack': [373], 'Citations': [374], 'ShareFacebookTwitterLinked': [375], 'InEmail': [376], 'Herein,': [377], 'we': [378, 783, 2485], 'report': [379], 'the': [380, 418, 449, 491, 552, 611, 710, 732, 748, 764, 777, 841, 854, 918, 927, 948, 986, 992, 1004, 1008, 1023, 1031, 1046, 1058, 1063, 1083, 1108, 1115, 1124, 1163, 1204, 1208, 1219, 1234, 1255, 1263, 1291, 1302, 1318, 1322, 1341, 1352, 1373, 1379, 1415, 1451, 1514, 1592, 1635, 1665, 1670, 1674, 1678, 1687, 1740, 1776, 1802, 1870, 1874, 1898, 1905, 1966, 2052, 2056, 2069, 2081, 2100, 2104, 2125, 2151, 2165, 2180, 2189, 2204, 2213, 2235, 2253, 2290, 2298, 2326, 2381, 2420, 2438, 2442, 2463, 2466, 2498, 2543, 2570, 2581, 2618, 2625, 2628, 2644, 2685, 2710, 2755, 2772, 2776, 2863, 2877, 2908, 2920, 2933, 2937, 2956, 2978, 3151, 3211, 3234, 3251, 3315, 3329, 3332, 3352, 3656, 3710, 3757, 4000, 4003, 4037, 4113], 'synthesis': [381, 414, 636, 751, 1009, 2544, 2944], 'structures': [383, 1048, 1131, 1968, 1988, 1998, 2464], 'two': [385, 712, 1013, 1306, 1309, 1363, 1385, 1599, 1631, 1658, 1696, 1701, 1935, 2719, 2725, 2901], 'novel': [386, 409, 790, 894, 1967, 3101], 'mixed-metal': [387, 895, 1133, 1962, 3102], 'clusters': [388, 395, 420, 515, 543, 556, 583, 592, 643, 660, 677, 692, 741, 756, 811, 826, 831, 896, 909, 1039, 1134, 1727, 1920, 1963, 1984, 2018, 2071, 2385, 2663, 2679, 2794, 2810, 2819, 2954, 3123, 3223], 'denoted': [389, 897], 'as': [390, 529, 684, 813, 898, 1519, 1737, 1858, 1860, 1994, 2526, 3447, 3575], 'Th9Ag6': [391, 899, 1236, 1375, 1438, 2864, 2921, 2951, 3062], 'Th9Ag12.': [393, 3077], 'Both': [394, 906, 3122], 'feature': [396, 910, 2476, 3124], 'unprecedented': [397, 1335], 'Th9': [398, 419, 471, 915, 1011, 1328, 1465, 1573, 2166, 2366, 2469, 2502, 3127, 3152, 3191], 'cores.': [399], 'The': [400, 560, 1036, 1067, 1285, 1532, 1566, 1926, 1982, 2032, 2063, 2120, 2168, 2210, 2274, 2654, 2942, 3345], 'cores': [401, 1466, 2020, 2470], 'are': [402, 408, 421, 516, 721, 802, 1043, 1177, 1294, 1500, 1550, 1641, 1654, 1692, 1773, 1949, 2045, 2115, 2615, 3155, 3301, 3307], 'tricapped': [403, 912, 1329, 1409, 3128], 'trigonal': [404, 913, 1330, 1410, 1461, 3129], 'prism': [405, 914, 1268, 1320, 1331, 1411, 1448, 1462, 3130], 'moieties': [406, 719], 'that': [407, 417, 476, 571, 584, 720, 728, 832, 1139, 1176, 1549, 1577, 1627, 1653, 1728, 1878, 1945, 2141, 2373, 2462, 2636, 2657, 2800, 2832, 2892], 'among': [410], 'actinides.': [411, 3140], 'Attempted': [412], 'alternative': [413], 'routes': [415], 'indicate': [416, 1799, 3142], 'accessible': [422, 3156], 'only': [423, 3157], 'through': [424, 1305, 1362, 1602, 3158], 'slow': [425, 2415], 'introduction': [426, 2688, 2783], 'Ag+': [428, 444, 880, 2369, 2418, 2803, 3039, 3143, 3165], 'into': [429, 681, 804, 1105, 2099, 3166, 3655], 'a': [430, 433, 455, 619, 652, 758, 785, 805, 882, 911, 939, 1144, 1245, 1266, 1327, 1572, 1615, 1718, 1784, 1854, 1888, 1908, 2143, 2282, 2391, 2401, 2428, 2477, 2487, 2551, 2567, 2595, 2650, 2735, 2836, 2841, 2928, 3125, 3134, 3145, 3159, 3167, 3256, 3501, 3534, 3576, 3649, 4081, 4151, 4186, 4190], 'solution': [431, 806, 883, 2379, 2382, 2439, 2528, 2552, 3168], 'containing': [432, 714, 2383, 2553], 'Th6': [434, 450, 473, 953, 1353, 1452, 1595, 1638, 2364, 2467, 2499, 2678, 2880, 3170, 3177, 3189], 'cluster': [435, 451, 465, 493, 886, 952, 1237, 1380, 1574, 1617, 1680, 1743, 2363, 2500, 2669, 2838, 2843, 2865, 2911, 2922, 2925, 3050, 3171, 3178], 'modified': [436, 815, 887], 'with': [437, 452, 479, 540, 707, 742, 816, 1123, 1211, 1244, 1269, 1317, 1358, 1395, 1598, 1704, 2049, 2179, 2196, 2234, 2289, 2400, 2592, 2661, 2667, 2692, 2724, 2795, 2828, 2835, 2932, 2983, 3004, 3607], '2-picolinic': [438, 889, 1185, 3173], 'acid.': [439, 3174], 'Alternative': [440], 'rapid': [441, 2693], 'addition': [442, 2375, 2416, 2547, 2694], 'leads': [445, 1390], 'dissociation': [447, 466, 822, 941, 2356, 2489, 2676, 2708, 3016, 3179], 'formation': [453, 1906, 2535, 2796, 2949, 3149], 'high-purity': [456], '(ThAg)∞': [457], 'two-dimensional': [458, 2402], 'layered': [459], 'structure': [460, 1443, 1449, 1463, 1568, 1757, 1804, 1912, 2102, 2405, 2737, 2758, 2831, 3022, 3030], 'material.': [461], 'A': [462, 3175], 'mechanism': [463, 944, 2359, 2492, 2947, 2972, 3182], 'for': [464, 622, 663, 734, 947, 965, 989, 1077, 1093, 1344, 1502, 1793, 1844, 1861, 1996, 2025, 2068, 2087, 2094, 2154, 2212, 2217, 2297, 2308, 2325, 2335, 2360, 2495, 2511, 2515, 2520, 2664, 2936, 2948, 3093, 3250, 3295, 3319, 3579], 'reassembly': [468, 943, 2358, 2491, 3181], 'yield': [470, 828, 870, 2862, 2907], 'from': [472, 696, 709, 1045, 1273, 1708, 1887, 1986, 2051, 2329, 2574, 2707, 2817, 2975, 3001, 3015, 3188, 3454, 3645, 3681, 4108], 'is': [474, 477, 557, 610, 618, 757, 851, 926, 945, 961, 1201, 1223, 1340, 1356, 1596, 1734, 1739, 1818, 2138, 2345, 2564, 2930, 2981, 3116, 3133, 3183, 3224, 3271], 'proposed': [475, 946, 2946, 2971, 3184], 'consistent': [478, 2233, 2288, 2931, 2982], 'spectroscopic': [480, 1005], 'observations': [481, 2984], 'computational': [483], 'results.': [484], 'Because': [485], 'Ag⋯Ag': [487, 1705, 1730, 1914, 3196], 'π–π': [489, 3200], 'interactions,': [490, 3197], 'Th9Ag12': [492, 903, 1616, 1679, 1752, 1919, 2910, 2924, 2953, 3212], 'exhibits': [494], 'high': [495, 2161, 2226, 2241], 'stability': [496, 1900, 2163, 2284, 3209, 3289], 'in': [497, 505, 526, 567, 575, 627, 635, 740, 893, 1030, 1143, 1158, 1290, 1479, 1484, 1513, 1537, 1586, 1614, 1634, 1646, 1684, 1723, 1775, 1821, 1833, 1847, 1851, 1950, 2011, 2046, 2073, 2080, 2117, 2172, 2394, 2427, 2569, 2607, 2876, 2893, 3024, 3148, 3233, 3452, 3500, 3709, 3766, 3835, 3936, 3999, 4033, 4080], 'air,': [498, 3204], 'at': [499, 776, 1203, 1262, 1937, 2437, 2597, 2630, 2639, 2646, 3366, 4036], 'elevated': [500], 'temperature,': [501], 'under': [502, 645, 724, 1790, 1864, 3368], 'γ-irradiation,': [503, 3205], 'common': [506, 1822], 'solvents.': [507], 'Download': [508, 510, 1504, 1506, 1760, 1762, 2351, 2353, 3095, 3097], 'figure': [509, 1505, 1761, 2352, 3096], 'PowerPoint': [511, 1507, 1763, 2354, 3098], 'Introduction': [512], 'Polynuclear': [513, 3475, 4233], 'metal': [514, 655, 798, 861, 872, 1221, 1246], 'interest': [518], 'due': [519], 'intriguing': [521], 'structures1–4': [522], 'numerous': [524], 'applications': [525], 'fields': [527], 'such': [528, 683, 812, 2927], 'molecular': [530, 2065], 'magnetic': [531], 'materials,5,6': [532], 'luminescence': [533], 'sensing,7,8': [534], 'catalysis,9': [535], 'optics.10': [537], 'In': [538, 668, 761, 780, 794, 1007, 1197, 1254, 2413, 2542, 3236], 'comparison': [539], 'many': [541], 'known': [542], 'based': [544, 606], 'on': [545, 607, 933, 2684, 3254, 4241], 'transition,': [546], 'main': [547], 'group,': [548], 'lanthanide': [550], 'metals,11–16': [551], 'realm': [553], 'actinide': [555, 616, 773, 1346], 'relatively': [558], 'underdeveloped.17': [559], 'tendency': [561], 'actinides': [563, 3232], 'hydrolyze': [565, 737], 'results': [566, 2655], 'soluble': [568], 'polynuclear': [569, 675], 'species': [570, 2706, 2827, 2962, 3137], 'play': [572], 'critical': [573, 3146], 'roles': [574], 'environmental': [576, 3227], 'transport': [577], 'migration': [579, 3230], 'radionuclides.18–20': [581], 'Actinide': [582, 3963], 'have': [585, 693, 1418, 2078, 2523], 'been': [586, 694, 2524], 'synthesized': [587, 3119], 'characterized': [589], 'include': [590, 2714], 'U(IV)/U(V)/U(VI)-containing': [591], 'U4,': [593], 'U6,': [594], 'U9,': [595], 'U13,': [596], 'U24,': [597], 'U38,21–25': [599], 'transuranic': [600], 'Pu3826,27': [601], 'Np38,28': [603], 'several': [605, 1845, 1862, 2425], 'uranyl-peroxide.29–36': [608], 'most': [612], 'abundant': [613], 'naturally': [614], 'occurring': [615], 'leading': [620], 'candidate': [621], 'next': [623], 'generation': [624], 'nuclear': [625, 688], 'fuel': [626], 'liquid': [628], 'fluoride': [629], 'thorium': [630, 638, 642, 676, 691, 698, 755, 792, 810, 825, 830, 843, 3222], 'reactors.37,38': [631], 'Despite': [632], 'recent': [633], 'advances': [634], 'complexes,39–45': [639], 'reports': [640], 'prepared': [644, 695], 'ambient': [646, 725, 1791], 'conditions': [647, 1792], 'remain': [648], 'less': [649], 'developed.': [650], 'As': [651, 1156, 1831, 2009, 2605, 2769], 'bridge': [653], 'between': [654, 1622, 1918, 2124, 2229], 'ions': [656, 699, 1691, 2614, 2659, 2786, 3040], 'bulk': [658], 'materials,': [659], 'provide': [661, 679], 'models': [662, 1037, 1995], 'understanding': [664], 'more': [665], 'complex': [666, 923, 1140, 1788, 1816, 1879, 1902, 1932, 2330, 2397, 2432, 2435, 2443, 2698, 2760, 2867, 2913, 3025, 3064, 3071, 3075, 3106, 3111], 'systems.': [667], 'particular,': [669, 762], 'syntheses': [670], 'characterization': [672], 'stable': [674, 753, 808, 1843, 2145, 2155, 2537, 3221, 3264], 'can': [678, 833, 1027, 2533, 2722, 2742], 'insights': [680], 'materials': [682, 775], 'thorium-based': [685], 'colloids': [686], 'fuels.': [689], 'Reported': [690], 'mononuclear': [697], 'or': [700, 717, 744, 1407, 1423, 1813], 'complexes': [701, 1769, 1970, 3296], 'ammonolysis,46': [703], 'hydrogenolysis,40': [704], 'hydrolysis17': [706], 'those': [708, 2050], 'first': [711, 1256, 1303, 1342, 1354, 1453, 3252], 'approaches': [713], 'bridging': [715, 2059], 'NH3': [716], 'H': [718, 1498, 3090], 'generally': [722], 'unstable': [723], 'conditions.': [726], 'Approaches': [727], 'take': [729], 'advantage': [730], 'propensity': [733], 'Th4+': [735, 2814], 'typically': [738], 'result': [739], 'low-nuclearity': [743], 'ThO2': [745, 849], 'nanoparticles.47–57': [746], 'Therefore,': [747], 'design': [749], 'high-nuclearity': [754], 'formidable': [759], 'challenge.': [760], 'exploring': [763], 'assembly': [765, 868, 2881, 3053, 3219], 'process': [766, 2980], 'facilitates': [767], 'further': [768, 983, 1655, 2097, 2743], 'development': [769], 'application': [771], 'functional': [774, 1061, 1980], 'later': [778], 'stage.': [779], 'work,': [782], 'employ': [784], 'lacuna-construction': [786], 'strategy': [787, 877], 'prepare': [789], 'large-nuclearity': [791], 'clusters.': [793, 838, 873, 2503, 3192, 3266], 'approach,': [796], 'competitive': [797, 860], 'ions,': [799, 862, 2691], 'here': [800], 'Ag+,': [801, 3259], 'introduced': [803], 'precursor': [809, 824, 842], 'Th6(μ3-O)4(μ3-OH)4(HCOO)12': [814, 885, 2384, 2554, 2957, 2994], 'organic': [817, 2387], 'ligands': [818, 1188, 1365, 1605, 1698, 2388, 2532, 2806, 3043], 'induce': [820], 'partial': [821, 2790], 'lacunary': [829], 'assemble': [834], 'form': [836, 2734, 2754, 2808, 2825, 2840, 3045], 'larger': [837, 2149], 'Dissociation': [839], 'clusters,': [844, 1012, 2252, 3103, 3153, 3246], 'specifically': [846], 'avoidance': [847], 'nanoparticles,': [850], 'controlled': [852], 'rate': [855, 2686], 'amount': [857], 'added': [859, 2616], 'which': [863, 891, 1648, 2026, 2159, 2721, 3132, 3154], 'may': [864, 2973], 'be': [865, 970, 1028, 2348, 2885], 'incorporated': [866], 'during': [867], 'mixed': [871], 'We': [874, 1896, 3313, 3326], 'employed': [875, 1057], 'adding': [879], 'acid,': [890], 'resulted': [892, 2389, 2423], '(complex': [900, 904, 1439, 1753], '1)': [901, 2004, 2261, 3107], '2).': [905, 1754, 2008], 'new': [907, 3135], 'Th-Ag': [908], 'unit.': [916, 2997, 3010], 'To': [917, 1964, 2243], 'best': [919], 'our': [921], 'knowledge,': [922], '2,': [924, 1052, 1509, 1647, 1973, 2109, 2287, 3076, 3843], 'Th9Ag12,': [925, 1482], 'largest': [928, 1741], 'reported': [929, 1343, 1725, 2525, 2545], 'actinide-silver': [930, 1742], 'cluster.': [931, 1376, 2167, 3019, 3047, 3213], 'Based': [932], 'structural': [934, 1055, 1534, 2996], 'considerations': [935], 'theoretical': [937], 'calculations,': [938], 'Ag+-induced': [940, 3176], 'observed': [949, 2943], 'conversion': [950, 2361, 2496], 'Th9.': [955], 'Experimental': [956], 'Methods': [957, 1035], 'Caution!': [958], 'nitrate': [960, 2378], 'radioactive;': [962], 'suitable': [963], 'precautions': [964], 'safety': [966], 'protection': [968], 'must': [969], 'taken.': [971], 'All': [972], 'chemicals': [973], 'reagent': [975], 'grade': [976], 'were': [977, 1020, 1103, 1842, 1975, 2030, 3118], 'commercially': [978], 'available': [979, 3272], 'used': [981, 1076, 1092], 'without': [982], 'purification.': [984], 'See': [985], 'Supporting': [987, 1032, 1150, 1159, 1226, 1281, 1367, 1428, 1526, 1538, 1581, 1607, 1714, 1777, 1806, 1834, 1892, 1922, 1955, 2012, 2038, 2074, 2221, 2313, 2407, 2455, 2481, 2587, 2601, 2608, 2701, 2729, 2749, 2765, 2847, 3267, 3269], 'Information': [988, 1151, 1160, 1227, 1282, 1368, 1429, 1527, 1539, 1582, 1608, 1715, 1778, 1807, 1835, 1893, 1923, 1956, 2013, 2039, 2075, 2222, 2314, 2408, 2456, 2482, 2588, 2602, 2609, 2702, 2730, 2750, 2766, 2848, 3268, 3270], 'details': [990, 2968], 'determination': [993], 'single-crystal': [995, 1522, 3283], 'structure,': [996, 3131, 3284], 'powder': [997, 1785, 1838], 'X-ray': [998, 1136, 1523, 1927], 'diffraction': [999, 1137, 1524], '(PXRD),': [1000], 'thermogravimetric': [1001], 'analysis,': [1002, 3288], 'measurements.': [1006], 'methods,': [1014], 'single-tube': [1015], 'diffusion': [1016, 2421], 'solvent': [1018, 3208], 'evaporation,': [1019], 'adopted,': [1021], 'detailed': [1024, 3275], 'experimental': [1025], 'procedures': [1026, 3279], 'found': [1029, 2372, 2681, 3023], 'Information.': [1033], 'Theoretical': [1034, 1959], '[Th9(μ3-O)7(μ3-OH)8Ag6(NO3)2(PyCOO)12]6+': [1040, 2002], '[Th9(μ3-O)8(μ3-OH)6Ag12(PyCOO)20]6+': [1042, 2006], 'cut': [1044], 'crystal': [1047, 1987, 2053], '1': [1050, 1141, 1167, 1239, 1433, 1456, 1468, 1478, 1579, 1623, 1640, 1770, 1795, 1971, 1990, 2088, 2249, 2300, 2433, 2444, 2472, 2868, 2883], 'respectively.': [1053], 'Full': [1054], 'optimization': [1056], 'Perdew–Burke–Ernzerhof': [1059], '(PBE)': [1060], 'using': [1062, 1107, 1977, 3255], 'ADF': [1064], '2013.01': [1065], 'package.58': [1066], 'triple-ζ': [1068], 'plus': [1069, 1085], 'one': [1070, 1086], 'polarization': [1071, 1087], '(TZP)': [1072], 'basis': [1073, 1089], 'set': [1074, 1090, 2346], 'was': [1075, 1091, 1120, 1240, 2257, 2371, 2680, 3349], 'Th': [1078, 1171, 1259, 1288, 1299, 1349, 1392, 1544, 1589, 1812, 2186, 2198, 2208, 2230, 2711, 3057, 3265], 'Ag': [1080, 1174, 1360, 1416, 1547, 1600, 1651, 1726, 1814], 'atoms,': [1081], 'while': [1082, 1414, 2635], 'double-ζ': [1084], '(DZP)': [1088], 'H,': [1094], 'C,': [1095, 1492, 3084], 'N,': [1096, 1496, 3088], 'O': [1098, 2194, 2232], 'atoms.': [1099], 'Scalar': [1100], 'relativistic': [1101, 1978], 'effects': [1102], 'taken': [1104], 'account': [1106], 'zero-order': [1109], 'regular': [1110], 'approximation': [1111], 'approach.59': [1112], 'Analysis': [1113], 'electron': [1116, 2227], 'localization': [1117], 'function': [1118], '(ELF)': [1119], 'carried': [1121], 'out': [1122], 'Multiwfn': [1125], 'program.60': [1126], 'Results': [1127], 'Discussion': [1129], 'Crystal': [1130], 'Single-crystal': [1135], 'reveals': [1138, 2225], 'crystallizes': [1142, 1512], 'monoclinic': [1145, 1515], 'space': [1146, 1516], 'group': [1147, 1517], 'C2/c': [1148], '(': [1149, 1225, 1366, 1427, 1525, 1580, 1606, 1713, 1805, 1891, 1921, 1954, 2037, 2220, 2406, 2454, 2480, 2586, 2600, 2700, 2728, 2748], 'Tables': [1152, 1528], 'S1': [1153, 1529], 'S2).': [1155, 1284, 1584], 'shown': [1157, 1536, 1683, 1774, 1832, 2010, 2072, 2116, 2606], 'Figure': [1161, 1228, 1283, 1369, 1430, 1432, 1540, 1583, 1685, 1716, 1746, 1808, 1894, 1924, 1957, 2014, 2043, 2076, 2118, 2173, 2223, 2315, 2317, 2483, 2589, 2603, 2610, 2703, 2731, 2751, 2767, 2780, 2849, 2990], 'S1a,': [1162], 'asymmetric': [1164, 1533], 'unit': [1165, 1535, 2479, 3000, 3014, 3037], 'consists': [1168], 'five': [1170, 1543], 'three': [1173, 1250, 1287, 1312, 1559, 1563, 1603, 2176], 'atoms': [1175, 1222, 1260, 1289, 1300, 1499, 1548, 1601, 1652, 1948, 3091], 'crystallographically': [1178, 1551], 'independent,': [1179, 1552], 'eight': [1180], 'μ3-O2−/OH−': [1181, 1554], 'anions,': [1182, 1192, 1555, 1558, 1561], 'six': [1183, 1258, 1546, 1644, 1650, 1661, 1689, 2888, 2896, 2904], 'deprotonated': [1184], 'acid': [1186], 'anion': [1187, 2531], '(PyCOO−),': [1189], 'four': [1190, 1298, 1628, 2218], 'NO3−': [1191, 1560, 1632, 1662, 2874, 2905], 'five-coordinated': [1194], 'H2O': [1195, 1389, 1629, 2860, 2872], 'molecules.': [1196], 'unit,': [1199], 'Th4': [1200], 'located': [1202], 'special': [1205], 'position': [1206, 1212], 'symmetry': [1209], 'axis': [1210], 'occupancy': [1213, 1217], '0.5,': [1215], 'whereas': [1216], 'other': [1220, 1724, 1811, 2000, 3244], '1.0': [1224], 'S1a).': [1229], 'Through': [1230], 'an': [1231, 1345, 1359, 3442], 'axisymmetric': [1232], 'operation': [1233], 'whole': [1235], 'obtained': [1241], '(Figure': [1242, 1252, 1278, 1332, 1618, 2310, 2493, 2559, 2717, 2738, 2762, 2811, 2844, 2869, 2890, 2915], '1a),': [1243], 'core': [1247, 1381, 2105, 2214, 2301, 2327, 2995], 'consisting': [1248], 'shells': [1251, 1454], '1b,e).': [1253], 'shell,': [1257], 'lie': [1261], 'vertices': [1264], 'triangular': [1267, 1319], 'Th⋯Th': [1270], 'distances': [1271, 1706, 2036], 'ranging': [1272, 1707], '3.781': [1274], '3.970': [1276], 'Å': [1277, 1712], '1c': [1279], 'remaining': [1286], 'second': [1292], 'shell': [1293, 1304, 1355, 1594, 1637, 1667, 2879], 'each': [1295, 1588, 1693, 2336], 'connected': [1296, 1316, 1357, 1597], 'μ3-O2−': [1307, 2060], 'μ3-OH−': [1310], 'forming': [1311], 'tetragonal': [1313], 'pyramid': [1314, 1424], 'units': [1315, 2799], 'face-sharing': [1323], 'mode': [1324], 'generate': [1326], '1d).': [1333], 'This': [1334, 1620, 3214], 'Johnson-type': [1336], '(J51)': [1337], 'nonanuclear': [1338], 'moiety': [1339], 'compound.61': [1347], 'Each': [1348], 'atom': [1350, 1361, 1393, 1590], 'PyCOO−': [1364, 1557, 1604, 1645, 1659, 1697, 2805, 2889, 2902], 'S3)': [1370], 'create': [1372, 1700], 'final': [1374, 2909], 'Coordination': [1377], '12': [1383], 'PyCOO−,': [1384], 'NO3−,': [1386, 2858], 'nine': [1388], 'environments': [1394], 'spherical': [1396, 1408], 'capped': [1397], 'square': [1398], 'antiprism': [1399], '(Th1,': [1400], 'Th3,': [1401], 'Th5),': [1403], 'augmented': [1404], 'sphenocorona': [1405], '(Th2)': [1406], '(Th4)': [1412], 'geometries,': [1413], 'sites': [1417], 'quadrilateral': [1419], '(Ag1': [1420], 'Ag2)': [1422], '(Ag3)': [1425], 'geometries': [1426, 1475], 'S4).': [1431], '|': [1434, 1748, 2319, 2992], '(a)': [1435, 1749, 2993], 'Structure': [1436, 1750, 3007, 3060], '1).': [1440], '(b)': [1441, 1755, 2998], 'Core': [1442, 1756], '1.': [1445, 3373], '(c)': [1446, 3006], 'Triangular': [1447], '2.': [1458, 1470, 1759, 2095, 3065, 3409], '(d)': [1459, 3011], 'Tricapped': [1460], '(e': [1471], 'f)': [1473], 'Simplified': [1474], 'Th9Ag6,': [1477, 3073], '(e)': [1480, 3020], '2': [1483, 1570, 1587, 1625, 1682, 1733, 1747, 1772, 1789, 1817, 1841, 1880, 1903, 1933, 1992, 2251, 2331, 2436, 2451, 2474, 2914], '(f).': [1485], 'Color': [1486, 3078], 'scheme:': [1487, 3079], 'Th,': [1488, 3080], 'green;': [1489, 3081], 'Ag,': [1490, 3082], 'purple;': [1491, 3083], 'gray;': [1493, 3085], 'O,': [1494, 3086], 'red;': [1495, 3087], 'blue.': [1497, 3089], 'omitted': [1501, 3092], 'clarity.': [1503, 3094], 'Complex': [1508, 1732, 4188], 'like': [1510, 1824, 2540, 2963], '1,': [1511, 3072], 'C2/c,': [1518], 'determined': [1520], 'S3).': [1531], 'S1b,': [1541], 'contains': [1542], 'seven': [1553], '10': [1556], 'coordinated': [1564, 1656, 1694], 'H2O.': [1565], 'complete': [1567, 1664], 'features': [1571], 'similar': [1575, 1720], 'However,': [1585], 'inner': [1593, 1636, 2878], 'Figures': [1609, 1779, 1836, 2409, 2457], 'S5': [1610], 'S6),': [1612], 'resulting': [1613], '2a,b).': [1619], 'difference': [1621], 'indicates': [1626, 2160], 'anions': [1633, 2875], 'replaced': [1642, 2886], 'capture': [1649, 2802, 2895], 'coordination': [1666, 2852, 2899], 'stabilize': [1669], 'overall': [1671], 'structure.': [1672], 'From': [1673], 'simplified': [1675], 'perspective': [1676], '1f,': [1686], 'additional': [1688], 'silver': [1690, 1947, 2377, 2613, 2658, 2690, 2785], 'Ag5': [1702], 'chains': [1703], '2.872': [1709], '3.304': [1711], 'S7),': [1717], 'range': [1719], 'distance': [1722], 'suggests': [1729, 2281], 'interactions.62–67': [1731], 'particularly': [1735], 'notable': [1736], 'it': [1738], 'yet': [1744], 'reported.': [1745], 'Some': [1764, 2813], 'important': [1765], 'physicochemical': [1766], 'properties': [1767], 'S22–S35.': [1780], 'After': [1781], 'storage': [1782], 'sample': [1786], 'almost': [1794], 'year,': [1796], 'PXRD': [1797, 1871], 'patterns': [1798, 1872], 'retention': [1800], 'original': [1803], 'S13).': [1809], 'Unlike': [1810], 'clusters,46,68–70': [1815], 'practically': [1819], 'insoluble': [1820], 'solvents': [1823, 1849], 'H2O,': [1825], 'dimethylformamide,': [1826], 'CH3OH,': [1827], 'CH3CN,': [1828], 'CHCl3.': [1830], 'S14–S16,': [1837], 'samples': [1839, 1876], 'days': [1846, 2393], 'these': [1848, 2016], 'water': [1852], 'over': [1853, 2452, 3648], 'wide': [1855], 'pH': [1856], 'range,': [1857], 'well': [1859], 'hours': [1863], 'UV': [1865], 'light': [1866], 'exposure.': [1867], 'impressively,': [1869], 'irradiated': [1875], 'confirm': [1877], 'fully': [1881], 'retains': [1882], 'its': [1883], 'crystallinity': [1884], 'after': [1885, 2390, 2424], 'γ-irradiation': [1886], '60Co': [1889], 'source': [1890], 'S17).': [1895], 'attribute': [1897], 'extraordinary': [1899], 'one-dimensional': [1909], 'supermolecular': [1910], 'chain': [1911], 'π⋯π': [1916], 'interactions': [1917, 3201], 'S8).': [1925], 'photoelectron': [1928], 'spectroscopy': [1929], 'spectrum': [1930], 'displays': [1934], 'peaks': [1936, 2573], 'binding': [1938], 'energies': [1939, 2079], '367.6': [1940], '373.6': [1942], 'eV,': [1943], 'indicating': [1944], 'all': [1946], 'oxidation': [1951], 'state': [1952], 'Ag(I)': [1953], 'S21).71,72': [1958], 'calculation': [1960, 3281], 'understand': [1965], 'calculations': [1974], 'performed': [1976, 2216], 'density': [1979, 2228], 'theory.': [1981], 'following': [1983, 2254], 'extracted': [1985], 'serve': [1993], 'electronic': [1997, 2101, 2162], 'properties:': [2001], '(model': [2003, 2007, 2260, 2268], 'S36,': [2015], 'representative': [2017, 2333], 'contain': [2019], '[Th9(μ3-O)7(μ3-OH)8]14+': [2021], '[Th9(μ3-O)8(μ3-OH)6]14+,': [2023], 'respectively,': [2024], 'full': [2027], 'geometry': [2028], 'optimizations': [2029], 'performed.': [2031], 'calculated': [2033, 2934], 'Th–O': [2034], 'bond': [2035], 'Table': [2040], 'S4': [2041], 'S37)': [2044], 'good': [2047], 'agreement': [2048], 'structures,': [2054], 'supporting': [2055], 'assignments': [2057], 'μ3-OH−.': [2062], 'occupied': [2064, 2132], 'orbitals': [2066], '(MOs)': [2067], 'model': [2070, 2108, 2248, 2286, 2299], 'S38': [2077], 'ranges': [2082], '−28.73': [2083], '−29.22': [2085], 'eV': [2086, 2093, 2137, 2296, 2305], '−27.05': [2090], '−27.83': [2092], 'For': [2096], 'insight': [2098, 2987], '[Th9(μ3-O)8(μ3-OH)6]14+': [2106, 2215, 2309, 2328], 'MOs': [2110, 2324, 2334, 2344], 'corresponding': [2112], 'energy': [2113, 2122, 2152, 2170, 2182, 2238, 2277, 2337, 2935], 'levels': [2114, 2171], '3.': [2119, 3026, 3032, 3426], 'large': [2121, 2236], 'gap': [2123, 2153, 2239, 2293], 'lowest': [2126, 2181], 'unoccupied': [2127], 'MO': [2128, 2133, 2169], '(LUMO)': [2129], 'highest': [2131, 2205], '(HOMO)': [2134], '3.95': [2136, 2304], 'close': [2139], 'highly': [2144], 'Hf13': [2146], 'cluster,': [2147, 3063], 'than': [2150, 2960], 'C60': [2156], 'Au20,7,73': [2158], '3': [2174, 2311, 2318, 2699, 2761, 3298], 'exhibit': [2175], 'distinct': [2177], 'bands,': [2178], 'band': [2183], 'comprised': [2184, 2191], '6p': [2187], 'orbitals,': [2188], 'middle': [2190], 'mainly': [2192], '2p': [2195], 'some': [2197, 2967], '5f': [2199], '6d': [2201], 'contributions,': [2202], 'dominated': [2206], '5f.': [2209], 'ELF': [2211], 'planes': [2219], 'S39)': [2224], 'HOMO–LUMO': [2237, 2292], 'stability.': [2242], 'assess': [2244], 'relative': [2245], 'stabilities': [2246], 'interconversion': [2255, 2938], 'reaction': [2256, 2276, 2939], 'considered:': [2258], '[Th9(μ3-O)7(μ3-OH)8Ag6(NO3)2(PyCOO)12(H2O)7]6+': [2259], '+': [2262, 2264, 2270, 2272], '6Ag+': [2263], '8(PyCOO−)': [2265], '→': [2266], '[Th9(μ3-O)8(μ3-OH)6Ag12(PyCOO)20(H2O)3]6+': [2267], '2)': [2269], '2NO3−': [2271], '5H2O.': [2273], 'computed': [2275], '−400.81': [2279], 'kcal/mol': [2280], 'higher': [2283], 'smaller': [2291, 2961], '3.52': [2295], '[Th9(μ3-O)7(μ3-OH)8]14+,': [2302], 'versus': [2303], 'noted': [2306], 'above': [2307], 'S40).': [2316], 'level': [2321, 2338], '(eV)': [2322], 'band.': [2339], '(The': [2340], 'isosurface': [2341], 'value': [2342], '0.03': [2349], 'au.)': [2350], 'Possible': [2355], 'induced': [2367], 'It': [2370], 'direct': [2374], 'few': [2392], 'crystals': [2395], '3,': [2398, 3484], '(ThAg)∞,': [2399], '(2D)': [2403], 'planar': [2404, 2697, 2757, 2830, 3029], 'S9': [2410], 'S20).': [2412], 'contrast,': [2414], 'method': [2422], 'weeks': [2426], 'solid': [2429], 'mixture': [2430, 2620], 'interface.': [2440], 'Notably,': [2441], 'component': [2445], 'gradually': [2446, 2633], 'transformed,': [2447], 'eventually': [2448], 'yielding': [2449], 'pure': [2450], 'time': [2453], 'S18': [2458], 'S19).': [2460], 'Given': [2461], 'both': [2475], 'Th5': [2478, 2798, 3009, 3036], 'S11),': [2484], 'suggest': [2486, 2656], 'possible': [2488, 2668], '4)': [2494], 'monomers': [2505, 2715], 'including': [2506], 'Th(OH)3+': [2507], 'Th(OH)22+;': [2509], 'dimers,': [2510], 'example,': [2512, 2516, 2521], 'Th2(OH)26+;': [2513], 'tetramers,': [2514], 'Th4(OH)124+;': [2517], 'hexamers,': [2519], 'Th6(μ3-O)4(μ3-OH)412+,': [2522], 'significant': [2527], 'species.34': [2529], 'Carboxylate': [2530], 'promote': [2534], 'neutral': [2538], 'hexamers': [2539], 'Th6(μ3-O)4(μ3-OH)4(RCOO)12.47,52,74': [2541], 'here,': [2546], 'PyCOOH': [2549], 'should': [2555], 'produce': [2556], 'Th6(μ3-O)4(μ3-OH)4(PyCOO)x(HCOO)12-x': [2557], '(Th6Lx)': [2558], '4a,b).': [2560], 'Such': [2561, 2675, 2740], 'ligand': [2562, 2622, 3114], 'replacement': [2563], 'indicated': [2565, 2774], 'shift': [2568], 'UV–vis': [2571], 'absorption': [2572, 2578], '264.3': [2575, 2640], 'nm': [2576, 2585, 2599, 2632, 2641, 2648], '(the': [2577], 'peak': [2579, 2596, 2629, 2638, 2645], 'ligand)': [2582], '267.5': [2584, 2647], 'S24a)': [2590], 'coincident': [2591], 'appearance': [2593], '274.5': [2598], 'S24c).': [2604], 'S24d,': [2611], 'when': [2612], 'aqueous': [2619], 'Th6,': [2624], 'intensity': [2626], '∼275': [2631], 'diminishes,': [2634], 'increases,': [2642], 'undergoes': [2649], 'slight': [2651], 'blue': [2652], 'shift.': [2653], 'compete': [2660], 'Th6Lx': [2662, 2793, 2818], 'carboxylate': [2665, 3042], 'ligands,': [2666], 'breakdown': [2670], 'upon': [2671], 'depletion': [2672], 'ligands.': [2674], 'depend': [2683], 'producing': [2695], '2D': [2696, 2756, 3028], 'S9).': [2704, 2768], 'Solution': [2705], 'hexamer': [2712], 'likely': [2713], 'Th(PyCOO)22+': [2716], '4d),': [2718], 'combine': [2723], 'metalloligands': [2726, 2746], 'cis-(Ag(PyCOO)2)−': [2727], 'S10a)': [2732], 'ring': [2736], '4e).': [2739], 'rings': [2741], 'interconnect': [2744], 'trans-(Ag(PyCOO)2)−': [2747], 'S10b)': [2752], '4f': [2763], 'suggested': [2770, 2979], 'route': [2773, 2929], 'red': [2777], 'arrow': [2778], 'below': [2779], '4c,': [2781], 'gradual': [2782], 'could': [2787, 2801, 2820, 2833, 2884], 'lead': [2788], 'decomposition': [2791], 'Th5Ag4': [2809, 2837, 3046, 3055], '4g,h).': [2812], 'cations': [2815], 'detached': [2816], 'condense': [2821], 'hydrolysis': [2823], 'tetramer': [2826], 'approximate': [2829], 'associate': [2834], 'Th9Ag4': [2842, 2854, 3049], '4i': [2845], 'S12).': [2850], 'Further': [2851, 2898], 'metalloligand': [2856], 'cis-(Ag(PyCOO)2)−,': [2857], 'would': [2861, 2906], '4j).': [2870], 'Coordinated': [2871], '4k)': [2891], 'turn': [2894], 'Ag+.': [2897], '4l).': [2916], 'Exothermic': [2917], 'transformation': [2918], 'considered': [2940], 'above.': [2941], 'require': [2955], 'precursor,': [2958], 'rather': [2959], 'monomeric': [2964], 'Th(NO3)4.': [2965], 'Although': [2966], 'differ': [2974], 'actual': [2976], 'growth,': [2977], 'provides': [2986], 'guidance.': [2989], '4': [2991], 'Th6(PyCOO)x(HCOO)12-x': [2999, 3018], 'replacing': [3002], 'HCOOH': [3003], 'PyCOOH.': [3005], 'Mononuclear': [3012], 'Th(PyCOO)2)2+': [3013], 'Ring': [3021], '(f)': [3027], '(g': [3033], 'h)': [3035], 'captures': [3038], '(i)': [3048], 'formed': [3051], 'tetramer.': [3058], '(j)': [3059], '(k': [3066], 'l)': [3068], 'Transformation': [3069, 3473], 'Conclusion': [3099], 'Two': [3100], 'Th9Ag6(O)7(OH)8L12(NO3)8(H2O)9': [3104], '(Th9Ag6,': [3105], 'Th9Ag12(O)8(OH)6L20(NO3)6(H2O)5': [3109], '(Th9Ag12,': [3110], '2),': [3112], 'where': [3113], 'L': [3115], '2-picolinate,': [3117], 'characterized.': [3121], 'rare': [3126], 'hydrolytic': [3136], 'tetravalent': [3139], 'Experiments': [3141], 'plays': [3144], 'role': [3147], 'modulated': [3160], 'approach': [3161], 'slowly': [3163], 'introducing': [3164], 'elaborate': [3186], 'evolution': [3187], 'Intermolecular': [3193], 'intramolecular': [3195], 'intermolecular': [3199], 'impart': [3202], 'excellent': [3203], 'thermal,': [3206], 'silver-induced': [3215], 'dissociation,': [3216], 'polymerization,': [3217], 'pertinent': [3225], 'speciation': [3228], 'environment.': [3235], 'contrast': [3237], 'previous': [3239], 'studies': [3240], 'Th–Fe/Ag': [3242], 'heterometallic': [3245, 3257], 'work': [3248, 3346], 'focuses,': [3249], 'time,': [3253], 'ion,': [3258], 'control': [3261], 'chemistry': [3262], 'includes': [3274], 'descriptions': [3276], 'synthetic': [3278], 'method,': [3282], 'spectral': [3285], 'characterization,': [3286], 'thermal': [3287], 'test,': [3290], 'micrographs.': [3292], 'Crystallographic': [3293], 'data': [3294], '1–': [3297], '(CCDC': [3299], '2062120–2062122)': [3300], 'available.': [3302], 'Conflict': [3303], 'Interest': [3305], 'There': [3306], 'no': [3308], 'conflicts': [3309], 'declare.': [3311], 'Acknowledgments': [3312], 'thank': [3314], 'Science': [3317, 3335], 'Fund': [3318], 'Distinguished': [3320], 'Young': [3321], 'Scholars': [3322], '(grant': [3323, 3339], 'no.': [3324], '21925603).': [3325], 'also': [3327], 'acknowledge': [3328], 'support': [3330], 'Natural': [3334], 'Foundation': [3336], 'China': [3338], 'nos.': [3340], '22076187,': [3341], '11975152,': [3342], '11875057).': [3344], 'J.K.G.': [3348], 'supported': [3350], 'U.S.': [3353], 'Department': [3354], 'Energy,': [3356], 'Office': [3357], 'Basic': [3359], 'Heavy': [3362], 'Element': [3363], 'program': [3365], 'LBNL': [3367], 'Contract': [3369], 'No.': [3370], 'DE-AC02-05CH11231.': [3371], 'References': [3372], 'Desireddy': [3374], 'A.;': [3375, 3495, 3627, 3669, 3732, 3863, 3986, 4204, 4219, 4228], 'Conn': [3376], 'B.': [3377, 3388, 3994], 'E.;': [3378, 3675, 3743, 3875, 4216], 'Guo': [3379], 'J.': [3380, 3411, 3430, 3563, 3677, 3779, 3870, 4029, 4209, 4227], 'S.;': [3381, 3528, 3558, 3623, 3629, 3704, 3747, 3850, 3979, 4061], 'Yoon': [3382], 'B.;': [3383, 3745, 3989, 4015, 4137], 'Barnett': [3384], 'R.': [3385, 3396, 3674, 3724, 3981, 4206, 4213], 'N.;': [3386, 3741, 3782, 3977, 4169, 4210], 'Monahan': [3387], 'M.;': [3389, 3555, 3666, 3780, 3793, 3826, 3854, 3868, 3871, 3907, 4047], 'Kirschbaum': [3390], 'K.;': [3391, 4027], 'Griffith': [3392], 'W.': [3393], 'P.;': [3394, 3511, 3514, 3566, 3785, 3856, 3974], 'Whetten': [3395], 'L.;': [3397, 3522, 3561, 3636, 3738, 3795, 4021, 4057, 4059, 4095, 4140, 4143, 4171, 4175, 4222], 'Landman': [3398], 'U.;': [3399, 3852], 'Bigioni': [3400], 'T.': [3401, 3671, 3913], 'P.Ultrastable': [3402], 'Silver': [3403, 3445, 3836], 'Nanoparticles.Nature2013,': [3404], '501,': [3405], '399–402.': [3406], 'Bai': [3410], 'F.;': [3412, 3428, 3437, 3752, 3859, 3861, 3901, 3955, 3984, 4099, 4146, 4177, 4207], 'Virovets': [3413], 'A.': [3414, 3973, 4014], 'V.;': [3415, 3992], 'Scheer': [3416], 'M.Synthesis': [3417], 'Inorganic': [3419], 'Fullerene-like': [3420], 'Molecules.Science2003,': [3421], '300,': [3422], '781–783.': [3423], 'Li': [3429, 3567, 3592, 3600, 3628, 3635, 3781, 3791, 4064], 'J.;': [3431, 3434, 3525, 3568, 3672, 3698, 3701, 3727, 3735, 3788, 3790, 3873, 4024, 4053, 4065, 4069, 4101, 4225], 'Guan': [3432], 'Z.': [3433, 3560, 4145], 'Yuan': [3435, 3904], 'S.': [3436, 3784, 3976, 3988, 4218, 4221], 'Wang': [3438, 3562, 3639, 3819, 3860, 4054, 4072, 4076, 4133, 4141, 4147], 'Q.': [3439, 3797], 'M.Formation': [3440], 'Alkynyl-Protected': [3443], 'Ag112': [3444], 'Nanocluster': [3446, 3574], 'Promoted': [3448], 'Chloride': [3450], 'Released': [3451], 'Situ': [3453], 'CH2Cl2.Angew.': [3455], 'Chem.': [3456, 3545, 3584, 3686, 3716, 3771, 3812, 3888, 4086, 4117, 4161, 4195], 'Int.': [3457, 3546, 3585, 3687, 3889, 4087, 4118], 'Ed.2020,': [3458], '59,': [3459], '5312–5315.': [3460], '4.': [3463], 'Yan': [3464], 'L.-L.;': [3465], 'Yao': [3466], 'L.-Y.;': [3467], 'Leung': [3468], 'M.-Y.;': [3469], 'Yam': [3470], 'Vivian': [3471], 'W.-W.Substituent-Mediated': [3472], 'Gold(I)-Sulfido': [3476], 'Complexes—From': [3477], 'Pentanuclear': [3478], 'Octadecanuclear': [3480], 'Cluster-to-Cluster': [3481], 'Transformation.CCS': [3482], 'Chem.2021,': [3483], '326–337.': [3485], 'Abstract,': [3486, 3845], '5.': [3489], 'Sessoli': [3490], 'R.;': [3491, 4097], 'Gatteschi': [3492], 'D.;': [3493, 3830, 4063], 'Caneschi': [3494], 'Novak': [3496], 'M.': [3497, 3734, 3740, 3787, 3858], 'A.Magnetic': [3498], 'Bistability': [3499], 'Metal-Ion': [3502], 'Cluster.Nature1993,': [3503], '365,': [3504], '141–143.': [3505], '6.': [3508], 'Liu': [3509, 3789, 4131], 'D.': [3510, 3865, 4017, 4020, 4023, 4026, 4212], 'Lin': [3512, 3778], 'X.': [3513, 3518, 3524, 3554, 3695, 3700, 3737, 3792], 'Zhang': [3515, 3637, 4046, 4062, 4138], 'H.;': [3516, 3597, 3866], 'Zheng': [3517, 3529, 3602, 3694, 3705, 3831, 3930], 'Y.;': [3519, 3625, 3634, 3696, 3749, 3903, 4055, 4073, 4130], 'Zhuang': [3520, 3823], 'G.': [3521, 3668], 'Long': [3526, 3702], 'L.': [3527, 3530, 3703, 3706, 3800, 4126], 'S.Magnetic': [3531], 'Properties': [3532], 'Single-Molecule': [3535], 'Lanthanide-Transition-Metal': [3536], 'Compound': [3537], 'Containing': [3538], '52': [3539], 'Gadolinium': [3540], '56': [3542], 'Nickel': [3543], 'Atoms.Angew.': [3544], 'Ed.2016,': [3547], '55,': [3548], '4532–4536.': [3549], '7.': [3552], 'Kang': [3553], 'H.': [3557, 4139], 'Q.;': [3564], 'Cheng': [3565, 4050, 4058, 4125], 'Zhao': [3569], 'B.An': [3570], 'Ultrastable': [3571], 'Matryoshka': [3572], '[Hf13]': [3573], 'Luminescent': [3577, 3611], 'Sensor': [3578], 'Concentrated': [3580], 'Alkali': [3581], 'Acid.Angew.': [3583], 'Ed.2019,': [3586, 4119], '58,': [3587, 4120], '16610–16616.': [3588], '8.': [3591], 'Z.;': [3593, 3621, 3801, 3820, 3931, 4075], 'Lv': [3594], 'Z.-H.;': [3595], 'Sun': [3598, 3829], 'Y.-Q.;': [3599], 'X.-X.;': [3601], 'S.-T.Giant': [3603], 'Ln30-Cluster-Embedded': [3604], 'Polyoxotungstate': [3605], 'Nanoclusters': [3606, 3837], 'Exceptional': [3608], 'Proton-Conducting': [3609], 'Properties.CCS': [3612], 'Chem.2022.': [3613], 'doi:': [3614], 'https://doi.org/10.31635/ccschem.021.202101573': [3615], 'Crossref,': [3616], '9.': [3619], 'Cui': [3620], 'Meng': [3622], 'Yi': [3624], 'Jafarzadeh': [3626], 'Neyts': [3630], 'E.': [3631, 4224], 'C.;': [3632, 3982, 4049, 4214], 'Hao': [3633], 'X.;': [3638, 3640, 4135], 'Bogaerts': [3641], 'A.Plasma-Catalytic': [3642], 'Methanol': [3643], 'Synthesis': [3644], 'CO2': [3646], 'Hydrogenation': [3647], 'Supported': [3650], 'Cu': [3651], 'Cluster': [3652, 4106], 'Catalyst:': [3653], 'Insights': [3654], 'Reaction': [3657, 4239], 'Mechanism.ACS': [3658], 'Catal.2022,': [3659], '12,': [3660], '1326–1337.': [3661], '10.': [3664], 'Romanelli': [3665], 'Kumar': [3667], 'Emge': [3670], 'Riman': [3673], 'Brennan': [3676], 'G.Intense': [3678], 'Near-IR': [3679], 'Emission': [3680], 'Nanoscale': [3682], 'Lanthanoid': [3683], 'Fluoride': [3684], 'Clusters.Angew.': [3685], 'Ed.2008,': [3688], '47,': [3689], '6049–6051.': [3690], '11.': [3693], 'Xie': [3697], 'S.Recent': [3707], 'Advances': [3708], 'Assembly': [3711], 'High-Nuclearity': [3713, 3767], 'Lanthanide': [3714], 'Clusters.Coord.': [3715], 'Rev.2019,': [3717], '378,': [3718], '222–236.': [3719], '12.': [3722], 'W.;': [3725, 3730, 3798, 4018, 4127, 4132], 'Yin': [3726], 'Dong': [3728, 3736, 3799, 3908], 'C.': [3729, 3914, 4129], 'Ghosh': [3731], 'Alhilaly': [3733], 'Hedhili': [3739], 'Abou-Hamad': [3742], 'Alamer': [3744], 'Nematulloev': [3746], 'Han': [3748], 'Mohammed': [3750], 'O.': [3751, 3754], 'Bakr': [3753], 'M.[Cu81(PhS)46((BuNH2)-Bu-t)10(H)32]3+': [3755], 'Reveals': [3756], 'Coexistence': [3758], 'Large': [3760, 3918, 4082], 'Planar': [3761], 'Cores': [3762], 'Hemispherical': [3764], 'Shells': [3765], 'Copper': [3768], 'Nanoclusters.J.': [3769], 'Am.': [3770, 3811, 4160, 4194], 'Soc.2020,': [3772, 3813, 4162], '142,': [3773, 3814, 4163], '8696–8705.': [3774], '13.': [3777], 'Yang': [3783], 'Jia': [3786], 'An': [3794], 'Tian': [3796], 'Lan': [3802], 'Y.': [3803, 4134, 4142], 'Q.Self-Assembly': [3804], 'Giant': [3806], 'Mo240': [3807], 'Hollow': [3808], 'Opening': [3809], 'Dodecahedra.J.': [3810], '13982–13988.': [3815], '14.': [3818], 'Su': [3821, 3855], 'H.-F.;': [3822], 'G.-L.;': [3824], 'Kurmoo': [3825], 'Tung': [3827], 'C.-H.;': [3828, 3899], 'L.-S.Carbonate–Water': [3832], 'Supramolecule': [3833], 'Trapped': [3834], 'Encapsulating': [3838], 'Ag11': [3840], 'Kernel.CCS': [3841], 'Chem.2020,': [3842], '663–672.': [3844], '15.': [3848], 'Bhattacharya': [3849], 'Basu': [3851], 'Haouas': [3853], 'Espenship': [3857], 'Sole-Daura': [3862], 'Taffa': [3864], 'Wark': [3867], 'Poblet': [3869], 'Laskin': [3872], 'Cadot': [3874], 'Kortz': [3876], 'U.Discovery': [3877], 'Supramolecular': [3879], 'Interactions': [3880], 'Neutral': [3882], 'Palladium-Oxo': [3883], 'Pd16': [3885], 'Pd24.Angew.': [3887], 'Ed.2021,': [3890, 4088], '60,': [3891, 4089], '3632–3639.': [3892], '16.': [3895], 'Luo': [3896], 'X.-M.;': [3897], 'Gong': [3898, 4060], 'Pan': [3900], 'Si': [3902], 'J.-W.;': [3905], 'Asad': [3906], 'X.-Y.;': [3909], 'Zang': [3910], 'S.-Q.;': [3911], 'Mak': [3912], 'W.Small': [3915], 'Symmetry-Breaking': [3916], 'Triggering': [3917], 'Chiroptical': [3919], 'Responses': [3920], 'Ag70': [3922], 'Nanoclusters.Nat.': [3923], 'Commun.2022,': [3924], '13,': [3925], '1177.': [3926], '17.': [3929], 'Burns': [3932], 'P.': [3933], 'C.Recent': [3934], 'Development': [3935], 'Rare': [3939], 'Earths': [3940], 'Actinides:': [3942], 'Materials;': [3945], 'Springer:': [3946], 'Oxford,': [3947], 'United': [3948], 'Kingdom,': [3949], '2017.': [3950], '18.': [3953], 'Thomas': [3954], 'Neck': [3956], 'V.Aquatic': [3957], 'Solubility': [3960], 'Phenomena': [3961], 'Oxides/Hydroxides.Pure': [3964], 'Appl.': [3965], 'Chem.2002,': [3966], '74,': [3967], '1895–1907.': [3968], '19.': [3971], 'Novikov': [3972], 'Kalmykov': [3975], 'Utsunomiya': [3978], 'Ewing': [3980], 'Horreard': [3983], 'Merkulov': [3985], 'Clark': [3987], 'Tkachev': [3990], 'V.': [3991], 'Myasoedov': [3993], 'F.Colloid': [3995], 'Transport': [3996], 'Plutonium': [3998, 4032], 'Far-Field': [4001], 'Mayak': [4004], 'Production': [4005], 'Association,': [4006], 'Russia.Science2006,': [4007], '314,': [4008], '638–641.': [4009], '20.': [4012], 'Kersting': [4013], 'Efurd': [4016], 'Finnegan': [4019], 'Rokop': [4022], 'Smith': [4025], 'Thompson': [4028], 'L.Migration': [4030], 'Ground': [4034], 'Water': [4035], 'Nevada': [4038], 'Test': [4039], 'Site.Nature1999,': [4040], '397,': [4041], '56–59.': [4042], '21.': [4045], 'Liang': [4048, 4128], 'G.-D.;': [4051], 'Chen': [4052, 4136], 'He': [4056], 'S.-X.;': [4067], 'Diwu': [4068], 'G.;': [4071], 'S.Intrinsic': [4077], 'Semiconducting': [4078], 'Behavior': [4079], 'Mixed-Valent': [4083], 'Uranium(V/VI)': [4084], 'Cluster.Angew.': [4085], '9886–9890.': [4090], '22.': [4093], 'Chatelain': [4094], 'Faizova': [4096], 'Fadaei-Tirani': [4098, 4176], 'Pecaut': [4100], 'Mazzanti': [4102, 4180], 'M.Structural': [4103], 'Snapshots': [4104], 'Growth': [4107], '{U6}': [4109], '{U38}': [4111], 'During': [4112], 'Hydrolysis': [4114], 'UCl4.Angew.': [4116], '3021–3026.': [4121], '23.': [4124], 'S.Three-Dimensional': [4148], 'Polycatenation': [4149], 'Uranium-Based': [4152], 'Metal-Organic': [4153], 'Cage:': [4154], 'Structural': [4155, 4235], 'Complexity': [4156], 'Radiation': [4158], 'Detection.J.': [4159], '16218–16222.': [4164], '24.': [4167], 'Jori': [4168], 'Barluzzi': [4170], 'Douair': [4172], 'I.;': [4173, 4179], 'Maron': [4174], 'Zivkovic': [4178], 'M.Stepwise': [4181], 'Reduction': [4182], 'Dinitrogen': [4184], 'Uranium-Potassium': [4187], 'Yielding': [4189], 'U(VI)/U(IV)': [4191], 'Tetranitride': [4192], 'Cluster.J.': [4193], 'Soc.2021,': [4196], '143,': [4197], '11225–11234.': [4198], '25.': [4201], 'Vanagas': [4202], 'N.': [4203], 'Higgins': [4205], 'Wacker': [4208], 'Asuigui': [4211], 'Warzecha': [4215], 'Kozimor': [4217], 'Stoll': [4220], 'Schelter': [4223], 'Bertke': [4226], 'Knope': [4229], 'E.Mononuclear': [4231], 'U-IV': [4234], 'Units:': [4236], 'Effects': [4237], 'Conditions': [4240]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W4281295144', 'counts_by_year': [{'year': 2024, 'cited_by_count': 6}, {'year': 2023, 'cited_by_count': 1}, {'year': 2022, 'cited_by_count': 1}], 'updated_date': '2025-01-06T06:45:47.512546', 'created_date': '2022-05-24'}