Title: Observation of Methanol Behavior in Fuel Cells In Situ by NMR Spectroscopy
Abstract: Angewandte ChemieVolume 124, Issue 16 p. 3908-3911 Zuschrift Observation of Methanol Behavior in Fuel Cells In Situ by NMR Spectroscopy† Prof. Dr. Oc Hee Han, Corresponding Author Prof. Dr. Oc Hee Han [email protected] Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea) Graduate School of Analytical Science and Technology, Chungnam National University, Daejeon, 305-764 (Korea) Department of Chemistry, Kyungpook National University, Daegu, 702-701 (Korea) These authors contributed equally to this work.Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorDr. Kee Sung Han, Dr. Kee Sung Han Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea) These authors contributed equally to this work.Search for more papers by this authorChang Woo Shin, Chang Woo Shin Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorJuhee Lee, Juhee Lee Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorSeong-Soo Kim, Seong-Soo Kim Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorMyung Sup Um, Myung Sup Um Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this authorDr. Han-Ik Joh, Dr. Han-Ik Joh Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this authorDr. Soo-Kil Kim, Dr. Soo-Kil Kim Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this authorDr. Heung Yong Ha, Dr. Heung Yong Ha Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this author Prof. Dr. Oc Hee Han, Corresponding Author Prof. Dr. Oc Hee Han [email protected] Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea) Graduate School of Analytical Science and Technology, Chungnam National University, Daejeon, 305-764 (Korea) Department of Chemistry, Kyungpook National University, Daegu, 702-701 (Korea) These authors contributed equally to this work.Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorDr. Kee Sung Han, Dr. Kee Sung Han Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea) These authors contributed equally to this work.Search for more papers by this authorChang Woo Shin, Chang Woo Shin Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorJuhee Lee, Juhee Lee Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorSeong-Soo Kim, Seong-Soo Kim Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu, 702-701 (Korea)Search for more papers by this authorMyung Sup Um, Myung Sup Um Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this authorDr. Han-Ik Joh, Dr. Han-Ik Joh Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this authorDr. Soo-Kil Kim, Dr. Soo-Kil Kim Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this authorDr. Heung Yong Ha, Dr. Heung Yong Ha Energy Storage Research Center, Korea Institute of Science and Technology, Seoul, 136-791 (Korea)Search for more papers by this author First published: 12 March 2012 https://doi.org/10.1002/ange.201108330Citations: 4 † This work was supported by the KBSI grants (K29030, K30030, and K31030) to O.H. Han. Dr. S. A. Chae and Dr. Y. Paik at the KBSI are acknowledged for their assistance in NMR experiments. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Die chemische Umwandlung von Methanol in Direktmethanolbrennstoffzellen wurde in situ durch NMR-Spektroskopie verfolgt. Der Vergleich von Daten der Methanoloxidation an Pt- und PtRu-Anodenkatalysatoren ermöglichte es, die Rolle von Ru bei Faradayschen und nicht-Faradayschen Reaktionen zu untersuchen. Die räumlichen Verteilungen chemischer Spezies konnten ebenfalls bestimmt werden (Bild: T1–T4=Ansaug- und Absaugröhrchen). Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201108330_sm_miscellaneous_information.pdf427.1 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1K. E. Martin, J. P. Kopasz, K. W. McMurphy in Fuel Cell Chemistry and Operation (Eds.: ), ACS Symposium Series; American Chemical Society, Washington, DC, 2010, pp. 1–13. 10.1021/bk-2010-1040.ch001 Google Scholar 2L. Carrette, K. A. Friedrich, U. Stimming, Fuel Cells 2001, 1, 5–39. 10.1002/1615-6854(200105)1:1<5::AID-FUCE5>3.0.CO;2-G CASWeb of Science®Google Scholar 3A. S. Arico, S. Srinivasan, V. Antonucci, Fuel Cells 2011, 1, 133–161. 10.1002/1615-6854(200107)1:2<133::AID-FUCE133>3.0.CO;2-5 Web of Science®Google Scholar 4P. Scharfer, W. Schabel, M. Kind, J. Membr. Sci. 2007, 303, 37–42. 10.1016/j.memsci.2007.06.051 CASWeb of Science®Google Scholar 5C. Rice, Y. Y. Tong, E. Oldfield, A. Wieckowski, J. Phys. Chem. B 2000, 104, 5803–5807. 10.1021/jp0007179 CASWeb of Science®Google Scholar 6S. Park, Y. Y. Tong, A. Wieckowski, M. J. Weaver, Electrochem. Commun. 2001, 3, 509–513. 10.1016/S1388-2481(01)00202-8 CASWeb of Science®Google Scholar 7B. M. Rush, J. A. Reimer, E. J. Cairns, J. Electrochem. Soc. 2001, 148, A 137–A148. 10.1149/1.1342164 CASWeb of Science®Google Scholar 8Y. Y. Tong, E. Oldfield, A. Wieckowski, Anal. Chem. News & Features 1998, 70, 518A–527A. 10.1021/ac981932c CASPubMedWeb of Science®Google Scholar 9O. H. Han, K. S. Han, US Pat. 7339378, 2008; Google ScholarO. H. Han, K. S. Han, Jpn. Pat. 4203099, 2008; Google ScholarO. H. Han, K. S. Han, D.E. Pat. 102007011598, 2011; Google ScholarO. H. Han, K. S. Han, Kor. Pat. 10-0695225, 2007. Google Scholar 10J. W. Rathke, R. J. Klingler, R. E. Gerald II, K. W. Kramarz, K. Woelk, Prog. Nucl. Magn. Reson. Spectrosc. 1997, 30, 209–253. 10.1016/S0079-6565(96)01037-0 CASWeb of Science®Google Scholar 11K. Woelk, J. Magn. Reson. 2000, 146, 157–164. 10.1006/jmre.2000.2144 CASPubMedWeb of Science®Google Scholar 12V. S. Bagotzky, YU. B. Vassiliev, O. A. Khazova, J. Electroanal. Chem. 1977, 81, 229–238. Google Scholar 13E. A. Batista, G. R. P. Malpass, A. J. Motheo, T. Iwasita, J. Electroanal. Chem. 2004, 571, 273–282. 10.1016/j.jelechem.2004.05.016 CASWeb of Science®Google Scholar 14G. T. Burstein, C. J. Barnett, A. R. Kucernak, K. R. Williams, Catal. Today 1997, 38, 425–437. 10.1016/S0920-5861(97)00107-7 CASWeb of Science®Google Scholar 15A. Hamnett in Handbook of Fuel Cells Fundamentals Technology and Applications, Vol. 1 (Eds.: ), Wiley, Hoboken, 2003, pp. 308–314. Google Scholar 16M. Watanabe, S. Motoo, Electroanal. Chem. Interfacial Electrochem. 1975, 60, 275–283. 10.1016/S0022-0728(75)80262-2 CASWeb of Science®Google Scholar 17H. A. Gasteiger, N. Marković, P. N. Ross, Jr., E. J. Cairns, J. Phys. Chem. 1994, 98, 617–625. 10.1021/j100053a042 CASWeb of Science®Google Scholar 18R. Satija, D. L. Jacobson, M. Arif, S. A. Werner, J. Power Sources 2004, 129, 238–245. 10.1016/j.jpowsour.2003.11.068 CASWeb of Science®Google Scholar 19A. Turhan, K. Heller, J. S. Brenizer, M. M. Mench, J. Power Sources 2006, 160, 1195–1203. 10.1016/j.jpowsour.2006.03.027 CASWeb of Science®Google Scholar 20K. W. Feindel, L. P.-A. LaRocque, D. Starke, S. H. Bergens, R. E. Wasylishen, J. Am. Chem. Soc. 2004, 126, 11436–11437. 10.1021/ja0461116 CASPubMedWeb of Science®Google Scholar 21J. Bedet, G. Maranzana, S. Leclerc, O. Lottin, C. Moyne, D. Stemmelen, P. Mutzenhardt, D. Canet, Int. J. Hydrogen Energy 2008, 33, 3146–3149. 10.1016/j.ijhydene.2008.01.053 CASWeb of Science®Google Scholar 22S. Tsushima, K. Teranishi, S. Hirai, Energy 2005, 30, 235–245. 10.1016/j.energy.2004.04.013 CASWeb of Science®Google Scholar 23T. A. Zawodzinski, Jr., M. Neeman, L. O. Sillerud, S. Gottesfeld, J. Phys. Chem. 1991, 95, 6040–6044. 10.1021/j100168a060 CASWeb of Science®Google Scholar 24M. Tada, S. Murata, T. Asakoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S.-i. Inada, M. Nomura, Y. Iwasawa, Angew. Chem. 2007, 119, 4388–4393; 10.1002/ange.200604732 Google ScholarAngew. Chem. Int. Ed. 2007, 46, 4310–4315. 10.1002/anie.200604732 CASPubMedWeb of Science®Google Scholar 25C. Roth, N. Benker, T. Buhrmester, M. Mazurek, M. Loster, H. Fuess, D. C. Koningsberger, D. E. Ramaker, J. Am. Chem. Soc. 2005, 127, 14607–14615. 10.1021/ja050139f CASPubMedWeb of Science®Google Scholar 26J. Inukai, K. Miyatake, K. Takada, M. Watanabe, T. Hyakutake, H. Nishide, Y. Nagumo, M. Watanabe, M. Aoki, H. Takano, Angew. Chem. 2008, 120, 2834–2837; 10.1002/ange.200705516 Google ScholarAngew. Chem. Int. Ed. 2008, 47, 2792–2795. 10.1002/anie.200705516 CASPubMedWeb of Science®Google Scholar 27I. Tkach, A. Panchenko, T. Kaz, V. Gogel, K. A. Friedrich, E. Rodunner, Phys. Chem. Chem. Phys. 2004, 6, 5419–5426. 10.1039/B411108G CASWeb of Science®Google Scholar 28Y. Paik, S. S. Kim, O. H. Han, Angew. Chem. 2008, 120, 100–102; 10.1002/ange.200703190 Google ScholarAngew. Chem. Int. Ed. 2008, 47, 94–96. 10.1002/anie.200703190 CASPubMedWeb of Science®Google Scholar Citing Literature Volume124, Issue16April 16, 2012Pages 3908-3911 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation
Publication Year: 2012
Publication Date: 2012-03-12
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 4
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot