Title: Olefin Metathesis in Compressed Carbon Dioxide
Abstract: Angewandte Chemie International Edition in EnglishVolume 36, Issue 22 p. 2466-2469 Communication Olefin Metathesis in Compressed Carbon Dioxide† Priv.-Doz. Dr. Alois Fürstner, Corresponding Author Priv.-Doz. Dr. Alois Fürstner Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorDaniel Koch, Daniel Koch Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorKlaus Langemann, Klaus Langemann Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorPriv.-Doz. Dr. Walter Leitner, Corresponding Author Priv.-Doz. Dr. Walter Leitner Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorChristian Six, Christian Six Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this author Priv.-Doz. Dr. Alois Fürstner, Corresponding Author Priv.-Doz. Dr. Alois Fürstner Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorDaniel Koch, Daniel Koch Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorKlaus Langemann, Klaus Langemann Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorPriv.-Doz. Dr. Walter Leitner, Corresponding Author Priv.-Doz. Dr. Walter Leitner Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this authorChristian Six, Christian Six Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int. code +(208) 306 2980 e-mail: [email protected] :[email protected]Search for more papers by this author First published: December 1, 1997 https://doi.org/10.1002/anie.199724661Citations: 122 † This work was supported by the Max-Planck-Gesellschaft and by the Gerhard-Hess-Program of the Deutsche Forschungsgemeinschaft (W. L.). K. L. thanks the Fonds der Chemischen Industrie for a Kekulé-Stipendium. We are especially indebted to Prof. Dr. G. Fink, Mülheim, for helpful suggestions and generous support concerning polymer analysis. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract The product distribution can be controlled by varying the density of the reaction medium when olefin metatheses of acyclic dienes are carried out in supercritical CO2 (scCO2), as shown below. Substrates with NH groups, which are generally not tolerated in conventional solvents, are compatible with Ru-based metathesis catalysts in scCO2. Avoidance of potentially hazardous organic solvents, simple isolation of the products, and the recovery of the catalysts in active form are additional practical advantages associated with using compressed CO2 as reaction medium for ring-closing metathesis (RCM) and ring-opening metathesis polymerization (ROMP). Citing Literature Volume36, Issue22December 1, 1997Pages 2466-2469 RelatedInformation
Publication Year: 1997
Publication Date: 1997-12-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 123
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