Title: Intercalates of Vanadyl Phosphate with Unsaturated Alcohols
Abstract: European Journal of Inorganic ChemistryVolume 2001, Issue 3 p. 713-719 Full Paper Intercalates of Vanadyl Phosphate with Unsaturated Alcohols Ludvík Beneš, Ludvík Beneš [email protected] Joint Laboratory of Solid State Chemistry of Academy of Sciences of the Czech Republic and University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic, Fax: (internat.) +420-40/603-6011Search for more papers by this authorKlára Melánová, Klára Melánová Joint Laboratory of Solid State Chemistry of Academy of Sciences of the Czech Republic and University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic, Fax: (internat.) +420-40/603-6011Search for more papers by this authorVítězslav Zima, Vítězslav Zima Joint Laboratory of Solid State Chemistry of Academy of Sciences of the Czech Republic and University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic, Fax: (internat.) +420-40/603-6011Search for more papers by this authorMiroslava Trchová, Miroslava Trchová Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 180 00 Prague, Czech Republic, Fax: (internat.) +420-02/2191-2351Search for more papers by this authorEva Uhlířová, Eva Uhlířová [email protected] Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 180 00 Prague, Czech Republic, Fax: (internat.) +420-02/2191-2351Search for more papers by this authorPavel Matějka, Pavel Matějka Department of Analytical Chemistry, Institute of Chemical Technology, Technická 5, 166 28 Prague, Czech RepublicSearch for more papers by this author Ludvík Beneš, Ludvík Beneš [email protected] Joint Laboratory of Solid State Chemistry of Academy of Sciences of the Czech Republic and University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic, Fax: (internat.) +420-40/603-6011Search for more papers by this authorKlára Melánová, Klára Melánová Joint Laboratory of Solid State Chemistry of Academy of Sciences of the Czech Republic and University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic, Fax: (internat.) +420-40/603-6011Search for more papers by this authorVítězslav Zima, Vítězslav Zima Joint Laboratory of Solid State Chemistry of Academy of Sciences of the Czech Republic and University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic, Fax: (internat.) +420-40/603-6011Search for more papers by this authorMiroslava Trchová, Miroslava Trchová Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 180 00 Prague, Czech Republic, Fax: (internat.) +420-02/2191-2351Search for more papers by this authorEva Uhlířová, Eva Uhlířová [email protected] Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 180 00 Prague, Czech Republic, Fax: (internat.) +420-02/2191-2351Search for more papers by this authorPavel Matějka, Pavel Matějka Department of Analytical Chemistry, Institute of Chemical Technology, Technická 5, 166 28 Prague, Czech RepublicSearch for more papers by this author First published: 02 February 2001 https://doi.org/10.1002/1099-0682(200103)2001:3<713::AID-EJIC713>3.0.CO;2-ACitations: 4Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Intercalates of VOPO4 with several linear unsaturated alcohols (2-propen-1-ol, 2-buten-1-ol, 2-propyn-1-ol, 2-butyn-1-ol, 3-butyn-1-ol 2-pentyn-1-ol, 3-pentyn-1-ol, 4-pentyn-1-ol, 5-hexyn-1-ol, 2-octyn-1-ol, and 10-undecyn-1-ol) have been prepared and characterized by powder X-ray diffractometry, IR and Raman spectrometry, and thermogravimetry. The arrangement of the alcohol molecules with respect to the type and position of the multiple bonds in the carbon chain is proposed. Alcohols with terminal triple bonds form very stable intercalates. It is presumed that these alcohols are anchored to the host layers by donor-acceptor bonds between their oxygen atoms and the vanadium atoms of the host, and by H-bonding between the acetylenic hydrogen of the terminal carbon and the oxygen atoms of the host. Citing Literature Volume2001, Issue3March 2001Pages 713-719 RelatedInformation
Publication Year: 2001
Publication Date: 2001-03-01
Language: en
Type: article
Indexed In: ['crossref']
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