Title: Gold-Catalyzed Cyclizations of<i>cis</i>-Enediynes: Insights into the Nature of Gold-Aryne Interactions
Abstract: Angewandte ChemieVolume 125, Issue 30 p. 7949-7953 Zuschrift Gold-Catalyzed Cyclizations of cis-Enediynes: Insights into the Nature of Gold–Aryne Interactions† Youliang Wang, Youliang Wang Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this authorAkop Yepremyan, Akop Yepremyan Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this authorDr. Subir Ghorai, Dr. Subir Ghorai Catalysis Research and Development, Sigma–Aldrich Chemical Corp., Milwaukee, WI (USA)Search for more papers by this authorDr. Robert Todd, Dr. Robert Todd Catalysis Research and Development, Sigma–Aldrich Chemical Corp., Milwaukee, WI (USA)Search for more papers by this authorProf. Dr. Donald H. Aue, Corresponding Author Prof. Dr. Donald H. Aue [email protected] Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this authorProf. Dr. Liming Zhang, Corresponding Author Prof. Dr. Liming Zhang [email protected] Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this author Youliang Wang, Youliang Wang Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this authorAkop Yepremyan, Akop Yepremyan Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this authorDr. Subir Ghorai, Dr. Subir Ghorai Catalysis Research and Development, Sigma–Aldrich Chemical Corp., Milwaukee, WI (USA)Search for more papers by this authorDr. Robert Todd, Dr. Robert Todd Catalysis Research and Development, Sigma–Aldrich Chemical Corp., Milwaukee, WI (USA)Search for more papers by this authorProf. Dr. Donald H. Aue, Corresponding Author Prof. Dr. Donald H. Aue [email protected] Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this authorProf. Dr. Liming Zhang, Corresponding Author Prof. Dr. Liming Zhang [email protected] Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlDepartment of Chemistry and Biochemistry, University of California, Santa Barbara, CA (USA) http://www.chem.ucsb.edu/∼zhang/index.htmlSearch for more papers by this author First published: 20 June 2013 https://doi.org/10.1002/ange.201301057Citations: 48 † L.Z. thanks the NSF (CAREER CHE-0969157 and CHE-1301343) and NIGMS (R01 GM084254) for generous financial support. D.H.A. acknowledges support from the Center for Scientific Computing at the CNSI and MRL (NSF MRSEC DMR-1121053 and NSF CNS-0960316), as well as the National Center for Supercomputing Applications (NSF TG-CHE100123) utilizing the NCSA Gordon and Blacklight systems. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Goldenes Arin? Gold-Arin-Komplexe werden als Übergangszustände in dualen Gold-katalysierte Cyclisierungen von cis-Endiinen angenommen (siehe Schema; DCE=1,2-Dichlorethan); sie werden besser beschrieben als ortho-Aurophenyl-Kationen, die mit schwachen Nucleophile reagieren und leichte intramolekulare Insertionen in C(sp3)-H-Bindungen eingehen. Mit der Methode wurden Indane, kondensierte Heteroarene und Phenolderivate auf einfache Weise hergestellt. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description ange_201301057_sm_miscellaneous_information.pdf5.6 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume125, Issue30July 22, 2013Pages 7949-7953 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation
Publication Year: 2013
Publication Date: 2013-06-20
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 50
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