Title: Isolation of Catalytic Intermediates in Hydroamination Reactions: Insertion of Internal Alkynes into a Zirconium–Amido Bond
Abstract: Angewandte ChemieVolume 122, Issue 36 p. 6526-6530 Zuschrift Isolation of Catalytic Intermediates in Hydroamination Reactions: Insertion of Internal Alkynes into a Zirconium–Amido Bond† David C. Leitch, David C. Leitch Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1 (Canada), Fax: (+1) 604-822-2847Search for more papers by this authorCourtney S. Turner, Courtney S. Turner Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1 (Canada), Fax: (+1) 604-822-2847Search for more papers by this authorLaurel L. Schafer Prof., Laurel L. Schafer Prof. [email protected] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1 (Canada), Fax: (+1) 604-822-2847Search for more papers by this author David C. Leitch, David C. Leitch Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1 (Canada), Fax: (+1) 604-822-2847Search for more papers by this authorCourtney S. Turner, Courtney S. Turner Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1 (Canada), Fax: (+1) 604-822-2847Search for more papers by this authorLaurel L. Schafer Prof., Laurel L. Schafer Prof. [email protected] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, B.C., V6T 1Z1 (Canada), Fax: (+1) 604-822-2847Search for more papers by this author First published: 17 August 2010 https://doi.org/10.1002/ange.201001927Citations: 15 † We gratefully acknowledge Boehringer Ingelheim (Canada) Ltd. and the NSERC for financially supporting this work. D.C.L. thanks NSERC for a CGSD scholarship. We thank N. Yonson for assistance with X-ray crystallography. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Alkin dazu, und weiter geht′s: Eine Insertion ungesättigter C-C-Bindungen in M-N-Bindungen wurde als Schlüsselschritt in Reaktionen an Lanthanoidzentren und kürzlich auch in Hydroaminierungen unter Katalyse durch Gruppe-4-Metalle vorgeschlagen. Mit der im Schema gezeigten Reaktion konnten erstmals solche Zwischenstufen an einem katalytisch aktiven d0-Metallzentrum isoliert und charakterisiert werden. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201001927_sm_miscellaneous_information.pdf1.8 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aT. E. Müller, K. C. Hultzsch, M. Yus, F. Foubelo, M. Tada, Chem. Rev. 2008, 108, 3795; 10.1021/cr0306788 CASPubMedWeb of Science®Google Scholar 1bJ. F. Hartwig, Nature 2008, 455, 314; 10.1038/nature07369 CASPubMedWeb of Science®Google Scholar 1cY. Takemoto, H. 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Google Scholar Citing Literature Volume122, Issue36August 23, 2010Pages 6526-6530 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation
Publication Year: 2010
Publication Date: 2010-07-21
Language: en
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