Publication Information

{'id': 'https://openalex.org/W4225674124', 'doi': 'https://doi.org/10.31635/ccschem.022.202201914', 'title': 'Identifying Key Descriptors for the Single-Atom Catalyzed CO Oxidation', 'display_name': 'Identifying Key Descriptors for the Single-Atom Catalyzed CO Oxidation', 'publication_year': 2022, 'publication_date': '2022-04-07', 'ids': {'openalex': 'https://openalex.org/W4225674124', 'doi': 'https://doi.org/10.31635/ccschem.022.202201914'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.31635/ccschem.022.202201914', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210239486', 'display_name': 'CCS Chemistry', 'issn_l': '2096-5745', 'issn': ['2096-5745'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310311897', 'host_organization_name': 'Chinese Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310311897'], 'host_organization_lineage_names': ['Chinese Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5107925295', 'display_name': 'Max J. Hülsey', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I165932596', 'display_name': 'National University of Singapore', 'ror': 'https://ror.org/01tgyzw49', 'country_code': 'SG', 'type': 'education', 'lineage': ['https://openalex.org/I165932596']}], 'countries': ['SG'], 'is_corresponding': False, 'raw_author_name': 'Max J. Hülsey', 'raw_affiliation_strings': ['Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585', 'institution_ids': ['https://openalex.org/I165932596']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5002752164', 'display_name': 'Sambath Baskaran', 'orcid': 'https://orcid.org/0000-0002-3154-9528'}, 'institutions': [{'id': 'https://openalex.org/I3045169105', 'display_name': 'Southern University of Science and Technology', 'ror': 'https://ror.org/049tv2d57', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I3045169105']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Sambath Baskaran', 'raw_affiliation_strings': ['Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055', 'institution_ids': ['https://openalex.org/I3045169105']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5082922110', 'display_name': 'Shipeng Ding', 'orcid': 'https://orcid.org/0000-0002-0065-1554'}, 'institutions': [{'id': 'https://openalex.org/I165932596', 'display_name': 'National University of Singapore', 'ror': 'https://ror.org/01tgyzw49', 'country_code': 'SG', 'type': 'education', 'lineage': ['https://openalex.org/I165932596']}], 'countries': ['SG'], 'is_corresponding': False, 'raw_author_name': 'Shipeng Ding', 'raw_affiliation_strings': ['Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585', 'institution_ids': ['https://openalex.org/I165932596']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5042365006', 'display_name': 'Sikai Wang', 'orcid': 'https://orcid.org/0009-0004-6761-2236'}, 'institutions': [{'id': 'https://openalex.org/I165932596', 'display_name': 'National University of Singapore', 'ror': 'https://ror.org/01tgyzw49', 'country_code': 'SG', 'type': 'education', 'lineage': ['https://openalex.org/I165932596']}], 'countries': ['SG'], 'is_corresponding': False, 'raw_author_name': 'Sikai Wang', 'raw_affiliation_strings': ['Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585', 'Joint School of National University of Singapore, Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585', 'institution_ids': ['https://openalex.org/I165932596']}, {'raw_affiliation_string': 'Joint School of National University of Singapore, Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207', 'institution_ids': ['https://openalex.org/I165932596']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5026073929', 'display_name': 'Hiroyuki Asakura', 'orcid': 'https://orcid.org/0000-0001-6451-4738'}, 'institutions': [{'id': 'https://openalex.org/I22299242', 'display_name': 'Kyoto University', 'ror': 'https://ror.org/02kpeqv85', 'country_code': 'JP', 'type': 'education', 'lineage': ['https://openalex.org/I22299242']}, {'id': 'https://openalex.org/I285663978', 'display_name': 'Weatherford College', 'ror': 'https://ror.org/02xwsbr93', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I285663978']}], 'countries': ['JP', 'US'], 'is_corresponding': False, 'raw_author_name': 'Hiroyuki Asakura', 'raw_affiliation_strings': ['615-8245', 'Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 615-8510; 615-8245', 'Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8245'], 'affiliations': [{'raw_affiliation_string': 'Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 615-8510; 615-8245', 'institution_ids': ['https://openalex.org/I22299242']}, {'raw_affiliation_string': 'Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8245', 'institution_ids': ['https://openalex.org/I22299242']}, {'raw_affiliation_string': '615-8245', 'institution_ids': ['https://openalex.org/I285663978']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5018115010', 'display_name': 'Shinya Furukawa', 'orcid': 'https://orcid.org/0000-0002-2621-6139'}, 'institutions': [{'id': 'https://openalex.org/I22299242', 'display_name': 'Kyoto University', 'ror': 'https://ror.org/02kpeqv85', 'country_code': 'JP', 'type': 'education', 'lineage': ['https://openalex.org/I22299242']}, {'id': 'https://openalex.org/I205349734', 'display_name': 'Hokkaido University', 'ror': 'https://ror.org/02e16g702', 'country_code': 'JP', 'type': 'education', 'lineage': ['https://openalex.org/I205349734']}], 'countries': ['JP'], 'is_corresponding': False, 'raw_author_name': 'Shinya Furukawa', 'raw_affiliation_strings': ['Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8245', 'Institute for Catalysis, Hokkaido University, Sapporo 001-0021'], 'affiliations': [{'raw_affiliation_string': 'Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8245', 'institution_ids': ['https://openalex.org/I22299242']}, {'raw_affiliation_string': 'Institute for Catalysis, Hokkaido University, Sapporo 001-0021', 'institution_ids': ['https://openalex.org/I205349734']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5031292832', 'display_name': 'Shibo Xi', 'orcid': 'https://orcid.org/0000-0002-8521-3237'}, 'institutions': [{'id': 'https://openalex.org/I115228651', 'display_name': 'Agency for Science, Technology and Research', 'ror': 'https://ror.org/036wvzt09', 'country_code': 'SG', 'type': 'government', 'lineage': ['https://openalex.org/I115228651']}], 'countries': ['SG'], 'is_corresponding': False, 'raw_author_name': 'Shibo Xi', 'raw_affiliation_strings': ['Institute for Chemical and Engineering Sciences, Agency for Science, Technology, and Research in Singapore, Singapore 138634'], 'affiliations': [{'raw_affiliation_string': 'Institute for Chemical and Engineering Sciences, Agency for Science, Technology, and Research in Singapore, Singapore 138634', 'institution_ids': ['https://openalex.org/I115228651']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5017725939', 'display_name': 'Qi Yu', 'orcid': 'https://orcid.org/0000-0003-3188-5377'}, 'institutions': [{'id': 'https://openalex.org/I99065089', 'display_name': 'Tsinghua University', 'ror': 'https://ror.org/03cve4549', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I99065089']}, {'id': 'https://openalex.org/I187175081', 'display_name': 'Shaanxi University of Technology', 'ror': 'https://ror.org/056m91h77', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I187175081']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Qi Yu', 'raw_affiliation_strings': ['Department of Chemistry, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084', 'Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hangzhou 723001'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084', 'institution_ids': ['https://openalex.org/I99065089']}, {'raw_affiliation_string': 'Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hangzhou 723001', 'institution_ids': ['https://openalex.org/I187175081']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5067009343', 'display_name': 'Cong‐Qiao Xu', 'orcid': 'https://orcid.org/0000-0003-4593-3288'}, 'institutions': [{'id': 'https://openalex.org/I3045169105', 'display_name': 'Southern University of Science and Technology', 'ror': 'https://ror.org/049tv2d57', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I3045169105']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Cong-Qiao Xu', 'raw_affiliation_strings': ['Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055', 'institution_ids': ['https://openalex.org/I3045169105']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5100361956', 'display_name': 'Jun Li', 'orcid': 'https://orcid.org/0000-0002-8456-3980'}, 'institutions': [{'id': 'https://openalex.org/I3045169105', 'display_name': 'Southern University of Science and Technology', 'ror': 'https://ror.org/049tv2d57', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I3045169105']}, {'id': 'https://openalex.org/I99065089', 'display_name': 'Tsinghua University', 'ror': 'https://ror.org/03cve4549', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I99065089']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Jun Li', 'raw_affiliation_strings': ['Department of Chemistry, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084', 'Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055', 'institution_ids': ['https://openalex.org/I3045169105']}, {'raw_affiliation_string': 'Department of Chemistry, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084', 'institution_ids': ['https://openalex.org/I99065089']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5071951449', 'display_name': 'Ning Yan', 'orcid': 'https://orcid.org/0000-0002-1877-9206'}, 'institutions': [{'id': 'https://openalex.org/I165932596', 'display_name': 'National University of Singapore', 'ror': 'https://ror.org/01tgyzw49', 'country_code': 'SG', 'type': 'education', 'lineage': ['https://openalex.org/I165932596']}], 'countries': ['SG'], 'is_corresponding': False, 'raw_author_name': 'Ning Yan', 'raw_affiliation_strings': ['Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585', 'institution_ids': ['https://openalex.org/I165932596']}]}], 'institution_assertions': [], 'countries_distinct_count': 4, 'institutions_distinct_count': 8, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 0, 'currency': 'USD', 'value_usd': 0, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 3.358, 'has_fulltext': False, 'cited_by_count': 31, 'citation_normalized_percentile': {'value': 0.999971, 'is_in_top_1_percent': True, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 97, 'max': 98}, 'biblio': {'volume': '4', 'issue': '10', 'first_page': '3296', 'last_page': '3308'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10192', 'display_name': 'Catalytic Processes in Materials Science', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10192', 'display_name': 'Catalytic Processes in Materials Science', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11784', 'display_name': 'CO2 Reduction Techniques and Catalysts', 'score': 0.9992, 'subfield': {'id': 'https://openalex.org/subfields/2105', 'display_name': 'Renewable Energy, Sustainability and the Environment'}, 'field': {'id': 'https://openalex.org/fields/21', 'display_name': 'Energy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11825', 'display_name': 'Catalysis and Oxidation Reactions', 'score': 0.9983, 'subfield': {'id': 'https://openalex.org/subfields/1503', 'display_name': 'Catalysis'}, 'field': {'id': 'https://openalex.org/fields/15', 'display_name': 'Chemical Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [], 'concepts': [{'id': 'https://openalex.org/C26517878', 'wikidata': 'https://www.wikidata.org/wiki/Q228039', 'display_name': 'Key (lock)', 'level': 2, 'score': 0.61703455}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.5934569}, {'id': 'https://openalex.org/C58312451', 'wikidata': 'https://www.wikidata.org/wiki/Q4817200', 'display_name': 'Atom (system on chip)', 'level': 2, 'score': 0.4888429}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.41375518}, {'id': 'https://openalex.org/C41008148', 'wikidata': 'https://www.wikidata.org/wiki/Q21198', 'display_name': 'Computer science', 'level': 0, 'score': 0.37121722}, {'id': 'https://openalex.org/C38652104', 'wikidata': 'https://www.wikidata.org/wiki/Q3510521', 'display_name': 'Computer security', 'level': 1, 'score': 0.14788514}, {'id': 'https://openalex.org/C149635348', 'wikidata': 'https://www.wikidata.org/wiki/Q193040', 'display_name': 'Embedded system', 'level': 1, 'score': 0.13947406}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.108232856}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.31635/ccschem.022.202201914', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210239486', 'display_name': 'CCS Chemistry', 'issn_l': '2096-5745', 'issn': ['2096-5745'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310311897', 'host_organization_name': 'Chinese Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310311897'], 'host_organization_lineage_names': ['Chinese Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'display_name': 'Quality education', 'id': 'https://metadata.un.org/sdg/4', 'score': 0.43}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 0, 'referenced_works': [], 'related_works': ['https://openalex.org/W3110362372', 'https://openalex.org/W2899084033', 'https://openalex.org/W2748952813', 'https://openalex.org/W2391464953', 'https://openalex.org/W2366284060', 'https://openalex.org/W2363925233', 'https://openalex.org/W2356380379', 'https://openalex.org/W2329452785', 'https://openalex.org/W1975883523', 'https://openalex.org/W1794016765'], 'abstract_inverted_index': {'Open': [0], 'AccessCCS': [1], 'ChemistryRESEARCH': [2], 'ARTICLE3': [3], 'Oct': [4], '2022Identifying': [5], 'Key': [6, 189, 202, 259], 'Descriptors': [7], 'for': [8, 135, 150, 160, 170, 176, 315, 332, 393, 442, 446, 455, 507, 535, 644, 674, 697, 753, 793, 908, 973, 985, 1226, 1309, 1469, 1527, 1812, 1891, 2011, 2363, 2408, 2505, 2592, 2764, 2773, 2987, 3046, 3121, 3143, 3266, 3307, 3430, 3457, 3525, 3536, 3695, 3749, 3793, 3802, 3986, 4020, 4047, 4067, 4213], 'the': [9, 334, 345, 350, 377, 389, 394, 405, 418, 438, 473, 479, 553, 570, 583, 594, 605, 610, 622, 632, 635, 656, 738, 768, 775, 782, 788, 831, 853, 864, 883, 922, 943, 952, 970, 974, 986, 992, 995, 1000, 1003, 1007, 1016, 1020, 1023, 1027, 1031, 1040, 1044, 1051, 1057, 1063, 1066, 1075, 1159, 1259, 1293, 1314, 1350, 1397, 1449, 1458, 1506, 1542, 1553, 1560, 1576, 1593, 1597, 1607, 1635, 1642, 1699, 1816, 1834, 1845, 1852, 1878, 1925, 1932, 1937, 1993, 2006, 2017, 2030, 2051, 2080, 2126, 2135, 2144, 2150, 2161, 2172, 2197, 2206, 2211, 2216, 2265, 2270, 2282, 2293, 2320, 2329, 2335, 2356, 2403, 2419, 2448, 2479, 2482, 2490, 2495, 2528, 2536, 2544, 2559, 2599, 2602, 2618, 2633, 2636, 2647, 2662, 2687, 2705, 2768, 2783, 2807, 2875, 2883, 2926, 2952, 2975, 3002, 3037, 3054, 3096, 3104, 3111, 3122, 3218, 3223, 3230, 3240, 3244, 3259, 3262, 3275, 3316, 3325, 3352, 3378, 3393, 3415, 3431, 3454, 3458, 3490, 3581, 3586, 3593, 3597, 3605, 3611, 3627, 3630, 3634, 3657, 3660, 3708, 3730, 3764, 3774, 3786, 3789, 3794, 3798, 3811, 3884, 3924, 3927, 3931, 3934, 3937, 3944, 3966, 4083, 4128, 4144, 4150, 4165, 4180, 4185, 4190, 4199, 4203, 4208, 4224, 4229, 4234, 4240, 4245], 'Single-Atom': [10], 'Catalyzed': [11], 'CO': [12, 352, 424, 556, 578, 595, 623, 734, 914, 975, 1674, 1681, 1686, 1708, 1717, 1720, 1841, 1846, 1907, 2887, 2901, 2934, 2945, 2957, 2980, 2995, 3023, 3055, 3128, 3140, 3152, 3169, 3188, 3432, 3437, 3459, 3537, 3584, 3673, 3703, 3712, 3766, 3948, 4005, 4034, 4088, 4096, 4131], 'Oxidation': [13, 3162, 3184, 3201], 'Max': [14, 38], 'J.': [15, 39], 'Hülsey,': [16], 'Sambath': [17, 54], 'Baskaran,': [18], 'Shipeng': [19, 68], 'Ding,': [20], 'Sikai': [21, 83], 'Wang,': [22], 'Hiroyuki': [23, 117], 'Asakura,': [24], 'Shinya': [25, 145], 'Furukawa,': [26], 'Shibo': [27, 167], 'Xi,': [28], 'Qi': [29, 186], 'Yu,': [30], 'Cong-Qiao': [31, 219], 'Xu,': [32], 'Jun': [33, 233], 'Li': [34, 234], 'and': [35, 44, 63, 73, 88, 137, 152, 172, 179, 207, 228, 252, 264, 275, 291, 362, 379, 498, 512, 542, 562, 577, 615, 661, 677, 695, 703, 740, 747, 764, 781, 846, 897, 913, 926, 937, 999, 1022, 1043, 1096, 1122, 1145, 1158, 1193, 1232, 1247, 1312, 1389, 1466, 1518, 1631, 1647, 1652, 1695, 1712, 1779, 1867, 1908, 1936, 1961, 1999, 2084, 2094, 2166, 2365, 2369, 2373, 2397, 2410, 2442, 2471, 2507, 2550, 2572, 2581, 2658, 2673, 2693, 2720, 2724, 2739, 2756, 2760, 2910, 2921, 2990, 3000, 3004, 3011, 3130, 3145, 3171, 3232, 3237, 3252, 3258, 3285, 3299, 3310, 3344, 3381, 3505, 3513, 3558, 3569, 3623, 3676, 3713, 3716, 3739, 3818, 3833, 3883, 3906, 3949, 3956, 4026, 4052, 4086, 4098, 4121, 4134, 4228], 'Ning': [36, 276], 'Yan': [37, 277], 'Hülsey': [40], 'Department': [41, 56, 70, 85, 119, 199, 221, 245, 256, 288], 'of': [42, 49, 57, 61, 71, 78, 86, 93, 99, 102, 108, 120, 125, 191, 195, 200, 204, 210, 212, 222, 226, 246, 250, 257, 261, 267, 269, 289, 296, 312, 336, 347, 355, 408, 437, 469, 481, 510, 555, 573, 634, 658, 700, 767, 777, 784, 790, 835, 855, 863, 871, 885, 945, 951, 994, 1002, 1006, 1019, 1030, 1039, 1065, 1074, 1103, 1127, 1130, 1135, 1149, 1162, 1211, 1253, 1323, 1352, 1359, 1401, 1549, 1595, 1601, 1638, 1661, 1703, 1828, 1851, 1886, 1901, 1918, 1979, 2029, 2041, 2069, 2079, 2114, 2143, 2202, 2281, 2347, 2367, 2378, 2418, 2447, 2456, 2481, 2494, 2500, 2540, 2547, 2635, 2639, 2664, 2690, 2704, 2708, 2715, 2732, 2752, 2796, 2925, 2956, 2974, 3039, 3058, 3069, 3098, 3106, 3117, 3164, 3221, 3239, 3246, 3277, 3318, 3324, 3354, 3377, 3383, 3388, 3392, 3400, 3407, 3412, 3421, 3435, 3476, 3498, 3510, 3543, 3563, 3583, 3596, 3619, 3629, 3659, 3679, 3686, 3729, 3773, 3788, 3797, 3851, 3880, 3929, 3933, 3943, 3947, 4001, 4042, 4130], 'Chemical': [43, 72, 87, 171, 290], 'Biomolecular': [45, 74, 89, 292], 'Engineering,': [46, 75, 90, 122, 126, 293], 'National': [47, 76, 91, 100, 294], 'University': [48, 60, 77, 92, 101, 194, 225, 249, 295], 'Singapore,': [50, 79, 94, 103, 182, 297], 'Singapore': [51, 80, 95, 183, 298, 2018], '117585': [52, 81, 96, 299], ',': [53, 67, 82, 116, 144, 166, 185, 218, 232], 'Baskaran': [55], 'Chemistry,': [58, 201, 223, 247, 258], 'Southern': [59, 224, 248], 'Science': [62, 227, 251], 'Technology,': [64, 178, 196, 229, 253], 'Shenzhen': [65, 230, 254], '518055': [66, 231, 255], 'Ding': [69], 'Wang': [84, 1519], 'Joint': [97], 'School': [98, 124], 'Tianjin': [104, 109], 'University,': [105, 110, 128, 141, 156, 163, 215, 272], 'International': [106], 'Campus': [107], 'Binhai': [111], 'New': [112, 1738], 'City,': [113], 'Fuzhou': [114], '350207': [115], 'Asakura': [118], 'Molecular': [121, 208, 265], 'Graduate': [123], 'Kyoto': [127, 129, 140, 142, 155, 157], '615-8510;': [130], '615-8245': [131, 143, 158], 'Elements': [132, 147], 'Strategy': [133, 148], 'Initiative': [134, 149], 'Catalysts': [136, 151], 'Batteries': [138, 153], '(ESICB),': [139, 154], 'Furukawa': [146], 'Institute': [159, 169], 'Catalysis,': [161, 192], 'Hokkaido': [162], 'Sapporo': [164], '001-0021': [165], 'Xi': [168], 'Engineering': [173, 209, 266], 'Sciences,': [174], 'Agency': [175], 'Science,': [177], 'Research': [180, 2102], 'in': [181, 322, 364, 402, 421, 642, 680, 729, 795, 818, 821, 852, 1078, 1132, 1203, 1301, 1349, 1488, 1729, 1755, 1802, 1883, 2057, 2122, 2131, 2261, 2274, 2284, 2427, 2489, 2680, 2698, 2782, 2806, 2939, 2985, 3075, 3095, 3109, 3134, 3366, 3585, 3649, 3655, 3919, 3940, 4013, 4023, 4037, 4056, 4127, 4143, 4149], '138634': [184], 'Yu': [187, 1515], 'Shaanxi': [188, 193], 'Laboratory': [190, 203, 260], 'Hangzhou': [197], '723001': [198], 'Organic': [205, 262], 'Optoelectronics': [206, 263], 'Ministry': [211, 268], 'Education,': [213, 270], 'Tsinghua': [214, 271], 'Beijing': [216, 273], '100084': [217, 274], 'Xu': [220], '*Corresponding': [235, 278], 'authors:': [236, 279], 'E-mail': [237, 241, 280, 284], 'Address:': [238, 242, 281, 285], '[email': [239, 243, 282, 286, 1608, 1643, 1645, 1662], 'protected]': [240, 244, 283, 287, 1609, 1663], 'https://doi.org/10.31635/ccschem.022.202201914': [300], 'SectionsSupplemental': [301], 'MaterialAboutAbstractPDF': [302], 'ToolsAdd': [303], 'to': [304, 342, 371, 399, 404, 416, 550, 609, 628, 671, 692, 811, 1014, 1140, 1433, 1447, 1485, 1502, 1537, 1557, 1574, 1584, 1634, 1698, 2074, 2263, 2269, 2535, 2543, 2566, 2574, 2631, 2881, 2919, 3015, 3088, 3358, 3450, 3532, 3575, 3590, 3639, 3706, 3762, 3839, 3857, 3990, 4059, 4106, 4177, 4218], 'favoritesDownload': [305], 'CitationsTrack': [306], 'Citations': [307], 'ShareFacebookTwitterLinked': [308], 'InEmail': [309], 'Fundamental': [310], 'knowledge': [311], 'structure-activity': [313], 'correlations': [314, 568], 'heterogeneous': [316, 675], 'single-atom': [317, 823, 856, 1470, 2381, 2884], 'catalysts': [318, 426, 471, 686, 865, 1260, 1298, 1853, 1880, 2383, 2405, 2449, 2600, 2695, 2719, 2735, 3112, 3125, 3148, 3328, 3689, 3752, 4116], '(SACs)': [319, 687], 'is': [320, 736, 841, 874, 2679, 3132, 3648], 'essential': [321, 673], 'guiding': [323], 'catalytic': [324, 351, 447, 456, 487, 611, 762, 867, 1052, 1067, 2411, 3233, 3765, 3938], 'design.': [325], 'While': [326, 525], 'linear': [327, 567, 805, 4221], 'scaling': [328, 374, 444, 492, 640, 791, 806, 3620, 3871], 'relations': [329, 375, 445, 792, 807, 1036, 3429], 'are': [330, 516, 546, 664, 669, 678, 756, 1098, 2776, 2780, 3873], 'powerful': [331, 727], 'predicting': [333], 'performance': [335], 'traditional': [337], 'metal': [338, 523, 564, 638, 659, 815, 1295, 2053, 2303, 2394, 2487, 2742, 2899, 2963, 3892, 3900, 3917, 4166, 4187], 'catalysts,': [339], 'they': [340, 668, 3895], 'appear': [341], 'fail': [343], 'with': [344, 366, 451, 501, 539, 604, 631, 843, 849, 1026, 1108, 1208, 1250, 1286, 1292, 1319, 1355, 1376, 1386, 1457, 1546, 1588, 1706, 1715, 1752, 1769, 1824, 1864, 1873, 1897, 1913, 1942, 1954, 2037, 2110, 2171, 2185, 2230, 2254, 2292, 2306, 2328, 2361, 2391, 2454, 2478, 2498, 2517, 2682, 2902, 2941, 3024, 3274, 3337, 3361, 3390, 3443, 3494, 3507, 3539, 3560, 3651, 3769, 3821, 3866, 3923, 3981, 4003, 4032, 4117, 4162], 'involvement': [346], 'SACs.': [348, 987], 'Comparing': [349], 'oxidation': [353, 425, 557, 596, 624, 735, 976, 1842, 1847, 3078, 3119, 3433, 3438, 3460, 3538, 3674, 3767, 4129], 'activity': [354, 378, 488, 625, 3434, 3595, 3675, 3768], 'different': [356, 769, 1475, 2717, 2733, 2765, 3123, 3146, 3326, 3413, 3465, 3680, 3732, 3750, 3754, 3881, 3889, 3977, 4214], 'atomically': [357, 1082, 3319], 'dispersed': [358, 1083, 3320], 'metals': [359, 820, 851, 3550], '(3d,': [360], '4d,': [361], '5d)': [363], 'conjunction': [365], 'computational': [367, 419, 749, 878, 3849, 3868], 'modeling': [368, 1422], 'enabled': [369], 'us': [370], 'establish': [372], 'multiple': [373], 'between': [376, 569, 761, 1037, 1505, 2656, 3339, 3472, 3877, 3909, 4223], 'simply': [380], 'calculated': [381, 1612, 1665, 1700, 2073, 2519], 'descriptors.': [382, 432], 'Through': [383], 'these': [384, 4071, 4156], 'efforts,': [385], 'we': [386, 881, 1061, 2148, 2204, 2221, 2595, 3776, 4153, 4175, 4206], 'found': [387, 627, 4154], 'that': [388, 485, 804, 2432, 2445, 2558, 2597, 2894, 3862, 4076, 4114, 4155, 4233], 'thermodynamic': [390, 431, 3860], 'driving': [391], 'force': [392], 'oxygen': [395, 1032, 2571, 4043, 4145], 'vacancy': [396, 1033], 'formation': [397, 1028, 1059, 1657, 1669, 2480, 2663, 3718, 4041, 4085, 4102, 4123], 'needed': [398], 'be': [400, 531, 672, 693, 2951, 2983, 3227, 3359, 3533, 3576, 3864, 4219], 'considered': [401, 2772], 'addition': [403], 'adsorption': [406, 497, 528, 571, 1017, 1041, 1598, 1704, 1713, 2499, 2521, 2935, 2981, 3245, 3402, 3715, 3734, 3878, 3945, 3984, 4018, 4029, 4035, 4119, 4141, 4157, 4182], 'energies': [407, 500, 529, 545, 572, 1018, 1042, 1637, 1702, 2522, 3719, 3879, 3946, 3985, 4010, 4019, 4036, 4103, 4124, 4158, 4183], 'substrates': [409, 1021, 3882, 4022], '(in': [410], 'particular': [411], 'CO).': [412], 'Our': [413], 'approach': [414, 2880], 'was': [415, 626, 1011, 1138, 1215, 1224, 1238, 1333, 1364, 1394, 1411, 1431, 1464, 1483, 1500, 1525, 1535, 1572, 1611, 1664, 1727, 1776, 1822, 1940, 1971, 2032, 2072, 2252, 2290, 2341, 2353, 2421, 2476, 2515, 2531, 2938, 3066, 3085, 3614, 3668, 3855, 4045, 4063, 4237], 'reduce': [417, 2075], 'requirements': [420], 'determining': [422], 'better': [423], 'using': [427, 1269, 1335, 1366, 1396, 1413, 1869, 2005, 2061, 2210, 2319, 2355, 2886], 'a': [428, 508, 599, 698, 726, 1104, 1147, 1336, 1356, 1367, 1377, 1384, 1390, 1402, 1414, 1547, 1730, 1746, 1756, 1770, 1825, 1857, 1870, 1884, 1898, 1914, 1955, 1969, 2038, 2062, 2111, 2186, 2223, 2231, 2255, 2285, 2307, 2344, 2387, 2629, 2889, 2911, 3040, 3060, 3070, 3076, 3150, 3330, 3363, 3419, 3444, 3495, 3540, 3577, 3825, 3914, 4220], 'few': [429, 3364], 'key': [430], 'This': [433, 825, 2514, 2678, 3647], 'work': [434], 'presents': [435], 'one': [436, 1589, 1707, 2501, 2913], 'first': [439, 2563], 'successful': [440], 'approaches': [441], 're-establishing': [443], 'reactions': [448, 511, 645], 'by': [449, 613, 748, 830, 877, 901, 911, 929, 959, 979, 1241, 1474, 1511, 1540, 1580, 1745, 2258, 2386, 2423, 2969, 3250, 3296, 3315, 3397, 3502, 3816, 3875], 'SACs': [450, 755, 765, 794, 812, 899, 1076, 2434, 2927, 3530, 3663, 3838, 3886, 3920, 4201], 'potentially': [452], 'broad': [453, 2904], 'implications': [454], 'processes': [457], 'actively': [458, 607], 'involving': [459, 646], 'this': [460, 620, 1079], 'support.': [461], 'Download': [462, 464, 1114, 1116, 2786, 2788, 3154, 3156, 3424, 3426, 3756, 3758], 'figure': [463, 1115, 2787, 3155, 3425, 3757], 'PowerPoint': [465, 1117, 2789, 3157, 3427, 3759], 'Introduction': [466], 'The': [467, 1222, 1235, 1297, 1438, 1452, 1478, 1522, 1532, 1569, 1655, 1774, 2026, 2067, 2117, 2243, 2337, 2380, 3235, 3287, 3519, 3698, 3726, 3807, 4040], 'design': [468], 'improved': [470], 'from': [472, 1197, 1290, 2301, 3292, 3616, 3890], 'vast': [474], 'chemical': [475], 'space': [476], 'relies': [477], 'on': [478, 521, 558, 591, 712, 814, 1100, 1606, 1641, 2334, 2611, 2929, 2959, 3018, 3127, 3168, 3187, 3204, 3464, 3720, 3781, 3959, 4164, 4179, 4184], 'discovery': [480], 'computationally': [482], 'inexpensive': [483], 'parameters': [484, 526, 654, 862, 3861], 'describe': [486, 882, 1448], 'adequately.1,2': [489], 'Among': [490], 'others,': [491], 'relationships': [493, 3872], 'linking': [494], 'properties': [495, 3772], 'like': [496, 527, 2570, 2577, 3051], 'reaction': [499, 612, 977, 1008, 1742, 1750, 1843, 3461, 3635, 3666, 3677, 3747, 3800, 3842, 3939, 4109, 4209, 4230, 4235], 'activation': [502, 544, 584], 'barriers': [503, 3843], 'have': [504, 688, 802, 3591, 3840], 'been': [505, 650, 690, 827], 'developed': [506], 'range': [509, 1351, 3097], 'surface': [513, 957, 1610, 3288, 3353, 3394], 'morphologies': [514], 'but': [515, 1054, 4006, 4062], 'so': [517], 'far': [518], 'predominantly': [519], 'focused': [520], 'extended': [522, 559, 2246, 3891], 'surfaces.': [524], 'could': [530, 2615, 2982, 3863], 'determined': [532, 928, 1268, 1964, 2300, 3290, 3396, 3815, 3865], 'relatively': [533], 'quickly': [534], 'large': [536], "materials'": [537, 872], 'libraries': [538, 873], 'high': [540, 3665, 4007, 4033, 4100], 'accuracy': [541], 'precision,': [543], 'significantly': [547, 2169, 3313], 'more': [548, 2532, 3727, 4191], 'challenging': [549], 'calculate.': [551], 'For': [552, 588, 619, 637, 1844, 2134, 2196, 2215, 2525, 2646, 2972, 2992, 3217, 3255, 3847], 'case': [554, 854, 3579], 'fcc(111)': [560], 'surfaces': [561, 763, 3893], 'transition': [563, 1577], '(TM)': [565], 'nanoparticles,': [566], 'O': [574, 617], 'atoms,': [575, 780], 'O2,': [576, 1602, 1651], 'molecules,': [579, 1718], 'as': [580, 582, 719, 725, 940, 942, 980, 982, 1263, 1509, 1613, 1666, 2399, 2425, 2628, 2668, 2878, 2888, 2966, 3043, 3485, 3824, 4189], 'well': [581, 630, 941, 1049], 'barriers,': [585], 'were': [586, 1261, 1267, 1299, 1317, 1445, 1555, 1782, 1807, 1838, 1854, 1881, 1922, 1934, 1963, 1983, 2003, 2045, 2055, 2087, 2120, 2129, 2299, 2317, 2384, 2406, 2435, 2626, 2696, 2997, 3007, 3101, 3248, 3268, 3305, 3311, 3441, 3462, 3469, 3521, 3552, 3743, 3804, 3887, 3979, 3997, 4011, 4079, 4125, 4159, 4247], 'predicted.3': [587], 'nanoparticles': [589, 3108], 'supported': [590, 813, 900, 1471], 'reducible': [592], 'oxides,': [593, 639], 'commonly': [597, 3044], 'follows': [598], 'Mars-van': [600], 'Krevelen': [601], '(MvK)': [602], 'mechanism': [603, 1005, 3801, 3809, 3813], 'support': [606, 3598, 3632, 3822, 3935], 'contributing': [608], 'donating': [614], 'accepting': [616], 'atoms.': [618], 'reason,': [621], 'correlate': [629, 3763], 'reducibility': [633], 'support.4,5': [636], 'relations,': [641], 'particular,': [643, 2986], 'C–H': [647], 'activation6–10': [648], 'had': [649, 3636], 'assessed': [651], 'previously.': [652], 'However,': [653], 'at': [655, 1306, 1794, 1809, 1894, 1928, 1992, 2016, 2034, 2047, 2089, 2097, 2107, 2153, 2343, 2907, 2914, 3009, 3028, 3063, 3082, 3447, 3664, 3701, 3753], 'interface': [657, 4148], 'species': [660, 1640], 'oxide': [662, 2304, 2624, 2725], 'supports': [663], 'rarely': [665], 'discussed,': [666], 'although': [667, 3528], 'known': [670, 2308, 2604], 'catalysis': [676, 2012], 'present': [679, 906], 'virtually': [681], 'all': [682, 960, 1489, 2433, 2455, 2598, 3110, 3960, 4198], 'industrial': [683], 'catalysts.11–14': [684], 'Single-atom': [685], 'recently': [689], 'shown': [691, 803, 2426, 2781], 'active': [694, 947, 996, 2483, 2605, 2649, 2665, 2688, 2769, 3492, 3535, 3901], 'selective': [696], 'variety': [699], 'oxidation,': [701], 'reduction,': [702], 'coupling': [704], 'reactions.15–28': [705], 'Density': [706], 'functional': [707, 1463], 'theory': [708, 2640], '(DFT)': [709], 'calculations': [710, 989, 1583, 3780], 'based': [711, 2333, 2610, 2928, 3126, 3186, 3203], 'structures': [713, 2614], 'obtained': [714, 1289], 'via': [715], 'various': [716], 'tools': [717], 'such': [718, 2965], 'X-ray': [720, 1973, 1987, 2007, 2247, 2311, 2538], 'absorption': [721, 1974, 1988, 2008, 2248, 2312, 2545], 'spectroscopy': [722, 920, 1332, 1975, 1989, 2249, 3625], '(XAS)': [723, 1990], 'serve': [724], 'tool': [728], 'revealing': [730], 'activity-structure': [731], 'correlations.15,16,27': [732], 'Although': [733, 4139], 'among': [737, 3976], 'earliest': [739], 'most': [741, 3491], 'thoroughly': [742], 'investigated': [743, 1077], 'reactions,': [744], 'performed': [745, 1334, 1365, 1412, 2004, 2088, 2318, 2354], 'experimentally': [746], 'modeling,29–33': [750], 'clear': [751, 3963], 'guidelines': [752], 'designing': [754], 'lacking.': [757], 'Obvious': [758], 'differences': [759, 3468, 3520, 3996], 'exist': [760], 'because': [766, 2160, 3894], 'electronic': [770, 785, 833, 1636, 1701], 'states,': [771, 1578], 'intimate': [772], 'metal-support': [773, 4147], 'interactions,': [774], 'absence': [776, 783, 3105], 'adjacent': [778, 3899], 'TM': [779, 1621, 1676, 1688, 3961], 'bands': [786, 2906], 'forcing': [787], 'treatment': [789], 'alternative': [796], 'ways.': [797], 'In': [798, 3053, 3760], 'fact,': [799], 'many': [800], 'reports': [801, 3017], 'do': [808], 'not': [809, 1048, 3312, 3897, 3912, 4094], 'apply': [810], 'oxides': [816, 3282], 'or': [817, 1604, 2138, 2146, 2156, 2177, 2440, 2961, 3279, 3844], 'host': [819, 850], 'so-called': [822], 'alloys.34–37': [824], 'has': [826, 3418], 'explained': [828], 'previously': [829, 3814], 'unique': [832], 'structure': [834, 925, 998, 1705, 1714, 2010, 2377, 2497, 2707, 2771, 3225, 3242, 3380], 'SACs,36,38': [836], 'geometric': [837], 'dynamics': [838], 'beyond': [839], 'what': [840], 'achievable': [842], 'nanoparticle': [844], 'catalysts,35': [845], 'ensemble': [847], 'effects': [848, 3905], 'alloys.34,37': [857], 'Without': [858], 'discovering': [859], 'simple': [860, 3770, 3859], 'physical': [861], 'governing': [866], 'activity,': [868, 1053], 'efficient': [869], 'screening': [870, 3850], 'severely': [875], 'prohibited': [876], 'expenses.39': [879], 'Herein,': [880], 'synthesis': [884, 1121, 3231], 'Cr,': [886, 1994, 3553], 'Mn,': [887, 1086, 1995, 3554], 'Fe,': [888, 1087, 1996, 3556], 'Co,': [889, 1088, 1997], 'Ni,': [890, 1089, 1998, 3559], 'Cu,': [891, 1090, 3555], 'Zn,': [892, 1091, 3557], 'Ru,': [893, 1092, 2081, 2548], 'Rh,': [894, 1093, 2082, 2092, 2549, 2988], 'Pd,': [895, 1094, 3503], 'Ag,': [896, 1095, 2989], 'Pt': [898, 2085, 2217, 2244, 3074, 3183], 'phosphomolybdic': [902], 'acid': [903, 1214], '(PMA).': [904], 'We': [905, 2278, 2873, 2892, 3835], 'evidence': [907], 'atomic': [909, 1562], 'dispersion': [910, 2417], 'XAS': [912, 2077, 2118, 2141, 2200, 2207, 2219, 2529, 3172], 'diffuse': [915], 'reflectance': [916], 'infrared': [917, 3253], 'Fourier': [918], 'transform': [919, 2359], '(DRIFTS),': [921], 'uniform': [923], 'catalyst': [924, 1725, 2590, 2613, 3631, 3790, 3852], 'morphology': [927, 3332, 3382], 'N2': [930, 3297, 3401], 'sorption,': [931], 'scanning': [932, 1407], 'electron': [933, 1408], 'microscopy': [934, 1409], '(SEM),': [935], 'Raman,': [936], 'IR': [938, 3026, 3624], 'spectroscopies,': [939], 'determination': [944], 'identical': [946], 'site': [948, 956, 997, 2376, 2606, 2650, 2666, 2770, 4167], 'structural': [949, 968], 'arrangement': [950], 'exposed': [953], 'four-fold': [954, 2491], 'hollow': [955, 2492], 'area': [958], 'Keggin-structured': [961], 'polyoxometalates': [962], '(POMs)': [963], '(Figure': [964, 2463, 2579, 2671, 3113, 3342, 3517, 4132, 4242], '1).40,41': [965], 'Despite': [966], 'their': [967, 2721, 2740, 2942, 4099], 'similarities,': [969], 'light-off': [971, 1045, 3439], 'temperatures': [972, 1046, 1933, 3448, 3456, 3667], 'differed': [978], 'much': [981, 3522], '400': [983, 1486, 2348, 3482], '°C': [984, 1308, 1811, 1896, 1903, 3641], 'DFT': [988, 1436, 2518, 3779], 'further': [990, 1012, 2414, 3617], 'confirmed': [991, 2422, 2444, 2661, 3249, 3626], 'stability': [993, 3236, 3628, 3658], 'dominance': [1001], 'MvK': [1004, 3812, 4151], 'kinetics.': [1009], 'It': [1010, 4112], 'used': [1013, 1262, 1432, 1501, 1526, 1573, 2407, 2627, 3792], 'predict': [1015], 'product,': [1024], 'along': [1025], 'energy': [1029, 1482, 1534, 1599, 1658, 2346, 4057, 4110], '(OV).': [1034], 'Scaling': [1035, 3428], 'each': [1038], 'did': [1047, 3896, 3911, 4093], 'match': [1050], 'after': [1055, 1965, 3243, 3633], 'including': [1056], 'OV': [1058, 1656, 3717, 4084, 4101, 4122], 'energy,': [1060], 'understood': [1062], 'trends': [1064, 3964, 3975], 'performance.': [1068], 'Figure': [1069, 2428, 2644, 2676, 2700, 3137, 3347, 3371, 3373, 3602, 3645, 3670, 3693, 3957, 3972, 4137, 4172], '1': [1070, 2791, 4238], '|': [1071, 2702, 2792, 3139, 3160, 3375, 3672], 'Schematic': [1072], 'depiction': [1073], 'study.': [1080], 'Different': [1081], 'TMs': [1084, 2420, 2578, 2931, 3247, 3988, 4002, 4078, 4092], '(Cr,': [1085], 'Pt)': [1097], 'anchored': [1099], 'POMs': [1101, 3309], 'composed': [1102], 'central': [1105], 'PO4': [1106], 'unit': [1107], '12': [1109], 'surrounding': [1110], 'edge-sharing': [1111], 'MoO6': [1112], 'units.': [1113], 'Experimental': [1118, 2759], 'Methods': [1119], 'Catalyst': [1120], 'characterization': [1123], 'An': [1124], 'aqueous': [1125], 'solution': [1126, 1148, 1223], 'appropriate': [1128, 1160, 1321, 1849, 2589], 'amounts': [1129, 1850], 'PMA': [1131, 1623, 1678, 1690, 3267], '30': [1133, 1204, 1219, 1251, 1813, 1966], 'mL': [1134, 1205, 1252, 1920], 'deionized': [1136, 1206, 1254, 1324], 'water': [1137, 1207, 1325], 'cooled': [1139], '0': [1141], '°C.': [1142, 3452], 'Under': [1143], 'stirring': [1144, 1231], 'cooling,': [1146], '365': [1150], 'mg': [1151, 1724, 1981], 'cesium': [1152, 2392], 'nitrate': [1153, 1164, 1170, 1173, 1176, 1179, 1182, 1186, 1191, 1195, 2395], '(MilliporeSigma,': [1154], 'Burlington,': [1155, 1199], 'MA,': [1156, 1200, 1284, 1347, 1767], 'USA)': [1157, 1201, 1285, 1348, 1768, 1953], 'amount': [1161], 'chromium': [1163], 'nonahydrate,': [1165, 1171], 'manganese': [1166], 'hydrate': [1167], 'tetrahydrate,': [1168], 'iron': [1169], 'cobalt': [1172], 'hexahydrate,': [1174, 1177, 1183], 'nickel': [1175], 'copper': [1178], 'hemi(pentahydrate),': [1180], 'zinc': [1181], 'ruthenium': [1184], 'nitrosyl': [1185], 'solution,': [1187], 'rhodium': [1188], 'nitrate,': [1189, 2393], 'palladium': [1190], 'dihydrate,': [1192], 'silver': [1194], '(all': [1196], 'MilliporeSigma,': [1198], 'dissolved': [1202, 1300], '5': [1209, 1227, 1902, 2259, 2368, 3671], 'drops': [1210], 'concentrated': [1212], 'nitric': [1213], 'added': [1216], 'gradually': [1217], 'over': [1218], 'min': [1220, 1893, 1967], 'period.': [1221], 'aged': [1225], 'h': [1228], 'under': [1229, 1304, 1784, 3149], 'constant': [1230, 2112], 'ice': [1233], 'cooling.': [1234], 'formed': [1236], 'solid': [1237, 2737], 'then': [1239, 1313, 4053], 'separated': [1240], 'centrifugation': [1242], '(5': [1243], 'min,': [1244, 1814], '8000': [1245], 'g)': [1246], 'washed': [1248], 'twice': [1249], 'water.': [1255], 'After': [1256], 'freeze-drying': [1257], 'overnight,': [1258], 'obtained.': [1264], 'Metal': [1265, 2623], 'contents': [1266], 'inductively': [1270], 'coupled': [1271, 4031], 'plasma-optical': [1272], 'emission': [1273, 1406], 'spectrometry': [1274], '(ICP-OES;': [1275], 'iCAP': [1276], '6000': [1277], 'series': [1278], 'instrument;': [1279], 'Thermo': [1280, 1337, 1757, 1763], 'Fisher': [1281, 1344, 1764], 'Scientific,': [1282, 1345, 1765], 'Waltham,': [1283, 1346, 1766], 'calibration': [1287], 'curves': [1288, 3440, 3685], 'solutions': [1291, 1316], 'pure': [1294], 'salts.': [1296], 'aqua': [1302], 'regia': [1303], 'heating': [1305, 1899], '80': [1307, 1919], '4': [1310, 1360, 3374], 'h,': [1311], 'filtered': [1315], 'diluted': [1318, 1817], 'an': [1320, 1874, 1943, 2588, 2652, 3025], 'volume': [1322], 'before': [1326, 1985], 'measurement.': [1327], 'Attenuated': [1328], 'total': [1329, 1533, 1618, 1915], 'reflection': [1330], '(ATR-IR)': [1331], 'Scientific': [1338, 1734, 1758], 'Nicolet': [1339, 1759], 'iS50': [1340, 1760], 'FT-IR': [1341, 1761], 'spectrometer': [1342, 1372], '(Thermo': [1343], '525–4000': [1353], 'cm−1': [1354, 1399, 3065, 3084, 3100], 'spectral': [1357], 'resolution': [1358, 2225], 'cm−1.': [1361], 'Raman': [1362, 1371, 3251, 3386, 3622], 'spectromicroscopy': [1363], 'Horiba': [1368], 'Yvon': [1369], 'Modular': [1370], '(Horiba,': [1373], 'Kyoto,': [1374], 'Japan)': [1375, 1419], '532': [1378], 'nm': [1379, 3341], 'excitation': [1380], 'laser,': [1381], '1%': [1382], 'filter,': [1383], 'grating': [1385], '1200': [1387], 'mm−1': [1388], 'x100': [1391], 'objective.': [1392], 'Calibration': [1393], 'done': [1395, 2291], '521': [1398], 'vibrations': [1400, 3006], 'silicon': [1403], 'wafer.': [1404], 'Field': [1405], '(FESEM)': [1410], 'JEM-6700F': [1415], '(JEOL,': [1416], 'Ltd.,': [1417], 'Tokyo,': [1418], 'microscope.': [1420], 'Computational': [1421], 'Vienna': [1423], 'Ab': [1424], 'initio': [1425, 2323], 'simulation': [1426], 'package': [1427], '(VASP;': [1428], 'version': [1429], '5.3.5)42–44': [1430], 'perform': [1434], 'spin-polarized': [1435], 'calculations.': [1437, 1490], 'projector': [1439], 'augmented': [1440], 'plane': [1441, 1479], 'wave': [1442, 1480], '(PAW)': [1443], 'pseudopotentials': [1444], 'employed': [1446, 2222, 2637, 2874], 'electron-ion': [1450], 'interaction.45': [1451], 'generalized': [1453], 'gradient': [1454], 'approximation': [1455], '(GGA)': [1456], 'Perdew–Wang': [1459], '91': [1460], '(PW91)': [1461], 'exchange-correlation': [1462, 2331], 'used,46': [1465], 'widely': [1467], 'applied': [1468], 'polyoxometalate': [1472], 'clusters': [1473], 'research': [1476], 'groups.47–49': [1477], 'cutoff': [1481], 'set': [1484, 1927, 2340], 'eV': [1487, 1539, 2260], 'A': [1491, 3080, 3115], '20': [1492, 1494, 1496], '×': [1493, 1495], 'Å3': [1497], 'cubic': [1498], 'box': [1499], 'avoid': [1503], 'interactions': [1504, 3908], 'periodic': [1507, 3967], 'images,': [1508], 'reported': [1510, 2279, 2400], 'Macht': [1512], 'et': [1513, 1516, 1520], 'al.,47': [1514], 'al.,48': [1517], 'al.49': [1521], 'Γ': [1523], 'point': [1524], 'Brillouin': [1528], 'zone': [1529], 'center': [1530], 'sampling.': [1531], 'converged': [1536], '10−4': [1538], 'applying': [1541], 'Gaussian': [1543, 2256], 'smearing': [1544], 'method': [1545, 2229, 2389], 'width': [1548, 2262], '0.05': [1550, 1567], 'eV.': [1551, 2349], 'All': [1552], 'ions': [1554], 'allowed': [1556], 'relax': [1558], 'until': [1559], 'maximum': [1561, 2039], 'forces': [1563], 'became': [1564, 4074], 'less': [1565, 3523, 4065], 'than': [1566, 3033], 'eV/Å.': [1568], 'dimer': [1570], 'method50–52': [1571], 'determine': [1575], 'followed': [1579, 3501, 4202], 'vibrational': [1581, 3263], 'frequency': [1582], 'confirm': [1585, 2632, 2882, 3785], 'saddle': [1586], 'points': [1587], 'imaginary': [1590], 'frequency.': [1591], 'Following': [1592], 'convention': [1594], 'thermodynamics,': [1596], '(Eads)': [1600], 'CO,': [1603, 3035], 'CO2': [1605], 'E': [1614, 1617, 1620, 1625, 1667, 1673, 1680, 1684], 'ads': [1615], '=': [1616, 1670, 3723], '−': [1619, 1624, 1671, 1683], '@': [1622], 'adsorbate': [1626], 'where': [1627, 1692, 2686, 3580], 'Etotal,': [1628], 'E[email': [1629], 'protected],': [1630, 1644, 1646], 'Eadsorbate': [1632], 'correspond': [1633, 1697], 'adsorbed': [1639, 2512, 2958, 2998], 'free': [1648], 'adsorbates': [1649, 3910], '(CO,': [1650], 'CO2),': [1653], 'respectively.': [1654, 1719, 3572], '(Evac': [1659], 'formation)': [1660], 'vac': [1668], '(': [1672, 2641, 3368, 3599, 3642, 3828, 3951, 3969, 4169], '-': [1675, 1687], '/': [1677, 1689], '+': [1679], '2': [1682, 1685, 2701, 3159, 3422], ')': [1691], 'ECO-TM/PMA,': [1693], 'ECO2,': [1694], 'E2CO-TM/PMA': [1696], 'molecule,': [1709, 2503], 'gas-phase': [1710, 3034], 'CO2,': [1711], 'two': [1716, 2903, 2994, 3731], 'DRIFTS': [1721, 2876, 3129, 3141, 3170, 3189], 'Approximately': [1722], '100': [1723], 'powder': [1726], 'loaded': [1728, 1855], 'Harricks': [1731], 'HV-DR2': [1732], '(Harrick': [1733], 'Products': [1735], 'Inc.,': [1736, 2192], 'Pleasantville,': [1737], 'York,': [1739], 'United': [1740], 'States)': [1741], 'cell': [1743], 'covered': [1744], 'Praying': [1747], 'Mantis': [1748], 'high-temperature': [1749], 'chamber': [1751, 1775], 'ZnS': [1753], 'windows': [1754], 'spectrometer;': [1762], 'mercury-telluride': [1771], '(MCT)': [1772], 'detector.': [1773, 1959], 'closed': [1777], 'gastight,': [1778], 'background': [1780, 3594], 'scans': [1781], 'recorded': [1783], '40': [1785, 1797, 1829], 'mL/min': [1786, 1798, 1830], 'nitrogen': [1787, 1831], 'gas': [1788, 1804, 1820, 1826, 1835, 1946], 'flow': [1789, 1821, 1827, 1861, 1885, 1916], '(Air': [1790, 1805], 'Liquide': [1791], 'purity,': [1792], '99.9995%)': [1793], 'room': [1795, 1929], 'temperature.': [1796, 1930], '5%': [1799, 1887, 3151], 'carbon': [1800, 1818], 'monoxide': [1801, 1819], 'argon': [1803], 'Liquide)': [1806], 'introduced': [1808, 1923], '50': [1810], 'whereupon': [1815], 'replaced': [1823], 'gas.': [1832], 'During': [1833], 'treatments,': [1836], 'spectra': [1837, 2071, 2119, 2208, 2272, 2314, 2660, 2714, 2731, 2763, 3142, 3387, 3406], 'collected': [1839, 2046, 2121], 'regularly.': [1840], 'reaction,': [1848, 1879], 'into': [1856, 1924], 'stainless-steel': [1858], 'tubular': [1859], 'plug': [1860], 'reactor,': [1862], 'fixed': [1863], 'quartz': [1865], 'wool,': [1866], 'heated': [1868], 'tube': [1871], 'furnace': [1872], 'external': [1875], 'thermocouple.': [1876], 'Before': [1877], 'activated': [1882], 'O2': [1888, 1910, 2502, 2520, 3714, 3733, 3746, 3950, 4008, 4028, 4140, 4181, 4212, 4225], '(balance': [1889, 1911], 'Ar)': [1890, 1912], '60': [1892], '250': [1895], 'rate': [1900, 1917], 'min−1.': [1904], 'Then': [1905, 2402], '2.5%': [1906, 1909], 'min−1': [1921], 'reactor': [1926, 1938, 3446], 'Subsequently,': [1931], 'increased,': [1935], 'efflux': [1939], 'analyzed': [1941, 3551], 'Agilent': [1944], '7890B': [1945], 'chromatograph': [1947], '(Agilent': [1948], 'Technologies,': [1949, 2191], 'Santa': [1950], 'Clara,': [1951], 'CA,': [1952], 'thermal': [1956], 'conductivity': [1957], '(TCD)': [1958], 'Conversions': [1960], 'yields': [1962], 'when': [1968, 3999], 'steady-state': [1970], 'reached.': [1972], 'Self-supported': [1976], 'undiluted': [1977], 'pellets': [1978], '200': [1980, 2042], 'sample': [1982], 'pressed': [1984], 'measurements.': [1986], 'measurements': [1991, 2078], 'Cu': [2000, 3178], 'K': [2001, 2711], 'edges': [2002, 2546], 'fine': [2009], '(XAFCA)': [2013], 'beamline': [2014], 'detector': [2015, 2189], 'Synchrotron': [2019, 2100], 'Light': [2020], 'Source': [2021], '(SSLS;': [2022], 'Buona': [2023], 'Vista,': [2024], 'Singapore).53': [2025], 'storage': [2027], 'ring': [2028], 'SSLS': [2031], 'operated': [2033, 2106], '0.7': [2035, 2866], 'GeV': [2036, 2109], 'current': [2040, 2113], 'mA.': [2043, 2116], 'Data': [2044, 2288], 'fluorescence': [2048, 2123, 2151, 2226, 2539], 'mode': [2049, 2059], 'while': [2050, 2125, 4090], 'respective': [2052, 2722, 2741], 'foils': [2054, 2743], 'measured': [2056, 2130, 2184, 2205, 2273, 3442, 4207], 'transmission': [2058, 2132, 2276], 'simultaneously': [2060], 'Si(111)': [2063], 'double': [2064], 'crystal': [2065, 2309], 'monochromator.': [2066], 'average': [2068], '3–5': [2070], 'noise.': [2076], 'Pd-edges': [2083], 'L3-edge': [2086, 2218, 2245], 'BL37XU': [2090], '(Ru,': [2091], 'Pd)': [2093], 'BL11XU': [2095], '(Pt)': [2096], 'SPring-8': [2098], '(Japan': [2099], 'Radiation': [2101], 'Institute,': [2103], 'Hyogo,': [2104], 'Japan),': [2105], '8.0': [2108], '99.5': [2115], 'mode,': [2124], 'standard': [2127], 'samples': [2128, 2305, 2625], 'mode.': [2133, 2277], 'Ru': [2136, 2154, 2173, 3179, 3506], 'K-edge': [2137, 2140, 2199], 'Rh': [2139, 2157, 2178, 3019, 3180, 3488, 3662], 'measurement': [2142, 2201], 'Ru/CsPMA': [2145], 'Rh/CsPMA,': [2147], 'exploited': [2149], 'lines': [2152, 2159, 2164, 2180], 'Kβ': [2155, 2158], 'Mo': [2162, 2541], 'Kβ1': [2163], '(19606': [2165], '19962': [2167], 'eV)': [2168, 2176], 'overlapped': [2170], 'Kα1': [2174], '(19279': [2175], 'Kα1,2': [2179], '(20216,': [2181], '20074': [2182], 'eV),': [2183], 'Ge': [2187], 'solid-state': [2188], '(Mirion': [2190], 'Atlanta,': [2193], 'GA,': [2194], 'USA).': [2195], 'Pd': [2198, 2212, 3181], 'Pd/CsPMA,': [2203], 'typically': [2209], 'Kα': [2213], 'line.': [2214], 'measurement,': [2220], 'high-energy': [2224], 'detection': [2227], '(HERFD)': [2228], 'Si(733)': [2232], 'spherically': [2233], 'bent': [2234], 'analyzer': [2235], '(XRS': [2236], 'TECH': [2237], 'LLC.,': [2238], 'Freehold,': [2239], 'NJ,': [2240], 'Unite': [2241], 'States).': [2242], '(EXAFS)': [2250], 'spectrum': [2251, 3057, 3276], 'broadened': [2253], 'function': [2257], 'make': [2264], 'EXAFS': [2266, 2271, 2443, 2474, 2730, 2793, 3205], 'amplitude': [2267], 'comparable': [2268, 3980], 'conventional': [2275], 'some': [2280, 2973, 3475], 'details': [2283], 'previous': [2286, 2684, 3016, 3653], 'paper.54': [2287], 'analysis': [2289, 2352, 2409, 2530, 2556, 2751, 3399, 3618], 'Demeter': [2294], 'software': [2295], 'package.55': [2296], 'σ2': [2297, 2815], 'values': [2298, 2362, 3304, 3480, 3509, 3562], 'commercial': [2302], 'structure.': [2310, 2607], 'near-edge': [2313], '(XANES)': [2315], 'simulations': [2316, 2609, 2775], 'CASTEP': [2321], 'ab': [2322], 'quantum': [2324], 'mechanical': [2325], 'program': [2326], 'code56': [2327], 'PW91': [2330], 'functional46': [2332], 'GGA.': [2336], 'plane-wave': [2338], 'basis': [2339], 'truncated': [2342], 'kinetic': [2345, 3819], 'Wavelet': [2350], 'transformation': [2351, 2555, 2750], 'Morlet': [2357, 2553, 2748], 'wavelet': [2358, 2554, 2749], 'procedure': [2360], 'κ': [2364], 'σ': [2366], '1,': [2370, 2466], 'respectively.57': [2371], 'Results': [2372], 'Discussion': [2374], 'Active': [2375], 'M1/CsPMA': [2379, 2382, 2718, 2734, 2766, 2799, 3124, 3147, 3165, 3260, 3327, 3389, 3436, 3681, 3688, 3721, 3751], 'synthesized': [2385], 'coprecipitation': [2388], 'starting': [2390], 'salts,': [2396], 'PMA,': [2398], 'previously.40,58': [2401], 'dried': [2404], 'testing': [2412], 'without': [2413, 2897], 'modification.': [2415], 'Atomic': [2416], 'XAS,': [2424], '2a.': [2429], 'XANES': [2430, 2608, 2713, 2762, 2774, 3131], 'revealed': [2431, 3962], 'highly': [2436, 3071], 'charged': [2437, 2962, 3073], '(2+,': [2438], '3+,': [2439], '4+),': [2441], 'none': [2446, 2573], 'exhibited': [2450, 2562, 2601, 3478], 'metal-metal': [2451], 'bond': [2452], 'scattering,': [2453], 'them': [2457], 'showing': [2458], 'significant': [2459, 3467], 'metal-oxygen': [2460], 'scattering': [2461, 2568], 'contributions': [2462], '2b,': [2464], 'Table': [2465, 2469, 2790, 3135, 3158, 3954], 'Supporting': [2467, 2582, 2642, 2674, 2808, 3345, 3369, 3600, 3643, 3691, 3829, 3952, 3970, 4135, 4170], 'Information': [2468, 2583, 2643, 2675, 2809, 3346, 3370, 3601, 3644, 3692, 3830, 3953, 3971, 4136, 4171], 'S1,': [2470], 'Figures': [2472, 2584, 3831], 'S1–10).': [2473], 'fitting': [2475], 'consistent': [2477, 2516, 3331], 'site,': [2484], 'which': [2485, 2509, 2937, 3477, 3656], 'displayed': [2486], 'atoms': [2488, 2569, 2576], 'sites': [2493, 2689, 2964, 4188], 'Keggin': [2496, 3241], 'except': [2504], 'Cu1/CsPMA': [2506], 'Pd1/CsPMA,': [2508], 'showed': [2510, 2932, 3329], 'no': [2511, 3092, 3271], 'O2.': [2513], '(vide': [2523], 'infra).': [2524], '4d': [2526, 3724], 'elements,': [2527, 2977], 'complicated': [2533], 'due': [2534, 3989], 'strong': [2537, 2979], 'close': [2542], 'Pd.': [2551], 'Nevertheless,': [2552], 'suggested': [2557], 'SAC': [2560, 2706, 3493, 3613], 'only': [2561, 4115], 'shell': [2564], 'coordination': [2565, 2621, 3582], 'light': [2567], 'heavier': [2575, 2976, 3987], '2c': [2580], 'S11–S19).': [2585], 'To': [2586, 3784, 4195], 'develop': [2587], 'model': [2591, 3791], 'atomistic': [2593], 'simulations,': [2594, 3795], 'ensured': [2596], 'same': [2603, 4204], 'DFT-calculated': [2612], 'help': [2616], 'identify': [2617, 3858], 'exact': [2619], 'local': [2620], 'environment.': [2622], 'reference': [2630, 2726], 'validity': [2634, 3787], 'level': [2638], 'S20).': [2645, 2677], 'predicted': [2648, 3808], 'structures,': [2651, 2667], 'almost': [2653, 3546, 4160], 'ideal': [2654], 'overlap': [2655, 3272], 'simulated': [2657, 2761], 'experimental': [2659], 'discussed': [2669], 'above': [2670, 3481], '2d': [2672], 'accordance': [2681, 3650], 'our': [2683, 2970, 3652], 'findings,': [2685], 'POM-supported': [2691, 3661], 'Rh1': [2692], 'Pd1': [2694], 'elucidated': [2697], 'detail.58,59': [2699], 'Confirmation': [2703], 'M1/CsPMA.': [2709, 3384], '(a)': [2710, 3385, 3683], 'edge': [2712], 'ten': [2716], 'metallic': [2723, 3107], 'materials.': [2727], '(b)': [2728, 3404, 3710], 'R-space': [2729], '(colored,': [2736], 'lines)': [2738], '(black,': [2744], 'dashed': [2745], 'lines).': [2746], '(c)': [2747, 3409, 3745], 'Cr': [2753, 3173], 'foil,': [2754], 'Cr2O3,': [2755], 'Cr1/CsPMA.': [2757], '(d)': [2758], 'catalysts;': [2767, 3414], 'shown.': [2777], 'Additional': [2778, 2801], 'data': [2779], 'supporting': [2784], 'information.': [2785], 'Fitting': [2794], 'Parameters': [2795], 'Some': [2797], 'Representative': [2798], 'Materials.': [2800], 'Details': [2802], 'Can': [2803], 'Be': [2804], 'Found': [2805], 'Coordination': [2810], 'Shell': [2811], 'CN': [2812], 'R': [2813], '(Å)': [2814], 'CoO': [2816], 'Co–O': [2817], '6': [2818, 2837, 2856], '2.10': [2819], '±': [2820, 2823, 2827, 2830, 2833, 2839, 2842, 2846, 2849, 2852, 2858, 2861, 2865, 2868, 2871], '0.04': [2821, 2831], '0.017': [2822], '0.008': [2824], 'Co1/CsPMA': [2825], '6.0': [2826], '1.9': [2828], '2.03': [2829], '0.009': [2832], '0.007': [2834], 'Rh2O3': [2835], 'Rh–O': [2836], '2.04': [2838], '0.01': [2840, 2850, 2869], '0.003': [2841, 2851], '0.001': [2843, 2860, 2870], 'Rh1/CsPMA': [2844, 3803], '6.8': [2845], '0.9': [2847], '2.02': [2848], '0.002': [2853, 2862, 2872], 'PtO2': [2854], 'Pt–O': [2855], '2.14': [2857], '0.02': [2859], 'Pt1/CsPMA': [2863], '3.9': [2864], '2.13': [2867], 'technique': [2877], 'another': [2879, 2947], 'identity': [2885], 'probe': [2890], 'molecule.': [2891], 'observed': [2893, 3045], 'even': [2895], 'CsPMA': [2896, 3144, 3257], 'additional': [2898, 2933, 3093, 3696], 'adsorbs': [2900, 3022], 'vibration': [2905, 3027], '1930,': [2908], '2042': [2909], 'sharper': [2912], '2122': [2915, 3064], 'cm−1,': [2916, 3013, 3030], 'probably': [2917, 3086], 'assignable': [2918], 'O–CO': [2920], 'Mo–CO': [2922], 'species.': [2923], 'None': [2924], 'early': [2930, 4077], 'bands,': [2936], 'line': [2940, 3700], 'generally': [2943], 'low': [2944, 4004, 4017], 'affinity;': [2946], 'possible': [2948], 'explanation': [2949], 'might': [2950], 'lower': [2953], 'extinction': [2954], 'coefficient': [2955], 'undercoordinated': [2960], 'those': [2967, 3355, 4163], 'presented': [2968], 'SACs.60': [2971], 'however,': [2978], 'observed,': [2984, 3067, 3102], 'Pt.': [2991], 'Rh1/CsPMA,': [2993], 'molecules': [2996], 'simultaneously,': [2999], 'both': [3001, 3256, 4021], 'symmetric': [3003], 'asymmetric': [3005], 'visible': [3008], '2027': [3010], '2099': [3012, 3083], 'similar': [3014], 'SACs.58,61': [3020], 'Ag1/CsPMA': [3021, 3573], '2182': [3029], 'slightly': [3031, 3982, 4064], 'higher': [3032, 3350], 'indicating': [3036], 'presence': [3038], 'non-classical': [3041, 3587], 'carbonyl': [3042, 3588], 'cationic': [3047], 'closed-shell': [3048], 'd10': [3049], 'systems': [3050], 'Ag+.62': [3052], 'DRIFT': [3056], 'Pt1/CsPMA,': [3059], 'dominant': [3061], 'peak': [3062], 'indicative': [3068], 'positively': [3072], '4+': [3077, 3212], 'state.': [3079], 'shoulder': [3081], 'related': [3087], 'Pt2+': [3089], 'species.32,63,64': [3090], 'Furthermore,': [3091, 3916], 'peaks': [3094], '1750–2080': [3099], 'suggesting': [3103, 4232], '3).63,65': [3114], 'summary': [3116], 'approximate': [3118], 'states': [3120], 'provided': [3133], '2.': [3136], '3': [3138], 'atmosphere.': [3153], 'Approximate': [3161], 'State': [3163], 'Materials': [3166], 'Based': [3167], 'Mn': [3174], 'Fe': [3175], 'Co': [3176, 3529], 'Ni': [3177], 'Ag': [3182], 'state': [3185, 3202], 'N.D.': [3190, 3191, 3192, 3193, 3194, 3195, 3196, 3198, 3215], '3+': [3197, 3206, 3208, 3213], '1+': [3199], '4+/2+': [3200], '2+': [3207, 3209, 3210, 3211, 3214, 3216], 'electrostatic': [3219], 'stabilization': [3220], 'SACs,': [3222, 3466, 3775], 'POM': [3224, 3379], 'must': [3226], 'preserved': [3228], 'during': [3229, 3936], 'reaction.': [3234], 'persistence': [3238], 'spectroscopies.': [3254], 'materials,': [3261, 3853], 'modes': [3264, 3735], 'typical': [3265, 3306], 'apparent,': [3269], 'whereas': [3270], 'existed': [3273], 'MoO3': [3278], 'other': [3280, 3837, 3841], 'molybdenum': [3281], '(Figures': [3283], '4a': [3284], '4b).66': [3286], 'areas': [3289, 3395], 'ranged': [3291], '89–132': [3293], 'm2': [3294], 'g−1': [3295], 'physisorption': [3298], 'Brunauer–Emmett–Teller': [3300], '(BET)': [3301], 'analysis.': [3302], 'Those': [3303], 'precipitated': [3308], 'affected': [3314], 'type': [3317], 'metal.': [3321], 'FESEM': [3322, 3410], 'images': [3323, 3411], 'featuring': [3333], 'spherical': [3334], 'particles': [3335, 3356], 'predominantly,': [3336], 'radii': [3338], '100–300': [3340], '4c': [3343], 'S21).': [3348], 'At': [3349], 'magnification,': [3351], 'appeared': [3357, 3531, 3574, 4113, 4217], 'rough': [3360], 'featured': [3362], 'nanometers': [3365], 'size': [3367], 'S22).': [3372], 'Characterization': [3376], 'labels': [3391], 'BET': [3398], 'isotherms,': [3403], 'Infrared': [3405], 'M1/CsPMA,': [3408], 'scale': [3416], 'bar': [3417], 'length': [3420], 'μm.': [3423], 'plug-flow': [3445], 'up': [3449, 3638, 4058], '500': [3451, 3609, 3640], 'When': [3453], 'T20': [3455, 3479, 3496, 3508, 3541, 3561, 3606], 'compared': [3463, 4012], 'visible,': [3470], 'especially': [3471], 'earlier': [3473, 3526], 'TMs,': [3474, 3527], '°C,': [3483, 3500, 3515, 3545, 3571, 3610], 'identified': [3484], 'noble': [3486], 'metals.': [3487], 'constituted': [3489], 'value': [3497, 3607], '∼88': [3499], 'Pt,': [3504], '173,': [3511], '244,': [3512], '308': [3514], 'respectively': [3516], '5a).': [3518], 'pronounced': [3524], 'particularly': [3534], 'temperature': [3542], '330': [3544], 'paralleling': [3547], 'Ru1/CsPMA.': [3548], 'Other': [3549], '382,': [3564], '413,': [3565], '425,': [3566], '430,': [3567], '465,': [3568], '466': [3570], 'special': [3578], 'seemed': [3589], 'inhibited': [3592], 'S23).': [3603], 'As': [3604], 'exceeded': [3608], 'Ag-based': [3612], 'omitted': [3615], 'relations.': [3621], 'reached': [3637], 'S24).': [3646], 'studies': [3654], 'demonstrated.58,67': [3669], 'descriptors': [3678], 'catalysts.': [3682, 4215], 'Light-off': [3684], 'select': [3687], '(see': [3690], 'S23': [3694], 'catalysts).': [3697], 'horizontal': [3699], '20%': [3702], 'conversion': [3704], 'serves': [3705], 'guide': [3707], 'eye.': [3709], 'Calculated': [3711], '(M': [3722], 'TM).': [3725], 'stable': [3728], '(O2,s': [3736], 'η2': [3737], 'side-on,': [3738], 'O2,e': [3740], 'η1': [3741], 'end-on)': [3742], 'considered.': [3744], 'order': [3748, 3761, 4236], 'temperatures.': [3755], 'physicochemical': [3771], 'carried': [3777], 'out': [3778], 'PMA-supported': [3782], 'TM.': [3783], 'analyses': [3796, 3820], 'assumed': [3799], 'also': [3805], 'performed.': [3806], 'matched': [3810], 'spectroscopic': [3817], 'reoxidation': [3823], 'rate-determining': [3826, 3845], 'step': [3827], 'S23a': [3832], 'S23b).58': [3834], 'expected': [3836], 'steps.': [3846], 'high-throughput': [3848], 'it': [3854, 4073], 'beneficial': [3856], 'minimum': [3867], 'efforts.': [3869], 'Often,': [3870], 'established': [3874], 'correlating': [3876], 'activity.': [3885], 'naturally': [3888], 'possess': [3898], 'sites;': [3902], 'thus,': [3903], 'coverage': [3904], 'lateral': [3907], 'play': [3913], 'role.': [3915], 'centers': [3918], 'interacted': [3921], 'solely': [3922], 'support,': [3925], 'highlighting': [3926], 'importance': [3928], 'considering': [3930], 'participation': [3932], 'modeling.': [3941], 'Screening': [3942], 'S2': [3955], 'S25)': [3958], 'throughout': [3965], 'table': [3968], 'S26).': [3973, 4138], 'Generally,': [3974], 'rows': [3978], 'larger': [3983], 'increased': [3991, 4055], 'nd': [3992], 'orbital': [3993], 'radii.': [3994], 'Stark': [3995], 'evident': [3998], 'groups': [4000, 4014, 4024, 4038, 4048], 'binding': [4009], '3–6;': [4015], 'generally,': [4016], '10–12': [4025], 'balanced': [4027, 4118], 'strength': [4030], '7–9.': [4039], 'vacancies': [4044], 'endothermic': [4046], '3–7': [4049], '(except': [4050], 'Mn)': [4051], 'monotonously': [4054], 'group': [4060, 4068], '11': [4061], 'favorable': [4066], '12.': [4069], 'From': [4070], 'trends,': [4072], 'obvious': [4075], 'too': [4080], 'oxophilic,': [4081], 'preventing': [4082], 'hampering': [4087], 'adsorption,': [4089], 'late': [4091], 'bind': [4095], 'strongly,': [4097], 'likely': [4104], 'led': [4105], 'thermodynamically': [4107], 'unbalanced': [4108], 'profiles.': [4111], 'strengths': [4120], 'effective': [4126], '5b': [4133], 'occurred': [4142], 'vacant': [4146], 'mechanism,': [4152, 4205], 'congruent': [4161], 'alone': [4168], 'S27).': [4173], 'Therefore,': [4174], 'decided': [4176], 'rely': [4178], 'vacancy-free': [4186], 'readily': [4192], 'accessible': [4193], 'parameter.': [4194], 'verify': [4196], 'if': [4197], 'PMA-based': [4200], 'orders': [4210, 4246], 'towards': [4211, 4239], 'There': [4216], 'correlation': [4222], 'partial': [4226], 'pressure': [4227], 'rate,': [4231], 'oxidant': [4241], '5c).': [4243], 'Since': [4244], 'com': [4248]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W4225674124', 'counts_by_year': [{'year': 2024, 'cited_by_count': 5}, {'year': 2023, 'cited_by_count': 24}, {'year': 2022, 'cited_by_count': 2}], 'updated_date': '2024-12-30T14:45:15.685604', 'created_date': '2022-05-05'}