Publication Information

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1345, 1355, 1408, 1527, 1659, 1788, 1797, 1885, 2403, 2585, 3136, 3194], 'Connector:': [11], 'General': [12, 2730], 'Construction': [13, 2479, 2790, 3058, 3241, 3261], 'of': [14, 29, 36, 63, 70, 97, 104, 118, 139, 156, 248, 270, 281, 338, 359, 371, 382, 389, 408, 439, 444, 516, 523, 587, 596, 618, 635, 675, 687, 699, 721, 739, 750, 769, 839, 861, 876, 1035, 1063, 1082, 1152, 1264, 1269, 1325, 1351, 1357, 1374, 1392, 1457, 1501, 1584, 1603, 1676, 1701, 1730, 1759, 1773, 1803, 1814, 1819, 1851, 1861, 1899, 1924, 1927, 1931, 1942, 1978, 1988, 1996, 2015, 2064, 2124, 2147, 2183, 2252, 2272, 2375, 2399, 2429, 2435, 2480, 2520, 2577, 2584, 2588, 2610, 2642, 2672, 2699, 2736, 2761, 2783, 2791, 2807, 2833, 2856, 2878, 2928, 3079, 3084, 3102, 3108, 3132, 3138, 3163, 3168, 3186, 3216, 3262, 3281, 3288, 3304, 3382, 3392, 3400], 'Alkyl–Alkyl': [15], 'Sulfones': [16, 2216, 2613, 2733, 3104, 3134], 'Yingying': [17, 24], 'Meng,': [18], 'Ming': [19, 48], 'Wang': [20, 49, 2320, 2511, 2777, 2868, 2870, 2991, 3029, 3053, 3180, 3233, 3255, 3275, 3322], 'and': [21, 32, 38, 66, 72, 81, 100, 106, 143, 184, 200, 223, 277, 314, 319, 379, 398, 449, 466, 470, 506, 659, 669, 693, 715, 733, 785, 809, 1114, 1177, 1195, 1223, 1238, 1255, 1354, 1378, 1413, 1415, 1443, 1462, 1519, 1535, 1610, 1635, 1684, 1705, 1722, 1734, 1765, 1787, 1796, 1810, 1831, 1836, 1856, 1890, 1915, 1938, 1967, 1973, 1986, 2011, 2023, 2045, 2144, 2159, 2187, 2219, 2258, 2268, 2325, 2334, 2353, 2373, 2471, 2621, 2647, 2676, 2705, 2710, 2765, 2904, 2952, 3143, 3190, 3221, 3247, 3309, 3324, 3371, 3377, 3390], 'Xuefeng': [22, 82], 'Jiang': [23, 83, 2038, 2078, 2297, 2322, 2515, 2779, 2805, 2922, 3031, 3055, 3237, 3259, 3279, 3325], 'Meng': [25, 2775], 'Shanghai': [26, 45, 60, 79, 94, 113, 1983, 1994, 3387, 3398], 'Key': [27, 61, 95, 116], 'Laboratory': [28, 62, 96, 117, 2188], 'Green': [30, 64, 98], 'Chemistry': [31, 37, 65, 71, 99, 105, 2580], 'Chemical': [33, 67, 101, 3354], 'Process,': [34, 68, 102], 'School': [35, 69, 103], 'Molecular': [39, 73, 107], 'Engineering,': [40, 74, 108], 'East': [41, 75, 109], 'China': [42, 76, 110], 'Normal': [43, 77, 111, 2158], 'University,': [44, 78, 112, 122], '200062': [46, 80, 114], ',': [47], '*Corresponding': [50, 84], 'authors:': [51, 85], 'E-mail': [52, 56, 86, 90], 'Address:': [53, 57, 87, 91], '[email': [54, 58, 88, 92], 'protected]': [55, 59, 89, 93], 'State': [115], 'Elemento-Organic': [119], 'Chemistry,': [120, 3336], 'Nankai': [121], 'Tianjin': [123], '300071': [124], 'https://doi.org/10.31635/ccschem.021.202000638': [125], 'SectionsSupplemental': [126], 'MaterialAboutAbstractPDF': [127], 'ToolsAdd': [128], 'to': [129, 284, 304, 375, 426, 530, 559, 576, 591, 606, 826, 1142, 1148, 1331, 1512, 1623, 1628, 1644, 1648, 1657, 1690, 2017, 2409, 2581, 2713, 2732, 2811, 3038], 'favoritesDownload': [130], 'CitationsTrack': [131], 'Citations': [132], 'ShareFacebookTwitterLinked': [133], 'InEmail': [134], 'A': [135, 612, 1080, 1754, 2119, 2474, 2649, 2708], 'multicomponent': [136, 1186, 1503, 1576, 1756], 'reductive': [137, 172, 202, 479, 514, 623, 685, 708, 723, 1037, 1187, 1205, 1232, 1401, 1504, 1577, 1757], 'cross-coupling': [138, 686, 724, 1038, 1165, 1505, 1578, 1758], 'unactivated': [140, 688, 726, 1760], 'alkyl': [141, 144, 237, 421, 450, 493, 507, 524, 573, 610, 689, 691, 727, 730, 1083, 1100, 1170, 1215, 1244, 1281, 1448, 1536, 1558, 1565, 1586, 1604, 1611, 1649, 1678, 1681, 1702, 1728, 1731, 1761, 1763, 1845, 1863], 'halides': [142, 397, 525, 566, 731, 1216, 1245], 'tosylates': [145, 639, 728, 1101, 1160, 1537, 1732], 'connected': [146, 1439], 'via': [147, 335, 356, 396, 521, 1273, 1396, 1907, 2331, 2402, 2734, 3059, 3105, 3193, 3285, 3331], 'sodium': [148, 175, 734, 1040, 1342, 1593, 1766, 1777], 'metabisulfite': [149, 176, 250, 694, 735, 823, 1041, 1343, 1706, 1767, 1778], 'was': [150, 190, 758, 764, 824, 1138, 1271, 1362, 1394, 1509, 1522, 1539, 1550, 1561, 1607, 1614, 1621, 1688, 1712, 1768, 1794, 1833], 'established': [151], 'for': [152, 353, 405, 464, 471, 572, 584, 630, 695, 873, 1770, 1921, 1958, 2009, 2020, 2477, 3362], 'the': [153, 180, 185, 242, 249, 253, 295, 309, 336, 357, 363, 376, 406, 418, 437, 445, 487, 502, 512, 541, 585, 592, 627, 631, 644, 650, 672, 676, 696, 737, 748, 767, 790, 816, 819, 828, 843, 859, 862, 866, 874, 1036, 1053, 1094, 1103, 1124, 1128, 1149, 1185, 1209, 1261, 1322, 1358, 1366, 1381, 1424, 1446, 1499, 1513, 1516, 1542, 1564, 1569, 1575, 1581, 1585, 1600, 1664, 1674, 1677, 1694, 1699, 1738, 1771, 1783, 1808, 1849, 1854, 1857, 1862, 1867, 1922, 2427, 2433, 2452, 2478, 2547, 2582, 3082, 3166], 'general': [154, 403, 1917, 1919], 'construction': [155, 355, 438, 698, 1772], 'alkyl–alkyl': [157, 324, 700, 1105, 1774, 1932], 'sulfones.': [158, 1211, 1775], 'Neither': [159], 'metal': [161, 165, 459, 528, 624, 1804], 'catalyst': [162, 754, 1793], 'nor': [163], 'reductant': [166, 529, 771, 1017, 1806], 'is': [167, 415, 424, 453, 481, 496, 626, 654, 865, 871, 1045, 1668, 1913], 'required': [168], 'in': [169, 241, 266, 301, 328, 347, 362, 420, 478, 544, 561, 661, 736, 742, 766, 772, 793, 818, 850, 1047, 1093, 1107, 1119, 1184, 1230, 1384, 1429, 1552, 1640, 1670, 1725, 1866, 1881, 1982, 2042, 2047, 2084, 2108, 2121, 2154, 2185, 2269, 2356, 2379, 2426, 2456, 2497, 3017, 3386], 'this': [170, 722, 773, 1136, 1204, 1221, 1247, 1265, 1326, 1435, 1502], '"green"': [171], 'cross-coupling.': [173, 709, 1188], 'Inorganic': [174, 1776, 2785, 3244], 'served': [177, 1780], 'both': [179, 1781], 'sulfur': [181, 361, 546, 581, 597, 802, 1784, 1876], 'dioxide': [182, 547, 582, 803, 1785], 'source': [183, 1008, 1786], 'robust': [186, 1789], 'connector.': [187, 1790], 'Safe': [188], 'formate': [189, 786, 1715], 'used': [191, 569], 'highly': [194, 632, 1811], 'efficient': [195], 'single-electron': [196, 645, 1660], 'reductant.': [197], 'Both': [198, 1234], 'intramolecular': [199, 1150], 'intermolecular': [201, 1143], 'cross-couplings': [203, 480, 515, 1402], 'were': [204, 214, 239, 604, 813, 1074, 1090, 1161, 1167, 1201, 1226, 1420, 1638], 'achieved': [205, 436, 1364, 1769, 1835], 'with': [206, 217, 225, 340, 430, 501, 579, 725, 1059, 1067, 1203, 1220, 1251, 1338, 1580, 1592, 1848, 1874, 2150, 2157, 2301, 2327, 2432, 2836, 2859, 2881, 3081, 3165], 'broad': [207, 1061], 'substrate': [208, 1567], 'scopes.': [209], 'Diverse': [210, 800, 3267], 'biologically': [211, 1821], 'important': [212, 1822], 'molecules': [213, 1337, 1428], 'efficiently': [215, 1075, 1207, 1438, 1834], 'cross-linked': [216], 'steroids,': [218, 1458, 1826], 'saccharides,': [219, 1459, 1827], 'amino': [220, 1197, 1405, 1460, 1828], 'acids,': [221, 1461, 1829], 'peptides,': [222, 1830], 'pharmaceuticals': [224, 302, 1339], 'sensitive': [226], 'functional': [227, 349], 'groups,': [228], 'affording': [229, 1423, 1718], 'sulfone-bridged': [230, 701, 1426, 1838], 'hybrid': [231, 1427, 1839], 'molecules.': [232, 1840], 'Mechanistic': [233, 1747, 1841], 'studies': [234, 1842], 'demonstrated': [235, 1573, 1653, 1843], 'that': [236, 540, 842, 1556, 1574, 1599, 1619, 1654, 1844], 'radicals': [238, 603, 1846], 'involved': [240, 660], 'singly': [243, 554], 'occupied': [244, 555], 'molecular': [245, 556], 'orbital': [246, 557, 653, 1860], '(SOMO)': [247, 558], 'salt,': [251], 'initiating': [252, 1853], 'transformation.': [254, 821, 1248, 1570], 'Download': [255, 257, 710, 712, 1315, 1317, 1493, 1495, 1749, 1751], 'figure': [256, 711, 1316, 1494, 1750], 'PowerPoint': [258, 713, 1318, 1496, 1752], 'Introduction': [259, 2519], 'Sulfone': [260, 2254, 2544, 3057, 3240, 3284], 'motifs': [261, 286, 300, 410, 1118], 'have': [262, 392, 435], 'attracted': [263], 'considerable': [264], 'interest': [265, 373], 'drug': [267, 289, 1360, 1418], 'discovery': [268], 'because': [269], 'their': [271, 305], 'dramatic': [272], 'effects': [273, 307], 'on': [274, 308, 2305], 'stability,': [275], 'liposolubility,': [276], 'metabolism.1–4': [278], 'The': [279, 665, 1033, 1249, 1267, 1349, 1372, 1390, 1400, 1455, 1817, 1902, 1944, 1954], 'linkage': [280, 1350, 1373, 1818], 'carbon': [282, 600], 'chains': [283], 'sulfone': [285, 299, 354, 409, 441, 1130, 1282, 1520, 1740, 1933], 'always': [287], 'improves': [288], 'metabolism.': [290], 'Alkyl–alkyl': [291], 'sulfones': [292, 325, 332, 391, 1058, 1154], 'are': [293, 326, 333, 370, 519, 640, 1217, 1878, 1956, 3360], 'among': [294], 'most': [296], 'frequently': [297], 'occurring': [298, 1336], 'due': [303, 374], 'excellent': [306, 1108, 1386], 'balance': [310], 'between': [311, 447, 490, 504, 1403, 2902, 2949, 2981], 'water': [312], 'solubility': [313, 749], 'lipid': [315], 'solubility.': [316], 'Several': [317], 'representative': [318], 'well-known': [320], 'pharmaceutical': [321], 'inhibitors': [322], 'containing': [323], 'shown': [327, 1046], 'Scheme': [329, 703, 1048, 1277, 1452, 1641, 1671, 1743], '1a.5–10': [330], 'Conventionally,': [331], 'prepared': [334], 'oxidation': [337, 365], 'sulfides': [339], 'strong': [341], 'oxidants': [342], 'after': [343], 'thiol-involved': [344], 'couplings,11,12': [345], 'resulting': [346], 'low': [348], 'group': [350], 'compatibility.': [351], 'Strategies': [352], 'introduction': [358, 407], 'hypervalent': [360], 'same': [364], 'state': [366], 'into': [367, 411], 'organic': [368, 413], 'frameworks': [369, 414], 'great': [372], 'oxidative': [377], 'economy': [378, 381], 'step': [380], 'such': [383, 1824], 'processes.13–20': [384], 'For': [385], 'instance,': [386], 'transition-metal-catalyzed': [387, 431], 'syntheses': [388], 'aryl–aryl(alkyl)': [390], 'been': [393], 'well': [394, 1091], 'developed': [395], 'organometallic': [399, 533], 'reagents.21–26': [400], 'However,': [401], 'approach': [404], 'C(sp3)−C(sp3)': [412, 1231], 'lacking': [416], 'since': [417, 649, 869], 'β-hydrogen': [419], 'coupling': [422, 494, 509, 670, 1084, 1095, 1729], 'partners': [423, 495, 518, 677], 'likely': [425, 1622], 'be': [427, 568, 607, 1624, 1896], 'poorly': [428], 'compatible': [429, 1202, 1219], 'systems.27,28': [432], 'Although': [433], 'we': [434, 538, 681, 1329], 'aryl–alkyl': [440], 'by': [442, 526, 1340, 1589, 1693, 1714, 1962, 2307, 2702, 2740, 3366], 'virtue': [443], 'distinction': [446, 489, 503], 'aryl': [448, 505], 'halides,': [451, 690, 1762], 'tin': [452], 'still': [454], 'necessary': [455], 'stoichiometric': [458], 'reductant.29,30': [460], 'Developing': [461], 'cheap': [462], 'salts': [463, 548, 583, 878, 1877], 'green': [465], 'safe': [467], 'hydrogen': [468, 614, 1799], 'storage': [469, 615, 1800], 'replacing': [472], 'environmentally': [473], 'unfriendly': [474], 'metals': [475], 'reductants': [477, 787], 'long-standing': [483], 'goal.31–38': [484], 'In': [485, 1212], 'addition,': [486, 1213], 'smaller': [488], 'two': [491, 1645], 'different': [492, 806, 1068], 'tough': [498], 'challenge': [499, 1229], 'compared': [500], 'halide': [508, 1587, 1612, 1650, 1679], 'partners.39': [510], 'Traditionally,': [511], 'direct': [513], 'electrophilic': [517], 'realized': [520], 'preactivation': [522], 'avoid': [531], 'precast': [532], 'reagents': [534], '(Scheme': [535, 678, 1347, 1524, 1545], '1b).': [536], 'Previously,': [537], 'showed': [539, 1598], 'SO2': [542, 890, 1007], 'motif': [543], 'inorganic': [545, 580, 751, 801, 877, 1875], 'possesses': [549], 'sufficiently': [551], 'active': [552], 'hybridized': [553], 'participate': [560], 'radical': [563, 577, 657, 667, 1528, 1559, 1582, 1682, 1703, 1709, 1716], 'process.29,40–51': [564], 'Alkyl': [565, 638, 2612, 2619, 2677, 2706, 2766, 2838, 2857, 2860, 2883, 2954], 'can': [567, 1437, 1895], 'precursors': [571, 1449], 'radicals,': [574], 'leading': [575], 'capture': [578], 'generation': [586], 'sulfonyl': [588, 602, 636, 1708, 1719, 1815], 'radicals.': [589, 611, 637, 1816], 'Due': [590], 'slightly': [593], 'higher': [594], 'electronegativity': [595], 'atoms': [598], 'than': [599, 609], 'atoms,': [601], 'apt': [605], 'reduced': [608, 1626, 1689, 1713], 'release-controlled': [613], 'salt': [616, 1779, 1801], 'instead': [617, 1802], 'rapid': [619], 'electron': [620], 'transfer': [621, 646], 'from': [622, 656, 1445, 1563, 1901, 2614, 2644, 3188, 3242], 'powders': [625], 'key': [628], 'factor': [629], 'selective': [633, 1812], 'reduction': [634, 658, 1583, 1601, 1631, 1661, 1813], 'rather': [641], 'inert': [642], 'during': [643, 1568], '(SET)': [647], 'process': [648], 'high-lying': [651, 1858], 'σ*(C–O)': [652, 1859], 'protected': [655], 'subsequent': [662, 1868], 'nucleophilic': [663, 1869], 'substitution.': [664, 1870], 'sequential': [666, 1809], 'release': [668], 'limits': [671], 'undesired': [673], 'homocoupling': [674], '1c).': [679], 'Herein,': [680], 'disclose': [682], 'transition-metal-free': [684, 1755], 'tosylates,': [692, 1764], 'modular': [697], 'compounds.': [702], '1': [704, 884, 896, 1286, 1466, 1733, 2263], '|': [705, 885, 1279, 1454, 1745], '(a–c)': [706], 'Sulfone-bridged': [707], 'Results': [714], 'Discussion': [716], 'We': [717], 'commenced': [718], 'our': [719, 780, 1882], 'evaluation': [720, 838], '1a,': [729], '2a,': [732, 1651], 'presence': [738], 'base': [741, 845, 1014], 'dimethyl': [743], 'sulfoxide': [744], '(DMSO).': [745], 'To': [746, 779, 1319, 1497], 'increase': [747], 'salts,': [752], 'phase-transfer': [753], 'tetrabuylammonium': [755], 'bromide': [756, 1566], '(TBAB)': [757], 'added.': [759], 'No': [760, 1791], 'desired': [761, 1104, 1164, 1210, 1739], 'product': [762, 792, 1383, 1548, 1741], '3a': [763, 849], 'detected': [765], 'absence': [768], 'transformation': [774], '(Table': [775, 796, 854, 879], '1,': [776, 797, 834, 855, 880], 'entry': [777], '1).': [778], 'delight,': [781], 'bench-stable': [782], 'formic': [783], 'acid': [784, 1377, 1406], 'could': [788], 'afford': [789], 'cross-coupled': [791], 'moderate': [794], 'yields': [795, 1109, 1431], 'entries': [798, 835, 856, 881], '2–4).': [799], 'surrogates': [804], 'possessing': [805], 'masking': [807], 'groups': [808], 'unique': [810], 'SET': [811], 'abilities': [812], 'tested': [814], 'connector': [817, 1044, 1346], 'current': [820, 1125], 'Sodium': [822, 3191, 3219], 'found': [825], 'provide': [827], 'best': [829, 867], 'efficiency': [830], '(65%': [831], 'yield,': [832, 1554], 'Table': [833, 883], '5–7).': [836], 'Further': [837, 1871], 'bases': [840], 'revealed': [841], 'stronger': [844], 'cesium': [846], 'carbonate': [847], 'delivers': [848], 'better': [852], 'yield': [853, 1387], '8–11).': [857], 'Considering': [858], 'effect': [860], 'solvent,': [863], 'DMSO': [864, 900, 906, 912, 918, 924, 930, 936, 942, 948, 954, 970, 1306, 1484], 'choice': [868], 'it': [870], 'beneficial': [872], 'dissolution': [875], '12–14).': [882], 'Conditions': [886], 'Optimizationa': [887], 'Entry': [888], 'Reductant': [889], 'Source': [891], 'Base': [892], 'Solvent': [893], 'Yields': [894], '(%)b': [895], '—': [897, 941], 'Na2S2O5': [898, 904, 910, 916, 940, 946, 952, 974, 980, 986, 1289, 1469], 'K2HPO4': [899, 905, 911, 917, 923, 929, 935], 'NP': [901], '2': [902, 958, 961, 963, 967, 1049, 1278, 1292, 1472], 'HCO2H': [903], '49': [907, 943], '3': [908, 969, 1453], 'HCO2Na': [909], '60': [913], '4': [914, 1744], 'HCO2K': [915, 921, 927, 933, 939, 945, 951, 973, 979, 985], '65': [919], '5': [920, 965, 1549], 'K2S2O5': [922], '40': [925], '6': [926], 'Na2S2O4': [928], '41': [931], '7': [932], 'DABSO': [934], '44': [937, 949], '8': [938], '9': [944, 1683, 1704], 'NaHCO3': [947], '10': [950, 1029, 1311, 1489], 'Et3N': [953], '57': [955], '11': [956, 1721, 1736], 'HCO': [957], 'K': [959], 'Na': [960], 'S': [962], 'O': [964], 'Cs': [966], 'CO': [968], '77': [971], '12': [972], 'Cs2CO3': [975, 981, 987, 1300, 1478], 'DMA': [976], '66': [977], '13': [978], 'DMF': [982], '54': [983], '14': [984], 'Toluene': [988], '22': [989], 'Note:': [990], 'NP,': [991], 'no': [992, 1163, 1947], 'product;': [993], 'DMA,': [994], 'dimethylacetamide;': [995], 'DMF,': [996], 'dimethylformamide.': [997], 'Bold-italic': [998], 'text': [999], 'represents': [1000], 'optimal': [1001], 'conditions': [1002, 1368, 1544], 'aConditions:': [1003], '1a': [1004, 1538, 1606], '(0.2': [1005, 1287, 1467], 'mmol),': [1006, 1010, 1013, 1016, 1019, 1022, 1288, 1291, 1296, 1299, 1302, 1305, 1468, 1471, 1474, 1477, 1480, 1483], '(0.4': [1009, 1015, 1290, 1301, 1470, 1479], '2a': [1011, 1613, 1620, 1655], '(0.5': [1012, 1018, 1298, 1473, 1476], 'TBAB': [1020, 1303, 1481], '(0.3': [1021, 1304, 1482], 'solvent': [1023], '(2.0': [1024], 'mL),': [1025, 1308, 1486], '100': [1026, 1309, 1487], '°C,': [1027, 1310, 1488], 'N2,': [1028], 'h.': [1030], 'bIsolated': [1031], 'yields.': [1032, 1314, 1492], 'scope': [1034], 'employing': [1039, 1341], '(for': [1050], 'characterizations': [1051], 'see': [1052], 'Supporting': [1054, 1909], 'Information).': [1055], 'Aryl': [1056, 2834, 2879, 2950, 3305], 'propyl': [1057], 'range': [1062], 'substituents,': [1064], 'including': [1065], 'those': [1066], 'electronic': [1069], 'properties,': [1070], 'at': [1071, 1633, 1993, 3397], 'various': [1072], 'positions': [1073], 'afforded': [1076], '(': [1077, 1096, 1110, 1132, 1155, 1171, 1175, 1179, 1192, 1199, 1236, 1240, 1253, 1257, 1369, 1388, 1432, 1450, 1533, 1888, 1893], '3a–': [1078], '3f).': [1079], 'series': [1081], 'partners,': [1085], 'even': [1086, 1196], 'linear': [1087, 1235], 'hexadecane': [1088], '(C16),': [1089], 'tolerated': [1092], '3g–': [1097], '3k).': [1098], 'Heterocycle-containing': [1099], 'provided': [1102, 1380, 1961, 3365], 'products': [1106, 1131, 1166], '3l).': [1111], 'Fused-ring': [1112], 'anthracene': [1113], 'pyrene': [1115], 'derivatives,': [1116], 'common': [1117], 'luminescent': [1120], 'materials,': [1121], 'successfully': [1122, 1182], 'underwent': [1123, 1246, 1658], 'transformation,': [1126, 1222, 1855], 'furnishing': [1127], 'corresponding': [1129, 1382, 1425, 1447, 1643], '3m–': [1133], '3n).': [1134], 'Furthermore,': [1135], 'reaction': [1137, 1666, 1700, 1928], 'not': [1139], 'only': [1140], 'restricted': [1141], 'variants': [1144], 'but': [1145], 'also': [1146, 1218], 'applicable': [1147], 'synthesis': [1151, 1923], 'cyclic': [1153, 1239], '3o–3p).': [1156], 'Regretfully,': [1157], 'when': [1158], 'secondary': [1159, 1214, 1243], 'employed,': [1162], 'detected.': [1168], 'Linear': [1169], '3q–': [1172], '3s),': [1173], 'trifluoropropyl': [1174], '3t),': [1176], 'alkoxyl': [1178], '3u)': [1180], 'derivatives': [1181], 'participated': [1183, 1865], 'Various': [1189], 'nitrogen-containing': [1190], 'structures': [1191], '3v–': [1193], '3y)': [1194, 1200], 'acids': [1198, 1442], 'cross-coupling,': [1206], 'providing': [1208], 'these': [1224], 'substrates': [1225], 'notable': [1228], 'cross-couplings.': [1233], '3z)': [1237], '3aa–': [1241], '3ae)': [1242, 1258], 'compatibility': [1250], '7-': [1252], '3ad)': [1254], '12-membered': [1256], 'rings': [1259], 'highlighted': [1260], 'high': [1262], 'tolerance': [1263], 'strategy.': [1266], 'structure': [1268, 1391], '3ab': [1270], 'confirmed': [1272, 1395], 'X-ray': [1274, 1397, 1935], 'diffraction': [1275, 1398], 'analysis.a': [1276], 'Collective': [1280], 'construction.': [1283], 'Reaction': [1284, 1464, 2671, 2760, 3137, 3215, 3303], 'conditions:': [1285, 1465], '(potassium': [1293], 'formate,': [1294], '0.5': [1295], 'HCOOK': [1297, 1475], '(2': [1307, 1485], 'h,': [1312, 1490], 'isolated': [1313, 1491], 'further': [1320], 'demonstrate': [1321, 1498], 'practical': [1323], 'applicability': [1324], 'cross-linking': [1327, 1456, 1872], 'protocol,': [1328], 'sought': [1330], 'link': [1332], 'structurally': [1333], 'complicated,': [1334], 'naturally': [1335], '3).': [1348], 'dehydroepiandrosterone,': [1352], 'estrone,': [1353], 'derivative': [1356], 'anti-inflammatory': [1359, 1417], 'isoxepac': [1361], 'smoothly': [1363], 'under': [1365, 1515, 1541, 2523, 3223], 'standard': [1367, 1517, 1543], '3af–': [1370], '3ah).': [1371], 'natural': [1375], 'cholic': [1376], 'tetrahydropyran': [1379], 'an': [1385, 1404, 1557, 2784, 3106], '3ai).': [1389], '3ai': [1393], 'analysisa.': [1399], '(l-tyrosine),': [1407], 'saccharide': [1409], '(glucose),': [1410], 'steroids': [1411], '(dehydroepiandrosterone': [1412], 'estrone),': [1414], 'nonsteroidal': [1416], 'oxaprozin': [1419], 'all': [1421], 'successful,': [1422], 'good': [1430], '3aj–3an).': [1433], 'Notably,': [1434], 'strategy': [1436], 'long-chain': [1440], 'linoleic': [1441], 'peptides': [1444], '3ao).': [1451], 'pharmaceuticals.': [1463], 'mechanism': [1500], 'reaction,': [1506], '2,2,6,6-tetramethylpiperidine-1-oxyl': [1507], '(TEMPO)': [1508], 'first': [1510], 'added': [1511], 'system': [1514], 'conditions,': [1518, 1929], 'production': [1521], 'suppressed': [1523], '4a).': [1525], 'Subsequently,': [1526, 1698], 'clock': [1529], 'experiment': [1530], 'involving': [1531], '(bromomethyl)cyclopropane': [1532], '4)': [1534], 'conducted': [1540], '4b).': [1546], 'Cyclopropane-opened': [1547], 'generated': [1551, 1680], '14%': [1553], 'indicating': [1555], 'intermediate': [1560, 1735], 'formed': [1562], 'These': [1571], 'results': [1572], 'began': [1579], 'followed': [1588], 'SOMO': [1590, 1850], 'interaction': [1591], 'metabisulfite.': [1594], 'Cyclic': [1595, 2215, 2253, 3289], 'voltammetric': [1596], 'analyses': [1597], 'potentials': [1602], 'tosylate': [1605, 1864], '−2.75': [1608], 'V': [1609, 1637], '−2.40': [1615, 1636], 'V,': [1616], 'which': [1617, 1652, 1687, 1711], 'indicated': [1618], 'preferentially': [1625], 'relative': [1627], '1a.': [1629], 'Two': [1630, 2982], 'peaks': [1632], '−1.50': [1634], 'observed': [1639], '4c,': [1642], 'successive': [1646], 'SETs': [1647], 'easily': [1656], 'process.': [1662], 'Thus,': [1663], 'proposed': [1665], 'pathway': [1667], 'depicted': [1669], '4d.': [1672], 'Initially,': [1673], 'homolysis': [1675], 'iodine': [1685], 'radical,': [1686], 'iodide': [1691], 'ion': [1692], 'slowly': [1695], 'released': [1696], 'formate.': [1697], 'furnished': [1707], '10,': [1710], 'cation,': [1717], 'anion': [1720], 'sulfinate': [1723], '11′': [1724], 'equilibrium.': [1726], 'Finally,': [1727], 'delivered': [1737, 1837], '3.': [1742, 2057], '(a–d)': [1746], 'study.': [1748], 'Conclusion': [1753], 'transition-metal': [1792], 'necessary,': [1795], 'controlled-release': [1798], 'powder': [1805], 'allowed': [1807], 'diverse': [1820], 'molecules,': [1823], 'pharmaceuticals,': [1832], 'interacted': [1847], 'metabisulfite,': [1852], 'protocols': [1873], 'being': [1879], 'explored': [1880], 'laboratory.': [1883], 'Footnote': [1884], 'CCDC': [1886, 1891], '2007887': [1887], '3ab)': [1889], '2007888': [1892], '3ai)': [1894], 'obtained': [1897], 'free': [1898], 'charge': [1900], 'Cambridge': [1903], 'Crystallographic': [1904], 'Data': [1905], 'Centre': [1906], 'www.ccdc.cam.ac.uk/data_request/cif': [1908], 'Information': [1910, 1912, 3348], 'Supplemental': [1911], 'available': [1914], 'includes': [1916], 'information,': [1918], 'procedure': [1920], 'sulfones,': [1925], 'optimization': [1926], 'characterization': [1930], 'products,': [1934], 'crystal': [1936], 'structures,': [1937], 'electrochemical': [1939], 'measurements.': [1940], 'Conflict': [1941], 'Interest': [1943], 'authors': [1945, 1955, 3359], 'declare': [1946], 'competing': [1948], 'financial': [1949, 1959, 3363], 'or': [1950], 'nonfinancial': [1951], 'interests.': [1952], 'Acknowledgments': [1953], 'grateful': [1957, 3361], 'support': [1960, 3364], 'NSFC': [1963, 3367], '(nos.': [1964, 1970, 3368, 3374], '22071057,': [1965, 3369], '21971065,': [1966, 3370], '21871089),': [1968, 3372], 'STCSM': [1969, 3373], '20XD1421500,': [1971, 3375], '20JC1416800,': [1972, 3376], '18JC1415600),': [1974, 3378], 'Innovative': [1975, 3379], 'Research': [1976, 3380], 'Team': [1977, 3381], 'High-Level': [1979, 3383], 'Local': [1980, 3384], 'Universities': [1981, 3385], '(no.': [1984, 3388], 'SSMU-ZLCX20180501),': [1985, 3389], 'Professor': [1987, 3391], 'Special': [1989, 3393], 'Appointment': [1990, 3394], '(Eastern': [1991, 3395], 'Scholar)': [1992, 3396], 'Institutions': [1995, 3399], 'Higher': [1997, 3401], 'Learning.': [1998, 3402], 'References': [1999], '1.': [2000], 'Ilardi': [2001], 'E.': [2002, 2117, 2171, 2367, 2534, 2965], 'A.;': [2003, 2060, 2095, 2178, 2210, 2286, 2292, 2600], 'Vitaku': [2004], 'E.;': [2005], 'Njardarson': [2006, 2061], 'J.': [2007, 2062, 2383, 2942], 'T.Data-Mining': [2008], 'Sulfur': [2010, 2069, 2081, 2376, 2400, 2436, 2453, 2472, 2522, 2548, 2674, 2737, 2763, 2786, 3060, 3085, 3109, 3141, 3169, 3245], 'Fluorine:': [2012], 'An': [2013, 2406], 'Evaluation': [2014], 'Pharmaceuticals': [2016], 'Reveal': [2018], 'Opportunities': [2019], 'Drug': [2021], 'Design': [2022, 2267], 'Discovery.J.': [2024], 'Med.': [2025, 2051, 2071, 2224, 2275], 'Chem.2014,': [2026, 2360], '57,': [2027], '2832–2842.': [2028], 'Google': [2029, 2055, 2075, 2090, 2113, 2129, 2167, 2193, 2229, 2279, 2315, 2340, 2363, 2388, 2416, 2441, 2462, 2487, 2506, 2530, 2557, 2596, 2629, 2658, 2683, 2719, 2747, 2772, 2800, 2817, 2845, 2865, 2890, 2911, 2936, 2960, 2988, 3003, 3022, 3046, 3067, 3090, 3118, 3150, 3175, 3201, 3230, 3252, 3272, 3295, 3314], 'Scholar': [2030, 2056, 2076, 2091, 2114, 2130, 2168, 2194, 2230, 2280, 2316, 2341, 2364, 2389, 2417, 2442, 2463, 2488, 2507, 2531, 2558, 2597, 2630, 2659, 2684, 2720, 2748, 2773, 2801, 2818, 2846, 2866, 2891, 2912, 2937, 2961, 2989, 3004, 3023, 3047, 3068, 3091, 3119, 3151, 3176, 3202, 3231, 3253, 3273, 3296, 3315], '2.': [2031], 'Feng': [2032], 'M.;': [2033, 2104, 2203, 2247, 2321, 2348, 2493, 2512, 2725, 2778, 2827, 2940, 2972, 3030, 3054, 3124, 3181, 3234, 3256, 3276], 'Tang': [2034], 'B.;': [2035], 'Liang': [2036], 'S.;': [2037, 2200, 2249, 2346, 2445, 2491, 2634, 2821, 2871, 2968, 3028, 3050, 3183, 3278, 3299], 'X.Sulfur': [2039], 'Containing': [2040, 2068], 'Scaffolds': [2041], 'Drugs:': [2043], 'Synthesis': [2044, 2545, 2587, 2609, 2641, 3101, 3131], 'Application': [2046, 2374], 'Medicinal': [2048], 'Chemistry.Curr.': [2049], 'Top.': [2050], 'Chem.2016,': [2052, 3000], '16,': [2053, 2191], '1200–1216.': [2054], 'Scott': [2058], 'K.': [2059, 2197, 2602], 'T.Analysis': [2063], 'US': [2065], 'FDA-Approved': [2066], 'Drugs': [2067], 'Atoms.Top.': [2070], 'Chem.2018,': [2072, 3269], '376,': [2073], '5.': [2074, 2092], '4.': [2077], 'X.,': [2079], 'Ed.': [2080], 'Chemistry;': [2082, 2086], 'Topics': [2083], 'Current': [2085], 'Springer:': [2087], 'Berlin,': [2088], '2018.': [2089], 'Carmine': [2093], 'A.': [2094, 2180, 2607, 2633, 2894, 2977], 'Brogden': [2096], 'R.': [2097, 2100, 2570], 'N.;': [2098], 'Heel': [2099], 'C.;': [2101, 2207, 2974], 'Speight': [2102], 'T.': [2103], 'Avery': [2105], 'G.': [2106, 2177, 3009], 'S.Tinidazole': [2107], 'Anaerobic': [2109], 'Infections.Drugs1982,': [2110], '24,': [2111, 2485], '85–117.': [2112], '6.': [2115], 'Deeks': [2116], 'D.Apremilast:': [2118], 'Review': [2120], 'Oral': [2122], 'Ulcers': [2123], "Behçet's": [2125], 'Disease.Drugs2020,': [2126], '80,': [2127], '181–188.': [2128], '7.': [2131], 'Van': [2132], 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'Permissions©': [3351], '2021': [3352], 'Chinese': [3353], 'SocietyKeywordsreductive': [3355], 'cross-couplingalkyl': [3356], 'sulfonesodium': [3357], 'metabisulfitetransition-metal-freeformateAcknowledgmentsThe': [3358], 'Downloaded': [3403], '3,243': [3404], 'times': [3405], 'PDF': [3406], 'downloadLoading': [3407], '...': [3408]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W4225665854', 'counts_by_year': [{'year': 2024, 'cited_by_count': 16}, {'year': 2023, 'cited_by_count': 17}, {'year': 2022, 'cited_by_count': 15}, {'year': 2021, 'cited_by_count': 14}], 'updated_date': '2025-01-11T03:53:59.798880', 'created_date': '2022-05-05'}