Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W3134092093', 'doi': 'https://doi.org/10.31635/ccschem.021.202100945', 'title': 'Dinitrogen Functionalization Affording Structurally Well-Defined Cobalt Diazenido Complexes', 'display_name': 'Dinitrogen Functionalization Affording Structurally Well-Defined Cobalt Diazenido Complexes', 'publication_year': 2021, 'publication_date': '2021-03-10', 'ids': {'openalex': 'https://openalex.org/W3134092093', 'doi': 'https://doi.org/10.31635/ccschem.021.202100945', 'mag': '3134092093'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.31635/ccschem.021.202100945', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210239486', 'display_name': 'CCS Chemistry', 'issn_l': '2096-5745', 'issn': ['2096-5745'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310311897', 'host_organization_name': 'Chinese Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310311897'], 'host_organization_lineage_names': ['Chinese Chemical Society'], 'type': 'journal'}, 'license': 'cc-by-nc', 'license_id': 'https://openalex.org/licenses/cc-by-nc', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': True, 'oa_status': 'diamond', 'oa_url': 'https://doi.org/10.31635/ccschem.021.202100945', 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5101957520', 'display_name': 'Mingdong Zhong', 'orcid': 'https://orcid.org/0000-0002-1306-3305'}, 'institutions': [{'id': 'https://openalex.org/I4210116048', 'display_name': 'Beijing National Laboratory for Molecular Sciences', 'ror': 'https://ror.org/02601yx74', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I4210116048']}, {'id': 'https://openalex.org/I20231570', 'display_name': 'Peking University', 'ror': 'https://ror.org/02v51f717', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I20231570']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Mingdong Zhong', 'raw_affiliation_strings': ['Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871'], 'affiliations': [{'raw_affiliation_string': 'Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871', 'institution_ids': ['https://openalex.org/I4210116048', 'https://openalex.org/I20231570']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5062112289', 'display_name': 'Xianlu Cui', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210159340', 'display_name': 'The Synergetic Innovation Center for Advanced Materials', 'ror': 'https://ror.org/05nzc1r88', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I134687103', 'https://openalex.org/I41198531', 'https://openalex.org/I4210159340', 'https://openalex.org/I76130692', 'https://openalex.org/I99065089']}, {'id': 'https://openalex.org/I134687103', 'display_name': 'Nanjing Tech University', 'ror': 'https://ror.org/03sd35x91', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I134687103']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Xianlu Cui', 'raw_affiliation_strings': ['Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816'], 'affiliations': [{'raw_affiliation_string': 'Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816', 'institution_ids': ['https://openalex.org/I4210159340', 'https://openalex.org/I134687103']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5005852026', 'display_name': 'Botao Wu', 'orcid': 'https://orcid.org/0000-0002-4724-0568'}, 'institutions': [{'id': 'https://openalex.org/I4210116048', 'display_name': 'Beijing National Laboratory for Molecular Sciences', 'ror': 'https://ror.org/02601yx74', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I4210116048']}, {'id': 'https://openalex.org/I20231570', 'display_name': 'Peking University', 'ror': 'https://ror.org/02v51f717', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I20231570']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Botao Wu', 'raw_affiliation_strings': ['Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871'], 'affiliations': [{'raw_affiliation_string': 'Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871', 'institution_ids': ['https://openalex.org/I4210116048', 'https://openalex.org/I20231570']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5077161401', 'display_name': 'Gao‐Xiang Wang', 'orcid': 'https://orcid.org/0000-0001-9369-9372'}, 'institutions': [{'id': 'https://openalex.org/I4210116048', 'display_name': 'Beijing National Laboratory for Molecular Sciences', 'ror': 'https://ror.org/02601yx74', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I4210116048']}, {'id': 'https://openalex.org/I20231570', 'display_name': 'Peking University', 'ror': 'https://ror.org/02v51f717', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I20231570']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Gao-Xiang Wang', 'raw_affiliation_strings': ['Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871'], 'affiliations': [{'raw_affiliation_string': 'Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871', 'institution_ids': ['https://openalex.org/I4210116048', 'https://openalex.org/I20231570']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5029642484', 'display_name': 'Wen‐Xiong Zhang', 'orcid': 'https://orcid.org/0000-0003-0744-2832'}, 'institutions': [{'id': 'https://openalex.org/I4210116048', 'display_name': 'Beijing National Laboratory for Molecular Sciences', 'ror': 'https://ror.org/02601yx74', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I4210116048']}, {'id': 'https://openalex.org/I20231570', 'display_name': 'Peking University', 'ror': 'https://ror.org/02v51f717', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I20231570']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Wen-Xiong Zhang', 'raw_affiliation_strings': ['Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871'], 'affiliations': [{'raw_affiliation_string': 'Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871', 'institution_ids': ['https://openalex.org/I4210116048', 'https://openalex.org/I20231570']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5033889166', 'display_name': 'Junnian Wei', 'orcid': 'https://orcid.org/0000-0001-9733-803X'}, 'institutions': [{'id': 'https://openalex.org/I4210116048', 'display_name': 'Beijing National Laboratory for Molecular Sciences', 'ror': 'https://ror.org/02601yx74', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I4210116048']}, {'id': 'https://openalex.org/I20231570', 'display_name': 'Peking University', 'ror': 'https://ror.org/02v51f717', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I20231570']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Junnian Wei', 'raw_affiliation_strings': ['Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871'], 'affiliations': [{'raw_affiliation_string': 'Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871', 'institution_ids': ['https://openalex.org/I4210116048', 'https://openalex.org/I20231570']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5063708327', 'display_name': 'Lili Zhao', 'orcid': 'https://orcid.org/0000-0003-2580-6919'}, 'institutions': [{'id': 'https://openalex.org/I4210159340', 'display_name': 'The Synergetic Innovation Center for Advanced Materials', 'ror': 'https://ror.org/05nzc1r88', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I134687103', 'https://openalex.org/I41198531', 'https://openalex.org/I4210159340', 'https://openalex.org/I76130692', 'https://openalex.org/I99065089']}, {'id': 'https://openalex.org/I134687103', 'display_name': 'Nanjing Tech University', 'ror': 'https://ror.org/03sd35x91', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I134687103']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Lili Zhao', 'raw_affiliation_strings': ['Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816'], 'affiliations': [{'raw_affiliation_string': 'Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816', 'institution_ids': ['https://openalex.org/I4210159340', 'https://openalex.org/I134687103']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5100652045', 'display_name': 'Zhenfeng Xi', 'orcid': 'https://orcid.org/0000-0003-1124-5380'}, 'institutions': [{'id': 'https://openalex.org/I4210116048', 'display_name': 'Beijing National Laboratory for Molecular Sciences', 'ror': 'https://ror.org/02601yx74', 'country_code': 'CN', 'type': 'facility', 'lineage': ['https://openalex.org/I4210116048']}, {'id': 'https://openalex.org/I20231570', 'display_name': 'Peking University', 'ror': 'https://ror.org/02v51f717', 'country_code': 'CN', 'type': 'education', 'lineage': ['https://openalex.org/I20231570']}], 'countries': ['CN'], 'is_corresponding': False, 'raw_author_name': 'Zhenfeng Xi', 'raw_affiliation_strings': ['Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871'], 'affiliations': [{'raw_affiliation_string': 'Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871', 'institution_ids': ['https://openalex.org/I4210116048', 'https://openalex.org/I20231570']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 4, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 0, 'currency': 'USD', 'value_usd': 0, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 1.69, 'has_fulltext': False, 'cited_by_count': 13, 'citation_normalized_percentile': {'value': 0.9998, 'is_in_top_1_percent': True, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 90, 'max': 91}, 'biblio': {'volume': '4', 'issue': '2', 'first_page': '532', 'last_page': '539'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T12557', 'display_name': 'Synthesis and Properties of Inorganic Cluster Compounds', 'score': 0.9994, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T12557', 'display_name': 'Synthesis and Properties of Inorganic Cluster Compounds', 'score': 0.9994, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10092', 'display_name': 'Transition Metal Catalysis', 'score': 0.9972, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10548', 'display_name': 'Transition Metal-Catalyzed Cross-Coupling Reactions', 'score': 0.9943, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/surface-modification', 'display_name': 'Surface modification', 'score': 0.90710413}, {'id': 'https://openalex.org/keywords/dinitrogen-reduction', 'display_name': 'Dinitrogen Reduction', 'score': 0.58574}, {'id': 'https://openalex.org/keywords/nickel-catalyzed', 'display_name': 'Nickel-Catalyzed', 'score': 0.522406}, {'id': 'https://openalex.org/keywords/homogeneous-and-heterogeneous-catalysis', 'display_name': 'Homogeneous and Heterogeneous Catalysis', 'score': 0.511751}], 'concepts': [{'id': 'https://openalex.org/C115537861', 'wikidata': 'https://www.wikidata.org/wiki/Q7645993', 'display_name': 'Surface modification', 'level': 2, 'score': 0.90710413}, {'id': 'https://openalex.org/C515602321', 'wikidata': 'https://www.wikidata.org/wiki/Q740', 'display_name': 'Cobalt', 'level': 2, 'score': 0.76577866}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.44339377}, {'id': 'https://openalex.org/C21951064', 'wikidata': 'https://www.wikidata.org/wiki/Q899212', 'display_name': 'Combinatorial chemistry', 'level': 1, 'score': 0.34741753}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.20645997}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.04411429}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.31635/ccschem.021.202100945', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210239486', 'display_name': 'CCS Chemistry', 'issn_l': '2096-5745', 'issn': ['2096-5745'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310311897', 'host_organization_name': 'Chinese Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310311897'], 'host_organization_lineage_names': ['Chinese Chemical Society'], 'type': 'journal'}, 'license': 'cc-by-nc', 'license_id': 'https://openalex.org/licenses/cc-by-nc', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.31635/ccschem.021.202100945', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4210239486', 'display_name': 'CCS Chemistry', 'issn_l': '2096-5745', 'issn': ['2096-5745'], 'is_oa': True, 'is_in_doaj': True, 'is_core': True, 'host_organization': 'https://openalex.org/P4310311897', 'host_organization_name': 'Chinese Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310311897'], 'host_organization_lineage_names': ['Chinese Chemical Society'], 'type': 'journal'}, 'license': 'cc-by-nc', 'license_id': 'https://openalex.org/licenses/cc-by-nc', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [{'score': 0.51, 'id': 'https://metadata.un.org/sdg/9', 'display_name': 'Industry, innovation and infrastructure'}], 'grants': [], 'datasets': ['https://openalex.org/W4397635980', 'https://openalex.org/W4397706548', 'https://openalex.org/W4397639022', 'https://openalex.org/W4397708118', 'https://openalex.org/W4397751781', 'https://openalex.org/W4397969390', 'https://openalex.org/W4397859193', 'https://openalex.org/W4397862655', 'https://openalex.org/W4397866885', 'https://openalex.org/W4398006047', 'https://openalex.org/W4398024501'], 'versions': [], 'referenced_works_count': 0, 'referenced_works': [], 'related_works': ['https://openalex.org/W3137173382', 'https://openalex.org/W2950446261', 'https://openalex.org/W2949166558', 'https://openalex.org/W2770495755', 'https://openalex.org/W2317496439', 'https://openalex.org/W2167894278', 'https://openalex.org/W2073912255', 'https://openalex.org/W2058508218', 'https://openalex.org/W2014815667', 'https://openalex.org/W1757607567'], 'abstract_inverted_index': {'Open': [0], 'AccessCCS': [1], 'ChemistryCOMMUNICATION1': [2], 'Feb': [3], '2022Dinitrogen': [4], 'Functionalization': [5, 3120, 3263, 3459, 3978], 'Affording': [6, 3460, 3980], 'Structurally': [7, 3124], 'Well-Defined': [8, 2896], 'Cobalt': [9, 3822, 3854, 3897, 4063, 4180, 4207], 'Diazenido': [10], 'Complexes': [11, 3134, 3585, 3725, 3798, 3856, 3969, 4064, 4208], 'Mingdong': [12, 29], 'Zhong,': [13], 'Xianlu': [14, 65], 'Cui,': [15], 'Botao': [16, 98], 'Wu,': [17], 'Gao-Xiang': [18, 134], 'Wang,': [19], 'Wen-Xiong': [20, 170], 'Zhang,': [21], 'Junnian': [22, 206], 'Wei,': [23], 'Lili': [24, 256], 'Zhao': [25, 257, 4464, 4484], 'and': [26, 43, 74, 112, 148, 184, 234, 279, 302, 331, 369, 379, 456, 482, 491, 553, 565, 597, 631, 649, 670, 758, 769, 799, 820, 835, 855, 881, 898, 997, 1001, 1017, 1034, 1093, 1108, 1166, 1182, 1210, 1221, 1247, 1262, 1269, 1334, 1432, 1438, 1444, 1450, 1507, 1558, 1621, 1642, 1720, 1766, 1791, 1948, 2004, 2046, 2099, 2187, 2231, 2268, 2272, 2285, 2301, 2328, 2331, 2366, 2397, 2407, 2493, 2498, 2518, 2528, 2578, 2590, 2628, 2636, 2682, 2690, 2699, 2724, 2735, 2740, 2798, 2824, 2871, 3010, 3025, 3060, 3083, 3117, 3137, 3166, 3204, 3236, 3242, 3262, 3286, 3399, 3434, 3514, 3537, 3567, 3617, 3654, 3695, 3731, 3769, 3821, 3953, 3975, 4021, 4058, 4068, 4080, 4154, 4179, 4255, 4282, 4286, 4330, 4359, 4384, 4615], 'Zhenfeng': [27, 303], 'Xi': [28, 304, 2918, 2968, 3457, 3478, 3793], 'Zhong': [30], 'Beijing': [31, 55, 100, 124, 136, 160, 172, 196, 222, 246, 319, 343], 'National': [32, 78, 101, 137, 173, 223, 283, 320, 2773], 'Laboratory': [33, 39, 102, 108, 138, 144, 174, 180, 224, 230, 321, 327], 'for': [34, 82, 103, 139, 175, 225, 287, 322, 410, 445, 591, 609, 665, 677, 1111, 1328, 1435, 1441, 1447, 1453, 1552, 1677, 1808, 1970, 1998, 2065, 2073, 2085, 2353, 2424, 2448, 2473, 2600, 2615, 2720, 2730, 2806, 3004, 3135, 3321, 3342, 3591, 3734, 4209, 4431, 4446], 'Molecular': [35, 44, 75, 104, 113, 140, 149, 176, 185, 226, 235, 280, 323, 332, 1311, 1537, 1983, 2851, 2897, 3848, 4055, 4206, 4524, 4566], 'Sciences': [36, 105, 141, 177, 227, 324], '(BNLMS),': [37, 106, 142, 178, 228, 325], 'Key': [38, 107, 143, 179, 229, 326, 2769], 'of': [40, 46, 48, 51, 68, 72, 109, 115, 117, 120, 145, 151, 153, 156, 181, 187, 189, 192, 231, 237, 239, 242, 273, 277, 328, 334, 336, 339, 413, 420, 458, 470, 484, 489, 504, 539, 542, 567, 578, 655, 680, 752, 794, 802, 824, 903, 925, 931, 959, 980, 1056, 1081, 1124, 1148, 1159, 1185, 1193, 1237, 1305, 1313, 1316, 1371, 1379, 1390, 1397, 1425, 1458, 1496, 1539, 1580, 1611, 1648, 1653, 1663, 1667, 1674, 1693, 1704, 1786, 1832, 1850, 1854, 1862, 1870, 1927, 1985, 2040, 2108, 2115, 2160, 2210, 2219, 2222, 2254, 2308, 2325, 2336, 2374, 2387, 2413, 2434, 2441, 2531, 2569, 2576, 2592, 2707, 2744, 2750, 2765, 2768, 2771, 2777, 2803, 2821, 2828, 2873, 2921, 2924, 2971, 3002, 3012, 3058, 3128, 3156, 3193, 3288, 3310, 3338, 3395, 3482, 3535, 3564, 3596, 3642, 3726, 3796, 3799, 3847, 3889, 3926, 3955, 3997, 4001, 4018, 4024, 4061, 4074, 4108, 4212, 4253, 4284, 4292, 4404, 4425, 4443, 4452, 4523, 4542, 4565, 4612, 4619], 'Bioorganic': [41, 110, 146, 182, 232, 329], 'Chemistry': [42, 73, 111, 147, 183, 233, 278, 330, 2767, 3816], 'Engineering': [45, 114, 150, 186, 236, 333], 'Ministry': [47, 116, 152, 188, 238, 335], 'Education,': [49, 118, 154, 190, 240, 337], 'College': [50, 119, 155, 191, 241, 338], 'Chemistry,': [52, 121, 157, 193, 243, 340], 'Peking': [53, 122, 158, 194, 244, 341, 2822, 4613], 'University,': [54, 87, 123, 159, 195, 245, 292, 342, 2823, 4614], '100871': [56, 125, 161, 197, 247, 344], 'Google': [57, 90, 126, 162, 198, 248, 295, 345, 2857, 2879, 2903, 2936, 2957, 2981, 3032, 3068, 3100, 3144, 3173, 3216, 3250, 3275, 3301, 3329, 3356, 3383, 3414, 3444, 3469, 3496, 3520, 3548, 3577, 3607, 3632, 3660, 3683, 3703, 3745, 3776, 3807, 3829, 3867, 3902, 3937, 3960, 3990, 4012, 4039, 4084, 4124, 4161, 4187, 4219, 4237, 4263, 4299, 4314, 4339, 4366, 4395, 4417, 4436, 4461, 4481, 4505, 4536, 4549, 4576], 'Scholar': [58, 91, 127, 163, 199, 249, 296, 346, 2858, 2880, 2904, 2937, 2958, 2982, 3033, 3069, 3101, 3145, 3174, 3217, 3251, 3276, 3302, 3330, 3357, 3384, 3415, 3445, 3470, 3497, 3521, 3549, 3578, 3608, 3633, 3661, 3684, 3704, 3746, 3777, 3808, 3830, 3868, 3903, 3938, 3961, 3991, 4013, 4040, 4085, 4125, 4162, 4188, 4220, 4238, 4264, 4300, 4315, 4340, 4367, 4396, 4418, 4437, 4462, 4482, 4506, 4537, 4550, 4577], 'More': [59, 92, 128, 164, 200, 250, 297, 347], 'articles': [60, 93, 129, 165, 201, 251, 298, 348], 'by': [61, 94, 130, 166, 202, 252, 299, 349, 385, 428, 501, 646, 788, 828, 851, 893, 909, 941, 1155, 1285, 1419, 1462, 1503, 1962, 2176, 2292, 2583, 2760, 2816, 2895, 3052, 3086, 3264, 3268, 3372, 3403, 3432, 3539, 3693, 3853, 4005, 4029, 4380, 4407, 4545, 4607], 'this': [62, 95, 131, 167, 203, 253, 300, 350], 'author': [63, 96, 132, 168, 204, 254, 301, 351], ',': [64, 97, 133, 169, 205, 255], 'Cui': [66], 'Institute': [67, 272], 'Advanced': [69, 83, 274, 288], 'Synthesis,': [70, 275, 3973, 4357], 'School': [71, 276], 'Engineering,': [76, 281], 'Jiangsu': [77, 282, 2804], 'Synergetic': [79, 284], 'Innovation': [80, 285], 'Center': [81, 286, 2764, 2827, 3370, 4618], 'Materials,': [84, 289], 'Nanjing': [85, 88, 290, 293, 2829, 4620], 'Tech': [86, 291, 2830, 4621], '211816': [89, 294], 'Wu': [99, 3787], 'Wang': [135, 3417, 3451, 3523, 3779, 4344], 'Zhang': [171, 2910, 2966, 3455, 3476, 3791], 'Wei': [207, 2908, 3789], '*Corresponding': [208, 258, 305], 'authors:': [209, 259, 306], 'E-mail': [210, 214, 218, 260, 264, 268, 307, 311, 315], 'Address:': [211, 215, 219, 261, 265, 269, 308, 312, 316], '[email': [212, 216, 220, 262, 266, 270, 309, 313, 317], 'protected]': [213, 217, 221, 263, 267, 271, 310, 314, 318], 'https://doi.org/10.31635/ccschem.021.202100945': [352], 'SectionsSupplemental': [353], 'MaterialAboutAbstractPDF': [354], 'ToolsAdd': [355], 'to': [356, 406, 473, 525, 614, 718, 736, 772, 1062, 1097, 1179, 1217, 1225, 1300, 1408, 1480, 1488, 1521, 1596, 1607, 1629, 1634, 1804, 1813, 1839, 1864, 1889, 2141, 2213, 2243, 2250, 2383, 2394, 2486, 2545, 2752, 2973, 3196, 3206, 3238, 3621, 3891, 4078, 4214, 4247], 'favoritesDownload': [357], 'CitationsTrack': [358], 'Citations': [359], 'ShareFacebookTwitterLinked': [360], 'InEmail': [361], 'Cobalt-bis(dinitrogen)': [362], 'complexes': [363, 402, 463, 519, 776, 807, 1005, 1278, 1581, 1975, 2514, 2625], '[LCo(N2)2]−': [364], '(': [365, 950, 991, 1105, 1228, 1264, 1381, 2226, 2476], '3,4)': [366], 'with': [367, 390, 441, 477, 507, 523, 602, 694, 743, 764, 847, 922, 961, 977, 1029, 1050, 1083, 1257, 1273, 1318, 1373, 1429, 1532, 1542, 1583, 1623, 1655, 1716, 1761, 1858, 1956, 1988, 2183, 2419, 2507, 2626, 2951, 3016, 3230, 3347, 3928, 3970, 4354], 'simple': [368, 854, 2512, 2627], 'commercially': [370, 856, 2629], 'available': [371, 857, 2630, 2698], 'bidentate': [372, 2463], 'phosphine': [373, 1614, 2464, 2527, 4596], 'ligands': [374, 570, 725, 1528, 1615], '(L:': [375], 'Cy2PCH2CH2PCy2)': [376], 'were': [377, 404, 1012, 1113, 1416, 1650, 1680, 1910, 2533, 2814, 4605], 'synthesized': [378, 2635], 'structurally': [380, 395, 842, 2637, 2641], 'characterized.': [381, 2638, 2649], 'Further': [382, 1369], 'N2': [383, 414, 459, 472, 479, 518, 540, 545, 551, 592, 681, 704, 809, 826, 972, 1037, 1060, 1139, 1149, 1426, 1467, 1490, 1510, 1527, 1834, 1873, 1882, 2048, 2220, 2283, 2388, 2405, 2474, 2731, 2972, 3019, 3082, 3165, 3202, 3316, 3398, 3559, 3568, 3740, 4213, 4245], 'functionalization': [384, 457, 475, 541, 624, 705, 827, 1957], 'treating': [386], 'the': [387, 393, 411, 421, 442, 478, 487, 502, 529, 559, 568, 572, 576, 584, 616, 620, 640, 659, 671, 685, 737, 770, 781, 792, 797, 840, 956, 978, 1003, 1023, 1054, 1079, 1156, 1173, 1180, 1186, 1218, 1226, 1238, 1243, 1274, 1289, 1301, 1306, 1314, 1377, 1459, 1489, 1493, 1498, 1522, 1525, 1608, 1612, 1635, 1661, 1713, 1751, 1762, 1784, 1809, 1814, 1830, 1833, 1851, 1859, 1871, 1890, 1918, 1928, 1959, 1963, 1971, 2037, 2041, 2044, 2086, 2096, 2109, 2116, 2129, 2138, 2142, 2153, 2158, 2161, 2165, 2178, 2203, 2207, 2211, 2214, 2223, 2244, 2247, 2251, 2255, 2263, 2276, 2282, 2293, 2309, 2320, 2348, 2362, 2372, 2384, 2404, 2414, 2420, 2428, 2435, 2439, 2442, 2449, 2496, 2542, 2556, 2574, 2584, 2602, 2688, 2727, 2761, 2791, 2817, 2825, 2833, 2866, 3005, 3368, 3592, 3643, 3727, 3998, 4075, 4210, 4231, 4385, 4402, 4408, 4428, 4608, 4616, 4624], 'complex': [388, 399, 424, 763, 846, 864, 1025, 1041, 1540, 1668, 1696, 1893, 1930, 1986, 2337, 2354, 2425, 2490, 2595, 2616, 2644], '3b': [389, 1125, 1160, 1254, 1317, 1649, 1656, 2538], 'iPr3SiCl': [391, 1654], 'afforded': [392, 2484], 'first': [394, 621, 660, 782, 841, 2640], 'characterized': [396, 645, 892], 'cobalt': [397, 422, 579, 585, 610, 627, 641, 708, 789, 803, 844, 1051, 1063, 1499, 1523, 1600, 1613, 1694, 2513, 2593], 'diazenido': [398, 423, 806, 845, 1695, 1903, 4598], '5.': [400, 1697, 2617, 2938], 'These': [401, 1412, 2587], '3–5': [403], 'found': [405, 1259], 'be': [407, 870, 1075, 1215, 1298, 2092, 2174, 2369], 'effective': [408], 'catalysts': [409, 657], 'transformation': [412], 'into': [415, 682, 2036, 2164, 3484, 3850, 4526, 4568], 'N(SiMe3)3.': [416], 'The': [417, 468, 550, 862, 1122, 1169, 1190, 1394, 1672, 1702, 1724, 1772, 1866, 2113, 2134, 2148, 2192, 2233, 2266, 2298, 2431, 2445, 2481, 2552, 2639, 2663, 2811], 'electronic': [418, 2104, 2350], 'structure': [419, 1123, 1312, 1495, 1538, 1703, 1984], '5': [425, 1669, 1675, 1705, 1855, 1904, 1932, 1987, 2090, 2124, 2338, 2355, 2426, 2596, 2645, 2656], 'is': [426, 511, 580, 611, 1152, 1472, 1484, 1501, 1748, 1759, 1856, 1874, 1878, 1905, 1915, 1953, 1969, 2125, 2146, 2452, 2505, 2669, 2697, 2747], 'supported': [427, 1154, 2759, 2815, 2832, 4606, 4623], 'quantum': [429], 'computational': [430, 2834, 4625], 'calculations': [431, 2652, 2813, 4604], 'based': [432, 2559], 'on': [433, 558, 702, 2560], 'state-of-the-art': [434], 'energy': [435, 2060], 'decomposition': [436, 2061], 'analysis': [437, 801, 897, 1679, 2058, 2062], '(EDA)': [438], 'in': [439, 594, 785, 808, 866, 873, 883, 912, 945, 985, 1014, 1068, 1172, 1253, 1260, 1292, 1376, 1410, 1465, 1657, 1660, 1706, 1750, 1783, 1917, 2052, 2077, 2089, 2102, 2122, 2314, 2341, 2358, 2466, 2570, 3739, 4003, 4027, 4143, 4449, 4454], 'conjunction': [440], 'natural': [443], 'orbitals': [444, 2064, 2306, 2437], 'chemical': [446, 2066, 2651], 'valence': [447, 849, 2067, 2611], '(NOCV)': [448, 2068], 'method.': [449], 'Download': [450, 452, 830, 832, 1100, 1102, 1365, 1367, 1575, 1577, 1698, 1700, 2029, 2031, 2456, 2458, 2618, 2620], 'figure': [451, 831, 1101, 1366, 1576, 1699, 2030, 2457, 2619], 'PowerPoint': [453, 833, 1103, 1368, 1578, 1701, 2032, 2459, 2621], 'Introduction': [454], 'Activation': [455, 3431, 3795, 3952, 4176, 4379], 'using': [460, 722, 852, 2059, 2491, 2511], 'homogeneous': [461], 'metal': [462, 573, 607, 1241, 1414], 'have': [464, 811, 2633], 'attracted': [465], 'considerable': [466], 'interest.1–3': [467], 'propensity': [469], 'coordinated': [471, 1487, 1502, 1531], 'undergo': [474], 'correlates': [476], 'binding': [480, 1055], 'mode': [481], 'extent': [483], 'activation.': [485, 1468], 'However,': [486, 639, 734, 1021], 'construction': [488], 'N–C': [490, 3344, 3488], 'N–E': [492], '(E': [493], '=': [494, 728, 1008, 1141, 1384, 1590, 1769, 1884, 1899, 1978, 2237], 'Si,': [495], 'Ge,': [496], 'B,': [497], 'P,': [498], 'etc.)': [499], 'bonds': [500], 'reaction': [503, 699, 876, 1080, 1370, 2575], 'metal-bound': [505], 'dinitrogen': [506, 623, 1960], 'various': [508], 'functionalizing': [509], 'agents': [510], 'still': [512, 711, 1485], 'very': [513], 'much': [514], 'limited.4–6': [515], 'Early': [516], 'transition-metal': [517, 544], 'display': [520], 'rich': [521], 'reactivity': [522], 'respect': [524], 'electrophilic': [526], 'attack': [527], 'at': [528, 625, 706, 915, 968, 1119, 1201, 1208, 1321, 1545, 1686, 1825, 1847, 1921, 1936, 1958, 1991, 2427, 3367, 3570, 4151, 4177], 'terminal': [530], 'N': [531, 729, 1810, 2393], 'atom.7–24': [532], 'In': [533, 618, 755, 1233, 1271, 1469, 1492, 1519, 1618, 1887, 2535], 'comparison,': [534, 2536], 'there': [535, 1471], 'are': [536, 555, 587, 658, 710, 1135, 1177, 1255, 1294, 1326, 1406, 1529, 1550, 1627, 1734, 1782, 1996, 2312, 2339, 2356], 'fewer': [537], 'examples': [538], 'late': [543], 'complexes,': [546, 1053], 'besides': [547], 'iron': [548, 1891], 'complexes.25–33': [549], 'lability': [552], 'electronegativity': [554, 577], 'strongly': [556], 'dependent': [557], 'metal’s': [560], 'oxidation': [561], 'state,': [562, 1235], 'overall': [563], 'charge,': [564], 'identity': [566], 'supporting': [569, 1829], 'surrounding': [571], 'center.': [574], 'As': [575, 2075], 'higher': [581], 'than': [582, 1137, 1737, 1880, 2128, 2296, 2672], 'iron,': [583, 603], 'counterparts': [586], 'typically': [588, 612], 'less': [589, 1474], 'reactive': [590, 739], 'activation': [593], 'isostructural': [595], 'Fe–': [596], 'Co–N2': [598], 'complexes.': [599, 1099], 'Thus,': [600], 'compared': [601, 1428], 'a': [604, 626, 689, 695, 707, 761, 853, 874, 933, 942, 981, 1145, 1473, 1504, 1513, 1664, 1742, 1792, 1821, 1840, 2679, 3013, 3017, 3053, 3087, 3092, 3197, 3207, 3269, 3289, 3311, 3348, 3373, 3400, 3404, 3435, 3588, 3674, 3894, 3929, 4450], 'more': [605, 1059, 1793, 2082], 'electron-rich': [606], 'center': [608, 628, 709, 1500, 1715], 'required': [613], 'activate': [615], 'N2.': [617], '2003,': [619], 'observed': [622, 1067, 1749], 'forming': [629, 1512], 'methyl-': [630], 'silyl-diazenido': [632], 'Co(II)': [633], 'employed': [634], 'an': [635, 929, 1802, 2658, 2683, 3157, 3735, 4115, 4381], 'anionic': [636], 'B-triphos': [637], 'ligand.34': [638], 'silyldiazenide': [642], 'was': [643, 891, 920, 937, 1026, 1042, 1196, 2539, 2548, 2555, 2581, 2758], 'only': [644, 1039, 1065], 'infrared': [647], '(IR)': [648], '1H': [650], 'NMR': [651, 948, 989, 2703, 4033], 'spectra.': [652], 'Subsequently,': [653], 'discoveries': [654], 'cobalt-based': [656], 'non-iron': [661], 'or': [662, 730, 964, 1058, 1602, 1901, 4071], '-molybdenum': [663], 'catalyst': [664], 'NH3': [666, 3566, 4256], 'production': [667], 'from': [668, 877, 1078, 1115, 1478, 1682, 2157, 2202, 2206, 2246, 2275, 2334, 2381, 2392, 2566, 2573, 2794, 3081, 3164, 3293, 3315, 3397, 3625, 3817, 4427], 'N2,35': [669], 'highest': [672], 'turnover': [673], 'number': [674], '(TON)': [675], 'reported': [676, 688, 760, 1284, 2510], 'catalytic': [678, 698, 2471, 2728], 'conversion': [679, 771], 'N(SiMe3)3.36': [683], 'Although': [684], 'Lu': [686, 3922, 4173], 'group37': [687], 'bimetallic': [690], 'cobalt-mediated': [691, 825], 'catalysis': [692], 'together': [693], 'computationally': [696], 'illustrated': [697], 'mechanism,': [700], 'studies': [701], 'direct': [703], 'relatively': [712], 'unexplored.': [713], 'Long': [714, 3946], 'et': [715, 1287], 'al.38': [716], 'attempted': [717], 'isolate': [719], 'CoNNSiMe3': [720], 'species': [721, 741, 935, 2101, 2221, 2284, 2333, 2406], 'neutral': [723, 2097, 2310, 2327], 'triphos': [724], '(EP3Ph,': [726], 'E': [727], 'CMe)': [731], '(Scheme': [732, 777, 860, 1087, 1392, 1670], '1a).': [733, 778], 'due': [735, 1299, 1606], 'highly': [738], 'silyldiazenido': [740, 1974, 2594], 'interacting': [742, 2304], 'other': [744], 'active': [745], 'species,': [746, 1604], 'further': [747, 1828], 'X-ray': [748, 895, 2718, 4054], 'diffraction': [749], '(XRD)': [750], 'characterization': [751, 1643], '(EP3Ph)Co(NNSiMe3)': [753], 'failed.': [754], '2018,': [756], 'Deng': [757, 1286, 2914, 3525, 3967, 4348], 'co-workers': [759], 'cobalt(−1)bis(dinitrogen)': [762, 1070], 'N-heterocyclic': [765], 'carbene': [766], '(NHC)': [767], 'ligation': [768], 'side-on': [773], 'bound': [774, 805, 1812], 'diazene': [775], 'It': [779], 'provided': [780], 'well-characterized': [783], 'intermediates': [784], 'N2-reduction': [786], 'catalyzed': [787], 'complexes.39': [790], 'To': [791, 2033], 'best': [793], 'our': [795], 'knowledge,': [796], 'isolation': [798, 1641, 2591], 'theoretical': [800], 'end-on': [804, 1509], 'silylation': [810, 1646, 2475, 2604, 2732], 'not': [812], 'yet': [813], 'been': [814, 1066, 2634, 2647], 'reported.': [815], 'Scheme': [816, 867, 1089, 1689, 2359, 2606], '1': [817, 865, 890, 919, 1082, 1309], '|': [818, 1091, 1310, 1536, 1691, 1982, 2411, 2608], '(a': [819, 1092], 'b)': [821, 1094], 'Different': [822, 3801], 'modes': [823], 'silylation.': [829], 'Results': [834], 'Discussion': [836], 'Herein,': [837], 'we': [838, 2055, 2468], 'report': [839], 'certified': [843, 2642], 'nonclassical': [848], 'π-bonding': [850], 'diphosphine': [858, 1505, 2631], 'ligand': [859, 1506, 1961, 2225, 2632], '1b).': [861], 'Co(II)-chloride': [863], '2a': [868], 'could': [869, 1214], 'easily': [871], 'prepared': [872, 1076, 1197], 'one-pot': [875], 'CoCl2,': [878], 'Cy2PCH2CH2PCy2': [879], '(dcpe),': [880], 'Li[(3,5-Me2-C6H3)NPiPr2]': [882], 'excellent': [884], 'yields': [885], '(see': [886, 1044, 2070], 'Supporting': [887, 951, 992, 1045, 1229, 1265, 2071, 2078, 2188, 2227, 2315, 2342, 2477, 2693, 2695], 'Information).': [888], 'Compound': [889], 'single-crystal': [894], 'structural': [896], 'has': [899, 1064, 2646, 2657], 'solution': [900, 958, 1666], 'magnetic': [901], 'moments': [902], '3.1': [904], '±': [905], '0.1': [906], '(as': [907], 'measured': [908], 'Evans’': [910], 'method40,41)': [911], 'd8-tetrahydrofuran': [913], '(THF)': [914], '295': [916], 'K.': [917, 3911], 'When': [918], 'treated': [921, 1028], '1.0': [923], 'equiv': [924], 'potassium': [926], 'graphite': [927], 'under': [928, 971, 1036, 1198, 4528, 4570], 'atmosphere': [930, 973, 1200], 'N2,': [932], 'diamagnetic': [934], '2': [936, 960, 1090, 1535], 'formed': [938], 'as': [939, 1032, 1587, 1836, 1967, 2095, 2257, 2259, 2290, 2371, 2495, 2525, 2541], 'judged': [940], 'sharpening': [943], 'resonance': [944, 984, 1175, 1914, 2351, 2610], 'its': [946], '31P': [947, 988], 'spectrum': [949, 1158, 1819, 1920, 1926], 'Information': [952, 993, 1046, 1230, 1266, 2072, 2079, 2189, 2228, 2316, 2343, 2478, 2694, 2696, 2755, 4587], 'Figure': [953, 1231, 1308, 1534, 1707, 1980, 2317, 2344, 2409], 'S4).': [954], 'Stirring': [955], 'THF': [957, 1658], 'Na,': [962, 1385], 'K,': [963, 1386], 'Cs': [965], '(3.0': [966], 'equiv)': [967], 'room': [969, 1202], 'temperature': [970], 'gave': [974], 'brown': [975], 'solutions,': [976], 'appearance': [979], 'new': [982, 2708], 'singlet': [983, 2660], 'their': [986, 1598, 1640, 2103, 2470], 'respective': [987], 'spectra': [990, 1176, 2704, 2711, 2715], 'Figures': [994, 1267, 2229], 'S7,': [995], 'S11,': [996], 'S15).': [998], 'After': [999], 'work-up': [1000], 'recrystallization,': [1002], 'cobalt-bis(dinitrogen)': [1004, 2462, 2624], '[(dcpe)Co(N2)2M](sol)': [1006], '(sol': [1007], 'THF,': [1009], 'Et2O)': [1010], '3a–3c': [1011], 'isolated': [1013, 1043], '37%,': [1015, 1016], '34%': [1018], 'yields,': [1019], 'respectively.': [1020, 1943, 2502], 'when': [1022, 2537], '(dcpe)CoCl2': [1024], 'directly': [1027, 1077], 'reductants': [1030], 'such': [1031, 1586], 'K': [1033, 2492], 'KC8': [1035, 2577], 'atmosphere,': [1038], '[(dcpe)2Co]': [1040], 'Page': [1047], 'S7).': [1048], 'Compared': [1049], 'mono(dinitrogen)': [1052], 'two': [1057, 1170, 1508, 1526, 1717, 1721, 2264, 2321], 'molecules': [1061], 'NHC-supported': [1069], 'complexes.39,42–46': [1071], 'Alternatively,': [1072], '3': [1073, 1293, 1372, 1430, 1582, 1690, 1708, 1981], 'can': [1074, 2091, 2173, 2368], 'excess': [1084], 'alkaline': [1085], 'metals': [1086], '2a).': [1088], 'Synthetic': [1095], 'routes': [1096], 'cobalt–N2': [1098], 'Single-crystals': [1104], '3a,': [1106], '3b,': [1107, 1194], '3c)': [1109], 'suitable': [1110, 1676], 'XRD': [1112, 1678], 'obtained': [1114, 1681, 2549], 'concentrated': [1116, 1683], 'THF/Et2O': [1117], 'solutions': [1118, 1685], '−30': [1120], '°C.': [1121, 1688], '(Figure': [1126, 1517, 2185], '1)': [1127], 'reveals': [1128, 1709], 'that': [1129, 1400, 2508, 2654, 2848, 3021, 3586], 'N−N': [1130, 1248, 1290], 'bond': [1131, 1251, 1280, 1331, 1402, 1555, 1726, 1744, 1774, 1868, 2001, 2088, 2612], 'lengths': [1132, 1252, 1332, 1403, 1556, 1727, 2002], '[1.128(3)–1.150(3)': [1133, 1249], 'Å]': [1134, 1246, 1250, 1283, 1405, 1733, 1781], 'longer': [1136, 1879], 'free': [1138, 1881], '(NN': [1140, 1883], '1.0975': [1142, 1885], 'Å),': [1143], 'indicating': [1144, 1741], 'certain': [1146], 'degree': [1147], 'activation.47': [1150], 'This': [1151, 2503, 2756], 'also': [1153, 1417, 1530], 'IR': [1157, 1174, 1206, 1420, 1818, 2710], 'showing': [1161, 1422], 'stronger': [1162, 2127, 2671], 'vibration': [1163, 1846], 'peaks': [1164], '(1837': [1165], '1931': [1167], 'cm−1).': [1168], 'bands': [1171, 1207], 'assignable': [1178], 'symmetric': [1181], 'asymmetric': [1183], 'stretching': [1184, 1845], 'tetrahedral': [1187, 1515], 'anion': [1188], '[(dcpe)Co(N2)2]–.': [1189], '15N2-labeled': [1191, 1852], 'sample': [1192, 1853], 'which': [1195, 1213, 1296, 1758, 1877, 2145, 2580, 2677], '15N2': [1199, 1219, 1454, 1863], 'temperature,': [1203], 'showed': [1204], 'strong': [1205, 2378], '1803': [1209], '1881': [1211], 'cm−1,': [1212], 'assigned': [1216], 'stretch': [1220], 'then': [1222], 'shifted': [1223], 'relative': [1224], '14N2': [1227], 'S38).': [1232], 'solid': [1234], 'irrespective': [1236], 'different': [1239, 1302], 'alkali': [1240, 1413], 'ions,': [1242], 'Co–N': [1244, 1725, 2087], '[1.750(2)–1.7784(19)': [1245], 'comparable': [1256, 2506], 'those': [1258, 1409], '3a': [1261], '3c': [1263, 1479, 2483], 'S51': [1268], 'S53).': [1270], 'comparison': [1272], 'NHC': [1275, 3971, 4355], 'ligand-supported': [1276], 'Co(−1)−N2': [1277], '[N−N': [1279], 'lengths:': [1281], '1.145(6)–1.162(5)': [1282], 'al.,39': [1288], 'distances': [1291, 1775], 'shorter,': [1295], 'might': [1297], 'electron-donating': [1303], 'ability': [1304, 2472, 2729], 'ligands.': [1307], 'dimer': [1315, 2554], 'thermal': [1319, 1543, 1989], 'ellipsoids': [1320, 1544, 1990], '30%': [1322, 1546, 1992], 'probability.': [1323, 1547, 1993], 'H': [1324, 1548, 1994], 'atoms': [1325, 1549, 1719, 1995], 'omitted': [1327, 1551, 1997], 'clarity.': [1329, 1553, 1999], 'Selected': [1330, 1554, 2000], '(Å)': [1333, 1557, 2003], 'angles': [1335, 1559, 2005], '(deg):': [1336, 1560, 2006], 'Co1–P1': [1337, 1561], '2.1766(6),': [1338], 'Co1–P2': [1339, 1563], '2.1771(6),': [1340], 'Co1–N1': [1341, 1565], '1.750(2),': [1342], 'Co1–N3': [1343, 1567, 2015], '1.7703(19),': [1344], 'Co2–P3': [1345], '2.1714(6),': [1346], 'Co2–P4': [1347], '2.1734(6),': [1348], 'Co2–N5': [1349], '1.7784(19),': [1350], 'Co2–N7': [1351], '1.751(2),': [1352], 'N1–N2': [1353, 1569, 2007], '1.150(3),': [1354], 'N3–N4': [1355, 1571, 1779, 2009], '1.135(3),': [1356], 'N5–N6': [1357, 2011], '1.128(3),': [1358], 'N7–N8': [1359], '1.139(3),': [1360], 'N1–Co1–N3': [1361, 1573], '112.15(8),': [1362], 'N5–Co2–N7': [1363], '111.97(9).': [1364], '2.2.2-cryptand': [1374], 'resulted': [1375, 1464, 1659], 'formation': [1378, 1662], '[(dcpe)Co(N2)2M(crypt-222)]': [1380], '4)': [1382], '(M': [1383], 'Cs)': [1387], 'via': [1388, 2928, 3487, 3561, 3673], 'encapsulation': [1389, 1457], 'M+': [1391, 1460], '2b).': [1393], 'crystal': [1395, 1494], 'structures': [1396], '4': [1398, 2186, 2410, 2607, 3130, 3232], 'reveal': [1399], 'N–N': [1401, 1773, 1867, 3114], '[1.129(2)–1.1418(19)': [1404], 'similar': [1407, 1423], '3.': [1411, 2881], 'exchanges': [1415], 'monitored': [1418], 'spectroscopy,': [1421], 'frequencies': [1424], 'stretches': [1427], '(1897': [1431], '1974': [1433], 'cm−1': [1434, 1440, 1446, 1452, 1827, 1849], '4a;': [1436], '1892': [1437], '1970': [1439], '4b;': [1442], '1876': [1443], '1956': [1445], '4c;': [1448], '1831': [1449], '1905': [1451], '–4b).': [1455], 'Overall,': [1456], 'adducts': [1461], '2.2.2-crypt': [1463], 'decreasing': [1466], 'addition,': [1470], 'dramatic': [1475], 'change': [1476], 'going': [1477], '4c': [1481, 1541], 'because': [1482, 2107], 'Cs+': [1483], 'partially': [1486], 'fragments.': [1491, 2265], '4c,': [1497], 'ligands,': [1511], 'distorted': [1514], 'geometry': [1516, 1711, 1807], '2).': [1518], 'addition': [1520], 'center,': [1524], 'Cs.': [1533], '2.1472(4),': [1562], '2.1520(4),': [1564], '1.7686(11),': [1566], '1.7623(11),': [1568], '1.1305(17),': [1570], '1.1357(17),': [1572], '115.18(5).': [1574], 'Reactions': [1579, 2950, 3121, 3979], 'Brönsted': [1584], 'acids': [1585], '[H(OEt2)2BArF4,': [1588], '(ArF': [1589], '3,5-(CF3)2C6H3))': [1591], '[Ph2NH2]BArF4,': [1592], '[Ph2NH2]OTf,': [1593], 'etc.]': [1594], 'failed': [1595], 'form': [1597], 'corresponding': [1599], 'hydrazido': [1601], 'hydrazine': [1603], 'probably': [1605], 'high': [1609], 'sensitivity': [1610], 'toward': [1616], 'acid.': [1617], 'being': [1619, 1837], 'isolobal': [1620], 'isocharged': [1622], 'H+,': [1624], 'silylium': [1625], 'ions': [1626], 'known': [1628], 'impart': [1630], 'enhanced': [1631], 'kinetic': [1632], 'stability': [1633], 'resultant': [1636], 'silyldiazenides,': [1637], 'thus': [1638], 'making': [1639], 'easier.48,49': [1644], 'Therefore,': [1645], 'reactions': [1647], 'investigated.': [1651], 'Reaction': [1652, 3234, 4530], 'purple': [1665], '3).': [1671], 'crystals': [1673], 'hexane': [1684], '−35': [1687], 'Formation': [1692, 3050, 3080, 3241, 3346], 'pesudotetraheral': [1710], 'around': [1712], 'Co': [1714, 2330, 2365, 2395], 'phosphorus': [1718], 'nitrogen': [1722], 'atoms.': [1723], '[Co1–N3': [1728], '1.6741(11)': [1729], 'Å,': [1730, 1778, 1876], 'Co2–N1': [1731, 2013], '1.6746(12)': [1732], 'significantly': [1735], 'shorter': [1736], 'typical': [1738, 1787], 'single': [1739], 'bonds,': [1740, 1790], 'multiple': [1743], 'characteristic.50–53': [1745], 'Slight': [1746], 'bending': [1747], 'Co–N–N': [1752], 'angle': [1753, 1796], '[Co1–N3–N4': [1754], '168.94(12)°,': [1755], 'Co2–N1–N2': [1756, 2027], '163.58(12)°],': [1757], 'consistent': [1760, 1857, 1955], 'π-interaction': [1763], 'between': [1764, 1946, 2043, 2364, 2687, 2868, 3651], '3d(Co)': [1765], 'π*(N=N–TIPS)': [1767], '(TIPS': [1768], 'triisopropylsilyl)': [1770], 'orbitals.': [1771], '[N1–N2': [1776], '1.2080(18)': [1777], '1.2051(17)': [1780], 'range': [1785], 'N=N': [1788, 1823], 'double': [1789], 'acute': [1794], 'N–N–SiiPr3': [1795], '[N1–N2–Si1': [1797], '147.54(13)°,': [1798], 'N3–N4–Si2': [1799, 2023], '143.98(12)°]': [1800], 'suggests': [1801], 'sp': [1803], 'sp2': [1805], 'hybridized': [1806], 'atom': [1811], 'TIPS': [1815], 'group.31': [1816], 'Its': [1817], 'shows': [1820, 1933], 'characteristic': [1822], 'band': [1824], '1696': [1826], 'assignment': [1831], 'unit': [1835], 'reduced': [1838], 'diazenide': [1841], 'fragment.34,38': [1842], 'A': [1843, 1924, 3318, 3648, 4110], '15N–15N': [1844], '1655': [1848], 'mass': [1860], 'difference': [1861], '14N2.': [1865], 'length': [1869], 'bridging': [1872], '1.1296(17)': [1875], 'Å).47': [1886], 'contrast': [1888], 'phenyldiazenido': [1892], '{(SiPPh3)Fe(N2C6H5)}': [1894], '[SiPR3': [1895], 'represents': [1896], '(Si(o-C6H4PR2)3)−,': [1897], 'R': [1898], 'Ph': [1900], 'i-Pr],': [1902], 'diamagnetic.25': [1906], 'No': [1907], 'EPR': [1908], 'signals': [1909], 'observed.': [1911], 'One': [1912], '29Si-NMR': [1913, 1919], 'present': [1916], '−1.94': [1922], 'ppm.': [1923], '15N-NMR': [1925], 'labeled': [1929], '15N-': [1931], 'three': [1934, 2375], 'resonances': [1935], '−51.13(d,': [1937], 'Nα),': [1938], '−192.26,': [1939], '−200.39(d,': [1940], 'Nβ)': [1941], 'ppm,': [1942], 'Large': [1944], 'separation': [1945], 'Nα': [1947], 'Nβ': [1949], '(Δδ': [1950], '149': [1951], 'ppm)': [1952], 'fully': [1954], 'trimethylsilyl': [1964], '(TMS)': [1965], 'group,': [1966], 'it': [1968], 'related': [1972], 'Fe': [1973], '[Fe(PP)2(NN–SiMe3)][BArF4]': [1976], '(PP': [1977], 'dmpe/depe).31': [1979], '1.2080(18),': [2008], '1.2051(17),': [2010], '1.1298(16),': [2012], '1.6746(12),': [2014], '1.6741(11),': [2016], 'Co1–N5': [2017], '1.8584(11),': [2018], 'Co2–N6': [2019], '1.8583(11),': [2020], 'N1–N2–Si1': [2021], '147.54(13),': [2022], '143.98(12),': [2024], 'Co1–N3–N4': [2025], '168.94(12),': [2026], '163.58(12).': [2028], 'gain': [2034], 'insight': [2035], 'bonding': [2038, 2057, 2280, 2402], 'nature': [2039], 'interactions': [2042, 2155, 2172, 2363, 2422], 'RCo-center': [2045], 'activated': [2047], 'speices': [2049], '(i.e.,': [2050, 2197], 'N=N–TIPS)': [2051], 'molecule': [2053, 2123, 2655], '5,': [2054], 'performed': [2056], '(EDA)–natural': [2063], 'method': [2069], 'details).54–58': [2074], 'shown': [2076, 2291, 2313, 2357], 'Table': [2080, 2190, 2479], 'S13,': [2081], 'appropriate': [2083], 'fragments': [2084, 2311], 'better': [2093], 'described': [2094, 2370], 'RCo(0)': [2098], 'N=N–TIPS': [2100, 2224, 2248, 2332, 2367, 2691], 'doublet': [2105], 'states,': [2106], 'lesser': [2110], 'ΔEorb': [2111, 2120, 2162], 'energy.57,58': [2112], 'contribution': [2114, 2240, 2270], 'orbital': [2117, 2154, 2167, 2171, 2194, 2209, 2253, 2421], 'interaction': [2118, 2195], 'term': [2119, 2163], '(45.5%)': [2121], 'slightly': [2126], 'electrostatic': [2130], 'attraction': [2131], 'ΔEelstat': [2132], '(44.5%).': [2133], 'dispersion': [2135], 'forces': [2136], 'provide': [2137, 2597], 'remaining': [2139], '10.0%': [2140], 'total': [2143], 'attraction,': [2144], 'nonnegligible.': [2147], 'most': [2149, 2302], 'important': [2150, 2303], 'information': [2151], 'about': [2152], 'comes': [2156, 2200], 'breakdown': [2159], 'pairwise': [2166], 'contributions.': [2168], 'Four': [2169], 'major': [2170, 2557], 'identified': [2175], 'inspecting': [2177], 'deformation': [2179, 2415], 'densities': [2180, 2416], 'Δρ(1)∼Δρ(4)': [2181], 'associated': [2182, 2418], 'ΔEorb(1)∼ΔEorb(4)': [2184], 'S13).': [2191], 'strongest': [2193], 'ΔEorb(1)': [2196], '−65.3': [2198], 'kcal/mol)': [2199, 2239], 'mainly': [2201], 'π-back': [2204, 2379], 'donation': [2205, 2380], '3d': [2208], 'Co-center': [2212, 2382, 2689], 'in-plane': [2215, 2385, 2664], 'π*': [2216, 2386], '(antibonding': [2217], 'orbital)': [2218], 'S60': [2230], 'S61).': [2232], 'second': [2234], 'larger': [2235, 2294], '(ΔEorb(2)': [2236], '−29.5': [2238], 'primarily': [2241], 'corresponds': [2242], 'σ-donation': [2245, 2391], 'fragment': [2249, 2436], '4s': [2252], 'Co-center,': [2256, 2286], 'well': [2258], 'some': [2260], 'polarization': [2261], 'inside': [2262], 'third': [2267], 'fourth': [2269], '(Δρ(3)': [2271], 'Δρ(4))': [2273], 'arise': [2274], 'delocalized': [2277, 2399], 'out-of-plane': [2278, 2400], 'π': [2279, 2401], 'among': [2281, 2403], 'but': [2287], 'obviously': [2288], 'polarized': [2289], 'ΔEorb(3)': [2295], 'ΔEorb(4).': [2297], 'individual': [2299], 'components': [2300], 'molecular': [2305], '(MOs)': [2307], 'S61,': [2318], 'while': [2319], 'MO': [2322], 'correlation': [2323], 'diagrams': [2324], 'both': [2326], 'ionic': [2329], 'resonant': [2335], 'given': [2340], 'S62.': [2345], 'Above': [2346], 'all,': [2347], 'recommended': [2349], 'formulas': [2352, 2614], '4,': [2360, 4547], 'where': [2361], 'combination': [2373], 'effects:': [2376], '(1)': [2377], 'species;': [2389], '(2)': [2390], 'center;': [2396], '(3)': [2398], 'Co-center.': [2408], 'Shape': [2412], 'Δρ(1)–(4)': [2417], 'ΔEorb(1)–(4)': [2423], 'UB3LYP+D3(BJ)/TZ2P//UPBE0+D3(BJ)/def2-SVP': [2429], 'level.': [2430], 'eigenvalues': [2432], 'υ': [2433], 'give': [2438], 'size': [2440], 'charge': [2443, 2450], 'migration.': [2444], 'color': [2446], 'code': [2447], 'transfer': [2451, 2685], 'red': [2453], '→': [2454, 2674], 'blue.': [2455], 'With': [2460], 'these': [2461], 'compounds': [2465], 'hand,': [2467], 'investigated': [2469], 'S1).': [2480], 'compound': [2482], 'up': [2485, 2544], '51.8': [2487], 'N(SiMe3)3': [2488, 2532, 2547, 3892], 'per': [2489, 2550], 'Me3SiCl': [2494], 'electron': [2497, 2684], 'silyl': [2499], 'cation': [2500], 'sources,': [2501], 'yield': [2504], 'previously': [2509], 'bearing': [2515], 'carbonyl,': [2516], 'cyclopentadienyl,': [2517], 'bipyridyl': [2519], '(bpy)': [2520], 'ligands.59': [2521], 'Dzik60': [2522], 'used': [2523], 'PPh3': [2524], 'monodentate': [2526], 'small': [2529], 'amounts': [2530], 'obtained.': [2534], 'applied': [2540], 'catalyst,': [2543], '89.4': [2546], 'complex.': [2551], 'TMS–TMS': [2553], 'side-product,': [2558], 'gas': [2561], 'chromatography': [2562], '(GC)': [2563], 'analysis,': [2564], 'presumably': [2565], 'radical': [2567], 'recombination': [2568], 'situ-generated': [2571], 'Me3Si•': [2572], 'Me3SiCl,': [2579], 'studied': [2582], 'Nishibayashi': [2585, 3844, 4520, 4562], 'group.61': [2586], 'experimental': [2588, 2701], 'results': [2589], 'complementary': [2598], 'insights': [2599], 'understanding': [2601], 'Co-catalyzed': [2603], 'process.': [2605], 'Electronic': [2609, 3732], '(VB)': [2613], 'Conclusion': [2622], 'Novel': [2623], 'cobalt-silyldiazenido': [2643], 'thoroughly': [2648], 'Quantum': [2650], 'indicate': [2653], 'open-shell': [2659], 'ground': [2661], 'state.': [2662], '[TIPS–N=N]': [2665, 2673], '←': [2666], 'RCo(3d)': [2667], 'π-back-donation': [2668], 'remarkably': [2670], 'RCo(4S)': [2675], 'σ-donation/polarization,': [2676], 'indicates': [2678], 'conjugation': [2680], 'effect': [2681], 'feature': [2686], 'fragment.': [2692], 'includes': [2700], 'details,': [2702], '(Figures': [2705, 2712, 2716, 2722, 2738], 'S1–S33)': [2706], 'products,': [2709], 'S34–S45),': [2713], 'UV–vis': [2714], 'S46–S48),': [2717], 'data': [2719], '1–5': [2721], 'S49–S58': [2723], 'Tables': [2725, 2741], 'S2–S11),': [2726], '(Table': [2733], 'S1),': [2734], 'calculation': [2736], 'details': [2737], 'S59–S62': [2739], 'S12–S14).': [2742], 'Conflict': [2743], 'Interest': [2745], 'There': [2746], 'no': [2748], 'conflict': [2749], 'interest': [2751], 'report.': [2753], 'Funding': [2754], 'work': [2757], 'Basic': [2762], 'Science': [2763, 2775, 2785, 2801], 'Transformation': [2766, 2920, 2970, 3846, 4522, 4564], 'Components': [2770], 'Air,': [2772], 'Natural': [2774, 2800, 4429, 4444], 'Foundation': [2776, 2786, 2802], 'China': [2778, 2783], '(no.': [2779, 2787, 2808], '21988101).': [2780], 'M.Z.': [2781], 'acknowledges': [2782, 2790], 'Postdoctoral': [2784], '2019M650294).': [2788], 'L.Z.': [2789], 'financial': [2792], 'support': [2793], 'NSFC': [2795], '(nos.': [2796], '21973044': [2797], '21703099),': [2799], 'Province': [2805], 'Youth': [2807], 'BK20170964).': [2809], 'Acknowledgments': [2810], 'DFT': [2812, 4603], 'High-Performance': [2818, 2826, 4609, 4617], 'Computing': [2819, 4610], 'Platform': [2820, 3320, 4611], 'University': [2831, 4622], 'resources.': [2835, 4626], 'References': [2836], '1.': [2837], 'Fryzuk': [2838, 2863, 2984, 3882, 4225], 'M.': [2839, 2864, 2883, 2886, 2985, 3667, 3883, 4226], 'D.Side-On': [2840], 'End-On': [2841], 'Bound': [2842, 3982], 'Dinitrogen:': [2843, 2922], 'An': [2844], 'Activated': [2845], 'Bonding': [2846, 4405, 4453, 4495], 'Mode': [2847, 2870, 3001], 'Facilitates': [2849], 'Functionalizing': [2850], 'Nitrogen.Acc.': [2852], 'Chem.': [2853, 3028, 3064, 3095, 3140, 3169, 3212, 3246, 3296, 3325, 3351, 3378, 3409, 3440, 3465, 3492, 3628, 3679, 3699, 3825, 3862, 3933, 3986, 4009, 4119, 4157, 4258, 4335, 4361, 4390], 'Res.2009,': [2854], '42,': [2855], '127–133.': [2856], '2.': [2859], 'Burford': [2860], 'R.': [2861, 3906], 'J.;': [2862, 2884, 2909, 2961, 2963, 3149, 3178, 3221, 3255, 3448, 3450, 3581, 3687, 3711, 3754, 3782, 3784, 3790, 3917, 4095, 4193, 4343], 'D.Examining': [2865], 'Relationship': [2867], 'Coordination': [2869, 2898, 3003, 4228], 'Reactivity': [2872, 3011, 3287], 'Dinitrogen.Nat.': [2874], 'Rev.': [2875, 4501], 'Chem.2017,': [2876], '1,': [2877], '0026.': [2878], 'Chalkley': [2882], 'Drover': [2885], 'W.;': [2887, 3945], 'Peters': [2888, 3556, 3582, 3614, 3669, 3688, 3813, 4203, 4242], 'J.': [2889, 3042, 3557, 3583, 3615, 3670, 3689, 3719, 3757, 3814, 4097, 4182, 4204, 4243], 'C.Catalytic': [2890, 3690, 3924], 'N2-to-NH3': [2891], '(or': [2892], '-N2H4)': [2893], 'Conversion': [2894, 3205, 3481, 3692, 3888, 4211], 'Complexes.Chem.': [2899, 4310], 'Rev.2020,': [2900, 2933, 2954], '120,': [2901, 2955], '5582–5636.': [2902], '4.': [2905], 'Lv': [2906, 3472], 'Z.-J.;': [2907, 2917, 3473], 'W.-X.;': [2911, 2967, 3456, 3477, 3792], 'Chen': [2912, 4048, 4133], 'P.;': [2913, 3107, 3280, 3306, 3334, 3555, 4129], 'D.;': [2915, 2986, 3180, 3500, 3708, 3714, 3884, 3912, 4273], 'Shi': [2916, 3507, 3533], 'Z.Direct': [2919, 2969], 'Synthesis': [2923, 3163, 3394], 'N-Containing': [2925, 2974], 'Organic': [2926, 2975], 'Compounds': [2927], 'N-C': [2929], 'Bond': [2930, 2948, 3049, 3079, 3115, 3240, 3345, 3489, 3619, 4332, 4378], 'Formation.Natl.': [2931], 'Sci.': [2932, 3518, 3601], '7,': [2934], '1564–1583.': [2935], 'Kim': [2939], 'S.;': [2940, 3424, 3502, 3636, 3833, 4277], 'Loose': [2941], 'F.;': [2942, 3750, 4091, 4374], 'Chirik': [2943, 3046, 3076, 3153, 3190, 3224, 3258, 3283, 3307, 3335], 'P.': [2944, 3047, 3077, 3106, 3109, 3154, 3191, 3225, 3259, 3284, 3308, 3336, 3710, 3766, 3944, 4165, 4303], 'J.Beyond': [2945], 'Ammonia:': [2946], 'Nitrogen−Element': [2947], 'Forming': [2949], 'Coordinated': [2952, 3565, 3819, 4076, 4293], 'Dinitrogen.Chem.': [2953], '5637–5681.': [2956], '6.': [2959], 'Li': [2960, 3449, 3783, 3965], 'Yin': [2962, 3447, 3453, 3781, 3785], 'Yu': [2964], 'C.;': [2965, 3282, 3720, 4098, 4372], 'Compounds.Acta': [2976], 'Chim.': [2977, 4413], 'Sinica2017,': [2978], '75,': [2979], '733–743.': [2980], '7.': [2983], 'Johnson': [2987], 'S.': [2988, 2996, 3279, 3305, 3333, 3603, 3749, 3760, 3941, 4016], 'A.;': [2989, 2994, 2997, 3043, 3389, 3812, 4043, 4166, 4224, 4370], 'Patrick': [2990], 'B.': [2991, 3763, 4128, 4136, 4223], 'O.;': [2992], 'Albinati': [2993], 'Mason': [2995], 'Koetzle': [2998], 'T.': [2999, 3811, 4192, 4324], 'F.New': [3000], 'Dinitrogen': [3006, 3055, 3089, 3133, 3159, 3199, 3228, 3294, 3322, 3365, 3483, 3510, 3768, 3849, 3855, 3890, 3927, 3950, 3977, 4077, 4288, 4525, 4543, 4567], 'Ligand:': [3007], 'Formation,': [3008], 'Bonding,': [3009], 'Tantalum': [3014], 'Complex': [3015, 3090, 4353], 'Bridging': [3018], 'Unit': [3020], 'Is': [3022], 'Both': [3023, 4152], 'Side-On': [3024, 3981], 'End-On.J.': [3026], 'Am.': [3027, 3063, 3139, 3168, 3211, 3245, 3324, 3439, 3464, 3491, 3627, 3678, 3698, 3824, 3932, 3985, 4156, 4334], 'Soc.2001,': [3029], '123,': [3030], '3960–3973.': [3031], '8.': [3034], 'Bernskoetter': [3035, 3071, 3181], 'W.': [3036, 3072, 3182, 4488, 4540], 'H.;': [3037, 3073, 3183, 3189, 3506, 3837, 4093, 4511, 4555], 'Olmos': [3038], 'A.': [3039, 3707, 3713, 3722, 4088], 'V.;': [3040, 3758, 3909], 'Pool': [3041], 'Lobkovsky': [3044, 3074, 3186, 3222, 3256], 'E.;': [3045, 3075, 3152, 3187, 3223, 3257, 3638, 3919, 4170, 4490], 'J.N−C': [3048], 'Promoted': [3051, 3085, 3267, 3371], 'Hafnocene': [3054, 3088, 3198, 3208, 3290], 'Complex:': [3056, 3160, 3200], 'Comparison': [3057], 'Zirconium': [3059, 3136], 'Hafnium': [3061, 3270, 3313, 3340], 'Congeners.J.': [3062], 'Soc.2006,': [3065], '128,': [3066], '10696–10697.': [3067], '9.': [3070], 'J.Nitrogen-Carbon': [3078], 'CO2': [3084], 'Yields': [3091], 'Substituted': [3093], 'Hydrazine.Angew.': [3094], 'Int.': [3096, 3297, 3352, 3379, 3410, 3863, 4120, 4259, 4362, 4391], 'Ed.2007,': [3097], '46,': [3098, 4415], '2858–2861.': [3099], '10.': [3102], 'Hirotsu': [3103], 'M.;': [3104, 3422, 3613, 3761, 4137, 4200, 4267, 4347, 4421, 4440, 4468, 4471, 4515, 4553], 'Fontaine': [3105], 'Zavalij': [3108], 'Y.;': [3110, 3428, 3504, 3552, 3839, 3875, 3877, 3964, 4045, 4279, 4513, 4559], 'Sita': [3111], 'L.': [3112, 3612, 3716, 3753, 3916, 4199], 'R.Extreme': [3113], 'Elongation': [3116], 'Facile': [3118], 'N-Atom': [3119], 'Within': [3122], 'Two': [3123], 'Versatile': [3125, 3319], 'New': [3126], 'Families': [3127], 'Group': [3129, 3231], 'Bimetallic': [3131], '“Side-On-Bridged”': [3132], 'Hafnium.J.': [3138], 'Soc.2007,': [3141], '129,': [3142], '12690–12692.': [3143], '11.': [3146], 'Knobloch': [3147, 3176, 3219, 3253], 'D.': [3148, 3177, 3220, 3254, 3611, 3752, 3994, 4102, 4198, 4470], 'Toomey': [3150, 3188], 'H.': [3151, 4489], 'J.Carboxylation': [3155], 'Ansa-Zirconocene': [3158], 'Regiospecific': [3161], 'Hydrazine': [3162, 3485], 'CO2.J.': [3167], 'Soc.2008,': [3170], '130,': [3171], '4248–4249.': [3172], '12.': [3175], 'Benito-Garagorri': [3179], 'Keresztes': [3184], 'I.;': [3185], 'J.Addition': [3192], 'Methyl': [3194], 'Triflate': [3195], 'Stepwise': [3201], 'Methylation': [3203], 'Hydrazonato': [3209], 'Compound.J.': [3210], 'Soc.2009,': [3213], '131,': [3214], '14903–14912.': [3215], '13.': [3218], 'J.Carbon': [3226], 'Monoxide-Induced': [3227], 'Cleavage': [3229, 3261], 'Metallocenes:': [3233], 'Scope': [3235], 'Coupling': [3237], 'N−H': [3239], 'CO': [3243], 'Deoxygenation.J.': [3244], 'Soc.2010,': [3247, 4158], '132,': [3248, 4159], '10553–10564.': [3249], '14.': [3252], 'J.Dinitrogen': [3260], 'Carbon': [3265], 'Monoxide': [3266], 'Complex.Nat.': [3271], 'Chem.2010,': [3272, 3574], '2,': [3273, 3575, 4082], '30–35.': [3274], '15.': [3277], 'Semproni': [3278, 3304, 3332], 'Milsmann': [3281], 'J.Structure': [3285], 'μ-Nitrido': [3291], 'Prepared': [3292], 'Cleavage.Angew.': [3295], 'Ed.2012,': [3298], '51,': [3299], '5213–5216.': [3300], '16.': [3303], 'J.Synthesis': [3309], 'Base-Free': [3312], 'Nitride': [3314], 'Cleavage:': [3317], 'Functionalization.J.': [3323], 'Soc.2013,': [3326, 3629], '135,': [3327, 3630], '11373–11383.': [3328], '17.': [3331], 'J.Activation': [3337], 'Dinitrogen-Derived': [3339], 'Nitrides': [3341], 'Nucleophilic': [3343], 'Terminal': [3349, 3675], 'Isocyanate.Angew.': [3350], 'Ed.2013,': [3353], '52,': [3354], '12965–12969.': [3355], '18.': [3358], 'Liao': [3359, 3386], 'Q.;': [3360, 3387, 3764], 'Saffon-Merceron': [3361, 3390], 'N.;': [3362, 3391, 3914, 4168], 'Mézailles': [3363, 3392], 'N.Catalytic': [3364], 'Reduction': [3366], 'Molybdenum': [3369, 3407, 4285], 'Bulky': [3374], 'Tetradentate': [3375], 'Phosphine': [3376, 3406], 'Ligand.Angew.': [3377], 'Ed.2014,': [3380], '53,': [3381, 3743], '14206–14210.': [3382], '19.': [3385], 'Cavaillé': [3388], 'N.Direct': [3393], 'Silylamine': [3396, 4527, 4569], 'Silane:': [3401], 'Mediated': [3402], 'Tridentate': [3405], 'Fragment.Angew.': [3408], 'Ed.2016,': [3411, 3864], '55,': [3412, 3658, 3865, 3958], '11212–11216.': [3413], '20.': [3416], 'B.;': [3418, 3665, 3788, 3907, 4196], 'Luo': [3419, 3427], 'G.;': [3420, 3966, 4202, 4241], 'Nishiura': [3421], 'Hu': [3423], 'Shima': [3425], 'T.;': [3426, 3668, 3871, 3879, 3881, 4047, 4132, 4271, 4275, 4322, 4399], 'Hou': [3429], 'Z.Dinitrogen': [3430, 3458, 3794], 'Dihydrogen': [3433], 'PNP-Ligated': [3436], 'Titanium': [3437], 'Complex.J.': [3438, 3463, 3931], 'Soc.2017,': [3441, 3680, 3700], '139,': [3442, 3681, 3701], '1818–1821.': [3443], '21.': [3446, 4548], 'G.-X.;': [3452, 3780], 'Z.;': [3454, 3475, 3786], 'Chromium': [3461], 'Hydrazido': [3462], 'Soc.2019,': [3466, 3493], '141,': [3467, 3494], '4241–4247.': [3468], '22.': [3471], 'Huang': [3474], 'Z.Scandium-Promoted': [3479], 'Direct': [3480, 3540], 'Derivatives': [3486], 'Formation.J.': [3490], '8773–8777.': [3495], '23.': [3498], 'Zhai': [3499, 3529], 'Xie': [3501, 3527, 4346], 'Xia': [3503], 'Fang': [3505, 3531], 'Z.-J.Silylamido': [3508], 'Supported': [3509], 'Heterobimetallic': [3511], 'Complexes:': [3512, 3951, 4289], 'Syntheses': [3513], 'Their': [3515, 3976], 'Catalytic': [3516, 3541, 3887], 'Ability.Natl.': [3517], 'Rev.2020.': [3519], '24.': [3522], 'K.;': [3524, 3835, 3841, 3843, 3873, 4051, 4269, 4517, 4519, 4557, 4561], 'Z.-H.;': [3526], 'S.-J.;': [3528], 'D.-D.;': [3530], 'H.-Y.;': [3532], 'Z.-J.Synthesis': [3534], 'Arylamines': [3536], 'N-Heterocycles': [3538], 'Nitrogenation': [3542], 'Using': [3543, 3893], 'N2.Nat.': [3544], 'Commun.2021,': [3545], '12,': [3546], '248.': [3547], '25.': [3550], 'Lee': [3551], 'Mankad': [3553], 'N.': [3554, 3664, 3947, 4195], 'C.Triggering': [3558], 'Uptake': [3560], 'Redox-Induced': [3562], 'Expulsion': [3563], 'Silylation': [3569, 3925], 'Trigonal': [3571, 4148], 'Bipyramidal': [3572], 'Iron.Nat.': [3573], '558–568.': [3576], '26.': [3579], 'Rittle': [3580], 'C.Fe–N2/CO': [3584], 'Model': [3587], 'Possible': [3589], 'Role': [3590], 'Interstitial': [3593], 'C': [3594], 'Atom': [3595], 'FeMo-Cofactor': [3597], '(FeMoco).Proc.': [3598], 'Natl.': [3599], 'Acad.': [3600], 'U.': [3602], 'A.2013,': [3604], '110,': [3605], '15898–15903.': [3606], '27.': [3609], 'Suess': [3610, 4197], 'C.H–H': [3616], 'Si-H': [3618], 'Addition': [3620], 'Fe≡NNR2': [3622], 'Intermediates': [3623], 'Derived': [3624], 'N2.J.': [3626], '4938–4941.': [3631], '28.': [3634], 'Ye': [3635], 'Bill': [3637, 3918, 4169], 'Neese': [3639], 'F.Electronic': [3640], 'Structures': [3641], '[Fe(N2)(SiPiPr3)]+1/0/–1': [3644], 'Electron': [3645], 'Transfer': [3646], 'Series:': [3647], 'Counterintuitive': [3649], 'Correlation': [3650], 'Isomer': [3652], 'Shifts': [3653], 'Oxidation': [3655], 'States.Inorg.': [3656], 'Chem.2016,': [3657], '3468–3474.': [3659], '29.': [3662], 'Thompson': [3663, 4194], 'Green': [3666, 3718], 'C.Nitrogen': [3671], 'Fixation': [3672], 'Fe(IV)': [3676], 'Nitride.J.': [3677], '15312–15315.': [3682], '30.': [3685], 'Fajardo': [3686], 'Nitrogen-to-Ammonia': [3691], 'Osmium': [3694], 'Ruthenium': [3696], 'Complexes.J.': [3697, 3984], '16105–16108.': [3702], '31.': [3705], 'Piascik': [3706], 'Hill': [3709], 'Crawford': [3712], 'Doyle': [3715], 'R.;': [3717, 4089, 4319, 4509], 'Ashley': [3721], 'E.Cationic': [3723], 'Silyldiazenido': [3724], 'Fe(diphosphine)2(N2)': [3728], 'Platform:': [3729], 'Structural': [3730], 'Models': [3733], 'Elusive': [3736], 'First': [3737], 'Intermediate': [3738], 'Fixation.Chem.': [3741], 'Commun.2017,': [3742], '7657–7660.': [3744], '32.': [3747], 'McWilliams': [3748], 'Broere': [3751], 'Halliday': [3755], 'C.': [3756, 3923, 4139, 4174, 4376], 'Bhutto': [3759], 'Mercado': [3762], 'Holland': [3765], 'L.Coupling': [3767], 'Hydrocarbons': [3770], 'through': [3771], 'Aryl': [3772], 'Migration.Nature2020,': [3773], '584,': [3774], '221–226.': [3775], '33.': [3778], 'Cyclopentadienyl-Phosphine–Iron': [3797], 'Three': [3800], 'Valences.CCS': [3802], 'Chem.2021,': [3803], '3,': [3804, 4503, 4574], '308–316.': [3805], 'Abstract,': [3806], '34.': [3809], 'Betley': [3810, 4323], 'P.Dinitrogen': [3815], 'Trigonally': [3818], 'Iron': [3820, 4178], 'Platforms.J.': [3823], 'Soc.2003,': [3826], '125,': [3827], '10782–10783.': [3828], '35.': [3831], 'Kuriyama': [3832], 'Arashiba': [3834], 'Tanaka': [3836, 4510, 4554], 'Matsuo': [3838, 4512], 'Nakajima': [3840, 4516], 'Yoshizawa': [3842, 4518, 4560], 'Y.Direct': [3845], 'Ammonia': [3851, 4079], 'Catalyzed': [3852, 4544], 'Bearing': [3857], 'Anionic': [3858], 'PNP': [3859], 'Pincer': [3860], 'Ligands.Angew.': [3861], '14291–14295.': [3866], '36.': [3869], 'Suzuki': [3870], 'Fujimoto': [3872], 'Takemoto': [3874], 'Wasada-Tsutsui': [3876], 'Ozawa': [3878, 4052], 'Inomata': [3880], 'Masuda': [3885], 'H.Efficient': [3886], 'Homogeneous': [3895], 'Mononuclear': [3896], 'Complex.ACS': [3898], 'Catal.2018,': [3899], '8,': [3900, 4479], '3011–3015.': [3901], '37.': [3904], 'Siedschlag': [3905], 'Bernales': [3908], 'Vogiatzis': [3910], 'Planas': [3913, 4167], 'Clouston': [3915], 'Gagliardi': [3920, 4171], 'L.;': [3921, 3942, 4172, 4345, 4465, 4485], 'Dicobalt': [3930], 'Soc.2015,': [3934], '137,': [3935], '4638–4641.': [3936], '38.': [3939], 'Apps': [3940], 'Miller': [3943], 'J.Cobalt(-I)': [3948], 'Triphos': [3949], 'Silyl-Functionalisation': [3954], 'N2.Chem.': [3956], 'Commun.2019,': [3957], '6579–6582.': [3959], '39.': [3962], 'Gao': [3963], 'L.Bis(dinitrogen)cobalt(−1)': [3968], 'Ligation:': [3972, 4356], 'Characterization,': [3974], 'Diazene': [3983], 'Soc.2018,': [3987], '140,': [3988], '2239–2250.': [3989], '40.': [3992], 'Evans': [3993], 'F.The': [3995], 'Determination': [3996], 'Paramagnetic': [3999, 4025], 'Susceptibility': [4000, 4020], 'Substances': [4002], 'Solution': [4004, 4028], 'Nuclear': [4006], 'Magnetic': [4007, 4019, 4022], 'Resonance.J.': [4008], 'Soc.1959,': [4010], '2003–2005.': [4011], '41.': [4014], 'Sur': [4015], 'K.Measurement': [4017], 'Moment': [4023], 'Molecules': [4026], 'High-Field': [4030], 'Fourier': [4031], 'Transform': [4032], 'Spectroscopy.J.': [4034], 'Magn.': [4035], 'Reson.1989,': [4036], '82,': [4037], '169–173.': [4038], '42.': [4041], 'Yamamoto': [4042], 'Miura': [4044], 'Ito': [4046], 'H.-L.;': [4049], 'Iri': [4050], 'F.Preparation,': [4053], 'Structure': [4056], 'Determination,': [4057], 'Chemical': [4059, 4432, 4447, 4593], 'Properties': [4060, 4283, 4424], 'Dinitrogen-Coordinated': [4062], 'Containing': [4065], 'Triphenylphosphine': [4066], 'Ligands': [4067, 4426], 'Alkali': [4069], 'Metal': [4070, 4309], 'Magnesium.': [4072], 'Protonation': [4073], 'Hydrazine.Organometallics1983,': [4081], '1429–1436.': [4083], '43.': [4086], 'Fout': [4087], 'Basuli': [4090], 'Fan': [4092], 'Tomaszewski': [4094], 'Huffman': [4096], 'Baik': [4099], 'M.-H.;': [4100], 'Mindiola': [4101], 'J.A': [4103], 'Co2N2': [4104], 'Diamond-Core': [4105], 'Resting': [4106], 'State': [4107], 'Cobalt(I):': [4109], 'Three-Coordinate': [4111], 'CoI': [4112], 'Synthon': [4113], 'Invoking': [4114], 'Unusual': [4116, 4147], 'Pincer-Type': [4117], 'Rearrangement.Angew.': [4118], 'Ed.2006,': [4121], '45,': [4122], '3291–3295.': [4123], '44.': [4126], 'Greenwood': [4127], 'Rowe': [4130], 'G.': [4131, 4321], 'C.-H.;': [4134], 'Foxman': [4135], 'Thomas': [4138], 'M.Metal-Metal': [4140], 'Multiple': [4141], 'Bonds': [4142], 'Early/Late': [4144], 'Heterobimetallics': [4145], 'Support': [4146], 'Monopyramidal': [4149], 'Geometries': [4150], 'Zr': [4153], 'Co.J.': [4155], '44–45.': [4160], '45.': [4163], 'Rudd': [4164], 'C.Dinitrogen': [4175], 'Metallalumatranes.Eur.': [4181], 'Inorg.': [4183], 'Chem.2013,': [4184], '2013,': [4185], '3898–3906.': [4186], '46.': [4189], 'Del': [4190], 'Castillo': [4191], 'Ung': [4201, 4240], 'C.Evaluating': [4205], 'NH3.Inorg.': [4215], 'Chem.2015,': [4216], '54,': [4217, 4261, 4364], '9256–9262.': [4218], '47.': [4221], 'MacKay': [4222], 'D.Dinitrogen': [4227], 'Chemistry:': [4229], 'On': [4230], 'Biomimetic': [4232], 'Borderlands.Chem.': [4233], 'Rev.2004,': [4234], '104,': [4235], '385–402.': [4236], '48.': [4239], 'C.Low-Temperature': [4244], 'Binding': [4246], 'Two-Coordinate': [4248, 4350], 'L2Fe0': [4249], 'Enables': [4250], 'Reductive': [4251], 'Trapping': [4252], 'L2FeN2−': [4254], 'Generation.Angew.': [4257], 'Ed.2015,': [4260, 4363], '532–535.': [4262], '49.': [4265], 'Hidai': [4266], 'Komori': [4268], 'Kodama': [4270], 'Jin': [4272], 'Takahashi': [4274], 'Sugiura': [4276], 'Uchida': [4278], 'Mizobe': [4280], 'Y.Preparation': [4281], 'Tungsten': [4287], 'XXI.': [4290], 'Trimethylsilylation': [4291], 'Dinitrogen.J.': [4294], 'Organomet.': [4295], 'Chem.1984,': [4296], '272,': [4297], '155–167.': [4298], '50.': [4301], 'Power': [4302], 'P.Stable': [4304], 'Two-Coordinate,': [4305], 'Open-Shell': [4306], '(d1–d9)': [4307], 'Transition': [4308], 'Rev.2012,': [4311], '112,': [4312], '3482–3507.': [4313], '51.': [4316], 'King': [4317], 'E.': [4318], 'Sazama': [4320], 'A.Co(III)': [4325], 'Imidos': [4326], 'Exhibiting': [4327], 'Spin': [4328], 'Crossover': [4329], 'C–H': [4331], 'Activation.J.': [4333], 'Soc.2012,': [4336], '134,': [4337], '17858–17861.': [4338], '52.': [4341], 'Du': [4342], 'L.A': [4349], 'Cobalt(II)': [4351, 4388], 'Imido': [4352, 4382], 'Structure,': [4358], 'Reactivity.Angew.': [4360], '12640–12644.': [4365], '53.': [4368], 'Reckziegel': [4369], 'Pietzonka': [4371], 'Kraus': [4373], 'Werncke': [4375], 'G.C−H': [4377], 'Cobalt(III)': [4383], 'Resulting': [4386], 'Amido': [4387], 'Complex.Angew.': [4389], 'Ed.2020,': [4392], '59,': [4393], '8527–8531.': [4394], '54.': [4397], 'Ziegler': [4398], 'Rauk': [4400], 'A.On': [4401], 'Calculation': [4403], 'Energies': [4406], 'Hartree': [4409], 'Fock': [4410], 'Slater': [4411], 'Method.Theor.': [4412], 'Acta1977,': [4414], '1–10.': [4416], '55.': [4419], 'Mitoraj': [4420, 4439], 'Michalak': [4422, 4441], 'A.Donor–Acceptor': [4423], 'Orbitals': [4430, 4445], 'Valence.Organometallics2007,': [4433], '26,': [4434], '6576–6580.': [4435], '56.': [4438], 'A.Applications': [4442], 'Valence': [4448], 'Description': [4451], 'Conjugated': [4455], 'Molecules.J.': [4456], 'Mol.': [4457, 4477], 'Model.2008,': [4458], '14,': [4459], '681–687.': [4460], '57.': [4463], 'Von': [4466], 'Hopffgarten': [4467], 'Andrada': [4469], 'Frenking': [4472, 4491], 'G.Energy': [4473], 'Decomposition': [4474, 4499], 'Analysis.WIREs': [4475], 'Comput.': [4476], 'Sci.2018,': [4478], 'e1345.': [4480], '58.': [4483], 'Hermann': [4486], 'M.;Schwarz': [4487], 'G.The': [4492], 'Lewis': [4493], 'Electron-Pair': [4494], 'Model:': [4496], 'Modern': [4497], 'Energy': [4498], 'Analysis.Nat.': [4500], 'Chem.2019,': [4502], '48–63.': [4504], '59.': [4507], 'Imayoshi': [4508], 'Yuki': [4514, 4552], 'Y.Cobalt-Catalyzed': [4521], 'Ambient': [4529, 4571], 'Conditions.Chem.': [4531], 'Eur.': [4532], 'J.2015,': [4533], '21,': [4534], '8905–8909.': [4535], '60.': [4538], 'Dzik': [4539], 'I.Silylation': [4541], 'Hydridodinitrogentris(triphenylphosphine)cobalt(I).Inorganics2016,': [4546], '61.': [4551], 'Sasaki': [4556], 'Miyake': [4558], 'Y.Iron-Catalysed': [4563], 'Conditions.Nat.': [4572], 'Commun.2012,': [4573], '1254.': [4575], 'Previous': [4578], 'articleNext': [4579], 'article': [4580], 'FiguresReferencesRelatedDetails': [4581], 'Issue': [4582], 'AssignmentVolume': [4583], '4Issue': [4584], '2Page:': [4585], '532-539Supporting': [4586], 'Copyright': [4588], '&': [4589], 'Permissions©': [4590], '2021': [4591], 'Chinese': [4592], 'SocietyKeywordsdinitrogen': [4594], 'functionalizationbidentate': [4595], 'ligandcobalt': [4597], 'complexdinitrogen': [4599], 'silylationcobalt-bis(dinitrogen)': [4600], 'complexEDA-NOCV': [4601], 'methodAcknowledgmentsThe': [4602], 'Downloaded': [4627], '1,429': [4628], 'times': [4629], 'PDF': [4630], 'DownloadLoading': [4631], '...': [4632]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W3134092093', 'counts_by_year': [{'year': 2024, 'cited_by_count': 4}, {'year': 2023, 'cited_by_count': 6}, {'year': 2022, 'cited_by_count': 3}], 'updated_date': '2024-09-25T01:42:53.078370', 'created_date': '2021-03-15'}