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1897, 1915, 1920, 1942, 1946, 1959, 1989, 1993, 2003, 2006, 2009, 2015, 2019, 2022, 2028, 2039, 2050, 2067, 2071, 2088, 2111, 2129, 2162, 2238, 2269, 2277, 2294, 2298, 2307, 2310, 2337, 2528, 2652, 2755, 2815, 3033, 3541, 3764, 3821, 3895, 3903, 3920, 3924, 3933, 3936, 3963], 'commonly': [212], 'used': [213, 671], 'pharmaceuticals': [214], 'biologically': [216, 700, 1404], 'active': [217, 701, 1405, 2089], 'natural': [218], 'products': [219, 1230, 1245, 1287, 1456, 1504, 1995, 2024], 'are': [220, 248, 399, 1584], 'nitrogen-containing': [221, 463], 'compounds.': [222], 'Recently,': [223], 'transition-metal-catalyzed': [225, 445, 543], 'or': [226, 446, 1750, 1846, 1865, 1906, 2018, 2375], 'radical-mediated': [228, 448], '1,2-carboamination': [229, 506], 'alkenes': [231, 247, 421, 451, 478, 493, 509, 535, 554, 590, 731, 1142, 1221, 1284, 2010, 2187], 'has': [232, 356, 393, 1376], 'been': [233, 396, 538, 556], 'well': [234, 1279], 'explored': [235], 'access': [237], 'amine': [238, 346, 385, 853, 2158, 2166], 'scaffolds.': [239, 347], 'However,': [240, 378], 'synthetic': [241], 'strategies': [242], 'toward': [243, 3121], '1,1-carboamination': [245, 533], 'severely': [249], 'limited.': [250], 'Herein,': [251, 630], 'we': [252, 631, 1132, 1395, 1821, 1978], 'describe': [253, 632], 'a': [254, 291, 317, 360, 473, 489, 516, 586, 608, 662, 704, 803, 903, 920, 1369, 1657, 1697, 1855, 1888, 1967, 1981, 2075, 2143, 2181, 2210, 2407, 2895, 2959, 3092, 3218, 3483, 3860], 'method': [255, 292, 684], 'achieve': [257], '1,1-arylamination': [259, 588, 640, 1068, 1244, 2080, 2184], 'using': [260], 'readily': [261], 'available': [262, 405, 840], 'building': [263], 'blocks': [264], 'enabled': [265], 'by': [266, 277, 559, 820, 1687, 2153, 2268, 2593, 3411, 3490, 3567, 3686, 3859, 3894], 'palladium': [267, 2090], 'catalysis.': [268], 'This': [269, 659, 1964, 2207, 2264], 'sequential': [270], 'three': [271], 'step-Heck': [272], 'arylation,': [273], 'metal': [274], 'migration,': [275], 'followed': [276, 2152], 'aza-1,6-Micheal': [278], 'addition': [279, 2098, 2156], 'process': [280, 660, 1968, 2017, 2040], 'exhibits': [281], 'excellent': [282], 'chemo-': [283], 'regioselectivity.': [285], 'To': [286, 1386, 1815, 1932], 'showcase': [287], 'potential': [289, 1370, 1889], 'as': [290, 367, 496, 607, 879, 1257, 1988, 2958, 3237], 'for': [293, 381, 384, 626, 672, 707, 787, 1104, 1333, 1478, 1588, 1629, 2247, 2332, 2510, 2527, 2616, 2754, 2848, 3032, 3240, 3719, 3763, 3958], 'diversity-oriented': [294, 708, 1372], 'drug': [295, 321, 388, 709, 1373], 'discovery,': [296, 1374], 'modification': [298], 'numerous': [300], 'structurally': [301, 440, 697, 1401], 'complex': [302, 698, 1402], 'bioactive': [303, 1357], 'molecules': [304, 315, 1358, 1406], 'was': [305, 728, 780, 793, 809, 818, 941, 1070, 1114, 1120, 1125, 1664, 1714, 1869, 1892, 1918, 1939, 2011, 2224, 2266, 3892], 'also': [306, 503, 1155, 1242, 1476, 1555, 2324, 3950], 'successfully': [307, 1535], 'performed.': [308], 'Download': [309, 311, 719, 721, 1811, 1813, 2061, 2063, 2173, 2175], 'figure': [310, 720, 1812, 2062, 2174], 'PowerPoint': [312, 722, 1814, 2064, 2176], 'Introduction': [313], 'Nitrogen-containing': [314], 'play': [316], 'vital': [318], 'role': [319, 1927], 'in': [320, 342, 387, 409, 435, 481, 525, 530, 611, 687, 772, 858, 884, 902, 915, 919, 1094, 1162, 1233, 1280, 1292, 1380, 1414, 1459, 1488, 1507, 1521, 1538, 1577, 1666, 1716, 1729, 1740, 1762, 1837, 1840, 1900, 1928, 1949, 2049, 2084, 2202, 2335, 2348, 2630, 2814, 2936, 3091, 3961], 'exploitation,': [322], 'sensor': [323], 'design,': [324], 'agrochemical': [326], 'development.1–4': [327], 'In': [328, 483, 540, 848, 1561, 1860], 'preceding': [330], 'decades,': [331], 'transition-metal': [332], 'catalysis,5–9': [333], 'photocatalysis,10–13': [334], 'electrocatalysis14–17': [336], 'have': [337, 536, 555, 1443, 2179], 'shown': [338, 2083], 'their': [339], 'unique': [340], 'merits': [341], 'synthesis': [344, 1367, 1659], 'The': [348, 602, 647, 676, 777, 807, 1352, 1435, 1829, 2322, 3948], 'development': [349], 'these': [351, 522], 'novel': [352], 'C–N': [353, 1876, 1929], 'bond-forming': [354], 'reactions': [355], 'proven': [357], 'be': [359, 670, 856, 913, 963, 1486, 1734, 2047], 'valuable': [361], 'supplement': [362], 'traditional': [364], 'methods,': [365], 'such': [366, 878, 1256], 'Hofmann': [368], 'alkylation,18': [369], 'amide': [370], 'reduction,19,20': [371], 'imine': [372], 'alkylation,21,22': [373], 'carbonyl': [375], 'reductive': [376], 'amination.23,24': [377], 'demand': [380], 'practical': [382], 'methods': [383], 'functionalization': [386], 'discovery': [389], 'industrial': [391], 'productions': [392], 'not': [394, 1071, 2012, 2046], 'yet': [395], 'fulfilled.': [397], 'deemed': [400], 'one': [401], 'most': [404], 'feedstocks,': [406], 'which': [407, 616, 668, 1410, 1732, 1850, 1912, 2036, 2117, 2150], 'engage': [408], 'diverse': [410, 441], 'organic': [411], 'transformations': [412, 1681], 'involving': [413, 1969], 'all': [414, 1197, 1277, 1412], 'facets': [415], 'chemistry.': [417], 'Catalytic': [418, 2756, 2791, 3687], 'difunctionalization': [419], 'is': [422, 452, 649, 685, 1465, 2034, 2082, 2151, 2235, 2256], 'an': [423, 436, 633, 652, 2154, 2217, 2373, 2376, 3825], 'elegant': [424], 'route': [425], 'that': [426, 1468, 1914, 2002, 2038], 'permits': [427], 'simultaneous': [429], 'generation': [430], 'two': [432], 'new': [433], 'bonds': [434], 'operation': [437], 'provide': [439], 'molecules.25–28': [442], 'Consequently,': [443], '1,2-/2,1-carboamination': [449], 'particularly': [453], 'popular': [454], 'provides': [456], 'efficient': [457], 'approaches': [458], 'generate': [460, 592, 1243], 'versatile': [462], 'architectures': [464], '(Scheme': [465, 600, 645, 1654, 1678, 1765, 1858, 1882, 1909, 1975, 2025, 2053], '1a).29–41': [466], 'For': [467], 'instance,': [468], 'Piou': [469, 3210], 'Rovis39': [471], 'achieved': [472, 857, 1413], 'rhodium-catalyzed': [474, 587], 'diastereoselective': [475], 'syn-carboamination': [476], 'with': [479, 494, 510, 596, 641, 730, 795, 838, 898, 1199, 1557, 1568, 1905, 1952, 1984, 2093, 2157, 2188, 2679, 3116, 3383, 3435, 3644], 'enoxyphthalimide': [480], '2015.': [482], '2018,': [484], 'Stephenson': [485, 3233], 'co-workers40': [487], 'disclosed': [488, 558], 'photocatalytic': [490], '1,2-aminoarylation': [491], 'arylsulfonylacetamides': [495], 'bifunctional': [498], 'reagents.': [499], 'Engle': [500, 3258], 'co-workers41': [502], 'reported': [504], 'unactivated': [508], 'amines': [511, 595, 741, 1425, 2199], 'aryl': [513, 1422, 1473, 1543, 2190], 'electrophiles': [514], 'via': [515, 2635, 3217, 3266], 'directed': [517], 'aminopalladation': [518], 'strategy.': [519], 'Aside': [520, 1541], 'from': [521, 980, 1542, 3668], 'remarkable': [523, 677], 'achievements': [524], 'alkene': [526, 639, 2108], '1,2-carboamination,': [527], 'however,': [528], 'advances': [529], 'site-selective': [532, 2182], 'rarely': [537], 'reported.': [539], 'addition,': [541, 1562, 1861], '1,1-aryloxygenation,': [544], '1,1-arylhalogenation,': [545], '1,1-diarylation,': [546], '1,1-arylborylation,': [547], '1,1-alkylborylation,': [548], '1,1-diborylation,': [549], '1,1-alkynylboration,': [550], '1,1-dialkynylation': [552], 'successively': [557], 'Sanford': [560, 3282, 3297], 'et': [561, 564, 567, 570, 573, 577], 'al.,42,43': [562], 'Toste': [563, 3324, 3344, 3372, 3474, 3533], 'al.,44–46': [565], 'Hong': [566, 3404], 'al.,47': [568], 'Sigman': [569, 3426, 3451, 3477, 3511, 3536, 3754, 3788, 3818, 3848], 'al.,48–52': [571], 'Yin': [572, 2882, 2912, 3562, 3584, 3611, 3637], 'al.,53–56': [574], 'Fu': [576, 2688, 3609, 3663], 'al.,57': [578], 'more': [580, 688], 'recently,': [581], 'Ellman': [582, 3682], 'co-workers58': [584], 'described': [585], 'α-branched': [593], 'secondary': [594], 'electrophilic': [597], 'aminating': [598], 'agents': [599], '1b).': [601], 'heteroatom-based': [603], 'directing': [604], 'group': [605, 1138], 'figured': [606], 'crucial': [609], 'factor': [610], 'control': [613, 2229], 'regioselectivity,': [615], 'promotes': [617], 'Rh': [619], 'catalyst': [620, 865, 1119], 'migration': [621], 'benzyl': [624], 'site': [625], 'nitrene': [628], 'insertion.': [629], 'innovative': [634], 'tactic': [635], 'show': [637], '4-iodophenols': [642, 736, 1442], 'N-nucleophiles': [644], '1c).': [646], 'regioselectivity': [648], 'derived': [650], 'through': [651, 802, 2096], 'intriguing': [653], 'palladium-catalyzed': [654, 2183], 'Heck': [655, 1112, 1749, 1872, 3301, 3740, 3766], 'arylation/metal': [656], 'migration/isomerization': [657], 'process.': [658], 'affords': [661, 2142], 'thermodynamically': [663, 2144], 'stable': [664, 2145], 'para-quinone': [665, 1916, 2146], 'methide': [666, 1917, 2147], 'intermediate,': [667, 1922], 'can': [669, 1241], 'further': [673, 1933], 'amination': [674], 'decoration.': [675], 'substrate': [678, 1431, 2219], 'scope': [679, 1432], 'generality': [681, 1389], 'this': [683, 836, 1157, 1225, 1281, 1393, 1479, 1539, 1589, 1649, 1935, 2079], 'demonstrated': [686, 1653, 1966], 'than': [689, 1151], '70': [690], 'examples,': [691], 'including': [692, 1168, 2237], 'over': [693], '20': [694], 'cases': [695], 'alkene-containing': [699, 1403], 'molecules,': [702], 'offering': [703, 1454], 'workable': [705], 'platform': [706], 'discovery.': [710], 'Scheme': [711, 1767, 2055, 2085, 2168], '1': [712, 972, 985, 1305, 1884], '|': [713, 973, 1297, 1593, 1769, 2057, 2170], '(a–c)': [714], 'Background': [715], 'reaction': [717, 778, 792, 940, 1158, 1226, 1559, 1753, 1819, 1830, 1943, 1983, 2081, 2208], 'synopsis.': [718], 'Experimental': [723], 'Methods': [724, 2753], 'A': [725, 2137, 2221], 'sealed': [726], 'tube': [727], 'assembled': [729], '(0.2': [732, 755, 1076, 1089, 1092, 1306, 1319, 1322, 1602, 1615, 1618], 'mmol,': [733, 738, 743, 748, 756, 766], '1.0': [734, 759, 769], 'equiv),': [735, 740, 745, 760, 770], '(0.4': [737, 742, 1079, 1082, 1309, 1312, 1605, 1608], '2.0': [739, 744], 'Pd2(dba)3': [746, 897, 992, 998, 1004, 1010, 1016, 1084, 1314, 1610, 1908], '(0.01': [747], '9.2': [749], 'mg,': [750, 758, 768], '5.0': [751, 862], 'mol': [752, 863, 1014, 1086, 1117, 1316, 1612], '%),': [753, 1087, 1317, 1613], 'K3PO4': [754, 957, 1022, 1028, 1034, 1038, 1088, 1318, 1614], '42.4': [757], 'tetrabutyl': [761], 'ammonium': [762], 'chloride': [763], '(TBAC,': [764], '0.2': [765], '55.6': [767], 'dry': [773, 1095, 1324, 1620], '1,4-dioxane': [774, 959, 1044, 1050, 1056, 1096, 1325, 1621, 1797], '(1.0': [775, 1097, 1326, 1622], 'mL).': [776], 'mixture': [779], 'stirred': [781], 'at': [782, 1099, 1328, 1624, 2894], '80': [783, 1100, 1329, 1625], '°C': [784, 1101, 1330, 1626, 1808], 'under': [785, 811, 1102, 1331, 1627, 1674, 1719, 1798, 1809], 'argon': [786, 1103, 1332, 1628], '24': [788, 1105, 1334, 1630], 'h.': [789, 1106, 1335, 1631], 'Then': [790], 'diluted': [794], 'ethyl': [796], 'acetate': [797], '(5.0': [798, 1085, 1315, 1611], 'mL)': [799, 1098, 1327, 1623], 'filtered': [801], 'plug': [804], 'Celite.': [806], 'solvent': [808, 949], 'removed': [810], 'vacuum': [812], 'conditions,': [813, 917, 1131], 'crude': [816], 'product': [817, 1069, 1345, 1640, 1683, 1835, 1947], 'purified': [819], 'flash': [821], 'chromatography': [822], 'on': [823, 1447, 1669, 2066, 2227, 2548, 2790], 'silica': [824], 'gel': [825], 'afford': [827], 'corresponding': [829, 1344, 1639, 1994], 'products.': [830], 'Results': [831], 'Discussion': [833], 'We': [834, 2178], 'initiated': [835], 'work': [837], 'commercially': [839], '1-phenylpent-4-en-1-one': [841], '1a,': [842], '4-iodophenol': [843, 1569, 2094], '2a,': [844], 'indoline': [846, 1267, 1691], '3a.': [847], '1,4-dioxane,': [849, 1777], 'branched': [851, 2164, 2197], 'tertiary': [852, 2165, 2198], '4a': [854, 888, 901, 911, 1161, 1836, 1996], 'could': [855, 912, 1154, 1485, 1570, 1733, 1754, 1924], '78%': [859], 'yield': [860, 886, 922, 1110, 1668, 1718, 1839, 1951], 'employing': [861], '%': [864, 1015, 1118], 'loading': [866], 'Pd2(dba)3,': [868], 'K3PO4,': [869], 'TBAC': [871, 1091, 1321, 1617], '(Table': [872, 889, 906, 923, 943, 953, 1143, 1419, 1433], '1,': [873, 890, 907, 924, 944, 954], 'entry': [874, 908, 925, 945], '1).': [875], 'Other': [876, 1150], 'Pd-catalysts,': [877], 'Pd(dba)2': [880, 989], 'Pd(PPh3)4,': [882], 'resulted': [883], 'low': [885, 921], 'entries': [891, 955], '2': [892, 1296, 1308, 1604, 1768], '3).': [894, 1434], 'Replacing': [895], 'Pd(OAc)2': [899], 'delivered': [900, 1502], 'trace': [904], 'amount': [905, 932], '4).': [909], 'Product': [910], 'observed': [914, 2029], 'Ni-catalyzed': [916], 'albeit': [918], '5).': [926], 'With': [927], 'reduction': [929], 'catalyst,': [934], 'transformation': [936, 1353], 'efficiency': [937, 1450], 'reduced': [942, 1736], '6).': [946], 'From': [947], 'extensive': [948, 2218], 'base': [951], 'screening': [952], '7–13),': [956], 'were': [960, 1196, 1411, 1426, 1475, 1554, 1651, 1685, 1880, 1999, 2200], 'determined': [961], 'optimal': [964, 1130], 'conditions': [965, 1677], '(': [966, 1170, 1173, 1178, 1181, 1184, 1188, 1192, 1215, 1246, 1259, 1262, 1265, 1268, 1271, 1275, 1288, 1407, 1494, 1499, 1511, 1515, 1528, 1533, 1546, 1552, 1566, 1703], 'Supporting': [967, 1146, 1216, 1704, 2231, 2233], 'Information': [968, 1147, 1217, 1705, 2232, 2234, 3882], 'Table': [969, 971, 1218, 1295, 1591], 'S1).': [970, 1149], 'Effect': [974], 'Reaction': [976, 3767], 'Parametersa': [977], 'Entry': [978], 'Deviation': [979], 'Standard': [981], 'Conditions': [982], 'Tield': [983], '(%)': [984], 'None': [986], '78b': [987], '2c': [988], 'instead': [990, 996, 1002, 1008, 1020, 1026, 1032, 1042, 1048, 1054], '67': [993], '3c': [994], 'Pd(PPh3)4': [995], '31': [999], '4c': [1000, 1174], 'Pd(OAc)2/PPh3': [1001], 'Trace': [1005, 1035], '5c,d': [1006], 'NiI2': [1007], '46': [1011], '6': [1012], '2.5': [1013], '63': [1017], '7': [1018], 'tBuOK': [1019], '28': [1023], '8': [1024, 1576], 'Na2CO3': [1025], '71': [1029], '9': [1030, 1709], 'Et3N': [1031], '10': [1036, 1728, 1745], 'Without': [1037], 'n.d.': [1039, 1065], '11': [1040, 1739], 'THF': [1041], '55': [1045], '12': [1046, 1759], 'DCM': [1047], '37': [1051], '13': [1052, 1761], 'DMF': [1053], '65': [1057], 'Note:': [1058], 'DCM,': [1059, 1782], 'dichloromethane;': [1060], 'DMF,': [1061], 'dimethylformamide;': [1062], 'THF,': [1063], 'tetrahydrofuran.': [1064], '=': [1066, 1339], 'detected.': [1072], 'aReaction': [1073, 1300, 1596], 'condition:': [1074], '1a': [1075, 1601, 1985, 2109], 'mmol),': [1077, 1080, 1083, 1090, 1093, 1307, 1310, 1313, 1320, 1323, 1603, 1606, 1609, 1616, 1619], '2a': [1078, 1144, 2095], '3a': [1081, 1311, 2159], 'Isolated': [1107, 1336, 1632], 'yields.': [1108, 1235, 1337, 1463, 1492, 1509, 1525, 1633, 2206], 'b11%': [1109], 'byproduct': [1113, 1873, 1878], 'isolated.': [1115], 'c10.0': [1116], 'used.': [1121, 1126], 'd1.0': [1122], 'equiv': [1123], 'Zn': [1124], 'After': [1127], 'determining': [1128], 'began': [1133], 'investigate': [1135], 'functional': [1137, 1166, 1701, 2213], 'tolerance': [1139], 'different': [1141], 'Figure': [1148, 1706], '4-iodophenol,': [1152], '4-bromophenol': [1153], 'perform': [1156], 'offered': [1160, 1517], '49%': [1163], 'yield.': [1164, 1579, 1742], 'Various': [1165], 'groups,': [1167], 'ketone': [1169], '4b),': [1171], 'esters': [1172], '4d),': [1176], 'sulfonamide': [1177], '4e),': [1179], 'sulfonyl': [1180], '4f),': [1182], 'cyano': [1183], '4g),': [1185], 'silyl': [1186], 'ether': [1187], '4h),': [1189], 'ethers': [1191], '4i': [1193], '4j),': [1195], 'compatible': [1198, 1556], 'reaction.': [1201, 1590], 'Single-crystal': [1202], 'X-ray': [1203, 2244], 'diffraction': [1204], 'analysis': [1205], 'clearly': [1206], 'confirmed': [1207, 2037], 'structure': [1209], '4d': [1211, 2248], '(CCDC': [1212, 2249], 'no.': [1213, 2250], '1962677)': [1214], 'S2).': [1219, 1707], 'Simple': [1220], 'styrene': [1223], 'underwent': [1224], 'smoothly': [1227, 1832], 'furnish': [1229], '4k–': [1231], '4n': [1232], '57–76%': [1234], 'directly': [1237], 'connected': [1238], 'heteroatoms': [1240], '4o': [1247], '4p).': [1249], 'Moreover,': [1250], 'polycyclic': [1252], 'heterocyclic': [1254], 'substituents,': [1255], 'phthalimide': [1258], '4q),': [1260], 'phenothiazine': [1261], '4r),': [1263], 'benzimidazole': [1264], '4s),': [1266], '4t),': [1269], 'anthraquinone': [1270], '4u),': [1272], 'furan': [1274], '4v),': [1276], 'performed': [1278], 'protocol.': [1282], 'Disubstituted': [1283, 3063], 'gave': [1285], '4w': [1289], '4x)': [1291], 'good': [1293, 1417, 1462, 1508, 1717, 1763, 1838, 2205], 'efficiency.': [1294], 'Substrate': [1298, 1594], 'Scopea': [1299, 1595], 'condition': [1301, 1597], '(unless': [1302, 1598], 'otherwise': [1303, 1599], 'specified):': [1304, 1600], 'bX': [1338], 'Br.': [1340], 'cYield': [1341, 1636], 'after': [1346, 1641], 'tert-butylchlorodimethylsilane': [1348], 'protection': [1349], '(TBSCl)': [1350], 'protection.': [1351, 1644], 'capable': [1354], 'functionalizing': [1356], 'into': [1359, 1696, 2110, 2128], 'related': [1360], 'analogues': [1361], 'without': [1362, 1907], 'resorting': [1363], 'de': [1365], 'novo': [1366], 'offers': [1368], 'aroused': [1377], 'widespread': [1378], 'interest': [1379, 2260], 'academia': [1381], 'pharmaceutical': [1384], 'industry.4,59': [1385], 'illustrate': [1387], 'practicality': [1391], 'method,': [1394], 'turned': [1396], 'our': [1397], 'attention': [1398], 'modifying': [1400], '4y–': [1408], '4as),': [1409], 'moderate': [1415, 1460, 2203], 'yields': [1418, 1764, 1904], '2b).': [1420, 1766], 'Subsequently,': [1421, 2104], 'iodides': [1423, 2191], 'checked': [1427], 'expand': [1429], 'electrical': [1436], 'properties': [1437], 'steric': [1439], 'hindrance': [1440], 'no': [1444, 2257], 'obvious': [1445], 'influence': [1446], 'conversion': [1449, 1689], 'reaction,': [1453, 1480], '5b–': [1457], '5m': [1458], 'It': [1464], 'worth': [1466], 'noting': [1467], '2-iodophenol': [1469], 'malonate': [1471], 'diesters-substituted': [1472], 'iodide': [1474], 'suitable': [1477], '5n': [1482], '5o': [1484], 'isolated': [1487], '62%': [1489], '41%': [1491], 'Indolines': [1493], '3b–': [1495], '3e)': [1496], 'tetrahydroquinolines': [1498], '3f–': [1500], '3h)': [1501], '6b–': [1505], '6h': [1506], 'Benzomorpholine': [1510], '3i),': [1512], 'N-acetyl-substituted': [1513], 'tetrahydroquinoxaline': [1514], '3j)': [1516], '6i': [1518], '6j': [1520], '67%': [1522], '51%': [1524, 1578], 'Acyclic': [1526], 'N-methylaniline': [1527], '3k)': [1529], 'simple': [1531], 'aniline': [1532], '3l)': [1534], 'took': [1536], 'part': [1537], 'transformation.': [1540], 'amines,': [1544], 'sulfonamides': [1545], '3m': [1547], '3n)': [1549], 'morpholin-4-amine': [1551], '3o)': [1553], 'system.': [1560], 'subjection': [1563], '2-(allyloxy)aniline': [1565], '7)': [1567], 'deliver': [1571, 2123], 'medium': [1573], 'ring': [1574], 'compound': [1575, 1727, 1738, 1898], 'At': [1580], 'present,': [1581], 'alkylamines': [1583], 'still': [1585], 'challenging': [1586], 'substrates': [1587], '3': [1592, 1607, 2056], 'b25': [1634], '°C.': [1635], 'TBSCl': [1643], 'Further': [1645, 1680, 1773], 'application': [1646], 'values': [1647], 'protocol': [1650], 'next': [1652], '2).': [1655, 1886], 'Initially,': [1656, 2087], 'gram-scale': [1658], '4q': [1661, 1684, 1725], '(1.21': [1662], 'g)': [1663], 'obtained': [1665], '77%': [1667], '3.8': [1671], 'mmol': [1672], 'scale': [1673], 'standard': [1676], '2a).': [1679], 'showcased': [1686], 'phenol': [1693, 1962], 'hydroxy': [1694], 'moieties': [1695], 'portfolio': [1698], 'useful': [1700], 'groups': [1702, 2214], 'Compound': [1708, 2403], 'containing': [1710], 'indole': [1712], 'framework': [1713], 'afforded': [1715], 'oxidation': [1721], 'condition.': [1722], 'Trifluoromethansulfonylation': [1723], 'provided': [1726], '87%': [1730], 'yield,': [1731], 'easily': [1735], '80%': [1741], 'Additionally,': [1743], 'subjecting': [1744], 'Pd-catalyzed': [1748], 'Suzuki': [1751], 'coupling': [1752], 'lead': [1755], 'compounds': [1758], '(a': [1770], 'b)': [1772], 'studies.': [1774, 2060], '(a)': [1775], 'PhI(OAc)2,': [1776], 'r.t.': [1778, 1783, 1789], '(b)': [1779], 'Tf2O,': [1780], 'Et3N,': [1781], '(c)': [1784], 'Pd/C,': [1785], 'Et2NH,': [1786], 'H2,': [1787], 'MeOH,': [1788], '(d)': [1790], 'Phenylboronic': [1791], 'acid,': [1792], 'trimethylamine,': [1793], 'Pd(OAc)2,': [1794, 1803], 'PPh3,': [1795, 1804], 'H2O,': [1796], 'argon.': [1799, 1810], '(e)': [1800], 'Methyl': [1801], 'acrylate,': [1802], 'K2CO3,': [1805], 'toluene,': [1806], '110': [1807], 'better': [1816], 'clarify': [1817], 'pathway,': [1820], 'designed': [1822], 'carried': [1824, 1979], 'out': [1825, 1980], 'some': [1826], 'verification': [1827], 'experiments.': [1828, 2230], 'occurred': [1831], 'give': [1834, 2133], 'presence': [1842], '2,2,6,6-tetramethyl-1-piperinedinyloxy': [1844], '(TEMPO)': [1845], 'butylated': [1847], 'hydroxytoluene': [1848], '(BHT),': [1849], 'excluded': [1851], 'possibility': [1853], 'radical': [1856], 'pathway': [1857, 2077], '3a).': [1859], 'when': [1862], 'iodobenzene': [1863], '14': [1864], '4-methoxybenzenediazonium': [1866], 'tetrafluoroborate': [1867], '16': [1868], 'tested,': [1870], 'only': [1871, 1992], '15': [1874], 'cross-coupling': [1877], '17': [1879], 'formed': [1881], '3b,': [1883, 1910], 'Afterward,': [1887], 'intermediate': [1890, 2115, 2124, 2135, 2148], '18': [1891], 'synthesized': [1893, 2201], 'examined,': [1895], 'delivering': [1896], '19': [1899], '88%': [1901], '91%': [1903], '3),': [1911], 'illustrated': [1913], 'likely': [1919], 'key': [1921], 'exclude': [1925], "palladium's": [1926], 'bond': [1930, 2113], 'formation.': [1931], 'explore': [1934], 'process,': [1936], '(but-3-en-1-yl-4,4-d2)benzene': [1937], '1l-D': [1938, 1987], 'added': [1940], 'yielded': [1945], '4l-D': [1948, 1998], '61%': [1950], 'approximately': [1953], '44%': [1954], 'deuterium': [1955], 'atom': [1956], 'transferred': [1957], 'β-position': [1960], 'framework.': [1963], 'result': [1965], 'β-H': [1970, 2042], 'elimination': [1971, 2121], 'reinsertion': [1973, 2016], 'steps': [1974], '3c).': [1976], 'Next,': [1977], 'crossover': [1982], 'substrates,': [1990], 'observed,': [2000], 'indicating': [2001], 'coordination': [2004], 'between': [2005], 'catalysts': [2007], 'dissociated': [2013], 'before': [2014], 'formation': [2020], 'final': [2023], '3d).': [2026], 'Finally,': [2027], 'kinetic': [2030], 'isotopic': [2031], 'effect': [2032], 'value': [2033], '1.13,': [2035], 'elimination/migratory': [2043], 'insertion': [2044, 2106], 'might': [2045], 'participated': [2048], 'rate-determining': [2051], 'step': [2052], '3e).': [2054], '(a–e)': [2058], 'Mechanistic': [2059, 3822], 'Based': [2065, 2547], 'literature': [2068], 'reports42–53,60–64': [2069], 'mechanistic': [2072], 'study': [2073], 'experiments,': [2074], 'proposed': [2076, 2225], '4.': [2086, 2414], 'species': [2091, 2102, 2130], 'reacts': [2092], 'oxidative': [2097], 'produce': [2100], 'arylpalladium': [2101], 'I.': [2103], 'migratory': [2105], 'Pd–Ar': [2112], 'generates': [2114], 'II,': [2116], 'undergoes': [2118], 'selective': [2119], 'β-Ha': [2120], 'III.60,61': [2125], 'PdHa': [2126], 'reinserts': [2127], 'III': [2131], 'benzylpalladium': [2134], 'IV.42–53': [2136], 'base-assisted': [2138], 'electron': [2139], 'transfer': [2140], 'process62–64': [2141], 'V,': [2149], 'aza-1,6-Michael': [2155], 'form': [2161], 'desired': [2163], '4a.': [2167], '4': [2169], 'Proposed': [2171], 'mechanism.': [2172], 'Conclusion': [2177], 'realized': [2180], 'terminal': [2186], 'phenol-derived': [2189], 'N-nucleophiles.': [2193], 'Diverse': [2194], 'synthetically': [2195], 'flexible': [2196], 'adopted': [2209], 'broad-spectrum': [2211], 'boasted': [2216], 'scope.': [2220], 'reasonable': [2222], 'mechanism': [2223], 'based': [2226], 'multiple': [2228], 'available,': [2236], 'experiment': [2239], 'procedures,': [2240], 'NMR': [2241], 'spectra,': [2242], 'crystallographic': [2245], 'data': [2246], '1962677).': [2251], 'Conflict': [2252], 'Interest': [2254], 'There': [2255], 'conflict': [2258], 'report.': [2262], 'Acknowledgments': [2263], 'research': [2265, 3891], 'supported': [2267, 3893], 'National': [2270, 2278, 3896, 3904], 'Science': [2271, 2279, 3897, 3905], 'Foundation': [2272, 2308, 3898, 3934], '(no.': [2275, 2292, 2320, 3901, 3918, 3946], '22071267),': [2276, 3902], 'Technology': [2281, 3907], 'Major': [2282, 3908], 'Project': [2283, 2312, 3909, 3938], '"Key': [2284, 3910], 'New': [2285, 3911], 'Drug': [2286, 2438, 3912], 'Creation': [2287, 3913], 'Manufacturing': [2289, 3915], 'Program,"': [2290, 3916], '2020ZX09201015),': [2293, 3919], 'Innovation': [2295, 3921], 'Team': [2296, 3922], '"Double-First': [2299, 3925], 'Class': [2300, 3926], 'Initiative"': [2301, 3927], '(nos.': [2302, 3928], 'CPU2018GY04': [2303, 3929], 'CPU2018GY35),': [2305, 3931], 'SKLNMZZ202023).': [2321, 3947], 'authors': [2323, 3949], 'sincerely': [2325, 3951], 'thank': [2326, 3952], 'Dr.': [2327, 3953], 'Timothy': [2328, 3954], 'Barnes': [2329, 3955], '(Auburn': [2330, 3956], 'University)': [2331, 3957], 'helpful': [2333, 3959], 'suggestions': [2334, 3960], 'preparing': [2336, 3962], 'manuscript.': [2338, 3964], 'References': [2339], '1.': [2340], 'Hili': [2341], 'R.;': [2342, 2467, 2602, 2710, 3021, 3510], 'Yudin': [2343], 'A.': [2344, 2391, 2426, 2709, 2748, 3278], 'K.Making': [2345], 'Carbon-Nitrogen': [2346], 'Bonds': [2347, 2508, 3691], 'Biological': [2349, 3853], 'Chemical': [2351, 3888], 'Synthesis.Nat.': [2352], 'Chem.': [2353, 2899, 2919, 3011, 3039, 3067, 3095, 3156, 3182, 3203, 3270, 3310, 3332, 3356, 3387, 3416, 3440, 3458, 3496, 3549, 3619, 3773, 3805, 3832, 3867], 'Biol.2006,': [2354], '2,': [2355, 3575, 3699], '284–287.': [2356], 'Google': [2357, 2381, 2412, 2443, 2462, 2479, 2496, 2515, 2538, 2556, 2579, 2598, 2622, 2641, 2660, 2685, 2705, 2724, 2744, 2763, 2780, 2800, 2822, 2859, 2879, 2903, 2924, 2948, 2971, 2986, 3016, 3043, 3071, 3100, 3128, 3160, 3186, 3207, 3224, 3245, 3274, 3292, 3314, 3336, 3361, 3391, 3420, 3445, 3462, 3500, 3523, 3553, 3577, 3594, 3624, 3652, 3674, 3701, 3730, 3748, 3777, 3809, 3836, 3871], 'Scholar': [2358, 2382, 2413, 2444, 2463, 2480, 2497, 2516, 2539, 2557, 2580, 2599, 2623, 2642, 2661, 2686, 2706, 2725, 2745, 2764, 2781, 2801, 2823, 2860, 2880, 2904, 2925, 2949, 2972, 2987, 3017, 3044, 3072, 3101, 3129, 3161, 3187, 3208, 3225, 3246, 3275, 3293, 3315, 3337, 3362, 3392, 3421, 3446, 3463, 3501, 3524, 3554, 3578, 3595, 3625, 3653, 3675, 3702, 3731, 3749, 3778, 3810, 3837, 3872], '2.': [2359], 'J.': [2361, 2365, 2502, 2713, 3023, 3026, 3683, 3816], 'W.': [2362, 2607], 'H.;': [2363, 2786, 2975, 2990, 3166, 3397, 3600, 3608, 3630, 3782, 3814], 'Vederas': [2364], 'C.Drug': [2366], 'Discovery': [2367], 'Products:': [2370], 'End': [2371], 'Era': [2374], 'Endless': [2377], 'Frontier?Science2009,': [2378], '325,': [2379], '161–165.': [2380], '3.': [2383], 'Richter': [2384], 'M.': [2385, 2469, 2524, 2587, 2610, 3283, 3298, 3427, 3452, 3468, 3478, 3512, 3529, 3537, 3755, 3789, 3819, 3849], 'F.;': [2386, 2730, 3077, 3136], 'Drown': [2387], 'B.': [2388, 3368, 3846], 'S.;': [2389, 2646, 2668, 2692, 2866, 3049, 3110, 3678, 3710], 'Riley': [2390], 'P.;': [2392, 2483, 2734, 2868, 3079, 3140, 3257, 3712, 3785, 3841], 'Garcia': [2393], 'A.;': [2394, 2500, 2519, 2583, 2694, 2696, 2728, 2952, 3281], 'Shirai': [2395], 'T.;': [2396, 2542, 2732, 2828, 2994, 3024, 3051, 3211, 3255, 3323, 3658, 3705], 'Svec': [2397], 'R.': [2398, 2712, 2841, 2863, 3231, 3235, 3322], 'L.;': [2399, 2419, 2810, 3134, 3168, 3172, 3194, 3506, 3656], 'Hergenrother': [2400], 'P.': [2401, 2835, 3737], 'J.Predictive': [2402], 'Accumulation': [2404], 'Rules': [2405], 'Yield': [2406], 'Broad-Spectrum': [2408], 'Antibiotic.Nature2017,': [2409], '545,': [2410], '299–304.': [2411], 'Blakemore': [2415], 'D.': [2416, 2423, 2429, 2809, 3020], 'C.;': [2417, 2424, 3174, 3232, 3343, 3399, 3561, 3583], 'Castro': [2418], 'Churcher': [2420], 'I.;': [2421, 2805], 'Rees': [2422], 'Thomas': [2425], 'W.;': [2427, 2992, 3581, 3606, 3636, 3753], 'Wilson': [2428], 'M.;': [2430, 2522, 2749, 2839, 3229, 3366, 3471, 3527, 3844], 'Wood': [2431], 'A.Organic': [2432], 'Synthesis': [2433, 2531, 2589, 2816, 2849, 3034, 3059, 3564, 3665], 'Provides': [2434], 'Opportunities': [2435], 'Transform': [2437], 'Discovery.Nat.': [2439], 'Chem.2018,': [2440], '10,': [2441, 2798, 3650], '383–394.': [2442], '5.': [2445], 'Bariwal': [2446], 'J.;': [2447, 2605, 2837, 3340, 3371, 3395, 3469, 3530, 3681], 'Van': [2448], 'der': [2449], 'Eycken': [2450], 'E.C–N': [2451], 'Bond': [2452, 2633, 2892], 'Forming': [2453, 2893], 'Cross-Coupling': [2454], 'Reactions:': [2455], 'An': [2456], 'Overview.Chem.': [2457], 'Soc.': [2458, 2552, 2575, 2637, 2740, 2855, 2944, 2967, 2982, 3726, 3744], 'Rev.2013,': [2459], '42,': [2460], '9283–9303.': [2461], '6.': [2464], 'Chemler': [2465], 'S.': [2466, 2485, 2521, 3190, 3714], 'Bovino': [2468], 'T.Catalytic': [2470], 'Aminohalogenation': [2471], 'Alkynes.ACS': [2475], 'Catal.2013,': [2476], '3,': [2477, 3592], '1076–1091.': [2478], '7.': [2481], 'Ruiz-Castillo': [2482], 'Buchwald': [2484], 'L.Applications': [2486], 'C-N': [2489, 2632], 'Cross': [2490], 'Coupling': [2491], 'Reactions.Chem.': [2492, 3743], 'Rev.2016,': [2493, 2553, 2576, 2741, 3727], '116,': [2494], '12564–12649.': [2495], '8.': [2498], 'Sharma': [2499], 'Hartwig': [2501], 'F.Metal-Catalysed': [2503], 'Azidation': [2504], 'Tertiary': [2506, 2591, 2617], 'C-H': [2507], 'Suitable': [2509], 'Late-Stage': [2511], 'Functionalization.Nature2015,': [2512], '517,': [2513], '600–604.': [2514], '9.': [2517], 'Trowbridge': [2518, 2582], 'Walton': [2520], 'Gaunt': [2523, 2586, 2609], 'J.New': [2525], 'Strategies': [2526, 2546], 'Transition-Metal': [2529], 'Catalyzed': [2530], 'Aliphatic': [2533], 'Amines.Chem.': [2534, 2854], 'Rev.2020,': [2535, 2856, 2945, 2983], '120,': [2536], '2613–2692.': [2537], '10.': [2540], 'Xiong': [2541, 2993], 'Q.New': [2544], 'Amination': [2545, 2615, 2813], 'Nitrogen-Centered': [2549], 'Radical': [2550, 2573, 2653, 2938, 2978, 3093], 'Chemistry.Chem.': [2551], '45,': [2554, 2577, 2742, 3728], '3069–3087.': [2555], '11.': [2558], 'Chen': [2559, 2665, 3048, 3078, 3139], 'J.-R.;': [2560], 'Hu': [2561], 'X.-Q.;': [2562], 'Lua': [2563], 'L.-Q.;': [2564], 'Xiao': [2565, 3661], 'W.-J.Visible': [2566], 'Light': [2567], 'Photoredox-Controlled': [2568], 'Reactions': [2569, 2793, 3031], 'N-Radicals': [2571], 'Ions.Chem.': [2574], '2044–2056.': [2578], '12.': [2581], 'Reich': [2584], 'D.;': [2585, 2909, 3075, 3132, 3279, 3296, 3346, 3369, 3401, 3476, 3535, 3559, 3602, 3632, 3708, 3735, 3817], 'J.Multicomponent': [2588], 'Alkylamines': [2592], 'Photocatalytic': [2594], 'Olefin-Hydroaminoalkylation.Nature2018,': [2595], '561,': [2596], '522–527.': [2597], '13.': [2600], 'Kumar': [2601], 'Flodén': [2603], 'N.': [2604], 'Whitehurst': [2606], 'G.;': [2608, 2883], 'J.A': [2611], 'General': [2612, 3760], 'Carbonyl': [2613, 3354], 'Alkylative': [2614], 'Amine': [2618], 'Synthesis.Nature2020,': [2619], '581,': [2620], '415–420.': [2621], '14.': [2624], 'Zhao': [2625], 'Y.;': [2626, 2664, 2666, 2907, 2996, 3164, 3251, 3318, 3598, 3610, 3628, 3787], 'Xia': [2627], 'W.Recent': [2628], 'Advances': [2629, 2935], 'Radical-Based': [2631], 'Formation': [2634], 'Photo-/Electrochemistry.Chem.': [2636], 'Rev.2018,': [2638], '47,': [2639], '2591–2608.': [2640], '15.': [2643], 'Sauer': [2644, 2690], 'G.': [2645, 2691], 'S.An': [2648], 'Electrocatalytic': [2649], 'Approach': [2650], 'Difunctionalization': [2654, 2889, 3431, 3829, 3864], 'Alkenes.ACS': [2656], 'Catal.2018,': [2657], '8,': [2658, 3126, 3672], '5175–5187.': [2659], '16.': [2662], 'Yuan': [2663], 'Tang': [2667, 3167, 3169], 'Huang': [2669], 'Z.;': [2670, 3081, 3142, 3249, 3253, 3320, 3557, 3604, 3634], 'Lei': [2671], 'A.Electrochemical': [2672], 'Oxidative': [2673, 2888, 3350, 3429, 3765], 'Oxysulfenylation': [2674], 'Aminosulfenylation': [2676], 'Hydrogen': [2680, 2847], 'Evolution.Sci.': [2681], 'Adv.2018,': [2682], '4,': [2683], 'eaat5312.': [2684], '17.': [2687], 'N.;': [2689, 3191], 'Saha': [2693], 'Loo': [2695], 'S.Metal-Catalyzed': [2698], 'Electrochemical': [2699], 'Diazidation': [2700], 'Alkenes.Science2017,': [2702], '357,': [2703], '575–579.': [2704], '18.': [2707], 'Taylor': [2708], 'Katritzky': [2711], 'K.Comprehensive': [2714], 'Organic': [2715], 'Functional': [2716], 'Group': [2717], 'Transformations': [2718], 'II;': [2719], 'Elsevier:': [2720], 'Oxford,': [2721], 'U.K.,': [2722], '2005.': [2723], '19.': [2726], 'Volkov': [2727], 'Tinnis': [2729], 'Slagbrand': [2731], 'Trilloa': [2733], 'Adolfsson': [2735], 'H.Chemoselective': [2736], 'Reduction': [2737], 'Carboxamides.Chem.': [2739, 2759], '6685–6697.': [2743], '20.': [2746], 'Smith': [2747], 'Whyman': [2750], 'R.Review': [2751], 'Hydrogenation': [2757], 'Rev.2014,': [2760], '114,': [2761], '5477–5510.': [2762], '21.': [2765], 'Bloch': [2766], 'R.Additions': [2767], 'Organometallic': [2769], 'Reagents': [2770, 3239], 'C=N': [2772], 'Bonds:': [2773], 'Reactivity': [2774], 'Selectivity.Chem.': [2776], 'Rev.1998,': [2777], '98,': [2778], '1407–1438.': [2779], '22.': [2782], 'Morisaki': [2783], 'K.;': [2784, 2826, 2833, 2864, 3000], 'Morimoto': [2785], 'Ohshima': [2787], 'T.Recent': [2788], 'Progress': [2789], 'Addition': [2792, 3792], 'N-Unsubstituted': [2795], 'Imines.ACS': [2796], 'Catal.2020,': [2797, 3591, 3649], '6924–6951.': [2799], '23.': [2802], 'Afanasyev': [2803], 'O.': [2804], 'Kuchuk': [2806], 'E.;': [2807, 3466, 3532, 3847], 'Usanov': [2808], 'Chusov': [2811], 'D.Reductive': [2812], 'Pharmaceuticals.Chem.': [2818], 'Rev.2019,': [2819], '119,': [2820], '11857–11911.': [2821], '24.': [2824], 'Murugesan': [2825], 'Senthamarai': [2827], 'Chandrashekhar': [2829], 'V.': [2830], 'G;': [2831], 'Natte': [2832], 'Kamer': [2834], 'C.': [2836, 3234], 'Beller': [2838], 'Jagadeesh': [2840], 'V.Catalytic': [2842], 'Reductive': [2843], 'Aminations': [2844], 'Using': [2845], 'Molecular': [2846, 3438], 'Different': [2851], 'Kinds': [2852], '49,': [2857, 2901, 2946, 2984], '6273–6328.': [2858], '25.': [2861], 'Dhungana': [2862], 'KC': [2865], 'Basnet': [2867], 'Giri': [2869], 'R.Transition': [2870], 'Metal-Catalyzed': [2871], 'Dicarbofunctionalization': [2872], 'Unactivated': [2874, 3179, 3264, 3408, 3571, 3589, 3642], 'Olefins.Chem.': [2875], 'Rec.2018,': [2876], '18,': [2877], '1314–1340.': [2878], '26.': [2881], 'Mu': [2884], 'X.;': [2885, 2998, 3053, 3138, 3660], 'Liu': [2886, 2933, 3001, 3082, 3103, 3143, 3165, 3248, 3256], 'G.Palladium(II)-Catalyzed': [2887], 'Alkenes:': [2891, 3377], 'High-Valent': [2896], 'Palladium': [2897, 3413, 3761], 'Center.Acc.': [2898], 'Res.2016,': [2900], '2413–2423.': [2902], '27.': [2905], 'Wu': [2908, 3133, 3558, 3601, 3631], 'Cheng': [2910], 'H.-G.;': [2911], 'G.Difunctionalization': [2913], 'Involving': [2916], 'Metal': [2917], 'Migration.Angew.': [2918], 'Int.': [2920, 3012, 3096, 3357, 3441, 3620], 'Ed.2020,': [2921], '59,': [2922], '7990–8003.': [2923], '28.': [2926], 'Z.-L.;': [2928], 'Fang': [2929], 'G.-C.;': [2930], 'Gu': [2931], 'Q.-S.;': [2932], 'X.-Y.Recent': [2934], 'Copper-Catalysed': [2937], 'Involved': [2939], 'Asymmetric': [2940, 3739], '1,2-Difunctionalization': [2941], 'Alkenes.Chem.': [2943, 2981], '32–48.': [2947], '29.': [2950], 'Minatti': [2951], 'Muñiz': [2953], 'K.Intramolecular': [2954], 'Aminopalladation': [2955], 'Step': [2961], 'Pyrrolidines': [2963], 'Related': [2965, 3742], 'Heterocycles.Chem.': [2966], 'Rev.2007,': [2968], '36,': [2969], '1142–1152.': [2970], '30.': [2973], 'Jiang': [2974], 'Studer': [2976], 'A.Intermolecular': [2977], 'Carboamination': [2979, 3030, 3056, 3177, 3199, 3262], '1790–1811.': [2985], '31.': [2988], 'Pu': [2991], 'Zhou': [2997], 'Sun': [2999], 'Q.;': [3002, 3508], 'Q.Copper-Catalyzed': [3004], 'Intermolecular': [3005, 3085, 3146, 3261, 3430], 'Aminocyanation': [3006], 'Diamination': [3008], 'Alkenes.Angew.': [3010, 3618], 'Ed.2013,': [3013], '52,': [3014], '2529–2533.': [3015], '32.': [3018], 'White': [3019], 'Hutt': [3022], 'Wolfe': [3025], 'P.Asymmetric': [3027], 'Pd-Catalyzed': [3028, 3303], 'Alkene': [3029, 3241, 3828, 3863], '2-Aminoindane': [3036], 'Derivatives.J.': [3037], 'Am.': [3038, 3066, 3155, 3181, 3202, 3269, 3309, 3331, 3386, 3415, 3457, 3495, 3548, 3772, 3804, 3831, 3866], 'Soc.2015,': [3040, 3333, 3388], '137,': [3041, 3334, 3389], '11246–11249.': [3042], '33.': [3045], 'Qian': [3046], 'B.;': [3047, 3425, 3662], 'Wang': [3050, 3074, 3076, 3131, 3135, 3171, 3250, 3252, 3507, 3580, 3605, 3635], 'Bao': [3054], 'H.Iron-Catalyzed': [3055], 'Olefins:': [3058], 'Amines': [3061, 3120, 3685], 'β-Amino': [3064], 'Acids.J.': [3065], 'Soc.2017,': [3068, 3157, 3271, 3550], '139,': [3069, 3158, 3272, 3551], '13076–13082.': [3070], '34.': [3073], 'G.Enantioselective': [3083], 'Copper-Catalyzed': [3084, 3145], 'Amino-': [3086], 'Azidocyanation': [3088], 'Process.Angew.': [3094], 'Ed.2017,': [3097], '56,': [3098], '2054–2058.': [3099], '35.': [3102], 'Y.-Y.;': [3104], 'Yang': [3105, 3319], 'X.-H.;': [3106], 'Song': [3107], 'R.-J.;': [3108], 'Luo': [3109], 'J.-H.Oxidative': [3112], '1,2-Carboamination': [3113], 'Alkyl': [3117, 3123], 'Nitriles': [3118], 'γ-Amino': [3122], 'Nitriles.Nat.': [3124], 'Commun.2017,': [3125, 3671], '14720.': [3127], '36.': [3130], 'Wan': [3137], 'G.Asymmetric': [3144], 'Aminoarylation': [3147], 'Styrenes:': [3149], 'Efficient': [3150], 'Access': [3151], 'Optical': [3153], '2,2-Diarylethylamines.J.': [3154], '6811–6814.': [3159], '37.': [3162], 'H.-J.;': [3170], 'Zhu': [3173], 'Feng': [3175], 'C.Intermolecular': [3176], 'Alkenes.J.': [3180, 3201, 3308], 'Soc.2018,': [3183, 3204], '140,': [3184, 3205], '10695–10699.': [3185], '38.': [3188], 'Gockel': [3189], 'Buchanan': [3192], 'T.': [3193, 3228, 3680, 3784, 3840], 'Hull': [3195], 'K.': [3196, 3259, 3424, 3707, 3781, 3813, 3843], 'L.Cu-Catalyzed': [3197], 'Three-Component': [3198], '58–61.': [3206], '39.': [3209], 'Rovis': [3212], 'T.Rhodium-Catalysed': [3213], 'Syn-Carboamination': [3214], 'Transient': [3219], 'Directing': [3220], 'Group.Nature2015,': [3221], '527,': [3222], '86–90.': [3223], '40.': [3226], 'Monos': [3227], 'McAtee': [3230], 'J.Arylsulfonylacetamides': [3236], 'Bifunctional': [3238], 'Aminoarylation.Science2018,': [3242], '361,': [3243], '1369–1373.': [3244], '41.': [3247], 'Zeng': [3254], 'M.Catalytic': [3260], 'Directed': [3267], 'Aminopalladation.J.': [3268], '11261–11270.': [3273], '42.': [3276], 'Satterfield': [3277], 'Kubota': [3280], 'S.Palladium-Catalyzed': [3284, 3428, 3453, 3790], '1,1-Aryloxygenation': [3285], 'Olefins.Org.': [3288], 'Lett.2011,': [3289], '13,': [3290], '1076–1079.': [3291], '43.': [3294], 'Kalyani': [3295], 'S.Oxidatively': [3299], 'Intercepting': [3300], 'Intermediates:': [3302], '1,2-': [3304], '1,1-Arylhalogenation': [3306], 'Soc.2008,': [3311], '130,': [3312], '2150–2151.': [3313], '44.': [3316], 'He': [3317], 'Thornbury': [3321], 'F.': [3325, 3345, 3373, 3475, 3534], 'D.Palladium-Catalyzed': [3326], 'Enantioselective': [3327, 3485, 3543, 3586, 3791, 3826, 3862], '1,1-Fluoroarylation': [3328], 'Aminoalkenes.J.': [3330], '12207–12210.': [3335], '45.': [3338], 'Mirý': [3339], 'del': [3341], 'Pozo': [3342], 'Fustero': [3347], 'S.Enantioselective': [3348], 'β,β-Fluoroarylation': [3351], 'α,β-Unsaturated': [3353], 'Derivatives.Angew.': [3355], 'Ed.2016,': [3358], '55,': [3359], '9045–9049.': [3360], '46.': [3363], 'Nelson': [3364], 'H.': [3365], 'Williams': [3367], 'Miro': [3370], 'D.Enantioselective': [3374], '1,1-Arylborylation': [3375], 'Merging': [3378], 'Chiral': [3379, 3491], 'Anion': [3380, 3492], 'Phase': [3381, 3493], 'Transfer': [3382], 'Pd': [3384], 'Catalysis.J.': [3385, 3414], '3213–3216.': [3390], '47.': [3393], 'Jeon': [3394], 'Ryu': [3396], 'Lee': [3398], 'Cho': [3400], 'Baik': [3402], 'M.-H.;': [3403], 'S.Site-Selective': [3405], '1,1-Difunctionalization': [3406, 3454, 3640], 'Enabled': [3410, 3489], 'Cationic': [3412], 'Soc.2019,': [3417], '141,': [3418], '10048–10059.': [3419], '48.': [3422], 'Urkalan': [3423], 'Organostannanes': [3436], 'Oxygen.Angew.': [3439], 'Ed.2009,': [3442], '48,': [3443], '3146–3149.': [3444], '49.': [3447], 'Vaneet': [3448], 'Saini': [3449, 3472, 3503], 'V.;': [3450, 3473, 3504], 'Ethylene.J.': [3456], 'Soc.2012,': [3459], '134,': [3460], '11372–11375.': [3461], '50.': [3464], 'Yamamoto': [3465, 3531], 'Hilton': [3467, 3528], 'Orlandi': [3470, 3526], 'S.Development': [3479], 'Analysis': [3481], 'Pd(0)-Catalyzed': [3484, 3542], '1,1-Diarylation': [3486, 3514, 3544, 3569], 'Acrylates': [3488], 'Transfer.J.': [3494], 'Soc.2016,': [3497], '138,': [3498], '15877–15880.': [3499], '51.': [3502], 'Liao': [3505], 'Jana': [3509], 'S.Pd(0)-Catalyzed': [3513], 'Ethylene': [3516], 'Allylic': [3518], 'Carbonates.Org.': [3519], 'Lett.2013,': [3520], '15,': [3521], '5008–5001.': [3522], '52.': [3525], 'S.Mechanistic': [3538], 'Investigations': [3539], 'Benzyl': [3546], 'Acrylates.J.': [3547], '12688–12695.': [3552], '53.': [3555], 'Ding': [3560, 3582], 'G.Modular': [3563], 'Diarylalkanes': [3566], 'Nickel-Catalyzed': [3568], 'Alkenes.CCS': [3573], 'Chem.2020,': [3574], '576–582.': [3576], '54.': [3579], 'G.Catalyst-Controlled': [3585], '1,1-Arylboration': [3587], 'Olefins.Nat.': [3590], '951–958.': [3593], '55.': [3596], 'Pang': [3599], 'Wei': [3607, 3629], 'G.Nickel-Catalyzed': [3612, 3638], '1,1-Alkylboration': [3613], 'Electronically': [3615, 3769], 'Unbiased': [3616], 'Ed.2019,': [3621], '58,': [3622], '8872–8876.': [3623], '56.': [3626], 'Chemodivergent': [3639], 'α-Olefins': [3643], 'Alkynyl': [3645], 'Electrophiles': [3646], 'B2pin2.ACS': [3648], '4888–4894.': [3651], '57.': [3654], 'Gong': [3657], 'Lu': [3659], 'Y.Nickel-Catalyzed': [3664], '1,1-Diborylalkanes': [3667], 'Alkenes.Nat.': [3670, 3697], '345.': [3673], '58.': [3676], 'Maity': [3677], 'Potter': [3679], 'A.α-Branched': [3684], '1,1-Addition': [3688], 'C–H': [3690], 'Aminating': [3693], 'Agents': [3694], 'Catal.2019,': [3698], '756–762.': [3700], '59.': [3703], 'Cernak': [3704], 'Dykstra': [3706], 'Tyagarajan': [3709], 'Vachal': [3711], 'Krska': [3713], 'W.The': [3715], "Chemist's": [3717], 'Toolbox': [3718], 'Late': [3720], 'Stage': [3721], 'Functionalization': [3722], 'Drug-like': [3724], 'Molecules.Chem.': [3725], '546–576.': [3729], '60.': [3732], 'Mc': [3733], 'Cartney': [3734], 'Guiry': [3736], 'J.The': [3738], 'Rev.2011,': [3745], '40,': [3746], '5122–5150.': [3747], '61.': [3750], 'Werner': [3751], 'E.': [3752], 'S.A': [3756], 'Highly': [3757], 'Selective': [3758], 'Catalyst': [3762], 'Nonbiased': [3770], 'Olefins.J.': [3771], 'Soc.2010,': [3774, 3833, 3868], '132,': [3775, 3834, 3869], '13981–13983.': [3776], '62.': [3779], 'Jensen': [3780, 3812], 'Pathak': [3783, 3839], 'Two': [3794], 'Distinct': [3795], 'Nucleophiles': [3796], 'across': [3797], 'Capable': [3799], 'Quinone': [3801], 'Methide': [3802], 'Formation.J.': [3803], 'Soc.2009,': [3806], '131,': [3807], '17074–17075.': [3808], '63.': [3811], 'Webb': [3815], 'S.Advancing': [3820], 'Understanding': [3823], 'Reaction.J.': [3830, 3865], '17471–17482.': [3835], '64.': [3838], 'Gligorich': [3842], 'Welm': [3845], 'S.Synthesis': [3850], 'Preliminary': [3852], 'Studies': [3854], '3-Substituted': [3856], 'Indoles': [3857], 'Accessed': [3858], '7870–7871.': [3870], 'Previous': [3873], 'articleNext': [3874], 'article': [3875], 'FiguresReferencesRelatedDetails': [3876], 'Issue': [3877], 'AssignmentVolume': [3878], '4Issue': [3879], '2Page:': [3880], '616-624Supporting': [3881], 'Copyright': [3883], '&': [3884], 'Permissions©': [3885], '2021': [3886], 'Chinese': [3887], 'SocietyKeywordspalladium-catalyzednitrogen-containing': [3889], 'moleculesalkenesite-selective1,1-arylaminationAcknowledgmentsThis': [3890], 'Downloaded': [3965], '1,645': 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