Title: Recent Application of Chiral Aryliodine Based on the 2-Iodoresorcinol Core in Asymmetric Catalysis
Abstract: Abstract Chiral iodoarenes have been steadily increasing in importance in recent years, especially in enantioselective synthesis and catalysis. Since the development of the concept of chiral iodine(I/III) catalysis, the use of various chiral aryliodine frameworks has been explored in this area. This short review gives an overview of the use of chiral hypervalent iodine(I/III) reagents based on the 2-iodoresorcinol core with two attached two lactic side chains bearing ester or amide groups for the catalytic enantioselective dearomatization of phenol compounds, asymmetric oxidation of alkenes, and enantioselective α-functionalization of carbonyl compounds highlighting the excellent reactivities in terms of yield and enantioselectivity. 1 Introduction 2 Enantioselective Dearomatization of Phenol Derivatives 3 Asymmetric Oxidation of Alkenes 4 Enantioselective α-Functionalization of Carbonyl Compounds 5 Conclusion and Outlook
Publication Year: 2020
Publication Date: 2020-11-12
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 20
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