Selective Synthesis of Phenanthrenes and Dihydrophenanthrenes via Gold-Catalyzed Cycloisomerization of Biphenyl Embedded Trienynes

Name: Work Video:
Duration: 3 min 30 s
Description: Readily available o'-alkenyl-o-alkynylbiaryls, a particular type of 1,7-enynes, undergo a selective cycloisomerization reaction in the presence of a gold(I) catalyst to give interesting phenanthrene and dihydrophenanthrene derivatives in high yields. The solvent used provokes a switch in the evolution of the gold intermediate and plays a key role in the reaction outcome.
Ana Milián; Patricia García‐García; Adrián Pérez‐Redondo; Roberto Sanz; Juan J. Vaquero; Manuel A. Fernández‐Rodríguez
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