Title: Electropolymerization of π-Conjugated Oligomers Containing Phosphole Cores and Terminal Thienyl Moieties: Optical and Electronic Properties
Abstract: Angewandte Chemie International EditionVolume 39, Issue 10 p. 1812-1815 Communication Electropolymerization of π-Conjugated Oligomers Containing Phosphole Cores and Terminal Thienyl Moieties: Optical and Electronic Properties Caroline Hay, Caroline Hay Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this authorCédric Fischmeister Dr., Cédric Fischmeister Dr. Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this authorMuriel Hissler Dr., Muriel Hissler Dr. Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this authorLoic Toupet Dr., Loic Toupet Dr. UMR 6626, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France)Search for more papers by this authorRégis Réau Prof., Régis Réau Prof. [email protected] Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this author Caroline Hay, Caroline Hay Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this authorCédric Fischmeister Dr., Cédric Fischmeister Dr. Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this authorMuriel Hissler Dr., Muriel Hissler Dr. Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this authorLoic Toupet Dr., Loic Toupet Dr. UMR 6626, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France)Search for more papers by this authorRégis Réau Prof., Régis Réau Prof. [email protected] Organométalliques et Catalyse Chimie et Electrochimie Moléculaires UMR 6509, CNRS-Université de Rennes Campus de Beaulieu, 35042 Rennes Cedex (France) Fax: (+33) 2-99286939Search for more papers by this author First published: 15 May 2000 https://doi.org/10.1002/(SICI)1521-3773(20000515)39:10<1812::AID-ANIE1812>3.0.CO;2-DCitations: 128 We thank the CNRS, the MENRT, the Conseil Régional de Bretagne for financial support of this work and Prof. C. Moinet for helpful discussions. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Extended π-conjugated systems and tunable optic properties are characteristic for compounds with linear backbones based on electron-donating thiophene, electron-accepting pyridine, and a σ3,λ3-phosphole core. The oligomers 1 and 2 are fluorescent chromophores and, for 2, these properties are tunable through chemical modification of the phosphorus-bound chalcogen atom. The σ4,λ4 derivatives of 2 are electropolymerized to electroactive polymers. Y=lone electron pair, or O, S, or Se atom. Citing Literature Volume39, Issue10May 15, 2000Pages 1812-1815 RelatedInformation
Publication Year: 2000
Publication Date: 2000-05-15
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 134
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