Title: New Zinc Catalyst for Hydrosilylation of Carbonyl Compounds
Abstract:A new zinc complex was synthesized and applied in the catalytic hydrosilylation of carbonyl compounds. Optimization of the reaction conditions showed that the presence a substoichiometric amount of me...A new zinc complex was synthesized and applied in the catalytic hydrosilylation of carbonyl compounds. Optimization of the reaction conditions showed that the presence a substoichiometric amount of methanol accelerates the process significantly. The reaction can proceed at very low catalyst load (down to 0.1 mol%) under mild reaction conditions. The reaction tolerates the presence of C=C bonds, and thus can be useful for the synthesis of allylic alcohols from α,β-unsaturated aldehydes and ketones.Read More
Publication Year: 2019
Publication Date: 2019-05-07
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 11
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