Title: Activation of Carbon–Hydrogen Bonds via 1,2-RH-Addition/-Elimination to Early Transition Metal Imides
Abstract:A tutorial addressing the activation of carbon–hydrogen bonds via the 1,2-RH-addition to high oxidation state, early metal XnM═NR complexes is described. Details regarding the reverse 1,2-RH-eliminati...A tutorial addressing the activation of carbon–hydrogen bonds via the 1,2-RH-addition to high oxidation state, early metal XnM═NR complexes is described. Details regarding the reverse 1,2-RH-elimination from Xn(R′)M–NHR, are also presented. The overall process is discussed as follows: (1) electrophilicity and electronics; (2) general mechanism; (3) kinetics of 1,2-RH-elimination; (4) periodic trends; (5) alkane complexes; (6) kinetic isotope effects (KIEs); (7) RH activation selectivities; and (8) future directions.Read More
Publication Year: 2018
Publication Date: 2018-02-05
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 46
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