Synthesis of 1-Phosphabarrelene Phosphine Sulfide Substituted Palladium(II) Complexes

Name: Work Video:
Duration: 3 min 30 s
Description: A general Diels-Alder-based synthesis of 1-phosphabarrelenes from substituted phosphinines is reported. Palladium complexes have been prepared which serve as good ligands for cross-coupling reactions and in the allylation of secondary amines with TON up to 7 × 106. X-ray crystal structural analysis and computational data of the complexes are presented.
Oleg M. Demchuk Contributor Victor Snieckus
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