Title: Role of quantum effects in the glass transition
Abstract:It is shown that quantum effects lead to a significant decrease of the glass transition temperature T(g) with respect to the melting temperature T(m), so that the ratio T(g)/T(m) can be much smaller t...It is shown that quantum effects lead to a significant decrease of the glass transition temperature T(g) with respect to the melting temperature T(m), so that the ratio T(g)/T(m) can be much smaller than the typical value of 2/3 in materials where T(g) is near or below ~60 K. Furthermore, it is demonstrated that the viscosity or structural relaxation time in such low temperature glass formers should exhibit highly unusual temperature dependence, namely a decrease of the apparent activation energy upon approaching T(g) (instead of traditional increase).Read More
Publication Year: 2013
Publication Date: 2013-03-22
Language: en
Type: article
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