Title: Polyoxometalates Catalysts for Sustainable Oxidations and Energy Applications
Abstract: Handbook of Advanced Methods and Processes in Oxidation Catalysis, pp. 586-630 (2014) No AccessChapter 21: Polyoxometalates Catalysts for Sustainable Oxidations and Energy ApplicationsMauro CARRARO, Giulia FIORANI, Andrea SARTOREL and Marcella BONCHIOMauro CARRAROITM-CNR and Department of Chemical Sciences, University of Padova, via Marzolo 135131 Padova, Italy, Giulia FIORANIITM-CNR and Department of Chemical Sciences, University of Padova, via Marzolo 135131 Padova, Italy, Andrea SARTORELITM-CNR and Department of Chemical Sciences, University of Padova, via Marzolo 135131 Padova, Italy and Marcella BONCHIOITM-CNR and Department of Chemical Sciences, University of Padova, via Marzolo 135131 Padova, Italyhttps://doi.org/10.1142/9781848167513_0021Cited by:2 PreviousNext AboutSectionsPDF/EPUB ToolsAdd to favoritesDownload CitationsTrack CitationsRecommend to Library ShareShare onFacebookTwitterLinked InRedditEmail Abstract: The aim of this capter is to present an overview on the use of polyoxometalates (POMs) as oxidation catalysts. POMs display several interesting features which make them attractive for condidates for these kinds of applications: (i) their composition mainly includes oxidatively stable d0 early series transition metals; (ii) they can be used as robust inorganic ligands for the coordination of redox active transition metals; (iii) they represent useful platforms for the development of hybrid organic-inorganic compounds, where the organic domain can synergistically contribute to implement the catalytic activity; (iv) their polyanionic nature can be exploited to foster the association with solubilizing organic-inorganic cations or to promote their immobilization onto different solid supports. The chapter will thus be focused on both homogeneous and heterogeneous POM-based oxidations of organic substrates by sustainable oxidants, as dioxygen and hydrogen peroxide, employing different activation techniques, including UV and microwave irradiation. Finally, the structural and mechanistic analogy of some POMs with natural metallo-enzymes has been underlined, as in the case of oxygenase activity and water oxidation catalysis. FiguresReferencesRelatedDetailsCited By 2Organic Solvent-Free Olefins and Alcohols (ep)oxidation Using Recoverable Catalysts Based on [PM12O40]3− (M = Mo or W) Ionically Grafted on Amino Functionalized Silica NanobeadsYun Wang, Florence Gayet, Pascal Guillo and Dominique Agustin9 October 2019 | Materials, Vol. 12, No. 20Recent Progress in Selective Oxidations with Hydrogen Peroxide Catalyzed by PolyoxometalatesOxana A. Kholdeeva2 October 2019 Handbook of Advanced Methods and Processes in Oxidation CatalysisMetrics History PDF download
Publication Year: 2014
Publication Date: 2014-08-04
Language: en
Type: book-chapter
Indexed In: ['crossref']
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Cited By Count: 3
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