Title: Assessment of indoor HONO formation mechanisms based on in situ measurements and modeling
Abstract: Indoor AirVolume 27, Issue 2 p. 443-451 Original Article Assessment of indoor HONO formation mechanisms based on in situ measurements and modeling M. Mendez, Corresponding Author M. Mendez [email protected] Laboratoire Image Ville Environnement - LIVE UMR 7362 CNRS, Université de Strasbourg, Strasbourg, France Laboratoire des Sciences de l'Ingénieur pour l'Environnement - LaSIE, UMR 7356 CNRS, Université de La Rochelle, La Rochelle, France Correspondence Maxence Mendez, Laboratoire Image Ville Environnement - LIVE, UMR 7362 CNRS, Université de Strasbourg, Strasbourg, France. Email: [email protected] for more papers by this authorN. Blond, N. Blond Laboratoire Image Ville Environnement - LIVE UMR 7362 CNRS, Université de Strasbourg, Strasbourg, FranceSearch for more papers by this authorD. Amedro, D. Amedro CNRS, UMR 8522, PC2A - Physicochimie des Processus de Combustion et de l'Atmosphère, Université Lille, Lille, FranceSearch for more papers by this authorD. A. Hauglustaine, D. A. Hauglustaine Laboratoire Image Ville Environnement - LIVE UMR 7362 CNRS, Université de Strasbourg, Strasbourg, France UMR 8212, Laboratoire des Sciences du Climat et de l'Environnement – LSCE, Gif sur, Yvette, FranceSearch for more papers by this authorP. Blondeau, P. Blondeau Laboratoire des Sciences de l'Ingénieur pour l'Environnement - LaSIE, UMR 7356 CNRS, Université de La Rochelle, La Rochelle, FranceSearch for more papers by this authorC. Afif, C. Afif Unité Environnement, Génomique Fonctionnelle et Études Mathématiques, Emissions, Measurements, and Modeling of the Atmosphere (EMMA) Laboratory, Centre d'Analyses et de Recherche, Faculty of Sciences, Saint Joseph University, Beirut, Lebanon Laboratoire Interuniversitaire des Systèmes Atmosphériques – LISA UMR 7583 CNRS, Université Paris-Est Créteil (UPEC), Université Paris Diderot (UPD), Créteil, FranceSearch for more papers by this authorC. Fittschen, C. Fittschen CNRS, UMR 8522, PC2A - Physicochimie des Processus de Combustion et de l'Atmosphère, Université Lille, Lille, FranceSearch for more papers by this authorC. Schoemaecker, C. Schoemaecker CNRS, UMR 8522, PC2A - Physicochimie des Processus de Combustion et de l'Atmosphère, Université Lille, Lille, FranceSearch for more papers by this author M. Mendez, Corresponding Author M. Mendez [email protected] Laboratoire Image Ville Environnement - LIVE UMR 7362 CNRS, Université de Strasbourg, Strasbourg, France Laboratoire des Sciences de l'Ingénieur pour l'Environnement - LaSIE, UMR 7356 CNRS, Université de La Rochelle, La Rochelle, France Correspondence Maxence Mendez, Laboratoire Image Ville Environnement - LIVE, UMR 7362 CNRS, Université de Strasbourg, Strasbourg, France. Email: [email protected] for more papers by this authorN. Blond, N. Blond Laboratoire Image Ville Environnement - LIVE UMR 7362 CNRS, Université de Strasbourg, Strasbourg, FranceSearch for more papers by this authorD. Amedro, D. Amedro CNRS, UMR 8522, PC2A - Physicochimie des Processus de Combustion et de l'Atmosphère, Université Lille, Lille, FranceSearch for more papers by this authorD. A. Hauglustaine, D. A. Hauglustaine Laboratoire Image Ville Environnement - LIVE UMR 7362 CNRS, Université de Strasbourg, Strasbourg, France UMR 8212, Laboratoire des Sciences du Climat et de l'Environnement – LSCE, Gif sur, Yvette, FranceSearch for more papers by this authorP. Blondeau, P. Blondeau Laboratoire des Sciences de l'Ingénieur pour l'Environnement - LaSIE, UMR 7356 CNRS, Université de La Rochelle, La Rochelle, FranceSearch for more papers by this authorC. Afif, C. Afif Unité Environnement, Génomique Fonctionnelle et Études Mathématiques, Emissions, Measurements, and Modeling of the Atmosphere (EMMA) Laboratory, Centre d'Analyses et de Recherche, Faculty of Sciences, Saint Joseph University, Beirut, Lebanon Laboratoire Interuniversitaire des Systèmes Atmosphériques – LISA UMR 7583 CNRS, Université Paris-Est Créteil (UPEC), Université Paris Diderot (UPD), Créteil, FranceSearch for more papers by this authorC. Fittschen, C. Fittschen CNRS, UMR 8522, PC2A - Physicochimie des Processus de Combustion et de l'Atmosphère, Université Lille, Lille, FranceSearch for more papers by this authorC. Schoemaecker, C. Schoemaecker CNRS, UMR 8522, PC2A - Physicochimie des Processus de Combustion et de l'Atmosphère, Université Lille, Lille, FranceSearch for more papers by this author First published: 13 July 2016 https://doi.org/10.1111/ina.12320Citations: 14Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract The photolysis of HONO has been found to be the oxidation driver through OH formation in the indoor air measurement campaign SURFin, an extensive campaign carried out in July 2012 in a classroom in Marseille. In this study, the INCA-Indoor model is used to evaluate different HONO formation mechanisms that have been used previously in indoor air quality models. In order to avoid biases in the results due to the uncertainty in rate constants, those parameters were adjusted to fit one representative day of the SURFin campaign. Then, the mechanisms have been tested with the optimized parameters against other experiments carried out during the SURFin campaign. Based on the observations and these findings, we propose a new mechanism incorporating sorption of NO2 onto surfaces with possible saturation of these surfaces. This mechanism is able to better reproduce the experimental profiles over a large range of conditions. Citing Literature Volume27, Issue2March 2017Pages 443-451 RelatedInformation