ChemInform Abstract: Optically Active Allylsilanes. Part 14. Stereochemistry and Mechanism of Asymmetric Allylation of Aldehydes with Optically Active Allylsiliconates.

Name: Work Video:
Duration: 3 min 30 s
Description: Abstract The triethoxyallylsilane (I) reacts with benzaldehyde (II) after activation to form mainly the erythro‐adduct (IIIa), together with minor parts of the threo‐isomer (IIIb).
Tamio Hayashi; Yasuko Matsumoto; Takao Kiyoi; Yoshihiko Ito; Shinya Kohra; Yoshinori Tominaga; Akíra Hosomi
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