ChemInform Abstract: Chemistry and Stereochemistry of Iridoids. Part 9. EPC Synthesis of (1R,2R,2′′Z)‐(‐)‐Methyl Jasmonate from Catalpol ‐ Crystal and Molecular Structure of Methyl Dehydrojasmonate Semicarbazone.

Name: Work Video:
Duration: 3 min 30 s
Description: Abstract The title compound (‐)‐(VIII) is synthesized starting from the compound (I) which in turn is available from the iridoid catalpol.
Klaus Weinges; H. GETHOEFFER; U. HUBER‐PATZ; Hans Rodewald; Hermann Irngartinger
{'id': 'https://openalex.org/W2402459354', 'doi': 'https://doi.org/10.1002/chin.198730272', 'title': 'ChemInform Abstract: Chemistry and Stereochemistry of Iridoids. Part 9. EPC Synthesis of (1R,2R,2′′Z)‐(‐)‐Methyl Jasmonate from Catalpol ‐ Crystal and Molecular Structure of Methyl Dehydrojasmonate Semicarbazone.', 'display_name': 'ChemInform Abstract: Chemistry and Stereochemistry of Iridoids. Part 9. EPC Synthesis of (1R,2R,2′′Z)‐(‐)‐Methyl Jasmonate from Catalpol ‐ Crystal and Molecular Structure of Methyl Dehydrojasmonate Semicarbazone.', 'publication_year': 1987, 'publication_date': '1987-07-28', 'ids': {'openalex': 'https://openalex.org/W2402459354', 'doi': 'https://doi.org/10.1002/chin.198730272', 'mag': '2402459354'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/chin.198730272', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S41354064', 'display_name': 'ChemInform', 'issn_l': '0931-7597', 'issn': ['0931-7597', '1522-2667', '1431-5890'], 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5053699130', 'display_name': 'Klaus Weinges', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I85384741', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/04rcqnp59', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I85384741']}, {'id': 'https://openalex.org/I223822909', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/038t36y30', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I223822909']}], 'countries': ['DE', 'US'], 'is_corresponding': False, 'raw_author_name': 'K. WEINGES', 'raw_affiliation_strings': ['Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg'], 'affiliations': [{'raw_affiliation_string': 'Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg', 'institution_ids': ['https://openalex.org/I85384741', 'https://openalex.org/I223822909']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5097067875', 'display_name': 'H. GETHOEFFER', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I85384741', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/04rcqnp59', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I85384741']}, {'id': 'https://openalex.org/I223822909', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/038t36y30', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I223822909']}], 'countries': ['DE', 'US'], 'is_corresponding': False, 'raw_author_name': 'H. + GETHOEFFER', 'raw_affiliation_strings': ['Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg'], 'affiliations': [{'raw_affiliation_string': 'Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg', 'institution_ids': ['https://openalex.org/I85384741', 'https://openalex.org/I223822909']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5073453456', 'display_name': 'U. HUBER‐PATZ', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I85384741', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/04rcqnp59', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I85384741']}, {'id': 'https://openalex.org/I223822909', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/038t36y30', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I223822909']}], 'countries': ['DE', 'US'], 'is_corresponding': False, 'raw_author_name': 'U. HUBER‐PATZ', 'raw_affiliation_strings': ['Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg'], 'affiliations': [{'raw_affiliation_string': 'Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg', 'institution_ids': ['https://openalex.org/I85384741', 'https://openalex.org/I223822909']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5084584882', 'display_name': 'Hans Rodewald', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I85384741', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/04rcqnp59', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I85384741']}, {'id': 'https://openalex.org/I223822909', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/038t36y30', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I223822909']}], 'countries': ['DE', 'US'], 'is_corresponding': False, 'raw_author_name': 'H. RODEWALD', 'raw_affiliation_strings': ['Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg'], 'affiliations': [{'raw_affiliation_string': 'Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg', 'institution_ids': ['https://openalex.org/I85384741', 'https://openalex.org/I223822909']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5089790583', 'display_name': 'Hermann Irngartinger', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I85384741', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/04rcqnp59', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I85384741']}, {'id': 'https://openalex.org/I223822909', 'display_name': 'Heidelberg University', 'ror': 'https://ror.org/038t36y30', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I223822909']}], 'countries': ['DE', 'US'], 'is_corresponding': False, 'raw_author_name': 'H. IRNGARTINGER', 'raw_affiliation_strings': ['Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg'], 'affiliations': [{'raw_affiliation_string': 'Org.-Chem. Inst., Univ. Heidelberg, D-6900 Heidelberg', 'institution_ids': ['https://openalex.org/I85384741', 'https://openalex.org/I223822909']}]}], 'institution_assertions': [], 'countries_distinct_count': 2, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 0.0, 'has_fulltext': False, 'cited_by_count': 0, 'citation_normalized_percentile': {'value': 0.0, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 0, 'max': 53}, 'biblio': {'volume': '18', 'issue': '30', 'first_page': None, 'last_page': None}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11613', 'display_name': 'Phytochemistry and Biological Activities', 'score': 0.9909, 'subfield': {'id': 'https://openalex.org/subfields/1110', 'display_name': 'Plant Science'}, 'field': {'id': 'https://openalex.org/fields/11', 'display_name': 'Agricultural and Biological Sciences'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11613', 'display_name': 'Phytochemistry and Biological Activities', 'score': 0.9909, 'subfield': {'id': 'https://openalex.org/subfields/1110', 'display_name': 'Plant Science'}, 'field': {'id': 'https://openalex.org/fields/11', 'display_name': 'Agricultural and Biological Sciences'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, {'id': 'https://openalex.org/T12748', 'display_name': 'Molecular spectroscopy and chirality', 'score': 0.9723, 'subfield': {'id': 'https://openalex.org/subfields/1607', 'display_name': 'Spectroscopy'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/catalpol', 'display_name': 'Catalpol', 'score': 0.9853261}, {'id': 'https://openalex.org/keywords/methyl-jasmonate', 'display_name': 'Methyl jasmonate', 'score': 0.7051652}, {'id': 'https://openalex.org/keywords/semicarbazone', 'display_name': 'Semicarbazone', 'score': 0.6194427}], 'concepts': [{'id': 'https://openalex.org/C2776160005', 'wikidata': 'https://www.wikidata.org/wiki/Q1050267', 'display_name': 'Catalpol', 'level': 3, 'score': 0.9853261}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.9844953}, {'id': 'https://openalex.org/C2777942875', 'wikidata': 'https://www.wikidata.org/wiki/Q26840883', 'display_name': 'Methyl jasmonate', 'level': 3, 'score': 0.7051652}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.67477274}, {'id': 'https://openalex.org/C83591994', 'wikidata': 'https://www.wikidata.org/wiki/Q416105', 'display_name': 'Semicarbazone', 'level': 2, 'score': 0.6194427}, {'id': 'https://openalex.org/C2778413156', 'wikidata': 'https://www.wikidata.org/wiki/Q416840', 'display_name': 'Iridoid', 'level': 3, 'score': 0.5813131}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.3427331}, {'id': 'https://openalex.org/C55493867', 'wikidata': 'https://www.wikidata.org/wiki/Q7094', 'display_name': 'Biochemistry', 'level': 1, 'score': 0.15320334}, {'id': 'https://openalex.org/C194671627', 'wikidata': 'https://www.wikidata.org/wiki/Q192639', 'display_name': 'Glycoside', 'level': 2, 'score': 0.14895716}, {'id': 'https://openalex.org/C104317684', 'wikidata': 'https://www.wikidata.org/wiki/Q7187', 'display_name': 'Gene', 'level': 2, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/chin.198730272', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S41354064', 'display_name': 'ChemInform', 'issn_l': '0931-7597', 'issn': ['0931-7597', '1522-2667', '1431-5890'], 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 1, 'referenced_works': ['https://openalex.org/W2044301975'], 'related_works': ['https://openalex.org/W3146758606', 'https://openalex.org/W2374463708', 'https://openalex.org/W2348249331', 'https://openalex.org/W2326907158', 'https://openalex.org/W2314831057', 'https://openalex.org/W2081403490', 'https://openalex.org/W2060589480', 'https://openalex.org/W2003028796', 'https://openalex.org/W1987402832', 'https://openalex.org/W1969871178'], 'abstract_inverted_index': {'Abstract': [0], 'The': [1], 'title': [2], 'compound': [3, 10], '(‐)‐(VIII)': [4], 'is': [5, 15], 'synthesized': [6], 'starting': [7], 'from': [8, 17], 'the': [9, 18], '(I)': [11], 'which': [12], 'in': [13], 'turn': [14], 'available': [16], 'iridoid': [19], 'catalpol.': [20]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2402459354', 'counts_by_year': [], 'updated_date': '2024-12-11T07:40:36.322005', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
