Title: Dissolution Properties of M(NTO)_n·mH_2O in Water
Abstract: With the help of the amount of the complex(a),the concentration of the solution(b),the heat effect of dissolution process(Q) and the molar enthalpy of dissolution in water(ΔdissH) of M(NTO)n·mH2O(M=Ba,n=1,m=3;M=Li,n=1,m=2;M=Ca,n=2,m=4;M=Na,n=m=1;M=Co,Mg,n=2,m=8;M=Ce,Pr,Gd,n=3,m=7;M=Tb,Dy,n=3,m=5;M=Y,Yb,n=3,m=6;NTO=3-nitro-1,2,4-triazol-5-one) obtained by a Calvet microcalorimeter,five empirical formulae describing the differential enthalpy of dissolution(ΔdifHθm),standard molar enthalpy of dissolution [ΔdissHθm(b=0)],relative apparent molar enthalpy(ΔdissHapparent),relative partial molar enthalpy(ΔdissHpartial) and enthalpies of dilution(ΔdilH1,2) in water of these metal complexes of NTO were obtained.
Publication Year: 2011
Publication Date: 2011-01-01
Language: en
Type: article
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