Title: ChemInform Abstract: New Reagents. Part 38. Addition of (α‐Lithioalkyl)diphenylarsane Oxides to Benzaldehyde and Acetophenone with Extreme Diastereoselectivity.
Abstract: Abstract In contrast to α‐lithiated alkyldiphenylarsine oxides (II) react extremely diastereoselectively with benzaldehyde or acetophenone to form the alcohols erythro‐(IIIa) and ‐(IV), whereasby reaction with aliphatic aldehydes a mixture of two diastereoisomeric alcohols(IIIb) and (IIIc) is obtained.
Publication Year: 1986
Publication Date: 1986-11-11
Language: en
Type: article
Indexed In: ['crossref']
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